2641 results about "Nanomaterials" patented technology

The invention relates to the technical field of nano materials, and particularly discloses a preparation method of surface modified nano calcium carbonate for a battery diaphragm coating. According to the method, the technical paths of microemulsion confinement crystal form regulation and control, gradient surface modification and boehmite compounding and porosity regulation and control are fused, and the functional nano calcium carbonate adaptive to the battery diaphragm coating is prepared. According to the technical scheme, limestone is used as a raw material, after calcination and digestion, the particle size of nano calcium carbonate is controlled through microemulsion carbonization (a cyclohexane-span 80-n-butyl alcohol system); a silane coupling agent KH560-KH570 is adopted for gradient modification to introduce an electrophilic functional group, boehmite is compounded to form a composite coating, and the porosity is regulated and controlled by adjusting the solid content in coating slurry and the coating speed. The method is stable in process and high in compatibility, and meets the requirements of diaphragm coatings of lithium ion batteries and solid-state batteries.

The invention relates to the field of enhanced intrinsic safety in a gas-liquid phase mixing process, and discloses a gas-liquid mixing device and a gas-liquid mixing vaporization method. The device comprises a shell, a Venturi gas-phase turbulent mixing section, a liquid-phase atomizing mixing section and a static mixing section are sequentially arranged in the shell in the flowing direction of material flow, the Venturi gas-phase turbulent mixing section comprises a reducing structure and an expanding structure, a liquid inlet component is arranged at the position, close to the reducing structure, of the expanding structure, and the static mixing section is connected with the liquid inlet component. The liquid phase atomization mixing section is provided with a membrane tube base body, the membrane tube base body is provided with a plurality of inner holes in the axial direction, the surfaces of the inner holes are coated with nanometer materials, and the static mixing section is provided with filler. According to the device, the liquid-phase oxidizing agent and the gas-phase oxidizing agent are subjected to multi-stage mixing vaporization, the atomization degree of the liquid phase is increased, the uniformity degree of the obtained mixed gas phase is improved, meanwhile, the device can be quenched after burning explosion by coupling a porous membrane pipe and filler, and the burning explosion risk in the mixing vaporization process is reduced.

The invention relates to the technical field of analysis and detection, in particular to a fluorescent switch sensor based on quantum dot-nano porphyrin and application. The specific technical scheme is as follows: the fluorescent switch sensor is constructed by utilizing cadmium telluride quantum dots modified by mercaptosuccinic acid and a 5, 10, 15, 20-tetra (4-nitrophenyl) porphyrin nano material modified by a cationic surfactant hexadecyl trimethyl ammonium bromide. And the method has a good enrichment effect on zearalenone. The sensor has high sensitivity, high selectivity and anti-interference performance, can accurately analyze trace zearalenone in actual grain samples (corn, rice, soybean and the like), and has the advantages of simplicity in operation, low detection limit, high sensitivity, low cost and the like.

The invention relates to the technical field of agricultural application of nano materials, and discloses a preparation method and application of a photosynthetic accelerant containing carbon quantum dots. Urea and citric acid are adopted as raw materials, and the nitrogen-carbon molar ratio and hydrothermal reaction parameters are optimized, so that efficient doping of nitrogen and accurate regulation and control of the particle size are achieved, and the photosynthetic accelerant containing the carbon quantum dots is obtained. The nitrogen-doped carbon quantum dot photosynthetic promoter with excellent upconversion performance is successfully synthesized, the promoter has good water solubility and biocompatibility, the photosynthetic efficiency of plants can be greatly improved within the concentration range of 0-100 mg / L, a safe application window is defined, and by establishing foliage spraying and water planting dual-mode application specifications, the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened, and the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened. The problems that current crops are insufficient in solar spectrum utilization and low in light energy conversion efficiency are solved in a targeted manner by utilizing an ultraviolet light-photosynthetically active radiation conversion function mediated by the carbon quantum dots and combining the targeted enrichment permeation characteristic of the carbon quantum dots in chloroplast.

The invention relates to the technical field of analysis and detection, in particular to a surface enhanced Raman spectroscopy (SERS)-based nano material detection method, which is characterized in that a heterojunction composite structure consisting of noble metal nano stars and semiconductor oxide nano particles is used as an SERS active substrate; and a specific recognition molecule carrying a Raman reporter molecule is used as a detection probe. During detection, the recognition molecules are firstly combined with the to-be-detected nano material, and then the compound is adsorbed on the surface of the substrate. The tip structure of the noble metal nanostar and a heterojunction interface jointly generate a synergistic effect of electromagnetic enhancement and chemical enhancement, and a reporter molecule signal is doubly amplified, so that high-sensitivity and high-selectivity detection on a to-be-detected nano material is realized. The method solves the problems of weak signal and poor selectivity of the traditional method, and is suitable for rapid and quantitative analysis of trace nano materials in the environment.

The invention discloses a surface oxidation monatomic nano-alloy catalyst as well as a preparation method and application thereof, and belongs to the technical field of advanced nano-energy materials and electro-catalysis. A surface-oxidized monatomic nano-alloy catalyst comprises a hydroxylated carbon nanotube carrier and bimetallic nano-alloy particles loaded on the hydroxylated carbon nanotube carrier, in the bimetallic nano-alloy particles, non-noble metal elements are dispersed in noble metal nano-particles in a monatomic form, the size of the bimetallic nano-alloy particles is 3-4 nm, and the surface-oxidized monatomic nano-alloy catalyst is prepared from a surface-oxidized monatomic nano-alloy catalyst. An oxide layer with the thickness of 0.3-0.6 nm is arranged on the surface of the bimetallic nano-alloy particle; the loading amount of the noble metal is 5-15wt%. Ruthenium and other non-noble metal elements are alloyed and anchored on the carbon material substrate, the conductivity of the catalyst can be greatly improved, the size of alloy particles is accurately controlled within the range of 3-4 nm, active sites can be exposed to the maximum extent, and structural stability is considered.

The invention belongs to the technical field of electrocatalysts, and discloses a method for preparing a heterogeneous monomolecular electrocatalyst by using water-soluble metalloporphyrin / phthalocyanine and a carbon carrier and application of the heterogeneous monomolecular electrocatalyst. The method comprises the following steps: 1) dissolving water-soluble metalloporphyrin / phthalocyanine in water to obtain a water-soluble metalloporphyrin / phthalocyanine solution; 2) soaking the electrode coated with the nanoscale carbon material in a water-soluble metalloporphyrin / phthalocyanine solution; or uniformly mixing the carbon nanomaterial organic solvent dispersion liquid with a water-soluble metalloporphyrin / phthalocyanine solution to obtain a composite catalyst; and dispersing the composite catalyst in an organic solvent, uniformly mixing with a binder solution, coating an electrode with the mixture, and drying to obtain the heterogeneous monomolecular electrocatalyst. The method disclosed by the invention is simple, catalyst molecules can be completely dispersed and adsorbed on a nanoscale carbon material in a single molecule form, and active sites are improved; the prepared monomolecular electrocatalyst is used for electrocatalysis of carbon dioxide reduction reaction, and high product selectivity and stability of carbon dioxide reduction can be realized.

The invention belongs to the field of battery materials, and particularly relates to a high-adhesion battery diaphragm binder, slurry, a diaphragm and a preparation method of the high-adhesion battery diaphragm binder, and the high-adhesion battery diaphragm binder based on an acrylate copolymer is prepared through a specific reaction. And then, mixing the binder with two inorganic nano materials, namely a lithium-doped aluminum borosilicate nanowire and a sulfo-functionalized lithium zirconate titanate nanosheet, boehmite and / or aluminum oxide and the like, so as to prepare the high-adhesion diaphragm coating slurry. Wherein the nanowires provide mechanical enhancement and chemical crosslinking points, and the nanosheets improve the interface adhesion and the ionic conductivity. And finally, coating the slurry on the surface of a polypropylene diaphragm, and performing multi-stage drying and heat treatment to obtain the composite diaphragm. The diaphragm has extremely high coating bonding strength, excellent electrolyte wettability and good thermal dimensional stability and ionic conductivity, and is particularly suitable for high-energy-density lithium ion batteries and sodium ion batteries.

This invention relates to the field of cement materials technology, specifically to an anti-carbonation early-strength agent for hypersulfate cement and its preparation method. The anti-carbonation early-strength agent comprises: a modified core formed by a water-soluble silicate and a water-storing superabsorbent polymer; an aluminum- and calcium-containing layered bimetallic hydroxide intermediate layer coating the outer surface of the core; and a silicon and / or aluminum active nanomaterial shell layer coating the outer surface of the intermediate layer, thereby forming a Si / Al@Ca / Al-LDHs@modified core dual-core-shell structure. The anti-carbonation early-strength agent of this invention effectively solves the problems of long setting and hardening time, low early strength, and easy carbonation inherent in traditional hypersulfate cement.

The invention relates to the field of preparation of nano materials, in particular to a preparation method of a metal-oxide cluster electro-catalytic material based on an ammonia-mediated electrostatic adsorption principle, and aims to solve the problem that a metal-oxide cluster heterogeneous interface is difficult to accurately construct by an existing method. The preparation method comprises the following steps: dispersing a carbon carrier, a soluble inorganic compound containing platinum, ruthenium and rhodium, a soluble metal complex anion salt and dopamine hydrochloride in a water-alcohol mixed solution, adding ammonia water, and preparing a metal-oxide heterogeneous cluster precursor through an ammonia-mediated electrostatic adsorption effect; and pyrolyzing the precursor in a reducing atmosphere to prepare the metal-oxide cluster electro-catalytic material. The prepared electro-catalytic material has a definite heterogeneous cluster interface and has excellent performance in alkaline hydroxide reaction. The method is simple and convenient to operate, low in cost and low in energy consumption, can be popularized to various metal-oxide cluster electro-catalytic materials, and has application potential.

The invention discloses a three-dimensional porous carbon encapsulated V2O5 carbon fiber electrode constructed by in-situ growth and a preparation method and application thereof, belongs to the technical field of aluminum ion battery positive electrode materials, and aims to solve the problems that the intercalation and deintercalation dynamics of AlCl4 in a polyacrylonitrile (Pan)-based carbon fiber is blocked due to disordered graphite structure, and the performance of the Pan-based carbon fiber is influenced. And the material cannot be used as an effective electrode material to be applied to an aluminum ion battery system. According to the preparation method, an in-situ growth technology is adopted, a three-dimensional porous carbon substrate is grown on the surface of carbon fiber, then an orthorhombic system vanadium pentoxide (V2O5) nano material which has high theoretical specific capacity and can realize large-current charging and discharging is packaged in the three-dimensional porous carbon substrate, and the V2O5-based carbon fiber electrode is prepared. According to the electrode, the electrostatic interaction between Al < 3 + > ions and crystal lattices is effectively relieved, the structural advantages of the carbon fibers and the energy storage performance of V2O5 are fully combined, the energy storage effect of the aluminum ion battery is remarkably improved, and a new effective scheme is provided for development of aluminum ion battery electrode materials.

The application discloses a medical natural antibacterial and antiviral mildew-proof wet non-woven fabric and a preparation method and application thereof, and belongs to the technical field of medical polymer materials and textiles. The non-woven fabric is prepared from the following raw materials: polyethylene terephthalate long fibers, polyethylene terephthalate short fibers, vinylon fibers and natural antibacterial and antiviral ultraviolet slow-release glue solution. The non-woven fabric is endowed with natural and non-toxic antibacterial and antiviral effects by using the extract of Chinese herbal medicine effective components. Meanwhile, the mechanical properties and the antibacterial and antiviral capacity of the non-woven fabric can be effectively improved by adding nano materials with far infrared function after surface modification to prepare high-efficiency natural antibacterial and antiviral ultraviolet slow-release microcapsule glue solution. The method improves the added value and application field of the wet non-woven fabric and is convenient for large-scale processing and production. The prepared wet non-woven fabric has excellent performance indexes, good air permeability and an antibacterial and antiviral efficiency of 99.99%.

The invention provides a method and a system for strengthening sludge treatment and nanometer material co-production through synergy of electrochemistry and ozone catalysis, and application of the method and the system, and relates to the technical field of environmental governance and resource recovery, in particular to the method for strengthening sludge treatment and nanometer material co-production through synergy of electrochemistry and ozone catalysis. Comprising the following steps: (a) performing electrochemical catalytic oxidation treatment on sludge slurry; (b) pyrolyzing the sludge treated in the step (a) to obtain volatile components; and (c) converting the volatile component into nano silicon dioxide through a vapor deposition reaction. According to the electrochemical-ozone catalysis synergistic enhanced sludge treatment and nano material co-production method provided by the invention, electrochemical catalytic oxidation, pyrolysis and vapor deposition processes are organically integrated, so that efficient removal of pollutants in sludge and synchronous conversion of high-value nano materials are realized.

The invention discloses a nickel-cobalt-selenium (Co1-xNixSe2) nano material for electrocatalytic oxidation of ethylene glycol as well as a preparation method and application of the nickel-cobalt-selenium (Co1-xNixSe2) nano material. The material is prepared by a hydrothermal method which comprises the following steps: (1) pouring 20mL of deionized water containing 475.9 mg of CoCl2. 6H2O into a 1mol / L NaOH solution containing 0.32 g of selenium powder to prepare a precursor solution; (2) placing in a stainless steel autoclave with a polytetrafluoroethylene lining, carrying out hydrothermal reaction at 180 DEG C for 18 hours, washing with absolute ethyl alcohol and deionized water, and carrying out vacuum drying at 60 DEG C to obtain a CoSe2 material; and (3) the molar feeding ratio of CoCl2. 6H2O to NiCl2. 6H2O is adjusted, so that the nickel / cobalt ratio x is 0.25, 0.50 or 0.75, and materials with different components, namely Co < 0.75 > Ni < 0.25 > Se < 2 >, Co < 0.50 > Ni < 0.50 > Se < 2 > and Co < 0.25 > Ni < 0.75 > Se < 2 >, are prepared. The series of materials are applied to ethylene glycol oxidation under the alkaline condition, the catalytic performance of Co < 0.50 > Ni < 0.50 > Se < 2 > is optimal, the current density reaches 111 mA cm <-2 > under the electric potential of 1.6 V vs.RHE, the total Faraday efficiency reaches up to 91.4%, and the application prospect in the field of PET plastic recovery is wide.

The invention belongs to the technical field of functional nano materials, and particularly relates to a preparation method of a detachable engine type braking nano motor, a nano drug carrier is jointly composed of HMSN and CAT modified PNA, tetraethyl orthosilicate serves as a silicon source, and solid silicon dioxide balls are synthesized; on the basis, tetraethyl orthosilicate is used as a silicon source, CTAB is used as a pore-forming agent to synthesize mesoporous silica coated solid silica spheres; etching the core silicon dioxide ball through sodium carbonate to obtain a hollow mesoporous silicon dioxide ball; then, amino modification is carried out on the CAT modified PNA2 through 3-aminopropyltrimethoxysilane, PNA1 is connected with HMSN through an amido bond, and a double-chain structure is formed by the CAT modified PNA2 and PNA1 through complementary base pairing. According to the nano motor provided by the invention, the engine CAT of the nano motor can be detached by adding the unwinding chain PNA3, so that in-vivo deceleration and braking are realized.

The invention relates to the technical field of biomedical materials, in particular to an alendronate-modified ZIF-8 encapsulated TPP-carbon dot bone targeting nano-material and a preparation method and application thereof.The alendronate-modified ZIF-8 serves as a carrier, TPP-modified carbon dots are encapsulated in the carrier, citric acid, urea and cerium salt serve as raw materials of the TPP-modified carbon dots, and the alendronate-modified ZIF-8 encapsulated TPP-carbon dot bone targeting nano-material is prepared through a one-step method. After cerium-doped carbon quantum dots are synthesized through a hydrothermal method, TPP is grafted through an amide method, alendronate endows the material with a bone targeting function, and TPP modified carbon dots endow the material with antioxidant and mitochondrial targeting functions. According to the invention, the bone targeting property is excellent, and bone focuses are efficiently enriched; the anti-oxidation and anti-inflammatory capacities are high, and the infected microenvironment can be improved; zIF-8 packaging is stable, and functional components can be controllably released; multiple components cooperate to promote bone repair, accumulation of non-target organs is little, and the composition is safe, reliable and suitable for treatment of various bone-related diseases.

The invention discloses iron oxide nanoparticles capable of responding to particle size change in a tumor microenvironment and a preparation method of the iron oxide nanoparticles, and belongs to the technical field of biomedical nano materials. The nano-particle comprises an iron oxide nano-crystal core with the particle size of 3-5nm and a tumor microenvironment response layer coating the surface of the iron oxide nano-crystal core. The response layer contains groups, such as disulfide bonds, enzyme digestion peptide fragments and the like, which can respond to acidic pH, high-concentration reduced glutathione or matrix metalloproteinase and other tumor characteristic stimuli to generate structural changes. In a tumor microenvironment, the hydration particle size of the nanoparticles can be directionally and controllably converted from 3-20 nm to 20-100 nm (or reversely). The preparation method mainly comprises two steps of preparing the core by a thermal decomposition method and modifying the surface response layer. The technical problems of insufficient tumor targeted enrichment capacity, limited imaging contrast and difficulty in balancing permeation and retention caused by fixed particle size of the existing iron oxide nanoparticles are solved, and the accuracy and efficiency of tumor diagnosis and treatment can be remarkably improved.

The invention relates to the technical field of building materials, in particular to a building sound insulation material based on nano material modification. Comprising the following raw materials in parts by weight: 30-50 parts of matrix resin, 8-15 parts of composite filler, 5-10 parts of a composite foaming agent, 4-8 parts of a curing agent, 3-8 parts of a fiber reinforcement, 3-6 parts of an epoxy toughening agent, 3-6 parts of a coupling agent, 2-5 parts of a plasticizer, 1-4 parts of a flame retardant, 0.5-2 parts of an antioxidant and 0.5-2 parts of a curing accelerator. According to the invention, by solving the problem of agglomeration of nanoparticles, uniform dispersion of carbon nanotubes and nano-silica is realized, the uniformly dispersed carbon nanotubes construct a continuous sound energy conduction dissipation channel by virtue of a high length-diameter ratio, incident sound energy is converted into heat energy through multiple reflections and friction, and the nano-silica cooperates with the composite foaming agent to form a uniform porous structure, so that the sound energy can be converted into heat energy. Sound energy transmission is further blocked, and the sound insulation performance is remarkably improved.

This invention discloses a copper-based ternary chalcogenide semiconductor material, its preparation method, and its applications. The material is prepared by mixing CuSn(OH)6 nanomaterials, thioacetamide, ethylenediaminetetraacetic acid, and water and carrying out a hydrothermal reaction to obtain Cu3SnS4 nanomaterials. This semiconductor material exhibits excellent photoelectrochemical properties. Photoelectrochemical sensors constructed based on this material demonstrate high detection accuracy, fast response speed, low detection limit, and strong stability, enabling rapid and accurate real-time detection of microplastic content. The preparation method is simple, low-cost, and suitable for industrial production.

Lipid nanoparticle compositions for the delivery of nucleic acids are provided.SOLUTION: In various embodiments, the lipid nanoparticle comprises an ionizable lipid of Formula (I). Also provided are methods of using such lipid nanoparticle compositions to achieve targeted delivery of therapeutic cargo without the need for a targeting ligand.SELECTED DRAWING: None

The invention discloses a carbon-coated zinc oxide / carbon nitride heterojunction photocatalyst as well as a preparation method and application thereof. The carbon-coated zinc oxide / carbon nitride heterojunction photocatalyst is formed by crosslinking a carbon-coated zinc oxide nanosheet and a carbon nitride nanosheet through a carbon layer, and a heterojunction is formed between the carbon-coated zinc oxide nanosheet and the carbon nitride nanosheet. The preparation method comprises the following steps: mixing and grinding a carbon-coated zinc oxide nano-material and a carbon nitride nano-sheet, and calcining in a protective atmosphere. The carbon-coated zinc oxide / carbon nitride heterojunction photocatalyst can effectively promote photon-generated carrier separation, reduce the recombination rate of electron-hole pairs, and significantly improve the efficiency of photocatalytic production of hydrogen peroxide in an air atmosphere. Meanwhile, hydrogen peroxide generated in situ can react with bicarbonate in the system to generate peroxybicarbonate with high oxidation activity, and active oxygen species such as hydroxyl radicals are generated through activation in the photocatalytic process, so that the degradation capacity on the organic pollutants is further enhanced, and efficient degradation of the organic pollutants is realized.

The invention belongs to the field of antibacterial materials, and discloses a preparation method of a composite material modified carbon-nitrogen material as well as a product and application of the composite material modified carbon-nitrogen material. In order to achieve the long-acting and efficient antibacterial performance of the nano material, g-C3N4 powder is taken and placed in methyl alcohol, zinc nitrate is added, stirring is conducted till the zinc nitrate is dissolved, then the mixture is mixed with a methanol solution of 2-methylimidazole, after the mixture is subjected to heat treatment, the mixture is mixed with a polyhexamethylene biguanide hydrochloride aqueous solution, and the nano material is obtained. A compact inert material protection layer can be grown on the surface of the material by adopting an atomic layer deposition technology. The method provided by the invention is simple to operate and can be used for batch production, the obtained composite material integrates the advantages of an organic antibacterial agent and an inorganic antibacterial agent and has long-acting and efficient antibacterial performance, and the antibacterial material obtained by the method can be applied to various fields, such as antibacterial performance modification of antibacterial plastics and textiles.

Provided are a metal-organic framework nanomaterial, a preparation method therefor, and a use thereof, belonging to the technical field of bionanomaterials, and resolving the technical problem of inhibiting atherosclerosis using biomimetic metal-organic framework nanoenzymes. The solution is: the components of the of the metal-organic framework nanomaterial and the ratio thereof are: metal ions Ce4+ and a ligand fumaric acid in a molar ratio of 1:5. The preparation method therefor is: measuring an FA regulator and water to prepare a mixed solution, then adding fumaric acid and cerium ammonium nitrate dropwise into the mixed solution, stirring at room temperature, centrifuging, repeatedly washing alternately with water and ethanol, and finally drying overnight in a vacuum oven. A simple, efficient and convenient method for synthesizing the metal-organic framework nanomaterial is provided. The synthesized metal-organic framework nanomaterial has excellent CEH-like enzyme activity and intrinsic antioxidant activity, and can be used to increase lipid efflux and reduce lipid uptake, and decrease ox-LDL-induced foam cell formation, thereby alleviating atherosclerosis.

The invention provides a high-temperature-resistant lipopeptide reinforced foam flooding system and a screening method and application, and relates to the technical field of microbial oil recovery, the high-temperature-resistant lipopeptide reinforced foam flooding system comprises the following steps: S1, screening applied oil reservoirs; s2, based on the oil reservoir temperature and the crude oil viscosity selected in S1, screening a high-temperature-resistant lipopeptide reinforced foam flooding system; the high-temperature-resistant lipopeptide reinforced foam oil displacement system comprises a foaming agent, a foam stabilizer, gas and water, the foaming agent comprises one or more of surfactin (C12-18), scabrin (C14-18), iturin (C14-17), deocytin, serratia marcescens and mucin fermentation liquor, and the foaming agent comprises one or more of lipopeptide, a foaming agent and a foaming agent. The foam stabilizer comprises one or more of biosynthetic nano-silver, nano-iron, nano-copper, nano-zinc, nano-zirconium and nano-nickel. The method has the beneficial effects that the oil reservoir application range is wide, the pertinence is high, the field test effect is good, and a high-temperature-resistant lipopeptide enhanced foam oil displacement system is specifically constructed according to the temperature-resistant stability characteristics of lipopeptide surfactants and biosynthetic nano materials of different structures and types.

The invention discloses a large-driving-force liquid crystal elastomer composite artificial muscle belt and a manufacturing method and application thereof. The preparation method comprises the following steps: reacting a mixed reaction system containing a liquid crystal monomer, a chain extender, a cross-linking agent, a photoinitiator, a catalyst and a nano material to prepare a composite oligomer; and placing the composite oligomer in a mold, removing the solvent, and then carrying out stretching and cross-linking treatment to obtain the liquid crystal elastomer composite artificial muscle band with large driving force. The composite artificial muscle belt can achieve linear contraction under thermal stimulation, and large thrust can be generated in the recovery process; meanwhile, the composite artificial muscle belt can achieve large driving force output without being assembled by an artificial muscle fiber bundle, and the technical problem caused by the fact that a plurality of artificial muscle fiber bundles are assembled to achieve contraction force amplification is solved.

The invention belongs to the technical field of photovoltaic packaging materials, and provides a light anti-reflection packaging adhesive film and a preparation method and application thereof. The light anti-reflection packaging adhesive film is prepared from 100 parts of matrix resin, 1 to 15 parts of light anti-reflection master batch, 0.4 to 1.5 parts of cross-linking agent, 0.8 to 3.0 parts of assistant cross-linking agent and 0.3 to 1.0 part of silane coupling agent, the light anti-reflection master batch comprises 100 parts of matrix resin, 0.5-10 parts of an anti-reflection nano material and 0.5-10 parts of a surfactant; the matrix resin is at least one of EVA (ethylene vinyl acetate) resin, POE (polyolefin elastomer) resin and PVB (polyvinyl butyral) resin; the anti-reflection nanometer material is a porous nanometer material, the porosity is 20-70%, the aperture is 2-35 nm, and the anti-reflection nanometer material is selected from one or more of porous nanometer silicon dioxide, porous silicon dioxide loaded zinc oxide, zinc sulfide, zinc oxide, titanium dioxide, zirconium oxide, aluminum oxide and organic silicon resin microspheres. According to the light anti-reflection packaging adhesive film, the light transmittance and the assembly efficiency can be further improved.

The invention relates to the technical field of carbon nanomaterials, and discloses a water-based high-dispersion carbon nanotube-graphene composite conductive liquid and a low-temperature curing process thereof, the process comprises pre-dispersion, fine dispersion, conductive liquid preparation, curing treatment, low-temperature curing and post-treatment, and by optimizing the composite dispersion process and a surface modification method, the conductive liquid is prepared. The agglomeration phenomenon of nano materials is inhibited, uniform and stable dispersion of the carbon nanotubes and graphene in a high-water-based medium is realized, and the storage stability and applicability of the conductive liquid are improved; by designing a multi-stage low-temperature cross-linking mechanism, the curing temperature is reduced, the process time is shortened, and damage of high temperature to a heat-sensitive base material is avoided; through the synergistic effect of the graphene and the carbon nanotubes and the application of an interface enhancement technology, a continuous and stable three-dimensional conductive path is formed in a low-temperature film forming process, and the conductivity, the mechanical strength and the environmental stability of the conductive film are improved.

The invention relates to the technical field of environmental restoration, and discloses a calcium carbonate coated calcium peroxide slow-release nano material as well as a preparation method and application thereof. The slow-release nano material comprises calcium peroxide and calcium carbonate and is of a core-shell structure, an inner core layer is calcium peroxide, and a shell is calcium carbonate; the preparation method comprises the following steps: continuously stirring a calcium peroxide suspension for 5-60 minutes in a normal-temperature normal-pressure and open system to spontaneously finish calcium carbonate coating without using other materials or chemical reagents. The calcium carbonate shell in the slow-release nano material provided by the invention not only enables calcium peroxide to realize H2O2 slow release, but also widens the pH application range of the material to 3.0-11.0. Compared with the prior art, the method is extremely simple in preparation process, low in cost, green, environmentally friendly and suitable for in-situ chemical oxidation repair of organic matter polluted sites.

The invention relates to the technical field of building materials, and discloses a mortar containing a nanometer material and a preparation method thereof, the mortar comprises 70-80 parts by weight of cement, 8-12 parts by weight of fly ash, 0.4-0.5 part by weight of a polycarboxylic acid water reducer, 0.4-0.6 part by weight of hydroxypropyl methyl cellulose, 1-2 parts by weight of the nanometer material, 2-3 parts by weight of modified silk fibroin and 40-50 parts by weight of water. Wherein the modified nano silicon dioxide is modified by gamma-aminopropyltriethoxysilane, the modified cubic nano calcium carbonate is subjected to compound modification by fumaric acid, sodium stearate and palmitic acid, and the modified silk fibroin is prepared by grafting modification by bis-aminopropyl terminated polysiloxane. According to the mortar, through optimization of component matching and modification treatment of the nano material and the silk fibroin, the mechanical property, durability and crack resistance of the mortar are remarkably improved, and the cost is controllable.

Generally speaking, this invention relates to hierarchical composites or delivery systems that are used to improve the performance of sealants, coatings, composites, adhesives, and other polymeric products. Hierarchical composites are materials that combine multiple types of structures at different scales to achieve enhanced properties and performance in such compositions. Expressly, but not limited to, the hierarchal composites carrying layers filled with, or otherwise, of nanomaterials, dyes, explosives, catalysts, metals, viscosity modifiers, thickeners, rheology modifiers, toughening agents, and like structures for the benefit of improved physical, chemical, electrical, conductive, color, rheological or other like properties minimizing or reducing for example, the need for more significant amounts of said materials.