4594 results about "Nanomaterials" patented technology

The invention discloses a high-toughness impervious polymer modified cement-based grouting material and a preparation method thereof, and belongs to the technical field of building repair materials. The component A is prepared from a cementing material, an admixture, a fine aggregate, a composite expanding agent, a polymer for concrete modification, fibers, an early strength agent, a water reducing agent, a composite retarder, a defoaming agent, an air entraining agent, a nano material and a functional component. The system solves the technical contradiction of toughness-strength-impermeability in the polymer modified cement-based material, and the material has excellent comprehensive performance: the initial fluidity is greater than or equal to 330 mm, the 28d compressive strength is greater than or equal to 82 MPa, the breaking strength is greater than or equal to 16.8 MPa, the bending-compression ratio is greater than or equal to 0.19, the impermeability pressure value is greater than or equal to 2.6 MPa, and the material is suitable for the fields of prefabricated buildings, tunnel engineering and the like.

The invention discloses a self-energy-supply multi-mode sensing electronic skin based on ionic gel heterojunction array integration and a preparation method and application of the self-energy-supply multi-mode sensing electronic skin. The electronic skin adopts a multi-layer composite structure design and comprises an electrode array layer, a silver paste connecting layer, a nano material doped ionic gel array layer and a pure ionic gel continuous layer, and passive self-energized work is realized through a space ion migration effect at a heterogeneous gel interface. The method is characterized in that the design of a multi-layer flexible composite structure is adopted, space-time coded light, temperature, pressure and humidity four-mode stimulation can be synchronously converted into electroneurographic signals, and a collaborative identification strategy of response intensity dynamic range and synaptic learning / delay time difference is utilized; and high-precision decoupling of the multi-source signals is realized in combination with a classification decision tree algorithm. The electronic skin has the characteristics of flexibility, deformation, environment self-repairing and bionic synapse, and geometrical characteristics of a reconfigurable target source are fused through time-space domain multi-modal data.

The invention relates to the technical field of antibacterial and antifouling fabrics, provides a preparation method of an antibacterial and antifouling fabric, and solves the problem of poor fabric durability caused by single functional component and lack of physical protection in the prior art. The preparation method comprises the following steps: S1, preparing MOFs loaded antibacterial fibers: blending a metal organic framework antibacterial composite nanomaterial and a polymer matrix material, and carrying out melt spinning to prepare the MOFs loaded antibacterial fibers; s2, constructing a self-cleaning functional coating: dispersing the fluorinated nanoparticles and a polymer adhesive in a solvent to prepare a self-cleaning coating solution; s2, performing surface activation treatment on the MOFs-loaded antibacterial fiber obtained in the step S1, soaking the MOFs-loaded antibacterial fiber in the self-cleaning coating liquid, and performing pulling and curing to form a bionic micro-nano structure coating on the surface of the MOFs-loaded antibacterial fiber so as to obtain a functional composite fiber; s3, spinning forming: taking the functional composite fibers obtained in the step S2 as warp yarns and / or weft yarns, and weaving to obtain the antibacterial and antifouling fabric.

The invention discloses high-performance fluid-state solidified soil for backfill based on composite ardealite of building residue soil, which is prepared by taking the building residue soil as a core raw material, taking a compound of a polycarboxylic acid water reducer and hydroxypropyl methyl cellulose as a fluidization regulator, and mixing the fluidization regulator and the building residue soil to prepare the high-performance fluid-state solidified soil for backfill. Superfine slag powder, fly ash, nano silicon dioxide, metakaolin and ardealite are used as curing agents, so that the fluid-state solidified soil with strong performance is obtained. Through the synergistic effect of all the components and innovative processes such as liquid nitrogen low-temperature grinding, nano material compounding and a segmented vacuum stirring process, the effect that the ultrahigh strength of the construction waste soil reaches 7.5 MPa within 14 days is achieved for the first time and is improved by 40% or above compared with that of conventional solidified soil, and the industrial problem that traditional waste soil is insufficient in solidification strength is solved; and collaborative optimization of strength and fluidity is realized. Meanwhile, efficient resource utilization of the construction waste is achieved, land occupation and environmental pollution caused by muck landfill are greatly reduced, and the requirement for green and sustainable development is met.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention relates to the technical field of reverse osmosis membrane supports, in particular to a polyester non-woven fabric and a preparation method and application thereof.The preparation method comprises the steps that S1, polyester main body fibers and polyester adhesive fibers are used as raw materials to prepare high-quantitation original cloth M0 and low-quantitation original cloth H0; carrying out hot pressing pretreatment on the H0 to obtain a product H0 '; s2, overlapping and hot-pressing M0 and H0 'to obtain a composite non-woven fabric M1H1; s3, the M1H1 is impregnated with a functional solution, and the functional solution contains para-aramid nanofibers and nano calcium carbonate modified by hexadecyl trimethyl ammonium bromide; and then carrying out cold pressing on the composite non-woven fabric impregnated with the functional solution to obtain the nano-material modified composite non-woven fabric. And S4, carrying out secondary hot pressing treatment to obtain the polyester non-woven fabric. The polyester non-woven fabric can effectively avoid the problems of excessive curling, excessive permeation of a polysulfone solution and the like during curing after being coated with polysulfone, and is more beneficial to application in a reverse osmosis membrane.

The invention relates to the technical field of nano materials, and particularly discloses a preparation method of surface modified nano calcium carbonate for a battery diaphragm coating. According to the method, the technical paths of microemulsion confinement crystal form regulation and control, gradient surface modification and boehmite compounding and porosity regulation and control are fused, and the functional nano calcium carbonate adaptive to the battery diaphragm coating is prepared. According to the technical scheme, limestone is used as a raw material, after calcination and digestion, the particle size of nano calcium carbonate is controlled through microemulsion carbonization (a cyclohexane-span 80-n-butyl alcohol system); a silane coupling agent KH560-KH570 is adopted for gradient modification to introduce an electrophilic functional group, boehmite is compounded to form a composite coating, and the porosity is regulated and controlled by adjusting the solid content in coating slurry and the coating speed. The method is stable in process and high in compatibility, and meets the requirements of diaphragm coatings of lithium ion batteries and solid-state batteries.

The invention discloses a method for preparing antioxidant MXene through electrochemical stripping, and belongs to the technical field of two-dimensional nano materials. Comprising the following steps: (1) centrifuging a Ti < 3 > C < 2 > T < x > MXene dispersion liquid to obtain a MXene wet solid, and coating the MXene wet solid on two sides of a copper foil; (2) the copper foil coated with the MXene wet solid serves as a cathode, and the cathode and the anode are placed in an electrolytic tank together; and (3) applying a constant voltage for electrolysis, collecting sediments in an electrolytic tank, centrifuging, washing, carrying out suction filtration, and drying to obtain the e-MXene film. The e-MXene prepared by the invention has excellent oxidation resistance and adjustable infrared emissivity, and can adapt to infrared camouflage application under damp and hot conditions.

The invention belongs to the technical field of epoxy resin coatings, and particularly relates to an epoxy resin insulating coating with high toughness and high ultraviolet aging resistance and a preparation method thereof. The epoxy resin insulating paint is composed of 2-5 g of a TiO2 (at) PDA (at) BTA nanometer material, 100 g of epoxy resin and 10-60 g of a curing agent, wherein the TiO2 (at) PDA (at) BTA nanometer material has a core-shell structure. The epoxy resin insulating paint is constructed on the basis of the multi-layer core-shell structure functional nanoparticles, so that the toughness of the material is improved, and the ultraviolet aging resistance of the paint is also improved.

The invention relates to the technical field of batteries, in particular to a negative electrode material, a preparation method thereof and a battery. The negative electrode material comprises a silicon nano material; the metal silicide layer at least partially coats the surface of the silicon nano material; the nitrogen and sulfur doped carbon layer at least partially coats the surface of the metal silicide; and the thickness of the metal silicide layer is greater than that of the nitrogen and sulfur doped carbon layer. According to the negative electrode material, the preparation method thereof and the battery provided by the invention, the coating structure of the negative electrode material is optimized, and the metal silicide / heteroatom doped carbon double-layer coated silicon nano material can be prepared by adopting a synthesis method which is low in energy consumption and capable of constructing a functional multi-layer coating structure, so that the long cycle life and the high-rate fast charging performance can be considered at the same time.

The invention discloses application of iron ruthenium nano-enzyme in preparation of nucleic acid detection products, and belongs to the technical field of biological detection and nano-materials. The RIN has stable peroxidase-like (POD) activity, and can catalyze a chromogenic reaction between 3, 3 ', 5, 5'-tetramethyl benzidine (TMB) and hydrogen peroxide (H2O2). The catalytic activity of the nano-enzyme can be selectively inhibited by pyrophosphate (PPi) generated in a nucleic acid amplification reaction, so that visual colorimetric analysis on whether target nucleic acid exists or not is realized. In combination with a polymerase chain reaction (PCR) system, the invention constructs a new nucleic acid detection strategy which does not need fluorescence labeling, is simple and convenient to operate and has high sensitivity. Through verification, the system can be widely applied to rapid on-site screening and visual interpretation of related nucleic acid of drug-resistant pathogens (such as ESKAPE flora) and the like, and has a good application prospect.

The invention discloses a preparation method of an environment-friendly degradable single-sided perspective sticker, and belongs to the technical field of modified nano materials. The method comprises the following steps: (1) preparation of a multi-layer composite structure: mixing polylactic acid and poly (butylene succinate), adding nano-montmorillonite and a surface modifier, and carrying out melt blending to form a first-layer melt; stirring poly (butylene adipate-co-terephthalate) and fluorescent carbon nanodots to form a second layer of melt; the first layer, the pressure-sensitive adhesive layer and the second layer are co-extruded and compounded to form a film blank. And (2) construction of the nano-film: biaxially stretching the film blank, imprinting a micropore array, dipping in the silver nanoparticle suspension, and drying to obtain the nano-film. And (3) coating functionalization treatment: immersing into a fluorine-containing nano coating solution, and curing. And (4) post-treatment: carrying out secondary curing. The obtained single-sided perspective sticker is suitable for the fields of buildings, vehicle privacy films and the like, and solves the problems of serious pollution and slow degradation of a traditional sticker.

The invention belongs to the technical field of composite materials, and discloses a basalt-based composite nanomaterial as well as a preparation method and application thereof. According to the invention, ZIF-67 in MOF is innovatively loaded on basalt nanosheets, so that not only can the dispersity and interfacial compatibility of basalt be improved and the sheet layers be prevented from being agglomerated in the coating, but also micropores possibly existing among the nanosheets can be blocked through a porous structure of the basalt, and the shielding effect and the penetration resistance of the whole coating are improved. In addition, the introduction of ZIF-67 endows the composite material with more functional regulation and control possibilities, such as ion capture, intelligent slow release and the like, so that the protection performance of the coating in a complex environment is further enhanced. Compared with a traditional filler, the composite structure has the advantages of being controllable in cost, excellent in performance, environmentally friendly and the like, and a new thought is provided for functional design of a water-borne epoxy resin anticorrosive coating.

The invention discloses a preparation method of a rare earth element doped nickel-based selenide nano-material and application of the rare earth element doped nickel-based selenide nano-material in electro-catalysis water full-hydrolysis reaction. According to the method, nickel salt, cerium salt, selenium dioxide and potassium chloride are prepared into electrolyte, and the electrolyte is subjected to electro-deposition on a foamed nickel substrate to obtain Ce-doped Ni0.85Se nanoparticles growing on foamed nickel. The crystal structure and electron distribution of Ni0.85Se are optimized by doping trace rare earth element cerium, so that the HER and OER performances of the Ni0.85Se are greatly improved. The prepared catalyst is self-supporting closely-packed nanoparticles, the formed amorphous structure is easy to expose more active sites, the catalyst has good electrocatalytic hydrogen evolution and oxygen evolution performance under alkaline conditions, the overpotential in electrocatalysis of nickel-based selenide is greatly reduced, and the electrocatalytic performance of nickel-based selenide is improved. And excellent electro-catalytic activity is shown in electro-catalytic water full hydrolysis. And the self-supporting electrode is not easy to fall off due to generation of bubbles in the reaction process, so that the working stability of the catalyst is improved.

The invention belongs to the field of carbon nanomaterials, and provides a method for preparing a carbon quantum dot material doped with elements such as silicon and aluminum by oxidative depolymerization and stripping of coal gangue. Comprising the steps of screening and matching of coal gangue, oxidative depolymerization stripping, centrifugal dialysis membrane filtration and modification, drying and the like, raw materials and all the steps are specifically set, and the particle size or fluorescence performance of fluorescent carbon dots can be specifically selected and set according to selective oxidative depolymerization stripping conditions. The main particle size of the prepared multi-inorganic-element doped carbon quantum dot material is kept within the range of 1.5-2.0 nm, the structure is stable, the optical performance also meets the requirements, and the material can be further modified and is expected to be applied to the fields of photovoltaic equipment, biological imaging, photocatalytic degradation of organic pollutants or sensing and the like.

The invention discloses a flame-retardant thermoplastic polyurethane elastomer material and a preparation method thereof, and belongs to the technical field of modified nano materials. The preparation method comprises the following steps: dissolving melamine, phytic acid and boron nitride in deionized water, carrying out oil bath, adding a coupling agent, stirring, carrying out vacuum filtration, washing with water, and drying to obtain a layered nano flame retardant; the preparation method comprises the following steps: dispersing a flame retardant in deionized water containing a nonionic dispersant, and carrying out ultrasonic treatment; the preparation method comprises the following steps: reacting polyether polyol with diisocyanate to obtain a primary prepolymer; adding other auxiliary agents, stirring, and carrying out gradient heating polymerization; and injecting into a mold, curing for 6-12 hours at 105-125 DEG C, and drying for 12-24 hours at 80-90 DEG C. A phosphorus-nitrogen-silicon ternary synergistic flame-retardant system is introduced, the boron nitride nanosheet surface grafting and dynamic pre-polymerization-gradient heating process is optimized, the dispersity is improved, and smoke suppression and thermal stability are achieved. Compared with the prior art, the flame retardant efficiency is high, the mechanical property is excellent, and environmental friendliness is achieved.

The invention relates to the technical field of materials, in particular to preparation of an amphiphilic tungsten disulfide nano material and application of the amphiphilic tungsten disulfide nano material in preparation of an oil displacement agent. The oil-displacing agent prepared from the amphiphilic tungsten disulfide nano material can reduce the interfacial tension of an oil-water interface, and can be quickly adsorbed to the oil-water interface to layer oil and water; the surface wettability of the rock is changed, the lipophilicity of the rock is changed into weak hydrophilicity, and the pore throat cannot be blocked due to excessive hydrophilicity while the oil phase is stripped. The nano oil-displacing agent disclosed by the invention can still have an enough stable use effect after being frozen at a low temperature and then unfrozen.

The invention provides a solar seawater desalination photothermal conversion efficiency optimization method and system based on machine learning, and the method comprises the steps: firstly collecting the solar spectrum distribution data, seawater turbidity spectrum data, real-time heat flow data and semiconductor nanomaterial data of a target sea area; and constructing a material spectrum mapping library based on the light absorption characteristics of the nano material. Through coupling analysis of a solar spectrum and a seawater turbidity spectrum, an environmental constraint condition is formed, a Bayesian optimization model is combined with a material spectrum mapping library and real-time heat flow data, and an optimal nano material mixing ratio is generated under environmental constraint. Then, the interface evaporation rate is predicted through the deep residual network, an optimal material morphology configuration scheme is obtained, and finally the morphology configuration is applied to semiconductor nanomaterial preparation. The photo-thermal conversion efficiency of the solar desalination system in the high-turbidity seawater environment is improved.

The invention discloses a method for constructing a dual-mode sensor through smartphone-assisted surface molecular imprinting for detecting diphenyl phosphate and application of the dual-mode sensor, and belongs to the technical fields of biochemical analysis, functional nano materials and life science. In synthesis, solubility and selectivity of a target object and photo-initiation efficiency in a polymerization process are optimized, and diphenyl phosphate molecularly imprinted nano-enzyme MIPs is rapidly prepared through a molecular imprinting technology; in the detection, H2O2 and 3, 3, 5, 5-tetramethyl benzidine TMB are catalyzed by peroxidase-like activity of Fe and N-CDs to generate a chromogenic reaction and an inner filter effect of oxTMB is used for inhibiting a fluorescence signal, dual-signal cross validation is realized in cooperation with a smart phone, and the colorimetric-fluorescence sensor for detecting diphenyl phosphate is constructed. The sensor has specific recognition selectivity and binding affinity of diphenyl phosphate, is simple to operate and low in cost, can realize sensitive detection of diphenyl phosphate in a wide linear range, has the detection limit as low as 16 pg / mL, and is suitable for field analysis of trace DPhP in a complex water environment.

The invention belongs to the technical field of nano materials, and relates to a carbon thermal reduction driven high-entropy oxide metastable-state material and a preparation method and application thereof.The preparation method comprises the steps that S1, carbon and soluble metal salt are dissolved in a solvent for ultrasonic treatment, and a metal salt solution and a carbon suspension are obtained; s2, adding a metal salt solution into the carbon suspension, adding strong base, and stirring to obtain a coprecipitation polymer; s3, re-dispersing the coprecipitation polymer in the solvent, adding extra ferric salt and urea, mixing and stirring, and freeze-drying the mixed solution to obtain precursor powder; s4, performing staged annealing treatment on the precursor powder under low oxygen partial pressure to obtain a carbon-loaded high-entropy oxide metastable-state material; the prepared high-entropy oxide metastable-state material is of an alloy phase and high-entropy oxide double-phase coupling structure, the polarization loss of electromagnetic waves is enhanced through a heterogeneous interface, and the high-entropy oxide metastable-state material has the advantages of being excellent in impedance matching and wide in electromagnetic wave absorbing bandwidth and can be widely applied to the fields of industrial electronics, medical communication and military stealth.

The invention discloses a metal polyphenol nano material based on chlorogenic acid and a preparation method and application thereof.The preparation method comprises the steps that chlorogenic acid and distearoyl phosphatidyl ethanolamine-polyethylene glycol 2000 are mixed and dissolved in an anhydrous tetrahydrofuran solvent, and a first mixed solution is prepared; adding a FeCl3 solution into the first mixed solution until a clear and transparent system is formed, so as to obtain a second mixed solution; and removing the anhydrous tetrahydrofuran solvent of the second mixed solution to obtain the metal polyphenol nano material (CA-Fe NPs) based on chlorogenic acid. The metal polyphenol nano material has excellent photothermal conversion performance, and can be applied to in-vitro antibiosis, antioxidation, anti-inflammation and wound healing promotion.

The invention relates to the field of enhanced intrinsic safety in a gas-liquid phase mixing process, and discloses a gas-liquid mixing device and a gas-liquid mixing vaporization method. The device comprises a shell, a Venturi gas-phase turbulent mixing section, a liquid-phase atomizing mixing section and a static mixing section are sequentially arranged in the shell in the flowing direction of material flow, the Venturi gas-phase turbulent mixing section comprises a reducing structure and an expanding structure, a liquid inlet component is arranged at the position, close to the reducing structure, of the expanding structure, and the static mixing section is connected with the liquid inlet component. The liquid phase atomization mixing section is provided with a membrane tube base body, the membrane tube base body is provided with a plurality of inner holes in the axial direction, the surfaces of the inner holes are coated with nanometer materials, and the static mixing section is provided with filler. According to the device, the liquid-phase oxidizing agent and the gas-phase oxidizing agent are subjected to multi-stage mixing vaporization, the atomization degree of the liquid phase is increased, the uniformity degree of the obtained mixed gas phase is improved, meanwhile, the device can be quenched after burning explosion by coupling a porous membrane pipe and filler, and the burning explosion risk in the mixing vaporization process is reduced.

The invention belongs to the technical field of industrial solid waste resource recycling, and discloses a nano composite filling material based on in-situ acid-base mutual modification enhancement and application thereof. According to the nano composite filling material, the alkalinity of the red mud and the acidity of the desulfurized gypsum are used for neutralization, the alkalinity of a system is reduced, a synergistic reaction is excited, a large number of ettringite crystals playing a key enhancing role are generated under the regulation and control of a nano material, and the ettringite crystals and a geopolymer form an interpenetrating network structure. The obtained slurry is low-viscosity and high-fluidity Newtonian fluid (diffusivity gt and 250 mm), the 7-day strength is larger than 2.0 MPa, the pH value is 7-9, and the fluorine ion concentration is lt; and the leaching of heavy metal ions is qualified, and the method is environment-friendly and safe. Efficient resource utilization of the red mud and the desulfurized gypsum is achieved, and the method is simple in process, low in cost and especially suitable for mine filling and engineering backfilling.

The invention discloses an organic silicon heat-conducting gasket and a preparation method thereof, and the preparation method comprises the following steps: mixing and uniformly stirring an organic silicon matrix, a heat-conducting filler, a nano material and a fibrous reinforcing filler to obtain mixed slurry; wherein the organic silicon matrix accounts for 10 to 50 parts; 20 to 80 parts of a heat-conducting filler; 1 part to 10 parts of a nano material; 1 part to 10 parts of fibrous reinforcing filler; the heat-conducting filler comprises surface-modified flaky boron nitride; the mixed slurry is subjected to multiple times of blade coating, forming and curing on a substrate, and an organic silicon heat conduction blank with sheet-shaped boron nitride oriented in the thickness direction is obtained; and cutting the organic silicon heat-conducting green body along the direction perpendicular to the blade coating plane to obtain the organic silicon heat-conducting gasket which is provided with a heat-conducting network in vertical orientation. According to the organic silicon heat-conducting gasket disclosed by the invention, extremely high heat conductivity coefficient can be obtained in the vertical direction by using relatively low heat-conducting filler content; meanwhile, the compression resilience of the gasket is obviously improved.

The invention relates to the technical field of analysis and detection, in particular to a fluorescent switch sensor based on quantum dot-nano porphyrin and application. The specific technical scheme is as follows: the fluorescent switch sensor is constructed by utilizing cadmium telluride quantum dots modified by mercaptosuccinic acid and a 5, 10, 15, 20-tetra (4-nitrophenyl) porphyrin nano material modified by a cationic surfactant hexadecyl trimethyl ammonium bromide. And the method has a good enrichment effect on zearalenone. The sensor has high sensitivity, high selectivity and anti-interference performance, can accurately analyze trace zearalenone in actual grain samples (corn, rice, soybean and the like), and has the advantages of simplicity in operation, low detection limit, high sensitivity, low cost and the like.

The invention discloses an MXene / rGO (at) SA coaxial composite fiber based on a core-shell structure and a preparation method and application thereof, and belongs to the technical field of nano composite materials and flexible electronics. The invention solves the problems of many interface defects, unstable performance and the like of the existing coaxial fiber. The MXene / rGO-SA coaxial composite fiber is prepared by adopting a coaxial wet spinning method, a high-performance SA fiber with excellent mechanical properties is used as a tough shell layer, a multi-element nano material MXene / rGO composite fiber is used as a core layer, a calcium chloride-ethanol mixed solution in a certain proportion is used as a coagulating bath, and the coaxial composite fiber is prepared by utilizing a coaxial needle head; the interface bonding force and the conductive network of the MXene / rGO (at) SA coaxial composite fiber are optimized by accurately controlling the core-shell ratio, and the mechanical strength, the conductivity and the stability are synergistically improved.

The invention relates to the technical field of agricultural application of nano materials, and discloses a preparation method and application of a photosynthetic accelerant containing carbon quantum dots. Urea and citric acid are adopted as raw materials, and the nitrogen-carbon molar ratio and hydrothermal reaction parameters are optimized, so that efficient doping of nitrogen and accurate regulation and control of the particle size are achieved, and the photosynthetic accelerant containing the carbon quantum dots is obtained. The nitrogen-doped carbon quantum dot photosynthetic promoter with excellent upconversion performance is successfully synthesized, the promoter has good water solubility and biocompatibility, the photosynthetic efficiency of plants can be greatly improved within the concentration range of 0-100 mg / L, a safe application window is defined, and by establishing foliage spraying and water planting dual-mode application specifications, the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened, and the application range of the nitrogen-doped carbon quantum dot photosynthetic promoter is widened. The problems that current crops are insufficient in solar spectrum utilization and low in light energy conversion efficiency are solved in a targeted manner by utilizing an ultraviolet light-photosynthetically active radiation conversion function mediated by the carbon quantum dots and combining the targeted enrichment permeation characteristic of the carbon quantum dots in chloroplast.

The invention belongs to the field of preparation of nano materials, and discloses a CoP / Co (OH) 2 sea urchin-shaped heterojunction catalyst growing on foamed nickel and a preparation method and application of the CoP / Co (OH) 2 sea urchin-shaped heterojunction catalyst. Alkali cobalt carbonate (CoCH) is used as a precursor, a crystalline phase CoP substrate is generated through a low-temperature phosphating method, then the surface of the crystalline phase CoP substrate is uniformly coated with an amorphous Co (OH) 2 layer through an electro-deposition process, and the self-supporting phosphating / hydroxyl heterogeneous structure catalyst (CoP / Co (OH) 2) is successfully constructed. The obtained CoP / Co (OH) 2 shows excellent complete water splitting performance, and is benefited from the high-activity specific surface area (Cdl = 44.66 mF cm <-2 >) and the interface rapid electron conduction characteristic (Rct = 0.43 omega) of a heterogeneous structure; when two electrodes are assembled to fully decompose water, the cell voltage is only 1.780 V when the current density is 250 mA cm <-2 >, and after continuous operation is carried out for 24 hours, the performance is basically kept unchanged, and the voltage fluctuation ratio is lower than 0.5%. CoP / Co (OH) 2 is prepared into a 2 * 2cm < 2 > self-supporting electrode to construct AEMWE, only 2.08 V cell voltage is needed under the ultrahigh current density of 1A cm <-2 >, the AEMWE can stably run for 250 hours, the attenuation rate is 80 mu V h <-1 >, meanwhile, the hydrogen production efficiency is calculated to reach 96.2% through gas metering and Faraday law, and the engineering potential of the AEMWE in large-scale hydrogen production application is verified.

The invention relates to the technical field of analysis and detection, in particular to a surface enhanced Raman spectroscopy (SERS)-based nano material detection method, which is characterized in that a heterojunction composite structure consisting of noble metal nano stars and semiconductor oxide nano particles is used as an SERS active substrate; and a specific recognition molecule carrying a Raman reporter molecule is used as a detection probe. During detection, the recognition molecules are firstly combined with the to-be-detected nano material, and then the compound is adsorbed on the surface of the substrate. The tip structure of the noble metal nanostar and a heterojunction interface jointly generate a synergistic effect of electromagnetic enhancement and chemical enhancement, and a reporter molecule signal is doubly amplified, so that high-sensitivity and high-selectivity detection on a to-be-detected nano material is realized. The method solves the problems of weak signal and poor selectivity of the traditional method, and is suitable for rapid and quantitative analysis of trace nano materials in the environment.

The invention relates to the technical field of functional coatings of medical instruments, in particular to a temperature-sensitive response type sodium polyacrylate catheter leakage-proof coating, a preparation method and application thereof, and the coating is of a three-layer composite structure. And the bottom bonding layer adopts a polydopamine modified silane coupling agent system, contains silver nanoparticles, has the thickness of 5-15 microns, and ensures strong bonding and antibiosis of the substrate. The middle functional layer is a three-dimensional cross-linking degree gradient interpenetrating network polymer, is composed of a plurality of monomers and nano materials, and is 50-100 [mu] m in thickness, the cross-linking degree of the middle functional layer is gradually increased from inside to outside, gradient transition of mechanical properties is achieved, the outer protective layer is composed of a copolymer, is 3-8 [mu] m in thickness, and provides excellent anti-fouling and biocompatibility. The coating is endowed with strong adhesive force, gradient mechanical property and surface stability, the sodium polyacrylate component absorbs water and expands in urine to form sealing, and the expansion degree of the sodium polyacrylate component is regulated and controlled by the pH value and ionic strength of the urine.