1258 results about "Gel method" patented technology

The invention discloses a high-strength and high-toughness aluminum nitride ceramic and a preparation method thereof, and relates to the technical field of ceramics, a sol-gel method is adopted to coat the surface of aluminum nitride with a stable shell layer to form a core-shell structure, meanwhile, the low lattice mismatch rate of a core-shell interface is utilized to reduce thermal resistance, and toughness and thermal conductivity are both considered; according to the external magnetic field tape casting method, the magnetic dipole moment orientation principle is utilized, an external magnetic field is applied in the tape casting stage, the in-plane mechanical property is improved, and the fracture toughness is improved through the magnetism of aluminum nitride whiskers; a reinforcement is introduced to improve the mechanical property and corrosion resistance of the aluminum nitride ceramic material, multi-granularity powder is compounded, large-particle aluminum nitride powder is used as a sintering and heat-conducting framework material, and high activity provided by submicron particles is utilized to promote sintering, so that the sintering temperature of aluminum nitride can be remarkably reduced, and the performance is greatly improved; and the aluminum nitride substrate expands more application fields on a future packaging circuit.

The invention belongs to the technical field of catalytic oxidation of carbon-containing industrial waste gas, and particularly relates to a Pd catalyst for catalytic combustion of carbon-containing waste gas as well as a preparation method and application of the Pd catalyst. The invention provides a Pd catalyst for catalytic oxidation of carbon-containing industrial waste gas such as CO and volatile organic pollutants VOCs. The Pd catalyst is obtained by compounding an amorphous CeO2 nano-cluster with a TiO2 substrate (marked as cCeO2 / TiO2) and indirectly regulating the form of Pd through gradient regulation of the content of the amorphous CeO2 nano-cluster by a sol-gel method on the basis of strong interaction of Pd and Ce species. The Pd catalyst prepared by the invention shows excellent low ignition temperature, high performance and certain universality in the catalytic combustion process of carbon-containing industrial waste gases such as CO and low-chain VOCs (Volatile Organic Compounds). In addition, the method for preparing the Pd catalyst is simple to operate and mild in condition, and has great industrial application potential and value.

The invention relates to the technical field of titanium dioxide, and discloses a preparation process of oil paint core-coated titanium dioxide, which comprises the following steps: a core layer is rutile type titanium dioxide particles with the particle size range of 0.1-0.5 mu m and the specific surface area of 8-15m < 2 > / g, an inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5), the coating thickness is 5-15% of the diameter of the core layer, and the inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5). Wherein the silicon dioxide is coated by a hydrolytic deposition method, the aluminum oxide is coated by a sol-gel method, the organic coating layer comprises a copolymer containing a silane coupling agent and organic silicon resin, the organic silicon resin is methyl phenyl silicon resin, the organic coating layer accounts for 1-8% of the total mass of the titanium dioxide, and the surface contact angle of the organic coating layer is greater than or equal to 110 degrees. According to the preparation process of the oil paint core-coated titanium dioxide, an inorganic-organic gradient coating system is constructed, so that the core-coated titanium dioxide has a gloss retention rate of more than 95% (ASTM D523) and a delta E color difference of less than 1.5 (ISO 7724) after 1000 hours in a QUV accelerated aging test, and the weather resistance of the core-coated titanium dioxide is improved by more than 3 times compared with that of the traditional titanium dioxide.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention belongs to the field of hydrogel preparation, and particularly relates to a preparation method of SA / CS / Ca < 2 + > dual-network hydrogel, an obtained product and application. The sodium alginate / chitosan / calcium ion (SA / CS / Ca < 2 + >) physical cross-linked double-network hydrogel is prepared through a semi-dissolution acidification sol-gel conversion method and an internal gel method, the hardness and chewiness of the hydrogel can be remarkably improved, and the elasticity and cohesiveness of the hydrogel can be improved; freeze-thaw stability research is carried out on the prepared SA / CS / Ca < 2 + > dual-network hydrogel, the influence of freezing temperature, thawing temperature, freezing and thawing cycle times and other conditions on properties such as gel structure, rheology, swelling rate, moisture distribution and the like is explored, and the result shows that when the freezing temperature is-80 DEG C and the thawing temperature is 4 DEG C, the gel subjected to one-time freezing and thawing cycle has good stability. Through detection and analysis, the hardness is relatively high, the elasticity and cohesiveness are also remarkably improved, the elastic modulus (G ') and the viscous modulus (G' ') of the gel are best, the swelling rate is relatively low, the free water content is relatively low, the bound water content is relatively high, and the gel structure is relatively stable.

The invention discloses light self-repairing concrete and a preparation method thereof, and relates to the technical field of concrete. The method comprises the following steps: firstly, efficiently packaging a calcium nitrate solution in hollow glass beads by utilizing a negative pressure impregnation technology; then growing a porous zeolite crystal coating on the surface of the microbead in situ by adopting a sol-gel method to form a self-repairing filler with a core-shell-hole gradient structure; when the concrete cracks to cause the cracking of the microbeads, the Ca < 2 + > in the cavity is quickly released, and the Ca < 2 + > adsorbed in the zeolite layer is gradually dissociated along with water permeation, so that the new microcracks are continuously repaired. Then, uniformly coating the surface and pores of the carboxymethyl cellulose hydrogel network with polydopamine in an in-situ oxidative polymerization manner to form composite hydrogel with photo-thermal responsiveness; lighting and heating to trigger dynamic coordination bond dissociation; meanwhile, heat drives rapid directional crystallization of a repair product by promoting the ion diffusion rate, and a compact mineralization layer is formed. The concrete prepared by the invention has the effects of light weight and self-repairing.

The invention discloses a preparation method of a carbon-coated Na3V2 (PO4) 2F3 sodium-ion battery positive electrode material, relates to a preparation method of a sodium-ion battery positive electrode material, and aims to solve the technical problem of poor rate capability of a Na3V2 (PO4) 2F3 positive electrode material prepared by an existing sol-gel method. The method comprises the following steps: weighing sodium salt, a vanadium source, phosphate, villiaumite and a carbon source, treating at 90-95 DEG C by using a sol-gel method, and then cooling to 75-80 DEG C for treatment to obtain wet gel; and drying the wet gel, pre-sintering, and sintering at high temperature to obtain the carbon-coated Na3V2 (PO4) 2F3 sodium ion battery positive electrode material. The first-week capacity of the material is 124.46 mA / g, the capacity retention rate reaches 77.24% after 1000 times of circulation, and the capacity reaches 103.58 mA / g under the 30C multiplying power. The invention can be used in the field of sodium-ion batteries.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The present invention relates to the field of battery materials, and provides a lithium manganate cathode material coated with lithium triborate and a preparation method thereof. The cathode material is a porous lithium manganate / lithium triborate composite electrode material, which includes porous lithium manganate with a highly connected directional columnar pore structure and a lithium triborate coating covering the pore surface, with a mass ratio of (86.0~92.0):(8.0~14.0), a coating thickness of 600~800 nm, a pore diameter of 45~95 μm, and a porosity of 65~78%. The preparation method includes: preparing a precursor colloidal solution by the sol-gel method, obtaining porous lithium manganate through low-temperature freezing molding and freeze-drying, and forming a cathode substrate through pre-oxidation and high-temperature sintering; subsequently, using vacuum-assisted impregnation, ultrasound, and nitrogen pressure to promote the penetration of the lithium triborate precursor solution, and forming a uniform coating layer through gradient drying and annealing treatment. The present invention significantly improves the crystal structure stability of the cathode material, inhibits manganese dissolution, improves the cycle life and rate performance, and has wide application value.

The invention relates to the technical field of catalyst materials, and particularly discloses a high-stability hydrogenation catalyst and a preparation method thereof. The invention relates to a preparation method of a high-stability hydrogenation catalyst, which comprises the following steps: preparing a hollow porous microsphere as an inner core from amino-terminated hyperbranched polyaryletherketone and polyvinyl alcohol, and then coating the porous microsphere with a mesoporous silicon dioxide intermediate layer by a sol-gel method; and finally, forming an Mg-Al hydrotalcite layer on the outermost side through a coprecipitation method, dipping and modifying with La (NO3) 3 and Ce (NO3) 3 solutions to obtain a catalyst carrier, dipping the catalyst carrier in an active metal dipping solution, and drying to obtain the catalyst. The high-stability hydrogenation catalyst provided by the invention has excellent mechanical properties and more reaction active sites, has high catalytic activity and catalytic efficiency, and is relatively long in catalytic life.

The invention discloses a sodium ferric pyrophosphate material with a sodium storage dominant crystal face regulated and controlled by cation doping as well as a preparation method and application of the sodium ferric pyrophosphate material. The chemical formula of the prepared sodium ferric pyrophosphate material with the regulated and controlled crystal structure is Na < 4 > Fe < 2.97 > M < 0.03 > (PO4) < 2 > P < 2 > O < 7 >. Wherein M = Sr, or Sr and a second doping element, and the second doping element is selected from one of Cd, Bi, Mo, Ni and Al. The material is prepared by adopting a sol-gel method, an iron source, a chelating agent, a sodium source, a phosphorus source and doping elements are dissolved in deionized water, and stirring is performed until a gel state is formed; and drying and calcining twice to obtain a final product. The sodium ferric pyrophosphate electrode material prepared by the invention has more sodium storage dominant crystal faces, shows good electrochemical performance, has the advantages of simple preparation process, easily available raw materials and low cost, has remarkable industrial application value, and is easy for large-scale production.

The invention discloses a large-current-carrying-capacity flexible power cable, which belongs to the technical field of cable preparation, is used for solving the technical problem that the flame retardant property and the mechanical property of the power cable need to be further improved in the prior art, and specifically comprises a cable core, a wrapping layer, an insulating layer and a sheath layer which are sequentially arranged from inside to outside. The preparation method comprises the following steps: preparing alkoxy silane containing a benzocyclobutene group, preparing flame-retardant particles by using a sol-gel method, preparing modified polyurethane by using modified polysiloxane and 2, 5-furandimethanol as soft segments, naphthalene diisocyanate as a hard segment and trimethylolpropane as a chain extender, and preparing the flame-retardant flame-retardant polyurethane. The linear low-density polyethylene, the MAH-g-PE, the modified polyurethane, the flame-retardant particles and the auxiliary additive are melted and extruded outside the wire core to form the insulating layer, so that the power cable is obtained, the flame-retardant property of the power cable is effectively improved, and the mechanical property and the current-carrying stability of the power cable are also improved.

The invention discloses a gadolinium boron molybdate magnetic refrigeration material with triangular magnetic resistance and a preparation method and application of the gadolinium boron molybdate magnetic refrigeration material. The chemical formula of the material is Gd2B2MoO9, the material belongs to a triclinic system, and the space group is P-1; the crystal structure has the characteristic that nearest rare earth Gd ions have magnetic resistance file; the material is prepared by a solid phase method or a sol-gel method; the magnetic phase change temperature of the material is 0.7-0.9 K, the material shows a remarkable magnetothermal effect at low temperature, the maximum isothermal magnetic entropy change values of the material are 30.0-35.0 J / kg.K and 51.0-55.0 J / kg.K respectively under the magnetic field change of 0-2T and 0-5T, and the material can be applied to low-temperature magnetic refrigeration. The gadolinium boron molybdate Gd2B2MoO9 material with triangular magnetoresistance provided by the invention has the advantages of low raw material price, simple process and lower equipment requirement, and is suitable for industrial production.

The invention discloses a preparation method of low-carbon-content high-purity quartz sand, which comprises the following steps: carrying out alkaline hydrolysis and drying on organosilane to obtain alkaline xerogel, putting the alkaline xerogel into a quartz tube of a rotary tube furnace, starting the furnace body, adjusting the rotation rate, heating to a specific low temperature, and introducing nitrogen to replace air; introducing oxygen, controlling the pressure, carrying out oxidation reaction, relieving the pressure to normal pressure after the reaction, pumping and discharging the product, and repeating the oxidation and pumping steps for many times until the tail gas carbon dioxide reaches the standard; raising the temperature, introducing chlorine-containing gas for purification, finally raising the temperature to a sintering temperature, and sintering in an air atmosphere to obtain the low-carbon-content high-purity quartz sand. According to the preparation method, the energy consumption and the equipment cost of the carbon removal procedure are greatly reduced, the specific surface area and the densification performance of the subsequent high-purity quartz sand product can be guaranteed, and a technical path which is low in energy consumption, high in efficiency and capable of giving consideration to the product performance is provided for industrial preparation of the high-purity quartz sand through a sol-gel method.

The invention discloses a preparation method of a solvent-resistant nanofiltration membrane with a polydopamine / amino silicon dioxide middle layer, belongs to the technical field of membrane separation, and solves the technical problems of low flux and poor stability of the solvent-resistant nanofiltration membrane. The preparation method of the solvent-resistant nanofiltration membrane with the polydopamine / amino silicon dioxide middle layer comprises the following steps: preparing a polyetherimide-based membrane by a phase inversion method-crosslinking method; preparing amino silicon dioxide nanoparticles by adopting a sol-gel method; preparing a deposition solution containing dopamine, an oxidizing agent and amino silicon dioxide by using a Tris buffer solution; depositing the polydopamine / amino silicon dioxide intermediate layer on the upper surface of the polyetherimide base film; carrying out interfacial polymerization reaction of piperazine and trimesoyl chloride on the surface of the membrane deposited with the middle layer, and carrying out heat treatment to obtain a composite membrane; and immersing the composite membrane into an organic solvent for activation to obtain the solvent-resistant nanofiltration membrane with a polydopamine / amino silicon dioxide intermediate layer. The solvent-resistant nanofiltration membrane constructed by taking polyetherimide as a base membrane, polydopamine / amino silicon dioxide as a middle layer and polyamide as a separation layer has excellent flux and stability, and has a wide application prospect in the aspects of drug separation, organic solvent recovery and the like.

The invention relates to a surface-coated oxide solid electrolyte and a preparation method thereof, the surface-coated oxide solid electrolyte comprises an oxide electrolyte and a surface coating layer, the chemical formula of the oxide solid electrolyte is Li7-xLa3Zr2MxO12-x (M = Ta, Nb, Hf, Ge, Sc, Ti, Al, Si, Sn, Y, 0 < = x < = 1), the chemical formula of the surface coating layer is LiXON (R = Ta, Nb, Al, Zr, Ga, In, N = F, Cl, Br, I), and a lithium source, a lanthanum source, a zirconium source, an M source, an X source and an N source, or an XN source are connected in series, garnet solid electrolyte powder with a stable surface coating layer is obtained by adopting a solid phase method or a sol-gel method and combining a low-temperature calcination process; and then mixing and reacting with a lithium salt and a polymer electrolyte, and pouring the obtained slurry on a polyfluortetraethylene plate to prepare the composite electrolyte. Compared with the prior art, the high-ion conductor layer formed on the surface of the product in situ constructs a rapid transmission channel for lithium ion transmission in the composite electrolyte, and high ion conductivity is achieved.

The invention discloses a high-resilience eTPU foaming material and a preparation process thereof, and belongs to the technical field of foaming materials. The process comprises the steps of raw material premixing and TPU chain extension reaction, precursor system injection, in-situ phase change energy storage core-shell particle generation, supercritical two-fluid foaming and molding post-treatment. Wherein the SiO2-coated TiO2 core-shell particles are prepared by a non-hydrolytic sol-gel method, the porous SiO2 core adsorbs and fixes the micro-crosslinked polyurethane-based phase change material, the TiO2 shell provides sealing and supporting, the particles are combined with the TPU matrix through covalent bonds, and the micro-crosslinked polyurethane-based phase change material has a unique micro-crosslinked network structure, so that the thermal conductivity of the TPU matrix is improved, and the thermal conductivity of the TPU matrix is improved. The hidden danger of leakage of the phase change material in the using process can be effectively eliminated, and meanwhile the interface bonding effect between the inorganic particles and the TPU matrix is synchronously enhanced. The eTPU foaming material prepared by the invention has the characteristics of high resilience, strong interface bonding, excellent energy storage stability and low compression set, and is suitable for shoe materials, automotive interiors and other scenes.

The invention provides a vanadium aluminum phosphate electrode material and a preparation method thereof. In target product components, an aluminum source, a vanadium source and a phosphorus source are respectively aluminum nitrate or other aluminum sources, vanadium pentoxide or ammonium vanadate, ammonium dihydrogen phosphate, phosphoric acid or other phosphorus sources, and a nitrogen source of nitrogen-doped carbon is from polyvinylpyrrolidone or other nitrogen sources of a gel component; the carbon source is selected from polyvinyl alcohol and glycerol. By adopting an exogenous plasticizing physical crosslinking sol-gel method, in the whole reaction system, uniform distribution of reaction ions and intermediates is maintained, and finally, gel is networked, so that the problem of capacity fading caused by an unstable structure of an existing aluminum ion battery positive electrode material in a circulating process is solved, and the service life of the aluminum ion battery positive electrode material is prolonged. And the problems of high reaction system selection requirement, long preparation period and complex process of the existing endogenous covalent polycondensation sol-gel method for preparing the electrode material are solved.

The invention discloses a multi-layer flexible radiation cooling composite diaphragm which structurally comprises a flexible base layer film, and a SiO2 inorganic coating, a first layer of polyvinylidene fluoride (PVDF), a nano-silver layer deposited by magnetron sputtering and a second layer of PVDF which are sequentially coated to form a base layer film / SiO2 / PVDF / Ag / PVDF sandwich structure. The SiO2 layer is prepared through a sol-gel method, the surface roughness is smaller than 2 nm, and the visible light transmittance is larger than 95%; the thickness of the silver layer is 50 + / -5 nm, and the total thickness of SiO2 / PVDF / Ag does not exceed 150 nm. According to the composite diaphragm, ultraviolet reflection, visible light high transmission (greater than 92%) and near-infrared high reflection (greater than 88%) are realized through spectrum selective regulation and control, and meanwhile, SiO2 and PVDF synergistically enhance the infrared emissivity of an atmospheric window wave band (8-13 [mu] m). The flexible PET base material is combined with the PVDF interlayer design to restrain silver layer oxidation and interface stripping, the recovery rate is larger than 95% after 1000 times of bending circulation, and the NIR reflectivity attenuation is smaller than or equal to 5%. The composite diaphragm disclosed by the invention has the advantages of high light transmission, efficient cooling, excellent flexibility and long-term stability, and is suitable for flexible scenes such as agricultural greenhouses and the like.

The invention relates to the field of fiber materials, and provides a low-dielectric constant glass fiber and a preparation method thereof, and the low-dielectric constant glass fiber comprises basalt glass fiber and a silicon oxyfluoride layer coating the surface of the basalt glass fiber. The basalt glass fiber is prepared by adopting a melting wire drawing method, the average diameter is 5.0-15.0 microns, and the volume ratio of a crystalline state to an amorphous state is controlled to be (5.0-15.0): (85.0-95.0). The thickness of the silicon oxyfluoride layer is 140-400 nm, and the silicon oxyfluoride layer is obtained through a sol-gel method and is formed by conducting dipping, ultrasonic treatment and purging on tetraethoxysilane and ammonium fluoride sol and then conducting heat treatment in an inert atmosphere. The preparation method comprises the steps of basalt raw material crushing, acid pickling, melting, wire drawing and gradient cooling, and the uniformity and stability of the fibers are ensured. The preparation conditions, impregnation parameters, purging pressure and heat treatment temperature of the modified sol are all optimized, so that uniform coating and stability enhancement are realized. The glass fiber provided by the invention has low dielectric constant and excellent heat resistance and hydrophobicity, and is suitable for the fields of high-frequency electronic substrates, aerospace and 5G communication.

The invention discloses a lithium-rich manganese-based positive electrode material and a preparation method, and relates to the technical field of lithium ion battery positive electrode materials, and the preparation method comprises the following steps: jointly dropwise adding a lithium acetate aqueous solution and a transition metal salt aqueous solution into a citric acid aqueous solution, maintaining the reaction temperature, and continuously stirring to form gel; and carrying out secondary calcination on the gel to obtain a lithium-rich manganese-based positive electrode material precursor, carrying out high shear stress and heat treatment combined treatment on the lithium-rich manganese-based positive electrode material precursor, washing, and drying to finally obtain the lithium-rich manganese-based positive electrode material. The lithium-rich manganese-based positive electrode material is prepared by adopting a sol-gel method, a two-step calcination method and a high shear stress and heat treatment combined mode, lattice oxygen can be stabilized by introducing oxygen vacancies, and the cycling stability is improved; by introducing the lithium vacancy, the migration energy of lithium ions can be reduced, the migration of the lithium ions is accelerated, and the rate capability is improved; the generation of the disordered layer hinders the contact between the electrolyte and the internal material, the reaction between the material and the electrolyte is reduced, the stress caused by lattice distortion is relieved by the internal local disorder, and the stability of the material is enhanced. The lithium-rich manganese-based positive electrode material prepared by the invention is applied to a lithium ion battery and shows excellent electrochemical performance, and the preparation method hardly generates waste liquid and shows the characteristic of environmental friendliness.

The invention relates to the technical field of tempered glass, in particular to a preparation method of low-warpage tempered glass, which comprises the following steps: (1) pretreatment: cleaning and drying the surface of glass by adopting an organic solvent and deionized water in sequence, and uniformly spraying an adhesive agent on the atmosphere surface of the glass; (2) SiO2-ZrO2 film coating: uniformly spraying SiO2-ZrO2 gel on the glass atmosphere surface by adopting a sol-gel method, and forming a SiO2-ZrO2 composite film layer with uniform texture on the glass atmosphere surface; and (3) strengthening: putting the coated glass into mixed molten salt, and strengthening at the temperature of 390-410 DEG C for 8-10 hours. The SiO2-ZrO2 composite film layer is arranged on the glass atmosphere surface, so that the ion exchange rate difference between the atmosphere surface and the tin surface can be reduced, the stress difference can be reduced, the component proportion can be accurately regulated and controlled, the tin permeation rate can be reduced, and the warping value of the tempered glass can be remarkably reduced through the synergistic effect of the SiO2-ZrO2 composite film layer and the tin surface.

The invention discloses an antioxidant carbon aerogel material and a preparation method thereof. The method comprises the following steps: sequentially adding a solvent, a boron-containing modifier and a silicon-containing modifier into phenolic resin for esterification reaction; sequentially curing, drying and carbonizing to obtain boron-silicon modified carbon aerogel; depositing a SiC inner coating on the boron-silicon modified carbon aerogel under the assistance of supercritical CO2; a Zr-Si ceramic oxygen barrier layer and a SiO2 sealing and filling layer are sequentially prepared through a sol-gel method, and the carbon aerogel material with the SiC-Zr / Si-SiO2 composite coating is prepared. The invention also provides the aerogel material prepared by the method, the oxidation resistance of the aerogel material is obviously improved, and the aerogel material can be used for preparing a thermal insulation material applied to the field of high-temperature thermal protection.

The invention relates to the field of ceramic materials, provides a high-voltage-resistant PTC (Positive Temperature Coefficient) thermal sensitive ceramic material as well as a preparation method and application thereof, and aims to improve the voltage resistance and PTC effect stability of thermal sensitive ceramic. The material is composed of aluminum oxide-coated manganese-doped barium titanate nanorods, hollow-core silicon dioxide microspheres and a glass phase sintering aid, and the electric heating performance and the microstructure stability are optimized by constructing a core-shell structure and a three-dimensional composite system. A hydrothermal method and a sol-gel method are adopted to precisely control a raw material structure, and alcohol dispersion, tape casting and weak oxidizing atmosphere sintering are combined, so that the compactness and consistency of the ceramic are ensured. The material is suitable for high-voltage temperature control elements and over-current protection devices, and is widely applied to the fields of new energy automobile battery pack over-temperature protection, high-voltage power equipment current limiting elements, industrial automatic temperature control switches and the like.

The invention discloses a preparation method of lithium manganese iron phosphate. Comprising the following steps: S1, preparing ferromanganese oxide from an iron source and a manganese source; s2, performing impurity removal and drying on the ferromanganese oxide precursor to obtain the ferromanganese oxide precursor; s3, obtaining a lithium salt solution through a lithium source and a phosphorus source; s4, adding a glucose solution and the ferromanganese oxide precursor prepared in S2 into a lithium salt solution to obtain a mixed system; and S5, grinding the mixed system, performing spray drying, and performing high-temperature sintering to obtain the lithium manganese iron phosphate material. Compared with an existing sol-gel method, the method for preparing the lithium iron phosphate material through the solid phase method is simple in process, mild in preparation condition, low in calcination temperature and short in heat treatment time, and meanwhile the prepared porous lithium manganese iron phosphate material is high in compaction density.

The invention relates to the technical field of batteries, in particular to a composite diaphragm, a preparation method thereof and a battery. The composite diaphragm comprises a base membrane and a coating arranged on at least one side surface of the base membrane along the thickness direction, the coating comprises a composite material, and the composite material comprises high-entropy alloy aerogel and solid electrolyte. The battery comprises the composite diaphragm. The sol-gel method is adopted to prepare the coating containing the solid electrolyte and the high-entropy alloy aerogel, and after the coating is coated on the two surfaces of the base membrane, the composite membrane with excellent comprehensive performance is obtained through normal-pressure drying. Compared with similar diaphragm coating materials, the multifunctional diaphragm coating prepared by the invention is more uniform and stable in structure, and has an obvious improvement effect on the high-temperature performance, the cycle performance and the like of the battery after being coated on the surface of the lithium battery diaphragm.

The invention belongs to the technical field of batteries, and relates to an oxide protection layer for a lithium metal negative electrode and a preparation method and application of the oxide protection layer, a prepared composite electrode comprises a lithium foil substrate and the oxide protection layer covering the surface of the lithium foil substrate, and the oxide protection layer is prepared through a sol-gel method. Comprising the following steps: sol preparation: dissolving metal alkoxide or metal salt in an aprotic polar solvent, adding a stabilizer and / or a catalyst, and stirring; and coating the sol on the surface of the lithium foil, drying and annealing. The oxide protective layer prepared by the method has a uniform and compact structure, can effectively inhibit the growth of lithium dendrites, improve interface contact and improve the cycle performance and coulombic efficiency of the lithium metal negative electrode, and is simple in preparation method, low in cost and easy to realize large-scale production. The invention also discloses an all-solid-state lithium metal battery comprising the composite electrode.

The invention belongs to the field of photocatalytic material preparation, and particularly relates to a ZnFe2O4 / TiO2 / BC composite material as well as a preparation method and application thereof. The novel photocatalytic material ZnFe2O4 / TiO2 / BC composite material is prepared through a sol-gel method and a coprecipitation method, the photocatalytic performance of titanium dioxide and zinc ferrite is improved, and the application field of titanium dioxide and zinc ferrite is widened. The dopant provided by the invention is relatively low in price, the process is relatively simple, and the photocatalyst with a wider light absorption range can be prepared and can be used for degrading sulfamethoxazole.

The invention discloses a method for manufacturing anode foil of ultra-high voltage aluminum electrolytic capacitor with high dielectric constant, and belongs to the technical field of anode foil of aluminum electrolytic capacitor. The method comprises: (1) preparation of ultra-high voltage etching foil, including pretreatment of aluminum plain foil, pore formation, secondary pore expansion and tertiary pore expansion of etching foil, etc.; (2) preparation of Ag / TiO2 precursor solution, preparing titanium dioxide gel doped with different Ag contents by sol-gel method; (3) immersion coating treatment, preparing a uniform gel layer on the etching foil by immersion-pulling method; (4) preparation of ultra-high voltage anode foil, anodizing the etching foil after coating the gel layer at high voltage, and then annealing at high temperature. The ultra-high voltage anode foil prepared according to the present invention has a higher specific capacitance, and can also maintain a smaller loss factor tanδ.

The invention belongs to the technical field of silicon dioxide preparation, and relates to a preparation method of spherical porous silicon dioxide, which comprises the following steps: S1, preparing a mixed solution, namely preparing a template solution, namely dissolving 0.5 g of hexadecyl trimethyl ammonium bromide into 100ml of deionized water mixed solution, and stirring by using a stirring mechanism until the solution is clear; adjusting the alkaline environment: adding 1ml of ammonia water, and adjusting the pH value to 10-11; s2, silicon source hydrolysis: slowly dropwise adding 2ml of tetraethyl orthosilicate into the solution in the step S1, and then carrying out stirring reaction; s3, aging and centrifugal washing: aging: stopping stirring, and standing for 12 hours to stabilize the structure; centrifugal washing: centrifuging for 5 minutes at 8000rpm, and sequentially washing for 3 times by using ethanol and water to remove unreacted substances; the spherical silicon dioxide can be protected by a simple sol-gel method without using a complex auxiliary agent, the mesoporous size of the spherical silicon dioxide is relatively uniform, the supercritical carbon dioxide is adopted for drying in a drying box, the pore structure is kept complete, and the use effect is improved.