2743 results about "Gel method" patented technology

The present invention relates to a polymer nano-composite of the functional inorganic nano-particle with intermingle prepared by electrospinning method, and the use of the composite. The precursory sol of the functional inorganic nano-particle is prepared by the sol-gel method, and is mixed with the polymer solution to form spinning fluid, adding precursor of dopant if necessary, and then the mixed spinning fluid is sprayed on to the electric collecting board with the action of the electric field force by electrospinning method to obtain functional polymer nano-composite with intermingle. The equipment of the invention is simple, the operation is easy, the components, structure and characteristics of the composite is easy to control, the structure is stable, the inorganic nano-particle is dispersed uniformly. According to the difference of the functionality of the inorganic nano-particles, the composite can be used in conducting material, antistatic material, magnetic material, electrochromic material, photocatalysis and ecology environment material, antibiosis material and biomaterial.

The invention discloses a porous titanium dioxide / graphene composite material and a preparation method thereof. The preparation method comprises the steps of: adding aniline and graphene into a surfactant-containing protonic acid solution according to a certain ratio; preparing a nanometer polyaniline / graphene composite material through an in-situ polymerization method; preparing titanium dioxide sol by using a sol-gel method; adding 0.05-0.20g of nanometer polyaniline / graphene composite material into 50mL of sol, uniformly mixing; standing and aging the sol for 3-5 days; drying in a drying oven at the temperature of 60-120 DEG C; milling; calcining the obtained composite for 30 minutes -2 hours at the temperature of 200-550 DEG C; and removing the polyaniline, thereby obtaining the porous titanium dioxide / graphene composite material. According to the invention, the porous titanium dioxide / graphene is prepared by utilizing the nanometer polyaniline and the titanium dioxide is deposited on the graphene, so that the contact area of the titanium dioxide and pollutants is increased, the separating efficiency of photo-generated electrons and holes is improved and the photocatalytic efficiency is improved.

Methods of controlling flow through a subterranean formation may include providing a cement slurry, a colloidal silica, and an activator. The methods may include introducing the cement slurry, the colloidal silica, and the activator into a portion of a well bore that penetrates a subterranean formation The methods may include allowing the cement slurry, colloidal silica, and activator to remain static.

The invention discloses a graphene-containing insulated radiating composition and preparation and application thereof. The composition comprises the components of silica-coating graphene, insulated heat-conducting filler, a surface treating agent, and a function additive. The preparation method comprises the following steps of: hydrolyzing ethyl silicate on the graphene surface by the sol-gel method to obtain graphene coated with a silica film on the surface; adding the surface treating agent to a mixture of the insulated heat-conducting filler and modified graphene; uniformly agitating; then adding the function additive; and uniformly dispersing to obtain the insulated radiating composition. The composition has the advantages that the graphene is processed by insulating and coating, and the insulated heat-conducting filler and additive of other forms are coordinately added, thus the composition shows high radiating improvement effect in the plastic cement and coating fields; and the composition can be widely applied to a heating element and a radiating facility of various electronic products and electrical equipment, and can greatly improve the radiating effect as well as prolong the service life of devices.

The invention discloses an organic-inorganic hybrid super-hydrophilic coating as well as a preparation method and an application thereof. The preparation method comprises: firstly carrying out hydrolysis condensation polymerization by a sol-gel method with ethyl orthosilicate used as a precursor, hydrochloric acid used as a catalyst, ethanol used as a solvent, a silane coupling agent used as a modifier and a proper amount of water to obtain a modified silica sol, then carrying out free radical polymerization on the modified silica sol and reactive hydrophilic monomers to obtain an organic-inorganic hybrid material, and carrying out solvent replacement to obtain an aqueous organic-inorganic hybrid super-hydrophilic coating. The coating is coated on plastics, glass or metal substrates through dipping or brushing to form a coating layer, the coating layer has a contact angle with water less than 5 degrees, the adhesion force with the substrates of level-0 and the hardness greater than 6H, and water drops can spread out quickly on the coating layer.

The invention relates to an acid-resistant magnetic chitosan microsphere adsorbent as well as a preparation method and the application thereof, and in particular relates to acid-resistant magnetic chitosan microspheres which have the excellent absorption performance and recycling performance for acid waste water containing hexavalent chromium, a preparation method of the acid-resistant magnetic chitosan microspheres and the application of the acid-resistant magnetic chitosan microspheres. The preparation method of the acid-resistant magnetic chitosan microspheres comprises the following steps: (1) preparing Fe3O4 nano-particles modified by citric acid by using a coprecipitation method; (2) preparing single-coated magnetic SiO2 nano-particles by using a sodium silicate hydrolysis method or a sol-gel method; and (3) preparing the chitosan microspheres coated with magnetic SiO2 by taking chitosan powder as a raw material by adopting an emulsion crosslinking method. Furthermore, in order to further improve the adsorbing capacity of the microspheres, in the method, dendritic polyethylene imine is taken as a functional group for modifying the adsorbent, so that the modified chitosan microspheres can be obtained. The magnetic chitosan microspheres prepared by adopting the method not only have the excellent acid resistance, but also have the good absorption performance on Cr (VI) ions.

The present invention relates to nano mesoporous and mesoporous-macroporous biological glass produced and through surfactant self-assembling and sol-gel process under mild reaction condition and possessing excellent bioactivity. The new type of biological glass has controllable mesoporous structure, homogeneous and adjustable mesopore distribution, relatively great specific surface area and porosity, macropores with adjustable size and porosity, and controllable shape. The present invention may be used as bone repairing material, dental material and rack material in tissue engineering and for medicine embedding and controlling releasing, etc.

The invention relates to an anode material composed by doping phosphate iron and lithium active substance and carbon and used for the secondary lithium battery and a manufacturing method thereof. The invention is characterized in that the general expression of the active substance is Li<3+Y>Fe<2-X>Mex(PO4)3(Me = Ti, Sc, Ge, Al, Zr, Mn, Hf, Nb, Ta, Mo, W, Ru, Ag, Sn, and Pb, etc.); the characteristic in preparation is that the raw material is synthesized into the crystal state of Li<3+Y>Fe<2-X>Mex(PO4)3 through a solid reaction, an hydrothermal method and a sol-gel method in a proper proportion. Then the prepared powder and the carbon is grinded and mixed through a planetary ball mill to obtain the anode material Li<3+Y>Fe<2-X>Mex(PO4)3 / C The specific capacity of the anode material can be up to 122mAhg<-1> (charging and discharging at the rate of C / 20) and 100mAhg<-1> (charging and discharging at the rate of C / 2); furthermore, the material has a good circulation performance and retentivity of specific capacity, thus providing a favorable anode material for the practicality of the secondary lithium ion battery.

The invention discloses a fiber mat, comprising 50-100 (weight ratio accounting for the dried fiber mat and the same below) glass fiber and chopped strands, and one or more of 0.1-30 inorganic fibers, 0.1-30 natural fibers, 0.1-30 synthetic fibers, 0.1-30 manmade fibers and an anti-radiation material besides the glass fibers and the chopped strands. The fiber mat is prepared by a needle punching method, a spun lacing method, a thermal rolling method, a wet type paper-manufacturing acid process, a wet type paper-manufacturing thickener method, a wet type paper-manufacturing gel method and the like. According to the preparation method for the fiber mat disclosed by the invention, the conductive thermal coefficient of a vacuum thermal insulation plate made of the fiber mat achieves 25-65% under the premise of adopting the same production mode, and a more superexcellent thermal insulation effect is obtained.

The invention discloses magnetic nanometer ion liquid composite particles as well as a preparation method and application of the magnetic nanometer ion liquid composite particles in removing pollutants in water bodies. The preparation method of the magnetic nanometer ion liquid composite particle comprises the following steps of: firstly synthesizing ferric oleate into magnetic Fe3O4 nanometer particles by taking ferric oleate as an iron source and adopting a chemical precipitation method; preparing nanometer nuclear shell type magnetic silicon dioxide with surface amino-functionalization by utilizing the nanometer magnetic particles as a kern, taking ethyl orthosilicate and a silane coupling agent as silicon sources, and utilizing a colloidal sol-gel method; and synthesizing a functionalized ion liquid by utilizing reaction between N, N-carbonyldimidazole (CDI) and an ion liquid containing carboxyl, and thus preparing the magnetic nanometer ion liquid composite particle by utilizing reaction between the functionalized ion liquid and amino on the surface of the magnetic nanometer silicon dioxide; and the method is used for removing pollutants in the water bodies. The method provided by the invention has the advantages that the operation is simple and convenient, the cost is low, the treatment process is simple, and the removal efficiency is high.

The gel method of printing variable information of the present invention involves applying inks onto a substrate that is part of or attached to a cylinder of the printing machine. Imaging is by means of an energy source in the UV, visible or infrared regions, modulated to represent a digital image pattern that has been composed on a computer. The consequence of imaging is to gel the ink and increase its adhesion to the substrate of the printing cylinder. The non-gelled background ink with lower adhesion is then removed by a squeegee action and returned to an ink reservoir. The remaining image is transferred to an offset blanket or directly to print stock by pressure. The process does not use a master, but produces an image that is erased after printing with each cylinder rotation so that the next rotation producing the next print can have fresh information written upon it.

The invention provides a composite material containing a perovskite structure oxide, a preparation method and application thereof. The composite material contains, by weight, 20%-99.99% of the perovskite structure oxide and 0.01%-80% of an oxygen ion conductor oxide. According to the invention, a sol-gel method can be employed to prepare the perovskite structure oxide, a combustion method can be employed to prepare the oxygen ion conductor oxide, and then the perovskite structure oxide and the oxygen ion conductor oxide can be mixed uniformly by means of ball milling or mechanical grinding, thus obtaining the composite material. The invention also relates to application of the composite material in solid oxide fuel cells and solid oxide electrolysis cells.

The invention relates to magnetic silicon dioxide microspheres with a nuclear shell and surface anisotropic double functional groups and a preparation method thereof. The preparation method comprises the following steps of: preparing superparamagetic microspheres by a solvothermal process; preparing magnetic microspheres which are coated by silicon dioxide by a sol-gel process; preparing the magnetic silicon dioxide microspheres of which the surface has amino group by taking the magnetic silicon dioxide microspheres as seeds and by the copolycondensation of alkyl ester orthosilicate and a silane coupling agent, and drying the magnetic silicon dioxide microspheres to obtain samples; and by a PICKERING emulsion technology, stabilizing a paraffin / aqueous emulsion system with a micrometer scale by using the aminated magnetic microspheres to form single-layer close packing of the magnetic microspheres on the surface of paraffin spheres, then reacting the amino group on the surface of the magnetic microspheres which is exposed in a liquid phase with succinic anhydride to introduce carboxyl into the partial surface of the microspheres, so that the surfaces of the magnetic microspheres have the anisotropic double functional groups. The obtained magnetic microspheres with the double functional groups have the advantages that: magnetic responsiveness is high; grain size can be controlled between 200 and 800 namometers; and the density of the surface functional groups can be adjusted.

The invention discloses Lyophobic and oleophylic micro nano-coatings applied to oil filtering dehydration and a preparation method thereof. Base material of the coatings is metal mesh grid with 50-1800 meshes, the surface of the metal mesh grid is coated with a layer of dense micro nano-coating which is dense thin film composed of nano silica global particles with partical size ranging from 90nm to 500nm.In the method of the invention, the sol-gel method is adopted, tetraethyl ester serves as the precursor, ammonia water serves as the catalyst, ethanol serves as the solvent, alkyl oxosilane serves as lyophobic modifier, the method of hydrolytie polycondensation is adopted to obtain lyophobic nano silica sol, the process of impregnation or spraying is adopted to coat the gel on the metal mesh grid with 50-1800 meshes, after thermal treatment, oil-water separation net with lyophobic and oleophylic properties is obtained. The method of the invention features simple process, no harm to the environment, no need of fluorine material, wide application to coalescing separator as a separation filter element and the function of filtration and dehydration of oil.

The invention provides a phase-change energy-storing wax microcapsule material used in the building field, which is characterized in that a capsule wall at the inner layer is made of tripolycyanamide modified urea resin and an outer layer is made of silicon dioxide, and the inner layer and the outer layer totally account for 20-45% of the total mass of a microcapsule; and a phase-change materials is an organic phase-change material and accounts for 80-55 percent of the total mass of the microcapsule. A core material is subjected to heat-conduction modification by adopting graphite, the surface of the microcapsule is modified by adopting a sol-gel method to ensure that the dual-layer microcapsule phase-change material used in the building field has better mechanical strength, heat conduction property and hot oxygen stability. The phase-change energy-storing wax microcapsule material provided by the invention has the advantages of low cost and wide source range of the raw materials; and the building wall body material with a self-temperature-regulating function is prepared by doping the phase-change microcapsule material into gypsum.

The invention relates to a preparation method of a composite material prepared by graphene oxide and magnetic mesoporous silica microspheres through chemical bonding interaction. The magnetic particles are prepared by a hydrothermal process; after acid ultrasonic treatment, the magnetic particles are firstly coated with a thin silicon oxide shell layer by a sol-gel method; after that, long-chain alkane is taken as a pore-forming agent, the magnetic particles are copolymerized with tetraethyl orthosilicate (TEOS) in the sol-gel reaction, and then the pore-forming agent is removed by thermal etching, so that the magnetic mesoporous silica particles with certain hydroxyl on the surfaces can be obtained; polyetherimide (PEI) surface modification is carried out on the magnetic mesoporous silica particles, and strong interaction between PEI and silicon hydroxyl is utilized; finally, the carboxyl on ethylene dichloride (EDC) activated graphene oxide reacts with amino on the PEI, so that the graphene oxide magnetic mesoporous silica composite material can be obtained. The preparation method is simple, convenient and controllable and is favorable for amplification preparation. The composite material has large specific surface area and good magnetic controllability, and can adsorb humic acid and heavy metal ions Pb (II) at the same time by virtue of surface groups.

The invention discloses technology of preparing aluminium oxide based continuous fibers by a sol-gel process, which is characterized by adding one or more organic acid containing 1-8 carbon atoms into distilled water, adding aluminum powder and a catalyst after the mixture is evenly mixed and ensuring the mixture to react under the conditions of continuous stirring and reflux condensation under certain temperature to obtain transparent aluminum carboxylate solution; evaporating redundant organic acid in the aluminum carboxylate solution and then adding a solvent, a silicon-containing additive and a given quantity of spinning assistants to obtain precursor solution of aluminium oxide based fibers; concentrating the solution to obtain precursor sol of spinnable aluminium oxide based fibers; spinning by a dry or wet method to obtain aluminium oxide based continuous precursor fibers containing organics; and drying and sintering the precursor fibers to obtain the aluminium oxide based fibers. The aluminium oxide based continuous fibers prepared by the technology can be used in reinforcement in the composite, further improve the strength, ductility and heat resistance of the material and are widely applied in the fields of aerospace, automobile and the like.

The invention discloses a graphene / inorganic semiconductor composite film and a preparation method thereof. The preparation method includes using graphene oxide or reducing graphene and inorganic semiconductor precursor as major raw materials, using a sol-gel method method or hydrothermal / solvent thermosynthesis method, using a function group on the surface of graphene as a nucleating point, and using the nucleating point to control size, shape and crystallization performance of an inorganic semiconductor to prepare an even composite film. Hydrogen bond, ion bond or covalent bond is formed by the prepared composite film using the function group on the surface of graphene with the inorganic semiconductor, dispersibility between graphene sheets is increased by the inorganic semiconductor, surface defects of graphene are compensated, conductivity and uniformity of graphene are increased, interface geometric contact and energy level matching of graphene and semiconductor nano-particles are improved, application range of a device is enlarged, and the graphene / inorganic semiconductor composite film is suitable for photoelectric fields of solar cells, sensors, OLEDs (organic light emitting diodes), touch screens and the like.

The invention relates to a manufacturing method for continuous direct spinning fine denier yarn by uhmwpe jelly method, belonging to the spinning area and solving the problem that the single yarn or yarn beam generated by prior technology is on the high side and bad uniformity so that the difficulty for stability of manufacturing and quality of subsequent product is enhanced and the applicable range is limited. The method is provided with reasonable and compact process flow, stable process control, skillful operation and improving the quality and uniformity of product. By the method continuous stable spinning in line is realized in process parameters and the production efficiency is improved. The labor cost and intensity are lessened. Because there is less turnover link in the middle of process it is favor of decreasing producing consumption and uncontrollable factors. Under the stable running, uhmwpe fine denier yarn or yarn beam with even and stable quality, and good performance is provided.

This invention relates to catalysts comprising a catalytic metal deposited on a composite support with well-dispersed chemical “anchor” species acting as nucleation centers for catalytic metal crystallites growth. The catalysts have the advantage that the average catalytic metal crystallite size can be controlled by the molar ratio of catalytic metal to chemical “anchor,” and is not limited by the porous structure of the support. A preferred embodiment comprises a cobalt-based catalyst on a silica-alumina support made by a co-gel method, wherein its average pore size can be controlled by the pH. The alumina species in the support most likely serve as chemical “anchors” to control the dispersion of cobalt species, such that the average cobalt crystallite size can be greater than the average pore size.

The invention discloses an aluminum-doped zinc oxide film coating and nano-rod array material as well as a preparation method thereof. The aluminum-doped zinc oxide film coating and nano-rod array material comprises the components based on the weight percentage: 95-99% of zinc oxide and 1-5% of aluminum-doped quantity. The preparation method adopts a sol-gel method, zinc acetate and aluminium nitrate are added with organic solvent according to the proportion for heating under reflux; the mixed solution is then added with certain quantity of stabilizing agent for water bath heating at certain temperature and added with organic reagents such as absolute ethyl alcohol, methanamide or methanol and the like to prepare sol according to the need; after that, a spin coating method is adopted to form a film, and the aluminum-doped zinc oxide nano film coating material can be obtained by the processes such as drying, pretreating, repeatedly spin coating, annealing, secondary annealing under the atmosphere of hydrogen and nitrogen and the like; then, a hydrothermal method is adopted for preparing highly oriented aluminum-doped zinc oxide nano-rod and array thereof. The invention has high utilization rate of the raw materials, low cost and simplified preparation technique, and can control the performance and the particle size of the material from the molecular design level.

The invention discloses a method for preparing a molecularly imprinted TiO2 / WO3 composite photocatalyst with visible light response through a direct method. The method is as follows: a titanium alkoxide is used as a sol and functional monomer precursor, an organic pollutant is used as a template molecule, absolute alcohol is used as a solvent, glacial acetic acid is used as an inhibitor, a sol-gel method is adopted, and the materials are prepared according to a certain ratio, wherein the molar ratio of the template molecule to Ti is 1:20-1:10, and the titanium alkoxide, absolute alcohol, glacial acetic acid and water are mixed in a volume ratio of 10:19:8:4. The method has the following technical effect: the titanium alkoxide has double functions, namely the titanium alkoxide can be used as a titanium source and can also be used as a functional monomer in the hydrolysis process. Other organic functional monomers are not required.

The invention discloses a meso-porous silicon nano-drug carrier with both reduction responsiveness and targeting ability and a preparation method thereof. Firstly, meso-porous silicon nano-particles are prepared with a sol-gel method, and are developed into a nanometer reservoir of drug molecules; then a disulfide bond is introduced into the surface of the meso-porous silicon nanometer reservoir with a simple chemical modification method and is used as a cohesive tie; secondarily, a biocompatible natural extracellular matrix-collagen molecule is creatively fixed to the surface of the meso-porous silicon nanometer reservoir and is developed into a nanometer encapsulator of the meso-porous silicon nanometer reservoir; and finally a lactobionic acid molecule is modified to the surface of a meso-porous silicon / collagen nanometer compounding system and is used as a specificity receptor of a liver cancer cell membrane surface receptor (ASGP-R) so as to construct a meso-porous silicon / collagen-lactobionic acid multifunctional compound type nano-drug carrier system with both cell specificity targeting ability and reducing substance / enzyme responsiveness.

The present invention pertains to a method for preparation of superhydrophobic timber on the basis of a sol-gel method, and the method is as follows: (1), silica sol synthesis, to be more specific, materials are prepared in the volume ratio of ammonia to anhydrous ethanol to ethyl orthosilicate of 1:15 to 17:1; (2), hydrophobic modification of monodispersed nano silica sol, to be more specific, hexadecyl trimethoxysilane, or triethoxysilane-1H, 1H, 2H, 2H-heptadecafluorodecyl silane is used for hydrophobic modification of the synthesized monodispersed nano silica sol, and the hydrophobic agent promotes mutual aggregation of nanoparticles to promote the formation of aggregates of silica nanoparticles; and (3) timber coating processing, to be more specific, the timber surface is coated with the hydrophobically modified silica sol solution by dipping or spraying process. Contact angles of the processed timber surface and water droplets are greater than 150 degrees, roll angles are less than 10 degrees, and a superhydrophobic film has good resistance to acid and alkali erosion and stability in high-humidity environment. The method is simple in operation, less demanding on equipment, and capable of scale production, and has wide market prospects.

The invention relates to a recoverable TiO2-SiO2 composite aero-gel photo-catalyst as well as the preparation method thereof. The invention is characterized in that the sol-gel method is firstly utilized for respectively preparing TiO2 sol and SiO2 sol, then the two are mixed according to a certain proportion to obtain a mixed sol, and then TiO2-SiO2 composite alcogel is obtained through polycondensation reaction; the TiO2-SiO2 composite alcogel is used for preparing TiO2-SiO2 composite aero-gel after drying, and the composite aerogel is used for obtaining composite aero-gel aggregates after baking for 6 to 8 hours. The pore size of the obtained composite aero-gel aggregates is distributed between 2.5 nm to 10 nm, and the particle diameter is distributed between 10 nm to 15 nm, while the particle diameter of the aggregates is distributed between 0.1 mm and 0.3 mm. Compared with the prior art, the TiO2-SiO2 composite aero-gel photo-catalyst has the advantages that the prepared TiO2-SiO2 composite aero-gel has large specific surface area, high porosity, uniform pore distribution, etc., wherein, TiO2 is in the anatase crystal form. Compared with the TiO2 nanometer powder absorbent, the photo catalytic activity of the TiO2-SiO2 composite aero-gel is higher, the photo catalytic efficiency is better, and the regeneration and the reuse of the composite aero-gel are convenient as the particles of the aero-gel aggregates are larger, thereby the recoverable TiO2-SiO2 composite aero-gel photo-catalyst is widely applicable to the treatment of a great amount of wastewater.

The invention belongs to the technical field of superhydrophobic materials, and particularly relates to a preparation method of a highly transparent wear-resistant superhydrophobic composite coating. Surface-modified nano-silica powder prepared by a sol-gel method is dispersed in anhydrous ethanol to obtain a superhydrophobic coating solution. The surface of a substrate of stone, metal, glass and the like is coated with reactive-diluent-modified E-51 epoxy resin glue, standing is carried out for 1 to 2 hours at room temperature, the superhydrophobic coating solution is used for brushing to obtain the highly transparent wear-resistant superhydrophobic coating. The contact angle between the coating and water is 165 to 175 DEG, a rolling angle is 2 to 5 DEG, the light transmittance of coating glass in the 500 to 650nm is greater than 84%, and at pressure intensity of 2500 Pa, the contact angle between the coating and water is greater than 90 DEG after the coating is rubbed with 320-mesh sandpaper along a line. The preparation method of the coating is simple, environmentally friendly and low in cost, is suitable for the surface of glass, stone, ceramics, wood, metal and the like, and has a wide application prospect.

The invention discloses a method for preparing a BiVO4 film with photocatalysis performance by using a sol-gel method. The method comprises the following steps of: respectively preparing a precursor solution A and a precursor solution B by taking bismuth nitrate pentahydrate (Bi(NO3)3.5H2O) and ammonium metavanadate (NH4VO3) as raw materials and taking citric acid as a solvent, preparing BiVO4 sol by mixing the precursor solution A with the precursor solution B; and coating the BiVO4 sol to a treated FTO (Fluorine-doped Tin Oxide) glass substrate surface in a spinning manner by adopting a spin coating method so as to form a film, and carrying out pre-annealing and annealing treatment on the film formed after spin coating, thereby obtaining the BiVO4 film fixed on the FTO glass substrate surface. According to the method for preparing the BiVO4 film with the photocatalysis performance by using the sol-gel method, the pure-monoclinic-phase BiVO4 film is prepared by combing the sol-gel method with the spin coating method, the prepared BiVO4 film has certain photocatalysis activity under visible light irradiation, meanwhile, the problem of immobilization of a BiVO4 photocatalyst is solved, and then, the separation, recovery and reuse of the BiVO4 photocatalyst are realized.

The invention relates to a manganese-based low-temperature denitration catalyst taking TiO2-SiO2 as a carrier and a preparation method thereof, belonging to the field of environmental catalysis and environmental protection. According to the manganese-based low-temperature denitration catalyst, a MnOx / TiO2-SiO2 catalyst is prepared by adopting a sol-gel method, wherein the mass percentage of SiO2 in the composite carrier is 40-60%, and the mass ratio of Mn to Ti+Si is (0.5-1.0): 1. The manganese-based low-temperature denitration catalyst is characterized in that due to the addition of SiO2, the specific surface area of the carrier is greatly increased, and the dispersion and stability of active substances on the surface of the carrier are benefited; and the TiO2-SiO2 is taken as the composite carrier, so that the alkali metal poisoning resistance of the catalyst can be improved. An active ingredient is low in cost, is non-toxic and can have good denitration catalysis activity at a lower temperature, so that the catalyst is applicable to the denitration catalysis of NOx of a low-temperature environment of a cement kiln after dust removal.

The invention discloses sodium borosilicate glass doped with In2S3 quantum dots and a preparation method thereof. According to the sodium borosilicate glass doped with the In2S3 quantum dots, the In2S3 quantum dots are uniformly doped into sodium-borosilicate-based glass, and the sodium-borosilicate-based glass contains the following ingredients in percentage by mass: 5-15% of Na2O, 15-30% of B2O3 and 55-80% of SiO2; and the doped amount of the In2S3 quantum dots is 0.1-5.0% of the mass of the sodium-borosilicate-based glass. The sodium borosilicate glass doped with the In2S3 quantum dots is prepared in a manner that a sol-gel method is combined with atmosphere control, has excellent third-order nonlinear optical performance and heat stability, and has high light transmittance in visible-infrared regions, thereby being an important candidate material which is expected to produce high-speed full-light logic devices.