This invention discloses a hydrothermal preparation process for
sodium ferric pyrophosphate, comprising the following steps: S1, preparation of precursor
mixed solution: weigh
sodium source,
iron source,
phosphorus source, and
pyrophosphate source according to stoichiometric ratio, add complexing agent and pH buffer, and stir evenly to obtain precursor
mixed solution A; S2, complexation and stabilization treatment of
pyrophosphate: add complexing agent B to precursor
mixed solution A to form a stable pyrophosphate complex, obtaining precursor solution B; S3,
hydrothermal reaction: after
hydrothermal reaction, naturally cool to obtain hydrothermal product; S4, post-treatment:
centrifuge, wash, and dry the hydrothermal product to obtain
sodium ferric pyrophosphate precursor
powder; S5,
carbon coating and
calcination: calcine the sodium
ferric pyrophosphate precursor
powder and
carbon source at wet high temperature to obtain carbon-coated sodium
ferric pyrophosphate material. This invention features high
crystallinity, high compaction density, strong process feasibility, and excellent comprehensive performance.