The invention provides an aluminum-ion battery using MoS2 as a positive electrode material and a preparation method of the battery, belongs to the technical field of batteries, can be widely applied to the fields of electronic industry and communications industry, and also can be taken as a power battery for an electric automobile. The aluminum-ion battery comprises a positive electrode active material, a negative electrode, a diaphragm material, a molten aluminum ion electrolyte solution and an electrolytic tank, wherein the positive electrode active material is MoS2, the negative electrode is a high-purity aluminum sheet, and the molten aluminum ion electrolyte solution is non-aqueous electrolyte solution containing Al3<+> ions. According to the aluminum-ion battery using the MoS2 as the positive electrode material and the preparation method of the battery, a provided aluminum-ion storage battery can be repeatedly charged and discharged, and has high capacity, high charging and discharging efficiency, good circulation stability and excellent charging and discharging features; in addition, the electrode material source is wide, the preparation method is easy, the cost is low, and the battery is green and environment-friendly and is low in price.