177 results about "Aluminum nitrate" patented technology

The invention provides titanium-containing anhydrous stemming for a blast furnace and a preparation method of the titanium-containing anhydrous stemming, and belongs to the technical field of refractory materials for the blast furnace. The titanium-containing anhydrous stemming for the blast furnace comprises the following raw materials: 40-60 parts of titanium corundum, 5-15 parts of silicon carbide, 10-20 parts of ferro-silicon nitride fine powder, 5-15 parts of titanium dioxide fine powder, 5-15 parts of vanadium-titanium slag fine powder, 5-10 parts of coke fine powder, 1-5 parts of monatomic silicon fine powder, 1-5 parts of ball clay micro powder, 1-5 parts of aluminum nitrate micro powder and 1-2 parts of magnesium alon micro powder. Gas-phase substances of Si (g), Al (g) and Mg (g) can be formed in the stemming at high temperature by the monatomic silicon fine powder and the MgAlON micro powder in the raw materials and react with CO and N2 in the environment to generate ceramic whiskers such as SiC, Si3N4, AlN and MgAl2O4, and the generated ceramic whiskers are distributed in a staggered manner and are filled in pores of the stemming, so that the high-temperature strength and the volume stability of the stemming are remarkably improved.

The invention relates to the technical field of agriculture, in particular to a plant nutrient solution for saline-alkali soil improvement and a preparation method thereof. The invention relates to a preparation method of a plant nutrient solution for improving saline-alkali soil. The preparation method comprises the following steps: preparing NO3-intercalated layered double hydroxides and acid modified calcium-based montmorillonite; preparing humic acid chelated calcium magnesium powder; preparing a binary compound; and preparing the plant nutrient solution. The preparation method comprises the following steps: preparing NO3-intercalated layered double hydroxides from calcium nitrate tetrahydrate and aluminum nitrate nonahydrate, carrying out acid modification on calcium-based montmorillonite by using dilute sulphuric acid, purifying humic acid, and mixing with calcium chloride and magnesium chloride hexahydrate to prepare humic acid chelated calcium magnesium powder. Finally, the three components are added into pig excrement fermentation liquor to prepare a plant nutrient solution, an adsorption-replacement-leaching closed loop can be formed, the desalination and alkali reduction efficiency is remarkably improved, the soil structure is improved, the effect of synergistically improving the saline-alkali soil is achieved, and therefore plant growth is promoted.

The invention relates to the field of lithium manganate positive electrode materials, in particular to a lithium manganate positive electrode material and a preparation method thereof, a positive electrode plate and a battery, which are used for solving the problems of Jahn-Teller distortion of Mn < 3 + >, Mn dissolution and low conductivity in circulation. Lithium carbonate, manganous-manganic oxide, potassium carbonate, aluminum nitrate and absolute ethyl alcohol are subjected to ball milling and then sintered to obtain K / Al co-doped lithium manganate powder, then the K / Al co-doped lithium manganate powder is coated with an acetylferrocene / diphenylamine polymer, finally, the K / Al co-doped lithium manganate powder is coated with an AlF3 (at) CeF3 suspension, and finally the lithium manganate positive electrode material is obtained. According to the lithium manganate positive electrode material, the electronic conductivity is greatly improved, the rate capability is improved, and the cycling stability is improved; and the material has excellent cycling stability and rate capability.

The invention discloses a catalyst for preparing trichlorosilane and a catalytic preparation method of trichlorosilane. The catalyst is prepared from the following components in percentage by mass: weighed copper nitrate, zinc nitrate, aluminum nitrate, lanthanum nitrate and the balance of a carrier, the preparation method comprises the following specific steps: S1, filling a catalyst; S2, purifying raw material gas; S3, reacting; and S4, separating and purifying a product, namely discharging a reacted gas product from an outlet of a reactor, and condensing through a condenser. In the prepared catalyst, the activity and selectivity of the catalyst are remarkably improved through the synergistic effect of the copper-zinc-aluminum composite oxide and the rare earth element lanthanum, the electronic structure and the surface acid-base property of the catalyst can be adjusted through doping of lanthanum, the reaction of silicon powder and hydrogen chloride is promoted, meanwhile, side reactions are inhibited, and the service life of the catalyst is prolonged. And the yield of trichlorosilane is improved.

The invention discloses a sensing material for detecting atmospheric carboxylic acid, a preparation method, a detection method and application, belongs to the technical field of environmental functional materials, and solves the problems that an existing method is complex in operation and cannot realize real-time online monitoring, the sensing material for detecting atmospheric carboxylic acid is an MOF-802-EDTA-Pt composite film, and the preparation method comprises the following steps: taking 1, 3, 4, 5-tetramethyl-1, 3, 5-tetramethyl-1, 3, 5-tetramethyl-1, 3, 5-tetramethyl-1, 3, 5-tetramethyl-1, 3, 5- The preparation method comprises the following steps: synthesizing an MOF-802 material through a hydrothermal reaction by taking 1, 3, 5-benzene tricarbonic acid (BTC) and aluminum nitrate as raw materials and ethylene diamine tetraacetic acid (Na-EDTA) as a ligand; the preparation method comprises the following steps: dispersing MOF-802 in DMF to form a coating solution, and forming a film on a glass substrate through a pulling method; and then loading platinum nanoparticles, and carrying out solvothermal reaction and vacuum drying to obtain the composite sensing film. The MOF-802-EDTA-Pt composite film has a porous structure and fluorescence characteristics, and detection is realized through a fluorescence quenching effect of carboxylic acid molecules and an MOF skeleton. The method disclosed by the invention is controllable in process and high in material stability, still keeps excellent selectivity under the coexistence condition of interferents such as CO2 and NO2, and is suitable for real-time monitoring of carboxylic acid pollutants in the atmospheric environment.

The invention provides a functional filler, a preparation method thereof, an inorganic thermal control coating and application, and belongs to the technical field of coatings. The preparation method of the functional filler comprises the following steps: by taking a zinc acetate aqueous solution as a raw material, adding indium nitrate and aluminum nitrate, stirring and dissolving, then sequentially adding a complexing agent and a stabilizer, heating in a water bath to form transparent gel, and finally sintering at high temperature. According to the preparation method, a sol-gel method and a high-temperature sintering process are adopted to dope an indium element and an aluminum element into zinc oxide to prepare indium-aluminum co-doped zinc oxide, and then the indium-aluminum co-doped zinc oxide is used as a functional filler to be added into inorganic silicate resin to prepare the inorganic thermal control coating. The aluminum element and the indium element can synergistically act to improve the temperature resistance of the coating, so that the inorganic silicate coating with protection and thermal control effects is obtained, can be used on the surface of a spacecraft and has good thermal control and temperature resistance effects.

The invention relates to the technical field of preparation methods of nano precursor powder, in particular to a synthesis method of Cr < 3 + > doped magnesium aluminum oxide nano powder, which comprises the following steps: weighing magnesium nitrate, aluminum nitrate and chromic nitrate according to the stoichiometric ratio of MgAl2-xO4: xCr < 3 + >; stirring and mixing the prepared magnesium nitrate solution, aluminum nitrate solution and chromic nitrate solution together to prepare a mixed solution I; ammonia water is dripped into the first mixed solution, then the first mixed solution dripped with the ammonia water is stirred and mixed, and a second mixed solution is prepared; pouring the mixed solution II into a high-pressure reaction kettle, and putting the high-pressure reaction kettle into a constant-temperature box for reaction to prepare a white precipitate; adding deionized water into the white precipitate for washing and precipitating, and centrifuging to obtain white precipitate powder; drying the white precipitate powder at a constant temperature; calcining the dried white precipitate powder to prepare nano precursor powder; the prepared nanometer precursor powder has the advantages of being high in purity and small in particle size.

The invention provides an aluminum-doped NiCoCe catalyst, a preparation method thereof and application of the aluminum-doped NiCoCe catalyst in low-temperature CO2 hydrogenation methane preparation reaction, the preparation method comprises the following steps: (1) dissolving nickel nitrate, cobalt nitrate, cerium nitrate, aluminum nitrate and an alkaline precipitator in deionized water, and fully stirring the solution at room temperature to obtain a solution A; (2) putting the solution A into a reaction kettle, and crystallizing the mother liquid at a constant temperature for a certain time to obtain a solid-liquid mixture B; (3) centrifuging and washing the solid-liquid mixture B in the step (2) to obtain a precipitate C; (4) drying the precipitate C in the step (3) to obtain a precursor D; and (5) reducing and passivating the precursor D in the step (4) to obtain the catalyst. The catalyst prepared by the invention effectively solves the problem of low CO2 conversion rate in low-temperature CO2 methanation reaction, lattice distortion is promoted by introducing the Al element, the migration ability of lattice oxygen is increased, and the formation of a large number of oxygen vacancies is beneficial to improving the oxidation-reduction property of the catalyst.

The invention discloses a Mo in-situ doped transition metal layered double hydroxide derivative catalyst. The Mo in-situ doped transition metal layered double hydroxide derivative catalyst is of a nanometer two-dimensional layered structure; nitrate, aluminum nitrate and molybdate are used as raw materials, and a series of nano flaky Mo-X / Al2O3 composite metal oxide catalysts with high activity, high selectivity and high stability are obtained through co-hydrothermal precipitation and one-step roasting reduction. The invention further discloses a preparation method and application of the Mo in-situ doped transition metal layered double hydroxide derivative catalyst. According to the invention, macromolecules in biomass or biomass waste can be effectively depolymerized and liquefied into high-calorific-value bio-oil, so that the effect of turning waste into wealth from oriented conversion of the waste into bio-fuel is realized, and meanwhile, the bidirectional positive effects of avoiding environmental pollution caused by direct emission of the biomass waste and realizing comprehensive utilization of resources are realized; and a path with more economic benefits is provided for conversion from biomass wastes to renewable energy sources.

The invention provides porous alumina ceramic and a preparation method thereof, and relates to the technical field of ceramic materials. The invention relates to a preparation method of porous alumina ceramic. The preparation method comprises the following steps: dispersing alpha-cellulose powder in deionized water to form a cellulose suspension; stirring to fully swell the cellulose and form uniform gel, and freeze-drying to obtain a template; dissolving aluminum nitrate hexahydrate, magnesium nitrate hexahydrate and yttrium nitrate hexahydrate in absolute ethyl alcohol to obtain a precursor solution; putting gamma-Al2O3 micro powder and ammonium fluoride into a ball milling tank, adding the precursor solution and a dispersing agent, adding zirconium oxide balls and absolute ethyl alcohol into the ball milling tank, and performing ball milling to obtain ceramic slurry; dipping a template into the ceramic slurry, and performing dipping treatment under a vacuum condition to form a composite green body; and sintering to obtain the porous alumina ceramic. According to the porous aluminum oxide ceramic, the process stability is improved, and the problem that the strength is sharply reduced when the porosity is too high is solved.

The invention relates to the technical field of etching solutions, and discloses a molybdenum-aluminum-niobium etching solution for a TFT-LCD (Thin Film Transistor Liquid Crystal Display), which comprises the following components in percentage by mass: 50 to 60 percent of phosphoric acid, 3 to 8 percent of nitric acid, 5 to 10 percent of glacial acetic acid, 1 to 5 percent of aluminum nitrate, 0.1 to 0.5 percent of diphenyl thiourea, 1 to 5 percent of etidronic acid, 3.0 to 5.0 percent of sodium hexametaphosphate, 0.1 to 0.2 percent of fatty alcohol-polyoxyethylene ether, 0.5 to 0.8 percent of amino trimethylene phosphonic acid and the balance of ultrapure water. The invention further discloses a preparation method of the molybdenum-aluminum-niobium etching solution. According to the invention, a phosphorus nitrate vinegar system, a composite additive, a novel corrosion inhibitor, a metal ion chelating agent and a surfactant matched with the etching liquid are adopted, so that the molybdenum-aluminum-niobium multi-layer composite metal film can be simultaneously etched at one time; the etching solution has the advantages of being uniform in etching, capable of inhibiting Mo / Nb etching, high in selectivity, controllable in etching rate, free of residues, long in service life, high in stability and the like.

This invention relates to a method for preparing carbon materials based on in-situ surface fluoride modification, comprising the following steps: ① dissolving carbon material powder, aluminum nitrate, and polyvinyl alcohol in anhydrous ethanol to obtain an aluminum nitrate solution; ② dissolving ammonium fluoride in a mixed solvent to obtain an ammonium fluoride solution; slowly adding the ammonium fluoride solution dropwise to the aluminum nitrate solution to carry out an in-situ AlF3 growth reaction to obtain a composite material precursor; ③ drying the composite material precursor and then calcining it using a programmed temperature rise method to solidify the coating layer, thereby obtaining the AlF3@C composite material. This invention also discloses the application of this carbon material. The preparation method of this invention is simple and low-cost, and can efficiently prepare AlF3@C composite materials. The obtained AlF3@C composite material, as a negative electrode material for potassium-ion or lithium-ion secondary batteries, can significantly improve a series of properties such as the initial coulombic efficiency, rate performance, cycle stability, and potassium ion diffusion kinetics of the battery.

This invention provides a method for preparing a tandem catalyst and its application in degrading organic matter in wastewater, belonging to the field of wastewater treatment technology. The tandem catalyst is prepared by co-precipitation of ferrous chloride, ferric chloride, and aluminum nitrate, followed by grinding and calcination with high-temperature kerosene and activated carbon. The tandem catalyst is then applied to degrade organic matter in wastewater. The tandem catalyst prepared by this invention comprises a hierarchical porous carbon support and a co-precipitate of iron(III) oxide and aluminum(III) oxide supported on the surface of the hierarchical porous carbon support. Using hierarchical porous carbon as the support and aluminum(III) oxide and iron(III) oxide in series as the catalyst facilitates the ozone decomposition of organic matter. The tandem catalyst of this invention can effectively degrade organic matter, achieving a degradation rate of over 95% for both total cyanide and ammonia nitrogen.

The invention provides a preparation method and application of a plasma-assisted catalyst for preparing methanol through CO2 hydrogenation, and belongs to the field of catalysts. Raw materials adopted by the method comprise biomass, metal salt and a precipitator, the molar ratio of the biomass to the metal salt is (0.05-1): 1, the biomass is one of chitosan, hyaluronic acid and alginic acid, and the metal salt is one or more of indium nitrate, cobalt nitrate, zirconium nitrate, zirconyl nitrate, titanium sulfate and aluminum nitrate; the catalyst is subjected to nitrogen doping and / or more oxygen vacancy metal interfaces are formed through combination of coprecipitation and plasma treatment, so that the carbon dioxide adsorption and activation capacity and the overall hydrogenation efficiency of the catalyst in the process of preparing methanol through carbon dioxide hydrogenation are effectively improved.

The present application relates to the technical field of catalyst production, in particular to a preparation method of a high-selectivity and high-stability methanol synthesis catalyst, comprising the following steps: step 1: dissolving zirconium nitrate, zinc nitrate and aluminum nitrate in water to form a zirconium-zinc-aluminum mixed salt solution A, dissolving zinc nitrate, aluminum nitrate and copper nitrate in water to form a copper-zinc-aluminum mixed salt solution B, dissolving sodium carbonate in water to form alkali solution C and alkali solution D; adding a small amount of alkali solution C into deionized water to form deionized water E; step 2: using the salt solution A, the alkali solution C and the deionized water E to form a precipitate 1, then using the salt solution B, the alkali solution D and the precipitate 1 to react to form a precipitate 2, then heating the precipitate 2, and aging the precipitate 2; step 3: after aging, filtering and washing the precipitate 2, drying the filter cake obtained by filtering, and then calcining and molding to obtain the methanol synthesis catalyst.

A kind of low agglomeration aluminum nitride powder preparation method, comprising the following steps: S1: 50-60 parts of aluminum nitrate nine water, 60-80 parts of film-forming solution and 20-30 parts of glucose monohydrate are mixed uniformly, after stirring 1-2h, it is poured into polytetrafluoroethylene dish at room temperature 25 ℃ and is stationary 4-6h, and crosslinked film is obtained;S2: the crosslinked film obtained in step S1 is burned at 300-400 ℃ for 30-40 min in argon environment, calcined at 800-900 ℃ for 1-2h in ammonia environment, then at 900-1000 ℃, heat preservation 1-2h, finally at 1200-1400 ℃, calcined 1-2h, and aluminum nitride powder is obtained.The low agglomeration spherical aluminum nitride powder machine preparation method of the application, the particle size of the prepared aluminum nitride powder is fine, the agglomeration rate is low, the conversion rate is high and the specific surface area is large.

The invention discloses a high-temperature-resistant electric insulation boron nitride coating and a preparation method thereof, and belongs to the technical field of high-temperature-resistant coatings, the boron nitride coating comprises the following raw materials by weight: 10-12 parts of large-particle-size boron nitride, 10-13 parts of small-particle-size boron nitride, 1.5-2 parts of boron oxide, 16-20 parts of mullite sol, 65-75 parts of water, 7-8 parts of an organic auxiliary agent, and 0.3-0.4 part of a wetting agent. 3.5 to 4.5 parts of a dispersing agent; 0.4 to 0.5 part of a defoaming agent; the preparation method of the mullite sol comprises the following steps: preparing an aluminum nitrate solution; preparing a mixed polyvinyl alcohol solution; preparing a first part of mullite sol; preparing a second part of mullite sol; the boron nitride coating disclosed by the invention has excellent adhesive ability and high temperature resistance, and is low in bonding temperature.

The invention discloses a water-based ink-jet coating liquid for a flexible packaging material and a preparation method of the water-based ink-jet coating liquid, and relates to the field of coating liquid preparation, the preparation method comprises the following steps: in a weak acid environment, performing surface modification treatment on aluminum oxide through aluminum nitrate to obtain surface modification slurry; preparing a solvent containing dimethylformamide a, carrying out polarity reduction mixing on the solvent and the surface modification slurry, and then adding a mixture containing silane to carry out an interface anchoring reaction, so as to obtain core-shell structure slurry; sequentially adding a film-forming polymer, dimethylformamide b and an auxiliary agent into the core-shell structure slurry, and carrying out a flexible pre-crosslinking reaction to form a pre-crosslinking coating liquid; and carrying out curing treatment on the pre-crosslinked coating liquid to obtain the water-based ink-jet coating liquid. The technical problems of slow ink absorption, image diffusion and poor adhesion in ink-jet printing of the flexible packaging base material are effectively solved, and unification of high image definition, quick drying, strong adhesion and high flexibility is realized.

The present application belongs to the field of combustible gas, and particularly relates to a composite catalyst, a preparation method thereof, and a method for preparing combustible gas. The preparation method of the composite catalyst comprises the following steps: dissolving humic acid in deionized water to obtain a humic acid aqueous solution, then adjusting the humic acid aqueous solution to be acidic, and finally adding ammonium bicarbonate, zinc chloride and aluminum nitrate into the humic acid aqueous solution and reacting for a period of time at a certain temperature to obtain a solution of the composite catalyst. The method for preparing combustible gas comprises the following steps: dissolving the above-mentioned solution of the composite catalyst in methanol to obtain a mixture, and gasifying the methanol reforming gas into combustible gas. After the composite catalyst aqueous solution and the methanol are mixed, the composite catalyst can be taken away by gasification while performing catalysis in the methanol reforming process, so that the problem of carbon deposition in the equipment is avoided, the efficient catalysis of the equipment is ensured, and the maintenance cost in the later period is reduced.

The invention relates to the field of refractory materials, in particular to a high-erosion-resistance refractory material based on boron nitride modification and a preparation method of the high-erosion-resistance refractory material. The problem that an existing refractory material is poor in erosion resistance is solved. The refractory material is prepared by taking zirconium dioxide, silicon dioxide, calcium oxide, ferric oxide and aluminum oxide as matrixes and adding samarium lanthanum magnesium aluminum composite gel powder and boron nitride loaded chromium sesquioxide, magnesium nitrate, aluminum nitrate, samarium nitrate, lanthanum nitrate and citric acid form gel, high-temperature treatment is performed to obtain the samarium lanthanum magnesium aluminum composite gel powder, and the samarium lanthanum magnesium aluminum composite gel powder is added to the boron nitride loaded chromium sesquioxide. Boron nitride is loaded with chromium sesquioxide after being treated by tannic acid, the corrosion resistance of the material is enhanced through the synergistic effect of all the components, and the material is suitable for high-temperature furnaces, high-temperature reactors and other industrial environments needing high-temperature resistance and high corrosion resistance.

The invention relates to the technical field of ceramic-based composite materials, and mainly relates to a high-strength porous ceramic and a preparation method thereof. The high-strength porous ceramic comprises the following components in parts by weight: 50-60 parts of aluminum oxide powder; 40-50 parts by weight of silicon carbide powder; 1-3 parts by weight of modified copper oxide particles; 1-5 parts by weight of aluminum nitrate; and 0.1 to 1 part by weight of polyvinylpyrrolidone. The preparation method comprises the following steps: preparing modified copper oxide particles and water into a suspension; mixing aluminum nitrate, polyvinylpyrrolidone and water to obtain a mixed solution; mixing the suspension, the mixed solution, alumina powder and silicon carbide powder to obtain a mixture; performing spray drying on the mixture to obtain mixed powder; pressing the mixed powder to obtain a green body; carrying out heat preservation on the green body at 450-550 DEG C for 1-3 hours to obtain a pre-sintered green body; and sintering the pre-sintered green body at high temperature to obtain the high-strength porous ceramic. The porous ceramic provided by the invention also has high strength on the premise of keeping relatively high porosity.

The present application relates to the technical field of welding material, in particular to a high-toughness gas shielded welding wire and a preparation method thereof.The welding wire comprises a low-carbon steel belt sheath and a flux cored powder, and the flux cored powder comprises reduced iron powder, manganese powder, carbonyl nickel powder, molybdenum powder, titanium powder, silicon powder, graphite powder, rutile titanium dioxide, calcium fluoride, potassium fluorotitanate and cerium-aluminum co-doped microparticle powder; the cerium-aluminum co-doped microparticle powder takes calcium-rich borosilicate as a core, is treated by isopropanol aluminum hydrolysis polycondensation sealing, aluminum oxide nanoparticle enhancement, aluminum nitrate-colloidal silicon dioxide bridging and cerium nitrate outer layer, and is prepared; the welding wire is suitable for high-strength steel thick plate multi-layer multi-pass gas shielded welding, can improve low-temperature impact toughness and refine inclusions while maintaining high deposited metal strength.

The invention discloses a preparation method of thermal shock resistant Nd: LuAG laser transparent ceramic. The preparation method comprises the following specific steps: weighing lutetium nitrate, aluminum nitrate and neodymium nitrate according to Lu3-xNdxAl5O12, and obtaining nano precursor powder by adopting a solvothermal method; carrying out two-step pre-sintering to form oxide powder with a sub-grain structure; and adding a thermal shock slow-release agent for main sintering, carrying out hot isostatic pressing treatment on the ceramic body after main sintering, and finally annealing in air to obtain the Nd: LuAG transparent ceramic with the density being greater than or equal to 99.9% and the thermal shock resistance temperature difference delta T being greater than or equal to 400 DEG C. The ceramics are particularly suitable for high repetition frequency laser systems.

The application discloses a kind of green repair upgrading regeneration technology of decommissioned lithium iron phosphate positive material, comprising the following steps: lithium salt and tea polyphenol are completely dissolved in solvent, to obtain reducing repairant solution;Decommissioned lithium iron phosphate positive material and direct reduction repairant solution are mixed, to obtain mixed suspension;The suspension is loaded into reaction kettle and placed in oven and heated and kept for a period of time, after cooling, precipitate is collected after washing;Precipitate is mixed with aluminum nitrate and diammonium hydrogen phosphate solution, after evaporating dry, add trace lithium salt under nitrogen atmosphere annealing, to obtain upgraded regeneration aluminum phosphate / lithium phosphate coated lithium iron phosphate positive material.The upgrading repair regeneration technology uses abundant natural green reducing repairant-tea polyphenol, and is environmentally friendly and can be recycled and reused;At the same time, the price of aluminum phosphate / lithium phosphate coating layer is low, and the electrochemical performance of lithium iron phosphate waste powder is obviously repaired and improved, which is suitable for industrialization and application.

The invention relates to the technical field of catalysts, in particular to a cerium oxide-aluminum oxide composite material as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing cerous nitrate, aluminum nitrate and water to obtain a mixed solution; the molar ratio of the cerium nitrate to the aluminum nitrate is 10: 1; and adding ammonia water into the mixed solution to carry out coprecipitation reaction, carrying out solid-liquid separation to obtain precursor powder, and calcining to obtain the cerium oxide-aluminum oxide composite material. By selecting raw materials and optimizing preparation steps and process parameters, the prepared catalyst has high activity. The high dispersion of Al2O3 on the carrier CeO2 and a proper crystal structure provide more effective active sites, so that the adsorption and conversion of reactant molecules are promoted. The cerium oxide-aluminum oxide composite material provided by the invention can be used as a catalyst to synergistically purify NOx and CVOCs, and has a matched reaction temperature window for oxidation of CVOCs and reduction of NOx.

This invention relates to the field of superhydrophobic composite coating technology, and discloses a method for preparing a SiO2-based bicovalent network superhydrophobic composite coating. This method uses tetraethoxysilane to synthesize silica nanoparticles to construct surface roughness, and utilizes the long fluorocarbon chain of perfluorooctyltriethoxysilane (POTS) to modify it with low surface energy. A silane coupling agent and aluminum nitrate are introduced to generate a Si-O-Si covalent network as molecular bridges and an Al-O-Al covalent network as a framework, respectively. An epoxy resin (EP) is used as a bonding layer to adhere the coating to a substrate. The SiO2-based bicovalent network superhydrophobic composite coating prepared by this method exhibits excellent superhydrophobicity, mechanical stability, chemical stability, and thermal stability, providing a simple manufacturing strategy for the industrial application of superhydrophobic materials.

The invention discloses a copper-based catalyst for synthesizing methanol from CO2 and a preparation method of the copper-based catalyst. The copper-based catalyst comprises the following components: a) sodium metaaluminate; b): hexadecyl trimethyl ammonium bromide; c): aluminum nitrate; d): zirconium nitrate; e): deionized water; f): aluminum sulfate; g): aluminum chloride; h): copper nitrate; according to the copper-based catalyst for synthesizing methanol from CO2 and the preparation method of the copper-based catalyst, zirconium-doped boehmite is prepared in advance and roasted to obtain zirconium-doped aluminum oxide with hierarchical pores, the zirconium-doped aluminum oxide serves as a carrier and is subjected to deposition and precipitation with the active component copper and zinc, and finally the catalyst which is high in activity and good in stability in the CO2 hydrogenation reaction is obtained. The zirconium-doped alumina carrier obtained by roasting zirconium-doped boehmite prepared in advance has hierarchical pores, high specific surface area, high-temperature stability and sintering resistance, is beneficial to uniform dispersion of copper-zinc active components, enhances the stability of the copper-zinc active components, inhibits migration and aggregation of the copper-zinc active components, and prolongs the service life of the catalyst.

The invention discloses a preparation method and application of an acid-base bifunctional magnesium-aluminum bimetallic oxide catalyst, and relates to the technical field of biomass catalytic conversion and heterogeneous catalytic materials.The preparation method comprises the steps that firstly, magnesium nitrate hexahydrate and aluminum nitrate nonahydrate are dissolved into a metal salt mixed solution; dropwise adding a sodium hydroxide aqueous solution into the metal salt mixed solution to obtain a turbid solution; heating and crystallizing in a water bath, transferring into a reaction kettle, and putting into a drying oven for hydrothermal crystallization. The method comprises the following steps: synthesizing a hydrotalcite-like precursor through a coprecipitation-hydrothermal coupling method, and carrying out high-temperature roasting to obtain the acid-base bifunctional composite metal oxide. The acid-base bifunctional composite metal oxide has the beneficial effects that the acid-base bifunctional composite metal oxide has a layered structure and a high specific surface area and is suitable for a biomass pyrolysis-catalytic reforming process, an alkaline site of the acid-base bifunctional composite metal oxide promotes a deoxidation reaction, an acidic site of the acid-base bifunctional composite metal oxide promotes an aromatization reaction, and the acid-base bifunctional composite metal oxide can effectively regulate and control the composition of biomass pyrolysis volatile components; the content of oxygen-containing compounds is obviously reduced, and the selectivity of monocyclic aromatic hydrocarbon is improved.

The invention discloses a preparation method and application of a bionic targeted three-dimensional porous cellulose microsphere heavy metal stabilizing agent, and the preparation method comprises the following steps: firstly, reacting ferric chloride hexahydrate with tannic acid to prepare TA-Fe; then, sodium carboxymethyl cellulose and TA-Fe are used as raw materials, and under the crosslinking action of aluminum nitrate, three-dimensional porous cellulose microspheres TA-Fe coated CMC with a metal-phenolic aldehyde network structure are prepared; and adding 4-(4, 6-dimethoxytriazine-2-yl)-4-methylmorpholine hydrochloride and aspartic acid, carrying out a stirring reaction, washing with deionized water, and carrying out freeze drying to obtain the final product. The preparation method is simple and convenient, the reaction condition is mild, and the raw material cellulose is green, environment-friendly and wide in source. The obtained stabilizing agent can efficiently, rapidly and selectively adsorb Pb, effectively reduces the bioavailability of Pb in soil, weakens the toxicity of Pb to plants, and can achieve a synergistic effect with a phytoremediation technology.

Provided is a separator used for a secondary battery. The separator may comprises a complex-containing layer which is provided on a surface in contact with a negative electrode of the secondary battery and which contains an electrolyte complex. The electrolyte complex may contain a nitrate and a coordination substance. The nitrate may include at least one selected from lithium nitrate, potassium nitrate, cesium nitrate, sodium nitrate, silver nitrate, calcium nitrate, zinc nitrate, copper nitrate, magnesium nitrate, indium nitrate, aluminum nitrate, ammonium nitrate, barium nitrate, and iron nitrate.