2460 results about "Sol-gel" patented technology

The invention discloses a high-strength and high-toughness aluminum nitride ceramic and a preparation method thereof, and relates to the technical field of ceramics, a sol-gel method is adopted to coat the surface of aluminum nitride with a stable shell layer to form a core-shell structure, meanwhile, the low lattice mismatch rate of a core-shell interface is utilized to reduce thermal resistance, and toughness and thermal conductivity are both considered; according to the external magnetic field tape casting method, the magnetic dipole moment orientation principle is utilized, an external magnetic field is applied in the tape casting stage, the in-plane mechanical property is improved, and the fracture toughness is improved through the magnetism of aluminum nitride whiskers; a reinforcement is introduced to improve the mechanical property and corrosion resistance of the aluminum nitride ceramic material, multi-granularity powder is compounded, large-particle aluminum nitride powder is used as a sintering and heat-conducting framework material, and high activity provided by submicron particles is utilized to promote sintering, so that the sintering temperature of aluminum nitride can be remarkably reduced, and the performance is greatly improved; and the aluminum nitride substrate expands more application fields on a future packaging circuit.

The invention relates to the technical field of sodium ion battery positive electrode materials, and provides a sodium ion battery layered high-entropy oxide positive electrode material, a preparation method thereof, a positive electrode plate and a sodium ion battery. The chemical general formula of the layered high-entropy oxide positive electrode material provided by the invention is NaxNiaMnbMcO2, wherein M is at least four of Li, Zn, Cu, Mg, Ca, Fe, Al, Co, Y, Ru, Ti, Ir, Sb, Te, Sn and Nb. The positive electrode material provided by the invention is good in structural stability, and can effectively inhibit phase change, so that the cycle stability is improved, and the electrochemical performance of sodium storage is enhanced. According to the invention, the precursor is obtained by adopting a sol-gel method, and then is sintered into a phase by adopting a solid-phase reaction method, so that the obtained positive electrode material is uniform in particle distribution and shows good structural stability, and the obtained positive electrode material is obviously superior to a material prepared by adopting a common high-temperature solid-phase method in the aspects of reversible capacity and electrochemical reversibility.

The invention relates to the field of composite materials, and particularly discloses high-entropy nano ceramic fiber reinforced silicon dioxide aerogel and a preparation method thereof. The high-entropy nano ceramic fiber is successfully prepared through the steps of preparation of a precursor spinning solution, electrostatic spinning, high-temperature cracking, a sol-gel method and the like, and the high-entropy nano ceramic fiber is compounded into silicon dioxide aerogel. According to the invention, high-entropy nano ceramic fibers are compounded in silicon dioxide aerogel. The high-entropy nano ceramic fiber not only can greatly improve the heat insulation property of the silicon dioxide aerogel at high temperature, but also can remarkably improve the mechanical properties such as toughness of the silicon dioxide aerogel, so that the application scene of the material can be widened.

The invention provides a high-porosity ceramic bond diamond micro-powder grinding tool and a preparation method and application thereof. The preparation method comprises the following steps: preparing ceramic bond diamond micro-powder composite powder by adopting a sol-gel method; the preparation method comprises the following steps: preparing porous agglomerated diamond microspheres by taking ceramic bond diamond micro-powder composite powder and an organic pore-forming agent as raw materials and adopting an atomization granulation method; the preparation method comprises the following steps: taking sodium alginate and calcium salt as raw materials, and preparing a calcium alginate water ball solution by adopting a multiple emulsion method and an atomization granulation method; the porous agglomerated diamond microspheres and the calcium alginate water balls are used as main raw materials, and a gel casting method is adopted for preparing the ceramic bond diamond micro-powder grinding tool. According to the diamond micro-powder grinding tool, the organic pore forming agent and the sodium alginate water balls are used as the pore forming agents, so that the particle size and proportion of pores in the prepared diamond micro-powder grinding tool can be accurately controlled, and the diamond micro-powder grinding tool has the characteristics of high porosity, good self-sharpening performance, low grinding resistance and the like and can be used for efficient and high-quality machining of semiconductor materials.

The invention provides an aerogel reinforced composite electrolyte thin film for a solid-state lithium battery and a preparation method of the aerogel reinforced composite electrolyte thin film, and belongs to the technical field of composite electrolytes.The thin film comprises a three-dimensional porous aerogel skeleton, a solid-state electrolyte compound and lithium salt nanocrystals; wherein the three-dimensional porous aerogel skeleton is prepared from inorganic oxide nanoparticles and a polymer precursor through a sol-gel method; pores of the three-dimensional porous aerogel skeleton are filled with the solid electrolyte compound, the solid electrolyte compound comprises lithium lanthanum zirconium oxide nanowires and a polyoxyethylene-lithium salt composite matrix, and the lithium lanthanum zirconium oxide nanowires are directionally arranged in the thickness direction of the film; the lithium salt nanocrystals grow on the surface of the pore wall of the three-dimensional porous aerogel in situ; the mass ratio of the aerogel skeleton to the solid electrolyte compound is (1: 3)-(1: 15). According to the thin film, the ionic conductivity, the mechanical strength and the interface stability of the electrolyte are remarkably improved.

The invention relates to the technical field of catalysts for gas purification, in particular to a hierarchical pore metal-based catalytic adsorbent as well as a preparation method and application thereof. The invention discloses an integrated preparation method combining a sol-gel method and a template method, which comprises the following steps of: adding a template agent before forming gel, adding a proper amount of ammonia water in an aging process, accurately controlling other reaction conditions and a raw material ratio, and controlling a spatial confinement effect of the template method and a chemical reaction in a sol-gel process to obtain a sol-gel composite material. The morphology and size of the catalytic adsorbent can be accurately regulated and controlled, the hierarchical pore metal-based catalytic adsorbent with a microporous structure as a main material and mesopores and macropores as coexistence is finally prepared, the hierarchical pore structure provides rich adsorption sites and catalytic activity centers, and the hierarchical pore metal-based catalytic adsorbent has high adsorption capacity, high selectivity, good catalytic activity, good stability and easy regeneration.

The invention relates to the field of coatings, and discloses an outer wall light radiation heat preservation and heat insulation decorative sheet and a preparation method thereof.A radiation refrigeration layer on the surface of the outer wall light radiation heat preservation and heat insulation decorative sheet comprises modified acrylate resin, silicon dioxide, ground calcium carbonate, talcum powder, modified hollow glass beads and auxiliaries; the modified acrylate resin is prepared by copolymerizing perfluorooctyl ethyl acrylate, methyl methacrylate, modified isocyano ethyl methacrylate and vinyltriethoxysilane, and the modified isocyano ethyl methacrylate is prepared by using salicylaldehyde and benzothiazole-2-formaldehyde as well as 1, 2, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator and using 2, 3, 4-trimethyl-1, 3-pentanediol monoisobutyrate as an initiator. The preparation method comprises the following steps: reacting amino groups at two ends of 1, 5-naphthylenediamine with DOPO, carrying out nucleophilic addition reaction with DOPO, and grafting with isocyano ethyl methacrylate. The modified hollow glass beads are prepared by using tetrabutyl titanate as a titanium source through a sol-gel method, and the prepared radiation refrigeration layer has the super-amphiphobic self-cleaning effect, the radiation refrigeration effect is good, and meanwhile the flame retardant property and the antibacterial effect are excellent.

The invention discloses a method for preparing nano barium titanate based on sol-gel synergistic hydrothermal reaction, which comprises the following steps: (1) dissolving barium acetate in an acetic acid aqueous solution to obtain a barium source solution; weighing tetrabutyl titanate according to the molar ratio of barium to titanium being greater than 1.25, and dissolving the tetrabutyl titanate in alcohol to obtain a titanium source solution; (2) uniformly mixing the barium source solution and the titanium source solution, preserving heat at 20-80 DEG C to obtain gel, drying and grinding to obtain white powder of the barium titanate precursor: (3) preparing a 2-4mol / L inorganic strong alkali aqueous solution, adding the white powder and a dispersing agent into the inorganic strong alkali aqueous solution, and fully stirring to obtain a barium titanate precursor suspension; and (4) transferring the barium titanate precursor suspension into a reaction kettle for hydrothermal reaction, and after the reaction is completed, washing, drying and grinding to obtain the nano barium titanate powder. The preparation method is low in cost, and the prepared nano barium titanate powder is uniform in distribution, spherical or sphere-like in morphology, small in particle size, 80-150nm in average particle size and good in particle crystallinity.

The invention discloses a lithium supplementing material and a preparation method thereof, and belongs to the technical field of lithium ion battery lithium supplementing materials. The lithium supplementing material has a spherical core-shell structure; the spherical core-shell structure sequentially comprises a lithium iron phosphate layer and a lithium-rich lithium ferrite layer from outside to inside. The lithium supplementing material is prepared by two steps: firstly, carrying out surface coating in a similar sol-gel mode to obtain a material precursor, and then carrying out heat treatment on the precursor to obtain the lithium iron phosphate coated lithium-rich lithium ferrite material; in the preparation process, tannic acid is introduced for modified coating, so that the lithium iron phosphate coated lithium-rich lithium ferrite material which is uniformly coated and has high lithium supplement efficiency, high stability and relatively high reversible capacity is obtained, and the prepared lithium supplement agent material shows excellent lithium supplement performance and charge-discharge performance in a lithium ion battery performance test. Meanwhile, the preparation method is simple to operate and beneficial to actual production.

The invention discloses a flexible PI heat-conducting insulating film pad and a preparation method thereof, and relates to the field of film pads. The preparation method comprises the following steps: preparing Fe3O4 magnetic heat-conducting core and SiO2 insulating shell composite nanoparticles by a sol-gel method, treating and grafting epoxy groups by a silane coupling agent, performing ring-opening addition with one end amino group of amino-terminated polydimethylsiloxane, and reacting the other end amino group with polyethylene glycol diglycidyl ether, so that two flexible long chains are grafted on SiO2. Due to the modified composite nanoparticles and the flexible long-chain structure, the flexibility of the film pad is remarkably improved; thermal vibration of silicon-oxygen bonds and ether bonds promotes heat transfer, a hydrogen bond network is formed with a PI substrate to improve dispersion stability, particles are orderly arranged under the action of a high-frequency magnetic field to construct a three-dimensional heat conduction network, and heat conduction efficiency is enhanced; the SiO2 isolates the inner core from conducting and improves the insulating property of the film pad by virtue of good insulativity and no free charge in the flexible long-chain polymer. The flexible PI heat-conducting insulating film pad prepared by the invention has the effects of flexibility, heat conduction and insulation.

The invention belongs to the technical field of catalytic oxidation of carbon-containing industrial waste gas, and particularly relates to a Pd catalyst for catalytic combustion of carbon-containing waste gas as well as a preparation method and application of the Pd catalyst. The invention provides a Pd catalyst for catalytic oxidation of carbon-containing industrial waste gas such as CO and volatile organic pollutants VOCs. The Pd catalyst is obtained by compounding an amorphous CeO2 nano-cluster with a TiO2 substrate (marked as cCeO2 / TiO2) and indirectly regulating the form of Pd through gradient regulation of the content of the amorphous CeO2 nano-cluster by a sol-gel method on the basis of strong interaction of Pd and Ce species. The Pd catalyst prepared by the invention shows excellent low ignition temperature, high performance and certain universality in the catalytic combustion process of carbon-containing industrial waste gases such as CO and low-chain VOCs (Volatile Organic Compounds). In addition, the method for preparing the Pd catalyst is simple to operate and mild in condition, and has great industrial application potential and value.

This invention belongs to the field of marine antifouling, and specifically relates to a transparent, self-lubricating organosilicon hybrid antifouling coating with a negatively charged surface and its preparation method. The antifouling coating is obtained by a sol-gel reaction of modified nanocellulose, hydroxy acid, and functional fluorine / siloxane monomers; the mass ratio of the hydroxy acid to the modified nanocellulose is 10–100:1; the mass ratio of the functional fluorine / siloxane monomer to the modified nanocellulose is 10–300:1. This invention, based on a multi-element green antifouling strategy, constructs a material surface with negative charge, self-lubrication, and low surface energy. The prepared antifouling coating exhibits excellent transparency, mechanical properties, and static antifouling performance. This antifouling coating is environmentally friendly and has broad application prospects in the field of marine antifouling.

The invention provides an aluminum-doped modified mixed sodium ferric phosphate positive electrode material and a preparation method thereof, and belongs to the technical field of sodium ion batteries. The chemical formula of the aluminum-doped modified mixed sodium ferric phosphate positive electrode material is Na < 4.4 > Fe < 3.4 > Al < 0.1 > (PO4) < 2.5 > (P2O7) / C. The aluminum-doped modified mixed sodium ferric phosphate positive electrode material is obtained by doping Al < 3 + > into NFPP through a sol-gel method and then carrying out high-temperature roasting. When the aluminum-doped modified mixed sodium ferric phosphate positive electrode material is used for a positive electrode of a sodium-ion battery, the initial capacity is high, excellent cycling stability and high rate performance are shown, and the reversible capacity is 133 mAh.g <-1 > under the current density of 0.2 C; under the current density of 20C, the capacity retention ratio is 99% after 500 cycles; and under the high current density of 50C, the capacity retention ratio is still 88% after 2500 cycles.

The invention relates to the technical field of titanium dioxide, and discloses a preparation process of oil paint core-coated titanium dioxide, which comprises the following steps: a core layer is rutile type titanium dioxide particles with the particle size range of 0.1-0.5 mu m and the specific surface area of 8-15m < 2 > / g, an inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5), the coating thickness is 5-15% of the diameter of the core layer, and the inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5). Wherein the silicon dioxide is coated by a hydrolytic deposition method, the aluminum oxide is coated by a sol-gel method, the organic coating layer comprises a copolymer containing a silane coupling agent and organic silicon resin, the organic silicon resin is methyl phenyl silicon resin, the organic coating layer accounts for 1-8% of the total mass of the titanium dioxide, and the surface contact angle of the organic coating layer is greater than or equal to 110 degrees. According to the preparation process of the oil paint core-coated titanium dioxide, an inorganic-organic gradient coating system is constructed, so that the core-coated titanium dioxide has a gloss retention rate of more than 95% (ASTM D523) and a delta E color difference of less than 1.5 (ISO 7724) after 1000 hours in a QUV accelerated aging test, and the weather resistance of the core-coated titanium dioxide is improved by more than 3 times compared with that of the traditional titanium dioxide.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention discloses light self-repairing concrete and a preparation method thereof, and relates to the technical field of concrete. The method comprises the following steps: firstly, efficiently packaging a calcium nitrate solution in hollow glass beads by utilizing a negative pressure impregnation technology; then growing a porous zeolite crystal coating on the surface of the microbead in situ by adopting a sol-gel method to form a self-repairing filler with a core-shell-hole gradient structure; when the concrete cracks to cause the cracking of the microbeads, the Ca < 2 + > in the cavity is quickly released, and the Ca < 2 + > adsorbed in the zeolite layer is gradually dissociated along with water permeation, so that the new microcracks are continuously repaired. Then, uniformly coating the surface and pores of the carboxymethyl cellulose hydrogel network with polydopamine in an in-situ oxidative polymerization manner to form composite hydrogel with photo-thermal responsiveness; lighting and heating to trigger dynamic coordination bond dissociation; meanwhile, heat drives rapid directional crystallization of a repair product by promoting the ion diffusion rate, and a compact mineralization layer is formed. The concrete prepared by the invention has the effects of light weight and self-repairing.

The invention relates to cerium dioxide and a preparation method and application thereof, and the preparation method of the sphere-like cerium dioxide comprises the following steps: (1) carrying out first mixing on cerium salt, doped metal salt, a solvent, inorganic acid and organic acid to obtain a first mixture; the doped metal salt comprises praseodymium salt and / or neodymium salt; (2) under a hydrothermal condition, carrying out second mixing on the first mixture, ammonia water and ammonium salt to obtain a second mixture with the pH value of 8-10, and carrying out sol-gel reaction to obtain sphere-like cerium dioxide sol; and (3) carrying out post-treatment on the sphere-like cerium dioxide sol to obtain the sphere-like cerium dioxide. According to the preparation method of the sphere-like cerium dioxide, provided by the invention, a mixing process and a reaction process of cerium salt and specific raw materials are designed, so that the sphere-like cerium dioxide with regular particle shape, good size uniformity and high purity and crystallinity is obtained.

The invention relates to the field of coating materials, and provides a high-wear-resistance stainless steel-based composite coating which is composed of dumbbell-shaped silver-doped silicon carbide, sea urchin-shaped titanium dioxide, 304 stainless steel powder, NiCrBSi nickel-based autolytic alloy powder and the like. The silver-doped silicon carbide is prepared through sol-gel, high-temperature carbonization and acid pickling, and the titanium dioxide filler is obtained through hydrothermal synthesis and calcination. Supersonic flame spraying deposition is adopted, the compactness and bonding strength are enhanced through laser remelting, and finally the wear resistance, the pollution resistance and the antibacterial performance are improved through vacuum annealing, mechanical polishing and hydrophobic coating modification. The design of dumbbell-shaped silver-doped silicon carbide and urchin-shaped titanium dioxide is adopted, high-wear-resistance, antibacterial and high-binding-force coating performance is achieved, the problems of wear resistance and bacteriostasis are solved, and the coating is suitable for the fields of cabinet door plates and the like.

The invention provides a chloride ion permeation resistant grouting material and application thereof. The chloride ion permeation resistant grouting material is prepared from the following raw materials in parts by weight: 35 to 40 parts of cement, 45 to 50 parts of quartz sand, 10 to 15 parts of admixture, 0.3 to 0.5 part of expanding agent, 0.1 to 0.3 part of early strength agent, 0.1 to 0.3 part of water reducing agent and 5 to 8 parts of SiO2 / carbon composite aerogel, the SiO2 / carbon composite aerogel is prepared by the following steps: carrying out sol-gel reaction on phenols, formaldehyde and an amino POSS derivative under the action of a catalyst, and drying, carbonizing and grinding the gel. The molar ratio of the phenols to the formaldehyde to the amino POSS derivative to the catalyst is 1: (2.5-4): (0.1-0.3): (0.1-0.3); the composite aerogel has excellent adsorption performance on chloride ions, is used together with a specific expanding agent to inhibit the self-constriction of the grouting material, and has the effects of remarkably improving the chloride ion penetration resistance and compensating the constriction of the grouting material.

The invention discloses a preparation method of a carbon-coated Na3V2 (PO4) 2F3 sodium-ion battery positive electrode material, relates to a preparation method of a sodium-ion battery positive electrode material, and aims to solve the technical problem of poor rate capability of a Na3V2 (PO4) 2F3 positive electrode material prepared by an existing sol-gel method. The method comprises the following steps: weighing sodium salt, a vanadium source, phosphate, villiaumite and a carbon source, treating at 90-95 DEG C by using a sol-gel method, and then cooling to 75-80 DEG C for treatment to obtain wet gel; and drying the wet gel, pre-sintering, and sintering at high temperature to obtain the carbon-coated Na3V2 (PO4) 2F3 sodium ion battery positive electrode material. The first-week capacity of the material is 124.46 mA / g, the capacity retention rate reaches 77.24% after 1000 times of circulation, and the capacity reaches 103.58 mA / g under the 30C multiplying power. The invention can be used in the field of sodium-ion batteries.

The invention discloses a preparation method of a photoresponsive self-cleaning optical coating with a dynamic self-repairing function. The preparation method comprises the following steps: adding a monomer containing a Diels-Alder reaction bond into a polyurethane prepolymer, and reacting to obtain the polyurethane elastomer with self-repairing capability. An azobenzene derivative is connected to a polyurethane elastomer through a covalent bond, and the photoresponsive self-repairing polymer is obtained. Hydrophobically modified TiO2 nanoparticles are prepared in situ through a sol-gel method. In order to further improve the dispersity of the TiO2 nanoparticles in the polymer, a silane coupling agent is adopted to carry out surface modification on the TiO2 nanoparticles. The preparation method comprises the following steps: mixing a photoresponsive self-repairing polymer and a TiO2 nanoparticle dispersion liquid in proportion, uniformly stirring, coating the mixed liquid on the surface of a base material, forming a uniform coating through a brush coating or spray coating method, and curing the coating at a proper temperature. Due to the excellent characteristics of light response self-repairing, ultraviolet resistance, wear resistance and the like, the coating can keep a long transparent period and good antifouling durability in an outdoor environment.

The invention relates to a multistage composite micro-nano particle with wide spectrum regulation and control performance and preparation and application thereof, the product comprises an inner core particle, an intermediate layer particle and an outer layer organic matter, the intermediate layer particle uniformly grows on the surface of the inner core particle and is coated by the outer layer organic matter; the preparation method comprises the following steps: firstly, pretreating the surfaces of inner core particles, then adding the pretreated inner core particles into a silane coupling agent solution for modification treatment to obtain silane coupling agent modified inner core particles, and finally forming intermediate layer nano-particles on the surfaces of the inner core particles by adopting a sol-gel method, a coprecipitation method, a hydrothermal method or an impregnation method to obtain the product. During application, the product and polymer master batches are uniformly mixed and dried, and then the fiber with the radiation refrigeration characteristic is prepared through a melt spinning process. The method is simple, and the product has a good radiation refrigeration effect; during application, the prepared fiber with the radiation refrigeration characteristic has the effects of dual regulation and control of solar radiation resistance and human body radiation refrigeration.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention discloses a neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material and a preparation method thereof, the chemical formula of the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material is Sr1-xNdxZr0. 2Fe11.8 O19, and x is more than or equal to 0.1 and less than or equal to 0.4. The method comprises the following steps: (1) mixing strontium nitrate, ferric nitrate nonahydrate, neodymium nitrate hexahydrate, zirconium nitrate pentahydrate, citric acid monohydrate and deionized water, stirring and dissolving to obtain sol; (2) adjusting the pH value of the sol to 6.5-7.5, and then heating to carry out sol-gel reaction to obtain wet gel; (3) drying and grinding the wet gel to obtain precursor powder; and (4) performing heat treatment on the precursor powder in a box-type furnace, cooling and grinding to obtain the neodymium-zirconium co-substituted M-type strontium ferrite wave-absorbing material. According to the material, effective wave-absorbing frequency band broadening is achieved, the matching thickness corresponding to the effective wave-absorbing bandwidth is as thin as 0.55-0.7 mm, and meanwhile, the performance requirements of thinness, width and strength in the field of electromagnetic compatibility are met.

The present invention relates to the field of battery materials, and provides a lithium manganate cathode material coated with lithium triborate and a preparation method thereof. The cathode material is a porous lithium manganate / lithium triborate composite electrode material, which includes porous lithium manganate with a highly connected directional columnar pore structure and a lithium triborate coating covering the pore surface, with a mass ratio of (86.0~92.0):(8.0~14.0), a coating thickness of 600~800 nm, a pore diameter of 45~95 μm, and a porosity of 65~78%. The preparation method includes: preparing a precursor colloidal solution by the sol-gel method, obtaining porous lithium manganate through low-temperature freezing molding and freeze-drying, and forming a cathode substrate through pre-oxidation and high-temperature sintering; subsequently, using vacuum-assisted impregnation, ultrasound, and nitrogen pressure to promote the penetration of the lithium triborate precursor solution, and forming a uniform coating layer through gradient drying and annealing treatment. The present invention significantly improves the crystal structure stability of the cathode material, inhibits manganese dissolution, improves the cycle life and rate performance, and has wide application value.

The invention relates to the field of coating materials, and provides an antiskid coating based on carbon fibers and a preparation method thereof. The coating is composed of a component A and a component B, the component A comprises KH-570 silane coupling agent surface modified carbon fibers, dog bone-shaped nano silicon dioxide, epoxy modified hydroxy acrylic resin, quartz sand antiskid aggregate, propylene glycol methyl ether acetate, iron oxide pigment and other auxiliaries, and the component B is an HDI tripolymer curing agent. The surface modified carbon fiber is prepared through the steps of cleaning and activating, silane coupling agent dipping, drying and curing and the like, and the dog bone-shaped nano silicon dioxide is prepared through a sol-gel method with hexadecyl trimethyl ammonium bromide and polyvinylpyrrolidone as morphology guiding agents. The preparation method comprises the steps of iron oxide color paste preparation, functional component dispersion, quartz sand addition, curing treatment, double-component mixing and curing and the like. The coating has excellent dry skid resistance, wet skid resistance, wear resistance and durability, and is suitable for the field of ground skid resistance coating.

The invention discloses a Janus cotton fabric with radiation refrigeration and antibacterial functions and a preparation method thereof.The preparation method creatively achieves multifunctional integration through multistage structural design and interface engineering and specifically comprises the steps that 1, a bionic silicon dioxide nano sheath layer grows on the surface of cotton fiber in situ through a controllable sol-gel method; the monodispersity of the nanoparticles is ensured by optimizing the ratio of the TEOS to the silane coupling agent; (2) introducing high-refractive-index nanoparticles to construct a dual-scale photonic crystal structure, and enhancing solar spectrum reflection by using a plasma resonance effect; (3) performing hydrophilic interface modification by adopting a biomacromolecule self-assembly technology to form a super-hydrophilic antibacterial layer; and (4) constructing a super-hydrophobic interface on the single side of the fabric through precise spraying, and finally forming a Janus structure with an asymmetric wetting gradient. The preparation process is mild in condition and high in controllability, and the obtained Janus fabric has excellent antibacterial performance (the antibacterial rate gt; 99.5%) and radiation refrigeration performance (daytime sub-environment temperature drop gt; 8 DEG C).

The invention relates to the technical field of catalyst materials, and particularly discloses a high-stability hydrogenation catalyst and a preparation method thereof. The invention relates to a preparation method of a high-stability hydrogenation catalyst, which comprises the following steps: preparing a hollow porous microsphere as an inner core from amino-terminated hyperbranched polyaryletherketone and polyvinyl alcohol, and then coating the porous microsphere with a mesoporous silicon dioxide intermediate layer by a sol-gel method; and finally, forming an Mg-Al hydrotalcite layer on the outermost side through a coprecipitation method, dipping and modifying with La (NO3) 3 and Ce (NO3) 3 solutions to obtain a catalyst carrier, dipping the catalyst carrier in an active metal dipping solution, and drying to obtain the catalyst. The high-stability hydrogenation catalyst provided by the invention has excellent mechanical properties and more reaction active sites, has high catalytic activity and catalytic efficiency, and is relatively long in catalytic life.

The invention discloses a sodium ferric pyrophosphate material with a sodium storage dominant crystal face regulated and controlled by cation doping as well as a preparation method and application of the sodium ferric pyrophosphate material. The chemical formula of the prepared sodium ferric pyrophosphate material with the regulated and controlled crystal structure is Na < 4 > Fe < 2.97 > M < 0.03 > (PO4) < 2 > P < 2 > O < 7 >. Wherein M = Sr, or Sr and a second doping element, and the second doping element is selected from one of Cd, Bi, Mo, Ni and Al. The material is prepared by adopting a sol-gel method, an iron source, a chelating agent, a sodium source, a phosphorus source and doping elements are dissolved in deionized water, and stirring is performed until a gel state is formed; and drying and calcining twice to obtain a final product. The sodium ferric pyrophosphate electrode material prepared by the invention has more sodium storage dominant crystal faces, shows good electrochemical performance, has the advantages of simple preparation process, easily available raw materials and low cost, has remarkable industrial application value, and is easy for large-scale production.

The invention discloses a lead zirconate titanate film material with an ultrahigh voltage coefficient as well as a preparation method and application of the lead zirconate titanate film material, and belongs to the technical field of electronic material development and film materials. The preparation of the lead zirconate titanate film material is realized by adopting a sol-gel spin-coating method and controlling the annealing times. The piezoelectric film material provided by the invention can be directly deposited on a Si substrate coated with metal Pt, does not need to introduce an additional buffer layer or dope any element, is short in annealing time and simple in preparation process, all required raw materials are cheap and easy to obtain, and the piezoelectric film material particularly has high orientation degree, low coercive voltage and excellent ferroelectric and piezoelectric properties, is suitable for preparing large-size (2-4 inches) wafers, and has a wide application prospect. And huge application potential is shown in the field of piezoelectric micro-electro-mechanical system (MEMS) devices.