1584 results about "Sol-gel" patented technology

The invention discloses a high-strength and high-toughness aluminum nitride ceramic and a preparation method thereof, and relates to the technical field of ceramics, a sol-gel method is adopted to coat the surface of aluminum nitride with a stable shell layer to form a core-shell structure, meanwhile, the low lattice mismatch rate of a core-shell interface is utilized to reduce thermal resistance, and toughness and thermal conductivity are both considered; according to the external magnetic field tape casting method, the magnetic dipole moment orientation principle is utilized, an external magnetic field is applied in the tape casting stage, the in-plane mechanical property is improved, and the fracture toughness is improved through the magnetism of aluminum nitride whiskers; a reinforcement is introduced to improve the mechanical property and corrosion resistance of the aluminum nitride ceramic material, multi-granularity powder is compounded, large-particle aluminum nitride powder is used as a sintering and heat-conducting framework material, and high activity provided by submicron particles is utilized to promote sintering, so that the sintering temperature of aluminum nitride can be remarkably reduced, and the performance is greatly improved; and the aluminum nitride substrate expands more application fields on a future packaging circuit.

The invention provides an aerogel reinforced composite electrolyte thin film for a solid-state lithium battery and a preparation method of the aerogel reinforced composite electrolyte thin film, and belongs to the technical field of composite electrolytes.The thin film comprises a three-dimensional porous aerogel skeleton, a solid-state electrolyte compound and lithium salt nanocrystals; wherein the three-dimensional porous aerogel skeleton is prepared from inorganic oxide nanoparticles and a polymer precursor through a sol-gel method; pores of the three-dimensional porous aerogel skeleton are filled with the solid electrolyte compound, the solid electrolyte compound comprises lithium lanthanum zirconium oxide nanowires and a polyoxyethylene-lithium salt composite matrix, and the lithium lanthanum zirconium oxide nanowires are directionally arranged in the thickness direction of the film; the lithium salt nanocrystals grow on the surface of the pore wall of the three-dimensional porous aerogel in situ; the mass ratio of the aerogel skeleton to the solid electrolyte compound is (1: 3)-(1: 15). According to the thin film, the ionic conductivity, the mechanical strength and the interface stability of the electrolyte are remarkably improved.

The invention discloses a method for preparing nano barium titanate based on sol-gel synergistic hydrothermal reaction, which comprises the following steps: (1) dissolving barium acetate in an acetic acid aqueous solution to obtain a barium source solution; weighing tetrabutyl titanate according to the molar ratio of barium to titanium being greater than 1.25, and dissolving the tetrabutyl titanate in alcohol to obtain a titanium source solution; (2) uniformly mixing the barium source solution and the titanium source solution, preserving heat at 20-80 DEG C to obtain gel, drying and grinding to obtain white powder of the barium titanate precursor: (3) preparing a 2-4mol / L inorganic strong alkali aqueous solution, adding the white powder and a dispersing agent into the inorganic strong alkali aqueous solution, and fully stirring to obtain a barium titanate precursor suspension; and (4) transferring the barium titanate precursor suspension into a reaction kettle for hydrothermal reaction, and after the reaction is completed, washing, drying and grinding to obtain the nano barium titanate powder. The preparation method is low in cost, and the prepared nano barium titanate powder is uniform in distribution, spherical or sphere-like in morphology, small in particle size, 80-150nm in average particle size and good in particle crystallinity.

The invention discloses a flexible PI heat-conducting insulating film pad and a preparation method thereof, and relates to the field of film pads. The preparation method comprises the following steps: preparing Fe3O4 magnetic heat-conducting core and SiO2 insulating shell composite nanoparticles by a sol-gel method, treating and grafting epoxy groups by a silane coupling agent, performing ring-opening addition with one end amino group of amino-terminated polydimethylsiloxane, and reacting the other end amino group with polyethylene glycol diglycidyl ether, so that two flexible long chains are grafted on SiO2. Due to the modified composite nanoparticles and the flexible long-chain structure, the flexibility of the film pad is remarkably improved; thermal vibration of silicon-oxygen bonds and ether bonds promotes heat transfer, a hydrogen bond network is formed with a PI substrate to improve dispersion stability, particles are orderly arranged under the action of a high-frequency magnetic field to construct a three-dimensional heat conduction network, and heat conduction efficiency is enhanced; the SiO2 isolates the inner core from conducting and improves the insulating property of the film pad by virtue of good insulativity and no free charge in the flexible long-chain polymer. The flexible PI heat-conducting insulating film pad prepared by the invention has the effects of flexibility, heat conduction and insulation.

The invention belongs to the technical field of catalytic oxidation of carbon-containing industrial waste gas, and particularly relates to a Pd catalyst for catalytic combustion of carbon-containing waste gas as well as a preparation method and application of the Pd catalyst. The invention provides a Pd catalyst for catalytic oxidation of carbon-containing industrial waste gas such as CO and volatile organic pollutants VOCs. The Pd catalyst is obtained by compounding an amorphous CeO2 nano-cluster with a TiO2 substrate (marked as cCeO2 / TiO2) and indirectly regulating the form of Pd through gradient regulation of the content of the amorphous CeO2 nano-cluster by a sol-gel method on the basis of strong interaction of Pd and Ce species. The Pd catalyst prepared by the invention shows excellent low ignition temperature, high performance and certain universality in the catalytic combustion process of carbon-containing industrial waste gases such as CO and low-chain VOCs (Volatile Organic Compounds). In addition, the method for preparing the Pd catalyst is simple to operate and mild in condition, and has great industrial application potential and value.

This invention belongs to the field of marine antifouling, and specifically relates to a transparent, self-lubricating organosilicon hybrid antifouling coating with a negatively charged surface and its preparation method. The antifouling coating is obtained by a sol-gel reaction of modified nanocellulose, hydroxy acid, and functional fluorine / siloxane monomers; the mass ratio of the hydroxy acid to the modified nanocellulose is 10–100:1; the mass ratio of the functional fluorine / siloxane monomer to the modified nanocellulose is 10–300:1. This invention, based on a multi-element green antifouling strategy, constructs a material surface with negative charge, self-lubrication, and low surface energy. The prepared antifouling coating exhibits excellent transparency, mechanical properties, and static antifouling performance. This antifouling coating is environmentally friendly and has broad application prospects in the field of marine antifouling.

The invention relates to the technical field of titanium dioxide, and discloses a preparation process of oil paint core-coated titanium dioxide, which comprises the following steps: a core layer is rutile type titanium dioxide particles with the particle size range of 0.1-0.5 mu m and the specific surface area of 8-15m < 2 > / g, an inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5), the coating thickness is 5-15% of the diameter of the core layer, and the inorganic coating layer is composed of silicon dioxide and aluminum oxide according to the mass ratio of 1: (0.2-1.5). Wherein the silicon dioxide is coated by a hydrolytic deposition method, the aluminum oxide is coated by a sol-gel method, the organic coating layer comprises a copolymer containing a silane coupling agent and organic silicon resin, the organic silicon resin is methyl phenyl silicon resin, the organic coating layer accounts for 1-8% of the total mass of the titanium dioxide, and the surface contact angle of the organic coating layer is greater than or equal to 110 degrees. According to the preparation process of the oil paint core-coated titanium dioxide, an inorganic-organic gradient coating system is constructed, so that the core-coated titanium dioxide has a gloss retention rate of more than 95% (ASTM D523) and a delta E color difference of less than 1.5 (ISO 7724) after 1000 hours in a QUV accelerated aging test, and the weather resistance of the core-coated titanium dioxide is improved by more than 3 times compared with that of the traditional titanium dioxide.

The invention belongs to the technical field of environmental protection, and provides a preparation method of an imine-modified functionalized mesoporous magnetic silicon dioxide nano material. The method comprises the following steps: synthesizing Fe3O4 magnetic nanoparticles in a Fe < 2 + > / Fe < 3 + > alkaline hydrolysis system through a coprecipitation method; then coating the magnetic nanoparticles with an amorphous silicon dioxide layer by taking TEOS (tetraethoxysilane) as a silicon source by adopting a sol-gel method, so as to prepare magnetic silicon coated nanoparticles; the prepared nano-particles are subjected to secondary silicon coating guided by a cetyl trimethyl ammonium bromide (CTAB) mesoporous template agent, and mesoporous magnetic silicon nano-particles are formed after calcination; and finally, carrying out surface amination modification on the mesoporous magnetic silicon nano-particles by utilizing an amino silane coupling agent, and then carrying out condensation reaction on the mesoporous magnetic silicon nano-particles and various aldehyde derivatives to construct imine bonds, so as to obtain the imine-modified functionalized mesoporous magnetic silicon dioxide nano-material. The imine-modified functionalized mesoporous magnetic silicon dioxide nano-material formed by the invention has the characteristics of efficient adsorption, rapid magnetic recovery and excellent environmental stability, and can effectively remove polystyrene micro-plastics and organic pollutants in a water body.

The invention relates to the field of plastic bags, and discloses a biodegradable plastic bag and a preparation method thereof, the biodegradable plastic bag comprises polylactic acid, poly (butylene adipate-co-terephthalate), a functional additive, modified starch, a lubricant and an antioxidant; the functional additive is prepared by grafting hydroxylated modified castor oil and isocyanated montmorillonite loaded titanium dioxide; the hydroxylation modified castor oil is prepared by modifying castor oil with chloroethyl isocyanate, then reacting with N-allylimidazole, and then reacting with 6-mercaptohexyl-1-alcohol; the isocyanated montmorillonite loaded titanium dioxide is prepared by reacting montmorillonite loaded titanium dioxide obtained by a sol-gel method with isophorone diisocyanate; the modified starch is prepared by reacting octadecanoyl chloride and acryloyl chloride with starch, then carrying out graft copolymerization with ethyl acrylate and further introducing glycidyl methacrylate, so that the plastic bag is endowed with excellent mechanical properties, biodegradability and antibacterial property.

The invention relates to the field of coating materials, and provides an antiskid coating based on carbon fibers and a preparation method thereof. The coating is composed of a component A and a component B, the component A comprises KH-570 silane coupling agent surface modified carbon fibers, dog bone-shaped nano silicon dioxide, epoxy modified hydroxy acrylic resin, quartz sand antiskid aggregate, propylene glycol methyl ether acetate, iron oxide pigment and other auxiliaries, and the component B is an HDI tripolymer curing agent. The surface modified carbon fiber is prepared through the steps of cleaning and activating, silane coupling agent dipping, drying and curing and the like, and the dog bone-shaped nano silicon dioxide is prepared through a sol-gel method with hexadecyl trimethyl ammonium bromide and polyvinylpyrrolidone as morphology guiding agents. The preparation method comprises the steps of iron oxide color paste preparation, functional component dispersion, quartz sand addition, curing treatment, double-component mixing and curing and the like. The coating has excellent dry skid resistance, wet skid resistance, wear resistance and durability, and is suitable for the field of ground skid resistance coating.

The invention relates to the technical field of catalyst materials, and particularly discloses a high-stability hydrogenation catalyst and a preparation method thereof. The invention relates to a preparation method of a high-stability hydrogenation catalyst, which comprises the following steps: preparing a hollow porous microsphere as an inner core from amino-terminated hyperbranched polyaryletherketone and polyvinyl alcohol, and then coating the porous microsphere with a mesoporous silicon dioxide intermediate layer by a sol-gel method; and finally, forming an Mg-Al hydrotalcite layer on the outermost side through a coprecipitation method, dipping and modifying with La (NO3) 3 and Ce (NO3) 3 solutions to obtain a catalyst carrier, dipping the catalyst carrier in an active metal dipping solution, and drying to obtain the catalyst. The high-stability hydrogenation catalyst provided by the invention has excellent mechanical properties and more reaction active sites, has high catalytic activity and catalytic efficiency, and is relatively long in catalytic life.

The present invention discloses a method for preparing a carbon aerogel material used as a silicon-carbon negative electrode. The method uses phenolic resin as the main raw material and adjusts the pore structure distribution of the carbon aerogel through sol-gel, crushing, drying, grading, carbon activation, impurity removal, grinding and other steps to control the impurity content, ash content, moisture content and particle size distribution, so as to meet the requirements for the use of carbon aerogel in the field of silicon-carbon negative electrodes. The prepared carbon aerogel material has a specific surface area of ​​1000 to 3000 m 2 / g, pore volume is 0.3~2cm 3 / g, with an average pore size of 0.5-10nm and a micropore ratio of 30%-100%, making it a porous carbon matrix material for silicon-carbon anodes. The present invention uses phenolic resin, formaldehyde, potassium hydroxide, and other ingredients as its primary raw materials, resulting in low costs. The materials are graded prior to carbon activation, ensuring controllability and consistency during activation. Furthermore, the impurity removal process is simple, and the overall process is highly efficient, facilitating the large-scale production of carbon aerogel materials.

The invention discloses stable silicon dioxide microspheres as well as a preparation method and application thereof. Mixing a sodium silicate diluent and an organic acid aqueous solution to form colloidal particles, and carrying out a sol-gel reaction to obtain silica sol; the preparation method comprises the following steps: in an air environment, throwing silica sol into water under stirring to form microspheres, injecting inorganic acid into the water at the same time, then injecting a sodium silicate diluent for reaction, and then adjusting the pH value of the system to 6-7; and aging, washing, drying and roasting to obtain the silicon dioxide microspheres. The preparation method comprises the following steps: mixing a sodium silicate diluent and an organic acid aqueous solution by an acid mixing method, granulating by air to form microspheres, and finally injecting inorganic acid to quickly remove heat, reduce pressure drop and maintain the state of the microspheres, thereby obtaining the stable silicon dioxide microspheres. The porous silicon dioxide microsphere with larger surface area and pore volume is obtained, has better catalytic performance when being used as a catalytic oxidation carrier, and has the advantages of high conversion rate and high stability.

The invention discloses a high-temperature-resistant thermal protection coating reinforced composite material and a preparation method thereof, belongs to the field of light thermal insulation materials, and solves the problems that high-temperature sintering is needed in the preparation process of an existing thermal protection coating, and the coating effect is affected. The method comprises the following steps: mixing a functional material, a reinforcing agent and a sintering aid, ball-milling, and sieving to obtain a filler; adding the binding agent into the dispersing agent and stirring; adding the filler into the dispersing agent solution, and performing ultrasonic treatment and stirring to obtain a mixture; spraying the mixture onto a fiber web tire, and curing; a fiber web tire loaded with the thermal protection coating is obtained; laying the fiber web tire on the surface of the fiber felt, and combining the fiber web tire and the fiber felt through a needling process to obtain a fiber preform; placing the fiber preform in a mold, pouring resin into the mold, and sealing the mold; and carrying out sol-gel and normal-pressure drying to prepare the high-temperature-resistant thermal protection coating reinforced composite material. The prepared composite material is low in density, low in heat conductivity and excellent in ablation resistance.

The invention discloses a preparation method of low-carbon-content high-purity quartz sand, which comprises the following steps: carrying out alkaline hydrolysis and drying on organosilane to obtain alkaline xerogel, putting the alkaline xerogel into a quartz tube of a rotary tube furnace, starting the furnace body, adjusting the rotation rate, heating to a specific low temperature, and introducing nitrogen to replace air; introducing oxygen, controlling the pressure, carrying out oxidation reaction, relieving the pressure to normal pressure after the reaction, pumping and discharging the product, and repeating the oxidation and pumping steps for many times until the tail gas carbon dioxide reaches the standard; raising the temperature, introducing chlorine-containing gas for purification, finally raising the temperature to a sintering temperature, and sintering in an air atmosphere to obtain the low-carbon-content high-purity quartz sand. According to the preparation method, the energy consumption and the equipment cost of the carbon removal procedure are greatly reduced, the specific surface area and the densification performance of the subsequent high-purity quartz sand product can be guaranteed, and a technical path which is low in energy consumption, high in efficiency and capable of giving consideration to the product performance is provided for industrial preparation of the high-purity quartz sand through a sol-gel method.

The invention relates to a surface-coated oxide solid electrolyte and a preparation method thereof, the surface-coated oxide solid electrolyte comprises an oxide electrolyte and a surface coating layer, the chemical formula of the oxide solid electrolyte is Li7-xLa3Zr2MxO12-x (M = Ta, Nb, Hf, Ge, Sc, Ti, Al, Si, Sn, Y, 0 < = x < = 1), the chemical formula of the surface coating layer is LiXON (R = Ta, Nb, Al, Zr, Ga, In, N = F, Cl, Br, I), and a lithium source, a lanthanum source, a zirconium source, an M source, an X source and an N source, or an XN source are connected in series, garnet solid electrolyte powder with a stable surface coating layer is obtained by adopting a solid phase method or a sol-gel method and combining a low-temperature calcination process; and then mixing and reacting with a lithium salt and a polymer electrolyte, and pouring the obtained slurry on a polyfluortetraethylene plate to prepare the composite electrolyte. Compared with the prior art, the high-ion conductor layer formed on the surface of the product in situ constructs a rapid transmission channel for lithium ion transmission in the composite electrolyte, and high ion conductivity is achieved.

The invention discloses a multi-layer flexible radiation cooling composite diaphragm which structurally comprises a flexible base layer film, and a SiO2 inorganic coating, a first layer of polyvinylidene fluoride (PVDF), a nano-silver layer deposited by magnetron sputtering and a second layer of PVDF which are sequentially coated to form a base layer film / SiO2 / PVDF / Ag / PVDF sandwich structure. The SiO2 layer is prepared through a sol-gel method, the surface roughness is smaller than 2 nm, and the visible light transmittance is larger than 95%; the thickness of the silver layer is 50 + / -5 nm, and the total thickness of SiO2 / PVDF / Ag does not exceed 150 nm. According to the composite diaphragm, ultraviolet reflection, visible light high transmission (greater than 92%) and near-infrared high reflection (greater than 88%) are realized through spectrum selective regulation and control, and meanwhile, SiO2 and PVDF synergistically enhance the infrared emissivity of an atmospheric window wave band (8-13 [mu] m). The flexible PET base material is combined with the PVDF interlayer design to restrain silver layer oxidation and interface stripping, the recovery rate is larger than 95% after 1000 times of bending circulation, and the NIR reflectivity attenuation is smaller than or equal to 5%. The composite diaphragm disclosed by the invention has the advantages of high light transmission, efficient cooling, excellent flexibility and long-term stability, and is suitable for flexible scenes such as agricultural greenhouses and the like.

The invention provides an efficient environment-friendly petroleum passivator as well as a preparation method and application thereof, and belongs to the technical field of passivators. The preparation method comprises the following steps: reacting bismuth nitrate with tetra (4-carboxyl phenyl) porphyrin and benzoic acid to prepare a carboxyl phenyl porphyrin bismuth-MOF material, reacting antimony nitrate with tetra (4-pyridyl) porphyrin and benzoic acid to prepare a pyridyl porphyrin antimony-MOF material, and performing sol-gel reaction on lanthanum isopropoxide and cerium isopropoxide to prepare lanthanum-cerium sol; the preparation method comprises the following steps: mixing calcium nitrate, magnesium chloride, organic acid, organic amine and hydrogen peroxide for reaction to prepare a calcium / magnesium organic matter, mixing the calcium / magnesium organic matter with other substances, adding the mixture into an acetonitrile / ethanol mixed solvent, and uniformly stirring and mixing to prepare the efficient environment-friendly petroleum passivator. The high-efficiency environment-friendly petroleum passivator prepared by the invention is green, safe, non-toxic and efficient, has better capturing and passivating effects on metal ions such as nickel and vanadium in the catalytic cracking reaction process of heavy oil, improves the activity of a catalyst, prolongs the service life of the catalyst, and thus, has a wide application prospect.

The invention relates to the technical field of tempered glass, in particular to a preparation method of low-warpage tempered glass, which comprises the following steps: (1) pretreatment: cleaning and drying the surface of glass by adopting an organic solvent and deionized water in sequence, and uniformly spraying an adhesive agent on the atmosphere surface of the glass; (2) SiO2-ZrO2 film coating: uniformly spraying SiO2-ZrO2 gel on the glass atmosphere surface by adopting a sol-gel method, and forming a SiO2-ZrO2 composite film layer with uniform texture on the glass atmosphere surface; and (3) strengthening: putting the coated glass into mixed molten salt, and strengthening at the temperature of 390-410 DEG C for 8-10 hours. The SiO2-ZrO2 composite film layer is arranged on the glass atmosphere surface, so that the ion exchange rate difference between the atmosphere surface and the tin surface can be reduced, the stress difference can be reduced, the component proportion can be accurately regulated and controlled, the tin permeation rate can be reduced, and the warping value of the tempered glass can be remarkably reduced through the synergistic effect of the SiO2-ZrO2 composite film layer and the tin surface.

The invention belongs to the field of photocatalytic material preparation, and particularly relates to a ZnFe2O4 / TiO2 / BC composite material as well as a preparation method and application thereof. The novel photocatalytic material ZnFe2O4 / TiO2 / BC composite material is prepared through a sol-gel method and a coprecipitation method, the photocatalytic performance of titanium dioxide and zinc ferrite is improved, and the application field of titanium dioxide and zinc ferrite is widened. The dopant provided by the invention is relatively low in price, the process is relatively simple, and the photocatalyst with a wider light absorption range can be prepared and can be used for degrading sulfamethoxazole.

The invention discloses a spinel and aluminosilicate composite Fenton-like catalyst derived from iron tailings as well as a preparation method and application of the spinel and aluminosilicate composite Fenton-like catalyst. Solid waste iron tailings are used as raw materials, a powdery spinel and aluminosilicate composite material is prepared through an improved sol-gel-calcination technology, then the powdery spinel and aluminosilicate composite material, biochar and water glass are mixed, molded and calcined, and the granular composite catalyst is prepared. The method is simple and convenient to operate and low in cost, and has industrial preparation feasibility. The prepared catalyst can efficiently activate oxidizing agents such as persulfate and hydrogen peroxide to generate active oxygen species, and organic pollutants in mineralized water can be rapidly degraded. The method is characterized in that the catalyst is prepared from iron tailings in a high-valued manner, the specific surface area of the material, the generation efficiency of active species and the cycling stability are remarkably improved through structure optimization, the problems that a traditional catalyst is high in cost, poor in industrial adaptability and the like are solved, and an economical and environment-friendly new thought is provided for large-scale treatment of organic pollution through an advanced oxidation technology; the method has double benefits of tailing recycling and environmental pollution treatment.

The invention discloses a samarium manganese mullite catalyst rich in Sm vacancy and a preparation method and application thereof, and belongs to the technical field of VOCs waste gas catalytic oxidation. According to the invention, samarium nitrate and manganous nitrate are used as precursors, citric acid monohydrate is used as a chelating agent, urea is used as an additive, and the samarium manganese mullite catalyst rich in Sm vacancies is synthesized through a sol-gel method. The Sm vacancy samarium manganese mullite catalyst prepared by the invention shows excellent toluene catalytic oxidation low-temperature activity due to selective removal of inert Sm atoms on the surface of samarium manganese mullite, more active Mn atoms are exposed, and the surface lattice oxygen migration performance is enhanced. The catalyst has excellent performance in a stability test and a water vapor resistance test, and has a wide industrial application prospect.

The invention relates to the technical field of amorphous TiC ceramics, in particular to a wear-resistant plate based on an amorphous TiC ceramic wear-resistant coating and a surfacing process thereof, and the wear-resistant plate comprises the following raw materials in parts by weight: 20-40 parts of multi-element powder, 70-80 parts of Ti powder and 20-30 parts of C powder; the preparation process of the multi-element powder comprises the following steps: step 1, synthesizing Al2O3-Cr2O3 core-shell particles through a sol-gel method; 2, mechanical alloying is carried out; 3, sintering is conducted, and multi-element powder is obtained; according to the invention, Al2O3 coated Cr2O3 core-shell particles are adopted to solve the problem of reinforcement phase / matrix interface failure; in-situ amorphous TiC forming realizes instantaneous high temperature and rapid cooling under the powder blank density of 60-80% through resistance wire short-circuit self-propagating reaction, and breaks through amorphous phase preparation limitation.

The invention provides a preparation method of a metal-based ceramic composite membrane with a catalytic ozone function. The preparation method comprises the following steps: preparing functional powder by taking tetrabutyl titanate as a titanium source and silver nitrate or ferric nitrate as a catalytic active metal source and adopting a sol-gel method; a porous metal pipe is used as a supporting body, metal powder and functional powder which are made of the same material as the supporting body are mixed to prepare functional slurry, the functional slurry is evenly deposited on the inner wall of the supporting body through vacuum filtration, and powder particles which are not firmly combined are removed through back flushing; and finally, the binding force between the functional film layer and the metal matrix is improved through high-temperature heat treatment. Wherein the thermal expansion coefficient difference between the metal supporting body and the functional film layer can be reduced by adding the metal powder, the metal powder is melted and diffused in the high-temperature heat treatment stage, and metallurgical bonding is formed between the functional powder and the metal substrate. The method is simple in process, and the prepared metal-based ceramic composite membrane has the advantages of being high in membrane layer binding force, not prone to falling off, high in catalytic activity, high in anti-pollution capacity, stable in operation and the like.

The invention belongs to the technical field of food safety sensing detection, adsorption and degradation, and particularly relates to an MIP / MOF / COF hybrid material and a preparation method and application thereof. Aiming at the defects and bottleneck problems of the existing patulin detection and removal technology, the preparation method comprises the following steps: firstly preparing an MOF / COF composite material, and then preparing an MIP / MOF / COF hybrid material by a sol-gel method, so that the photoelectrochemical sensor based on the MIP / MOF / COF hybrid material is constructed and is used for detecting patulin; meanwhile, based on the MIP / MOF / COF hybrid material, an attachment and degradation test platform is constructed. The prepared photoelectrochemical sensor can successfully detect trace patulin, and the hybrid material has good adsorption and degradation performance on patulin.

The invention relates to the technical field of solar cells, in particular to a CZTSSe absorption layer film and a preparation method and application thereof, and the preparation method comprises the following steps: S1, preparing a CZTS precursor solution of a DMF solution system; s2, preparing a CZTS precursor film by adopting a sol-gel method; and S3, coating the CZTS precursor thin film with a NaF solution with the concentration of 0-0.2 mol / L, and then carrying out drying and selenylation treatment to obtain the CZTSSe absorption layer thin film. According to the invention, the CZTS precursor film prepared by using the green and environment-friendly solvent DMF is used for carrying out a NaF solution spin-coating annealing process, so that the improvement of the battery efficiency is successfully realized. The change of CZTSSe film element redistribution, defect chemical environment and grain boundary potential difference after the Na element is doped is avoided.

The invention discloses an anti-oxidation and anti-scouring heat prevention and insulation composite material, a preparation method and application, and belongs to the technical field of high-temperature thermal protection materials. According to the method, a two-step in-situ modification method is adopted, hydrolyzed organosilane reacts with phenolic resin to prepare silicon modified phenolic resin, then the silicon modified phenolic resin is bonded with an organoboron compound to obtain boron-silicon co-modified phenolic resin, a curing agent is added, then the boron-silicon co-modified phenolic resin is injected into a fiber reinforcement mold, and a finished product is obtained through a sol-gel reaction and normal-pressure drying. According to the invention, boron and silicon elements are embedded into phenolic aldehyde molecular chains through covalent bonds to form a boron-silicon-carbon hybrid network, a nano ceramic phase and a compact glassy protective layer are generated at high temperature, and the coating has excellent anti-scouring property, thermal stability and heat insulation property. The preparation process is simple and controllable, is suitable for large-scale production, can accurately regulate and control the performance, and is suitable for thermal protection parts of supersonic aircrafts.

The invention discloses a self-repairing type phase change microcapsule and application thereof in a wood-based energy storage wall, the self-repairing type phase change microcapsule is characterized in that an inner core layer is composed of composite paraffin and butyl stearate composite phase change materials, gradient refractive index silicon dioxide microspheres are arranged on the surface of the inner core layer, and a middle shell layer is a composite film formed by polyurea and furan-epoxy monomer copolymer; the reinforced shell layer is of a three-dimensional network structure which is formed by nano SiO2 through a sol-gel method, has the porosity of 20-25% and is in gradient distribution; according to the invention, a three-dimensional network structure formed by a Diels-Alder dynamic bonding network of a middle shell layer and nano SiO2 of an enhanced shell layer is used for synergistically constructing a self-repairing system of the microcapsule, so that the self-repairing function of the phase change microcapsule material is realized, the defect of failure caused by physical damage of the microcapsule is avoided, and the service life of the phase change microcapsule material is prolonged. And meanwhile, through gradient packaging preparation of the inner core layer and the enhanced shell layer, the problem of thermal stress concentration is effectively solved.

The invention discloses a layered structure solid oxide fuel cell composite cathode catalyst as well as a preparation method and application thereof, and belongs to the field of solid oxide fuel cells. The invention aims to solve the problem that the electro-catalytic performance and low-oxygen reduction reaction activation energy of the existing medium-temperature solid oxide fuel cell are poor. The Sr2. 9Ca0. 1Fe2O7-CuO composite cathode catalyst is prepared by adopting a sol-gel method and a solid phase method, the components in a sol-gel system are in a nanometer range, the reaction is easier to carry out, the reaction temperature is low, the prepared materials are uniformly mixed, and the sol-gel method is carried out in a solution, so that even if the content of doped elements is very low, the doping can be easily realized; the material is prepared by adopting a solid phase method, and the method has the advantages of convenience in operation, simple synthesis process, uniform particle size, no agglomeration of powder particles, good filling property, low cost, high yield and the like, so that the electrochemical performance of the cathode catalyst is improved, and the method is convenient to operate and suitable for industrial production.

The invention relates to the technical field of sustained-release microcapsules, and particularly discloses a thermochromic sustained-release microcapsule as well as a preparation method and application thereof. A capsule core of the microcapsule comprises perfume and a thermochromic composite material, a capsule wall is of a double-layer structure, the inner capsule wall is a porous silicon dioxide layer, and the outer capsule wall is a polyurethane layer formed by xylooligosaccharide and isocyanate; the thermochromic composite material is a reversible thermochromic compound comprising a color former, a color developing agent and a solid solvent. According to the invention, a porous silicon dioxide inner shell layer is prepared by a sol-gel method, polyurethane formed by xylooligosaccharide and isocyanate through nucleophilic addition reaction is taken as an outer shell layer, and through the combined action of a double-layer capsule wall structure, the functions of thermochromism and perfume slow release are continuously exerted. In addition, xylooligosaccharide serving as one of raw materials of the outer capsule wall is wide in source, green and environmentally friendly, the biocompatibility of the microcapsule can be effectively improved, and the xylooligosaccharide microcapsule has very important significance in expanding the application field of the microcapsule.