919 results about "Light responsive" patented technology

The invention discloses an intelligent defect detection system and a self-repairing method for a flexible base material RFID tag, and belongs to the technical field of Internet of Things electronic device manufacturing. According to the system, a three-dimensional dynamic scanning system is constructed by integrating a high-resolution image acquisition module, a multispectral sensor array and a mechanical arm motion platform, and surface and internal structure characteristics of a flexible substrate are captured in real time. A defect identification algorithm based on deep learning is combined with a multi-scale convolutional neural network and a transfer learning technology, precise classification of 12 types of defects such as microcracks, conductive layer fractures and base material deformation is realized, and the detection precision reaches 99.2%. A dual-mode self-repairing mechanism is put forward, specifically, nano-silver conductive colloid is injected through a microfluid channel for the defects of the conductive layer, and 3D structure reconstruction is achieved through a controllable temperature field; for substrate damage, a photoresponse shape memory polymer patch is adopted, and molecular-level bonding repair is achieved after ultraviolet light activation. According to the scheme, the detection efficiency is improved by more than 5 times, and the radio frequency performance of the tag is recovered to 98.7% of the initial value after self-repairing.

The invention discloses a p-type or n-type COF film, the film thickness is 50 nm to 5 m, the aperture is 0.7 nm to 4 nm, and the film has a regular pore channel structure and light response performance. According to the invention, proper monomers are selected, and liquid-solid interface polymerization reaction is carried out, so that COF membranes grow along the tube wall, and p-type and n-type COF membranes are respectively prepared. The growth direction of the film is inconsistent with the transmission direction of the monomer and the catalyst, and the process can effectively promote the dissolution growth and self-repair of the COF film, so that the crystallinity and stacking orientation of the film are improved, and the structural characteristics of the COF film are optimized. The obtained COF film has a remarkable advantage of light-driven ion pump performance. The obtained COF membrane is used for preparing a desalting device.

The invention relates to the technical field of intelligent illumination, and discloses an intelligent illumination explosion-proof single lamp controller optimization scheduling method and system, and the method comprises the steps: firstly obtaining the deployment position of a controller, determining a target illumination region, collecting ambient light data to construct an illumination distribution diagram, and recognizing a distribution control link; monitoring real-time energy consumption of a link, analyzing load characteristics and calculating an optimal dimming coefficient; acquiring a signal response frequency band based on the dimming coefficient, fitting to generate a dimming response curve, identifying a defect response section and calculating a harmonic distortion rate; illumination compensation is carried out according to the harmonic distortion rate, scheduling grouping is carried out after a compensation threshold value is determined, high-load nodes are identified, and power is corrected; and finally, acquiring the temperature change gradient of the lamp according to the load correction parameter, generating a regulation and control instruction, and formulating an optimal scheduling strategy. According to the invention, the scheduling optimization of the explosion-proof single lamp can be improved.

The invention provides a backlight dynamic refreshing method and system based on content change frequency, and is applied to the field of image data processing. According to the method, the inter-frame variable quantity of the current image content of the display screen is pre-collected, whether the image refreshing speed is matched with the backlight response or not is judged, the pixel change rate in unit time is calculated based on the frame difference method, the content change frequency index is reasonably divided, the backlight PWM parameters are dynamically adjusted in combination with user setting, and the display quality is improved. The response coordination of the display screen under the dynamic image is effectively improved, when the frame rate fluctuation is recognized, the gray scale compensation frame is introduced and the brightness change slope is limited, and the problems of smear, splash screen and the like caused by asynchronous refreshing can be relieved.

The invention discloses an ultra-large octave wave absorber based on a photoconductive material, and belongs to the field of electromagnetic metasurfaces and metamaterials. Comprising a light response wave-absorbing metasurface and a light driving module capable of projecting different patterns on the surface of the light response wave-absorbing metasurface, array wave-absorbing units of different sizes are obtained on the light response wave-absorbing metasurface by switching the projected patterns, and impedance of a target frequency band is matched by changing equivalent capacitance / inductance of a wave-absorbing unit structure; the light driving module can project a preset light pattern on the light response wave-absorbing metasurface, so that the equivalent impedance distribution of the light response wave-absorbing metasurface is changed; according to the light response wave-absorbing metasurface, the conductivity distribution of the metasurface units is changed through light control, and the wave-absorbing frequency band is adjusted in real time, that is, dynamic adjustment of the wave-absorbing performance is achieved through non-contact light control. According to the invention, the limitation of narrow bandwidth and passive fixation of a traditional wave absorber is broken through, and electromagnetic wave control with ultra-large octave, high absorptivity and real-time reconfigurability is realized.

The invention provides a Mini LED backlight module system for improving the color gamut range of display equipment, which is characterized in that firstly, high-precision electronic control and an intelligent feedback mechanism are integrated, a distributed driving framework is adopted, and refined light source adjustment is realized; secondly, the light source ratio is adjusted in real time by dynamically analyzing the image content, and the color expression range is widened; then, continuously monitoring the driving current through a closed-loop feedback system, and adopting a self-adaptive correction driving strategy to effectively inhibit the interference of environment and device aging on color stability; finally, through temperature management, power consumption and heat dissipation requirements are dynamically balanced, and stable operation of the system is ensured; in addition, a low-delay processing architecture is adopted, and video signals and backlight response are seamlessly connected. Through deep collaboration of software and hardware, the problems of poor uniformity, thermal color cast and response delay caused by color gamut limitation and aging in the prior art are systematically solved, and the display performance is remarkably improved.

The invention discloses a household nano self-cleaning material containing rare earth elements and a preparation method of the household nano self-cleaning material, and aims at solving the problems that a traditional self-cleaning material is narrow in light response range, single in function, poor in durability, non-environment-friendly in preparation process and the like. The material comprises 5-15 parts of rare earth oxide, 50-70 parts of nano titanium dioxide, 10-20 parts of mesoporous silica, 3-8 parts of a fluorinated modifier and 2-5 parts of a bio-based adhesive. Wherein the rare earth elements are doped in titanium dioxide crystal lattices, so that the forbidden band width is reduced, the photocatalytic response range is widened to visible light, and the photocatalytic efficiency is remarkably improved. The preparation method of the material comprises the steps of precursor preparation, hydrothermal reaction, fluorination modification and coating forming, a low-temperature hydrothermal method, supercritical CO2 modification and a photocuring technology are adopted, and the material has the functions of self-cleaning, antibiosis and VOCs degradation, is suitable for various base materials such as household building materials, textiles and electric appliance surfaces, meets the composite requirements of modern home for health and environmental protection, and has wide application prospects. And the preparation process is green and pollution-free, and conforms to the sustainable development concept.

The invention provides a wafer production method and system based on image segmentation, and relates to the technical field of wafer production, and the method comprises the steps: constructing a multi-region time-space thermal response matrix through image segmentation, and automatically determining an optimal temperature disturbance quantity in combination with a thermal diffusion equation, thereby achieving the precise marking of a thermal diffusion abnormal region; then multi-wavelength measuring light is applied to the marked area, the light intensity is dynamically corrected, and the recognition sensitivity of different depth and morphology defects is enhanced; micro-vibration and light response data are introduced, a pre-training defect prediction model is utilized to extract multi-modal features, and a preliminary defect index is generated; and finally, multiplication correction is performed by adopting the polarization degree of the polarization structured light and the phase delay, so that a real defect signal can be amplified, noise interference can be suppressed, the detection accuracy, discrimination and robustness are remarkably improved, and the production quality of wafers is improved.

This invention discloses a visible-light-responsive dynamically covalently cross-linked self-healing polyurethane and its preparation method, belonging to the field of self-healing materials technology. The material is prepared by reacting diisocyanate, long-chain diol, butanediol, trimethylolpropane, and a monool containing an azophenylboronic acid structure in a certain proportion at 60°C. This invention achieves visible-light-responsive self-healing of the polyurethane material by introducing a visible-light-responsive azophenylboronic acid structure into the polyurethane and utilizing the photoresponsive cis-trans isomerization of the azo structure to regulate the reversible breakage and recombination of the boron-oxygen hexacyclic ring. The visible-light-responsive dynamically covalently cross-linked self-healing polyurethane material prepared by this invention maintains high mechanical strength (16.47 MPa) while exhibiting a strength self-healing efficiency of 95.8% after 8 hours of visible light irradiation, showing broad application prospects in smart materials, anti-corrosion coatings, and other fields.

The invention relates to the technical field of transmission membranes, in particular to a transmission membrane based on dithienylethene and a preparation method of the transmission membrane. The transmission film comprises a base film and light-operated molecules, the base film is coated with the light-operated molecules, and the light-operated molecules have light response groups. A detection result shows that after ultraviolet irradiation, the transmission film can quickly realize complete conversion from an open loop to a closed loop; after visible light irradiation is recovered, the transmission film can efficiently and reversibly recover to an open-loop state. In addition, the transport membrane has a high on-off ratio to five ions of sodium, potassium, lithium, magnesium and calcium. The transmission membrane based on dithienylethene, which is prepared by taking terminal amino-modified dithienylethene as a basic unit, not only has abundant nano-channels, but also is endowed with the characteristic of regulating and controlling the opening and closing of the nano-pore by a photoresponse functional group, and the closing and opening of an ion channel can be accurately regulated and controlled through the alternate irradiation of ultraviolet light and visible light, so that the transmission membrane has a good application prospect. And the controllability of light-operated ion transmission is finally realized.

The invention discloses modified asphalt and a preparation process thereof, and belongs to the technical field of road materials. The modified asphalt is prepared from 80-90 parts of matrix asphalt, 4-8 parts of butadiene styrene rubber, 2-5 parts of nano montmorillonite, 1.5-3 parts of core-shell structure nanoparticles (the core is SiO2 grafted with-SO3H, the middle layer is thermo-sensitive PNIPAM containing a photoinitiator, and the shell is GO grafted with a hindered phenol antioxidant group and a photosensitive coumarin group), 1-3 parts of a compatilizer, 3-6 parts of a plasticizer and 0.3-0.8 part of an antioxidant. The preparation process comprises the following steps: pretreating the modifier master batch, performing melt blending, performing high-speed shearing, performing ultrasonic dispersion, cooling, discharging and the like. The light response crosslinking mechanism is utilized, crosslinking is achieved under illumination through the light response characteristic of the core-shell structure nanoparticles, the high-temperature stability, the anti-aging performance and the fatigue life of the modified asphalt are remarkably improved, and the modified asphalt is suitable for the fields of high-grade road construction and the like.

The invention discloses a composite film based on light-biological synergistic gradient degradation and a preparation method thereof, the composite film sequentially comprises a light response layer, a transition layer and a biological response layer from outside to inside, and the light response layer comprises a polycaprolactone matrix, a tetraphenylporphyrin iron photosensitizer and anatase type TiO2 nanorods; the transition layer is a gradient blend of polylactic acid and modified starch; the biological response layer comprises polyhydroxyalkanoate and bacterial cellulose nanofibers; through the design of the three-layer gradient structure and the construction of the bionic microchannel, the synergistic effect of light degradation, hydrolysis and biodegradation is realized; the composite membrane has excellent mechanical properties and environmental adaptability, the degradation period can be accurately regulated and controlled within 30-180 days, and the soil degradation rate within 60 days reaches 91% or above; the preparation method comprises the processes of electrostatic spinning, gradient co-extrusion and bacterial cellulose in-situ culture. The material can be widely applied to the fields of agricultural mulching films, food packaging and the like, and the problems that a traditional degradable film is poor in mechanical property and uncontrollable in degradation are solved.

The invention discloses a color cast correction method and device for white picture brightness compensation and a storage medium. The color cast correction method and device are used for performing dual correction on a display screen after Demura compensation is performed on the basis of a white picture. The method comprises the following steps: collecting regional images of a target screen under different exposure times, and calculating to obtain a brightness data mean value of a plurality of regional images; establishing a mapping relation according to the brightness data mean value and the actual brightness data of the regional image; calculating Euclidean distances from the centers of the plurality of regional images to the center of the target screen; constructing a brightness-exposure response function according to the mapping relation and the Euclidean distance to obtain a brightness-exposure characteristic matrix; correcting the brightness data mean value for the first time by using the brightness-exposure characteristic matrix to obtain first corrected brightness data; constructing a chromaticity-brightness correction function of each pixel point in the target screen; and correcting the first corrected brightness data for the second time by using the chroma-brightness correction function to obtain second corrected brightness data.

The invention discloses a visual detection test method for damage cracks of a solidified soil test piece, and particularly relates to the technical field of geotechnical engineering material detection. The method comprises the following steps: doping fluorescence labeling particles in a solidified soil test piece, and applying periodic load to induce crack formation after curing and forming; synchronously exciting fluorescent particles through an ultraviolet excitation light source, and collecting a short-wave fluorescence response image sequence; inputting the image sequence into a deep residual neural network model, identifying a nonlinear enhancement region of a fluorescence signal, and deducing a crack initiation position and a propagation path; constructing a three-dimensional dynamic model of crack evolution in combination with an image space reconstruction algorithm and time sequence comparison, extracting indexes such as a crack propagation rate, a bending angle and crack density, performing comparative analysis on the indexes and initial parameters of a material, evaluating a microstructure damage development mechanism, and outputting a visual damage evolution result; the method provided by the invention can realize high-precision, non-destructive and dynamic detection of the fine cracks in the solidified soil, and has the advantages of high identification sensitivity, strong modeling precision and good engineering adaptability.

The invention discloses an instrument capable of being separated through light control and a preparation method and application of the instrument, and belongs to the technical field of biomedical engineering and flexible electronics. The instrument capable of being separated through light control comprises a flexible substrate layer, an electrode layer and a gel integration layer, the preparation method comprises the following steps: (1) forming an electrode pattern on a silicon wafer through photoetching, and carrying out oxygen plasma treatment to prepare a hydrophilic surface; (2) spin-coating a water-soluble polymer solution to form a sacrificial layer; (3) spin-coating silicone rubber pre-polymerized liquid and curing to form a flexible substrate layer; (4) dissolving the sacrificial layer with water to realize demolding, and embedding a patterned conductive material into the surface to form an electrode layer; and (5) coating the photo-responsive adhesive hydrogel pre-polymerization liquid, and performing cross-linking curing to form a gel integration layer, thereby obtaining the photo-responsive adhesive hydrogel. Through integrated structural design and functional material integration, the brain-computer interface ECoG electrode with high flexibility, high adhesion, high conductivity and controllable debonding capacity and the like is provided, and a technical basis and an application platform are provided for a next-generation intelligent implantable brain-computer system.

The invention discloses a rare earth metal polymer with multiple stimulation responsiveness and a preparation method thereof, two monomers SP and VTPY are mixed with methyl methacrylate (MMA) according to a certain proportion, a polymer skeleton Poly (VTPY-co-SP-co-MMA) is prepared through a free radical polymerization reaction, the polymer and Tb (Com) 3.2 H2O are further subjected to a coordination reaction according to a specific proportion, and the rare earth metal polymer with multiple stimulation responsiveness is obtained. The Poly-Tb (Coum) 3 with the stimuli-responsive discoloration characteristic is prepared by the aid of the method. The rare earth metal polymer with methyl methacrylate as a framework and rare earth terbium ions and spiropyran monomers as double emission centers is synthesized, has multiple stimulation response characteristics, provides a brand new strategy and possibility for development of rare earth-based multifunctional intelligent materials, and has wide application prospects. An innovative solution is provided for development of a thermal enhanced rare earth luminescent material, the thermosensitive fluorescence response performance of the material is greatly improved, and a new thought is provided for design of an intelligent temperature response type rare earth luminescent material.

The invention relates to the technical field of electronic devices, in particular to a single-molecule photoelectric memristor based on photoresponse rotating shaft molecules and a preparation method of the single-molecule photoelectric memristor. The single-molecule electric memristor comprises a light response rotating shaft molecule and a graphene point electrode pair, and the light response rotating shaft molecule is connected between the graphene point electrode pair. When ultraviolet light irradiates the photoresponse rotating shaft molecule, a high conductivity state occurs when the corresponding rotating shaft molecule rotates, and when visible light irradiates the photoresponse rotating shaft molecule, a low conductivity state occurs when the corresponding rotating shaft molecule rotates. Based on this, the monomolecular photoelectric memristor has high and low conductivity bistable states, and can realize rapid and reversible change of the conductivity state, thereby improving response speed, operation efficiency, and stability, flexibility and adaptability of performance. The single-molecule photoelectric memristor provided by the invention is expected to be widely applied to the fields of neuromorphic calculation, artificial intelligence, brain-like calculation and the like. The preparation method provided by the invention is simple and convenient to operate, mild in reaction condition and beneficial to industrial production.

The invention provides a photo-thermal response T-type liquid crystal molecule, a preparation method thereof and application of the photo-thermal response T-type liquid crystal molecule to an intelligent window. The structural formula of the T-type liquid crystal molecule is shown in the formula (1). According to the technical scheme, the liquid crystal molecule is in a T type, an azobenzene structure in the liquid crystal molecule is subjected to reversible conversion of cis and trans under switching of ultraviolet light and visible light, and meanwhile, a molecular structure of 8CB and a butylene adipate structure can be subjected to phase change at room temperature, so that the molecule has a light response function, and meanwhile, the light response effect of the molecule is improved. The material also has a thermal response function at room temperature; besides passive control through light and heat, after electrification, liquid crystal molecules are arranged in order, an electric response function is achieved, and the intelligent window can be actively recovered to be transparent. The molecule not only has multiple responses, but also is a low-carbon environment-friendly material. According to the technical scheme, the alkoxy chain is linked to the side chain of the liquid crystal molecule, asymmetry is increased, the liquid crystal molecule has a richer phase structure, and the liquid crystal molecule has a huge development prospect in the field of intelligent windows.

The invention discloses a multi-modal sensory artificial synaptic device based on a framework material and a preparation method and application thereof. The artificial synaptic device comprises a substrate and a channel, wherein the channel is arranged on the surface of the substrate; the channel is an amorphous organic metal framework film which responds to light and gas stimulation; the metal electrode is arranged on the surface of the channel; the metal electrode comprises a source electrode and a drain electrode. Compared with the prior art, the framework material with excellent photoelectric response performance is adopted, and a novel artificial synapse device with multi-mode sensing ability is constructed by fully utilizing the regular pore structure, large specific surface area and good photoresponse characteristic of the MOF material. The two electrodes of the device are connected into electrical test equipment, the conductivity of the amorphous MOF thin film can be changed under the stimulation of optical pulse signals, and finally simulation based on photoresponse synaptic plasticity is achieved. The device is placed in different gas environments, and the conductivity of the MOF film can be changed by capturing and releasing target gas molecules through the porous characteristic of the amorphous MOF material, so that simulation based on gas response synaptic plasticity is realized.

The present disclosure relates to the field of optical communication, and relates to an optical transmission system, a switching method, an optical amplifier board, a medium, and an electronic device, which are able to avoid switching failure of OMSP protection. The switching method is a switching method for redundancy protection of an optical transmission system. The optical transmission system comprises a main optical channel and a standby optical channel. The switching method comprises: acquiring a received optical power of an amplifier in an optical channel among the main optical channel and the standby optical channel through which an optical signal is currently being transmitted; comparing the received optical power with a threshold value, the threshold value being associated with a reference value and a relative threshold, and the relative threshold being associated with an optical fiber characteristic of a span in which the amplifier is located; if the received optical power is lower than the threshold value, turning off light output of the amplifier; and in response to turning off the light output of the amplifier, switching the transmission of the optical signal to the optical channel among the main optical channel and the standby optical channel through which the optical signal is not currently being transmitted.

The invention relates to a near-infrared light response in-situ gelling and synergistic photo-thermal-photodynamic gel delivery system and a preparation method and application thereof, a mesoporous silicon coated up-conversion nano-carrier and an efficient photosensitizer are compounded to form a photo-response core unit, and then the photo-response core unit is intelligently integrated with photo-curing hydrogel to form the near-infrared light response in-situ gelling and synergistic photo-thermal-photodynamic gel delivery system. The general problem of aggregation and quenching of photosensitive molecules is relieved by utilizing the unique space confinement effect of the mesoporous structure, the ICG photo-thermal efficiency and photodynamic performance are enhanced, under precise excitation of a near-infrared light source, the system can activate a photo-crosslinking reaction through an up-conversion luminescence process, in-situ conversion from a liquid eye drop preparation to a stable gel state is achieved, and the stability of the eye drop preparation is improved. A lasting drug reservoir is formed on the surface of the cornea; synchronously excited photodynamic and photo-thermal dual-mode treatment generates a remarkable synergistic antibacterial effect, and shows an excellent removal capability on pathogens including highly drug-resistant bacteria; meanwhile, an ideal microenvironment is created for tissue repair through high biocompatibility and a stable mechanical matrix, and integrity recovery of cornea structures and functions is promoted.

The invention relates to an energy storage type photo-generated cathode protection coating material and a preparation method thereof, and belongs to the technical field of chemical materials. The coating material is a binary composite material which is composed of nanometer MoO3 and BiVO4. The preparation method comprises the following steps: firstly, preparing nano MoO3 by a precipitation method, and then preparing a nano MoO3 and BiVO4 binary composite material in situ by a low-temperature hydrothermal method, namely the coating material disclosed by the invention. In the coating material, nano MoO3 and BiVO4 are adopted to form a heterojunction material, so that the photoresponse range of BiVO4 is widened, and the photoelectron-hole separation efficiency is effectively improved; meanwhile, nano MoO3 is used as an energy storage material with high theoretical specific capacity, part of photo-induced electrons generated by BiVO4 can be stored in the form of a compound, and in a dark state environment, the electrons stored in MoO3 are released and quickly transferred to the surface of metal or a film-forming substrate, so that cathode protection of the metal in the dark environment is realized; the technical problems that in the prior art, nano BiVO4 is low in electron-hole separation efficiency and poor in metal surface adhesive force, and the cathode protection effect cannot be continued in the dark state are solved.

The invention provides a heterojunction-based multi-mode photoelectric synapse device and a preparation method thereof. The heterojunction-based multi-mode photoelectric synapse device comprises a bottom electrode, a memristive functional layer, a photosensitive layer and a top electrode which are stacked in sequence, the memristive functional layer comprises metal oxide rich in oxygen vacancies and is provided with a micro-nano structure surface; the photosensitive layer covers the surface of the micro-nano structure of the memristive function layer, and forms a heterojunction interface with the memristive function layer; the oxygen vacancies and the heterojunction interface act synergistically, so that the device can respond to changes of optical signals, ambient temperature and ambient oxygen partial pressure at the same time, and the optical pulse intensity and the optical response current generated by the device have a non-linear relationship. Through cooperative regulation and control of an oxygen vacancy and a heterojunction interface, the device can respond to changes of an optical signal, environment temperature and environment oxygen partial pressure at the same time, a non-linear relation exists between optical pulse intensity and optical response current generated by the device, and then the function of integrating multi-mode sensing and sensing storage calculation is achieved.

The invention discloses a heat-insulating film with self-adjusting light transmittance and high heat insulation and a preparation method thereof, and relates to the technical field of heat-insulating films. The preparation method comprises the following steps: preparing aerogel slurry from aerogel powder, an auxiliary agent, water and a resin emulsion, preparing a photoresponse gel layer from a polymeric monomer and a photoresponse monomer, preparing a metal photosensitive coating from a metal oxide, a surfactant and a silane coupling agent, coating a substrate with the aerogel slurry, and drying to obtain the thermal insulation film. The light response gel layer continues to be attached to the slurry coating, after drying, the light sensation coating continues to be attached to the light response gel layer, and finally a layer of base material is attached to the upper portion. The heat-insulating film provided by the invention not only has the functions of blocking infrared rays and ultraviolet rays and insulating heat, but also has the function of self-adjusting the light transmittance, the light transmittance can be adjusted according to the external temperature, the light transmittance can be reduced in high-temperature weather, and the high light transmittance can be kept in low-temperature weather.

The invention relates to the technical field of agricultural lighting, in particular to a rubber forest multiband bionic light supplementing system. The device is composed of a light source module, an environment sensing module, an intelligent control module and an adjustable supporting structure. The light source module is composed of at least three LED units with different wave bands, and the light intensity proportion of each wave band can be independently adjusted. The environment sensing module collects light environment parameters and meteorological data of a rubber forest canopy in real time. The intelligent control module dynamically adjusts the light intensity proportion of each wave band based on a light response curve of photosynthesis of the rubber tree and feedback data of the environment sensing module; the adjustable supporting structure adopts a modular truss design. The invention provides a multi-band bionic light supplementing system capable of simulating the dynamic characteristics of natural light and self-adapting to the physiological needs of rubber trees, and accurate matching of light quality, light intensity and light period is realized through intelligent sensing and dynamic regulation, so that the photosynthetic efficiency, the latex yield and the energy sustainability are improved.

The invention relates to the technical field of biological materials, in particular to a pillararene-based photoresponse MOF-based ion gating nanochannel and a preparation method thereof. According to the pillararene-based photoresponse MOF-based ion gating nano-channel, a bullet-shaped nano-channel is prepared by taking PET (Polyethylene Terephthalate) as a substrate, and the substrate can provide structural support; p5A-MOF-1 based on pillararene is used as a core functional layer, and the core functional layer can provide a stable cavity environment; a P5A-MOF-1 cavity is filled with an organic aromatic azo compound, so that the light response structure change is realized. And the effective volume of the P5A-MOF-1 cavity is regulated and controlled through the photoisomerization effect of the azo group, so that precise gating of ion transmission is achieved. The preparation method provided by the invention is simple and convenient to operate, mild and controllable in condition and beneficial to large-scale production.

The invention relates to the field of packaging detection, in particular to a full-color Micro LED micro display module packaging detection method, device and equipment, and the method comprises the following steps: carrying out pixel-level thermal induction on a micro display module to be detected, collecting global pixel thermal induction self-luminous response parameters, carrying out instantaneous light response analysis, and generating an instantaneous light response curvature; multi-time-point response trend analysis is carried out based on the instantaneous light response curvature, global pixel thermal disturbance coupling evolution is carried out, and a pixel thermal disturbance response map is constructed; performing inter-pixel multi-dimensional response difference calculation and abnormal deviation region positioning according to the pixel thermal disturbance response map, and extracting an abnormal deviation display module region; performing spatial arrangement inversion on the abnormal deviation display module area to generate actual pixel point coordinates of the abnormal area; according to the method, error compensation is carried out on the offset pixels through precise and efficient huge transfer error analysis, and the packaging precision and reliability control level of the micro-display module are enhanced.

The invention discloses a preparation method and application of a photoelectric collaborative flexible optical fiber, and belongs to the technical field of multifunctional flexible optical fiber preparation. Conductive fibers are prepared through a wet spinning / melt co-extrusion spinning process, the conductive fibers are placed in a hollow part of a hollow cladding preform of an optical fiber, and the photoelectric synergistic flexible optical fiber sensor is obtained through synchronous hot wire drawing. According to the invention, the flexible electrode is combined with the transparent high polymer material with good light guide performance to form the photoelectric cooperative sensing flexible optical fiber sensor with both light response and electric response, and the unique optical fiber structure not only achieves the photoelectric cooperative sensing function, but also plays a role in packaging the flexible electrode, so that the durability of the optical fiber sensor is higher. The fiber has excellent performances of flexibility, fatigue resistance and the like, can be used as optical fiber sensing equipment for monitoring human joint movement, and has huge application potential in the fields of optical fiber communication, sensing detection, biomedical treatment and the like.

The invention discloses an electrochemical biosensor of a light-driven nanopore channel and application of the electrochemical biosensor. According to the sensor, a photoresponse nanopore membrane is constructed, an outer surface aptamer probe is combined, asymmetric photothermal gradient driven ion transmission induced by near-infrared light is utilized, and ultra-sensitive detection on a target object is realized by regulating and controlling the charge density of the outer surface. According to the electrochemical biosensor provided by the invention, traditional voltage driving is replaced by asymmetric near-infrared light driving, so that the electrochemical biosensor has a relatively wide detection range and an extremely low detection limit, and high-sensitivity and specific detection on a target object can be realized. The electrochemical biosensor can be used for detecting microcystin-LR (MC-LR), the detection limit reaches 1 * 10 <-7 > mu g / L, the sensitivity is improved by 5 orders of magnitude compared with that of a traditional voltage-driven sensor, and the electrochemical biosensor can be applied to trace pollutant detection in the fields of environmental monitoring, food safety and the like.

The invention discloses a preparation method of photoresponse COFs coated CeO2 nano-enzyme, and relates to the field of nano-materials. According to the invention, FePc, TAPP and 2, 5-dihydroxy-1, 4-phthalaldehyde are used for creating a core-shell material CeO2 (at) FePC / por-COF of photoresponse peroxidase based on COFs (Covalent Organic Frameworks), and the core-shell material CeO2 (at) FePC / por-COF is used for preparing the photoresponse peroxidase based on COFs. According to the invention, the highly ordered structural characteristic of the COFs material is utilized, so that the problem of fluorescence quenching caused by aggregation of traditional micromolecule photosensitizers (such as porphyrin, phthalocyanine and the like) in the use process is effectively solved. According to the present invention, the photoresponsive peroxidase activity is significant, and the chromogenic substrate of tetramethyl benzidine (TMB) can be effectively catalyzed; fePc is integrated into a COFs structure, so that the photoresponse activity of the COFs under near-infrared 808 nm is enhanced, and the COFs have excellent reactive oxygen species (ROS) generation capacity, and have great potential in the aspects of photodynamic therapy, antibacterial treatment, cell imaging and the like in biomedical application.