168 results about "Amine ligands" patented technology

A method of forming (and an apparatus for forming) a metal oxide layer on a substrate, particularly a semiconductor substrate or substrate assembly, using a vapor deposition process and one or more precursor compounds that include organo-amine ligands and one or more precursor compounds that include organo-oxide ligands.

A method of forming (and an apparatus for forming) a metal oxide layer on a substrate, particularly a semiconductor substrate or substrate assembly, using a vapor deposit ion process and one or more precursor compounds that include organo-amine ligands and one or more precursor compounds that include organo-oxide ligands.

A method of preparing a poly(arylene ether) includes oxidatively coupling a monohydric phenol in a reaction solution at a reaction temperature that exceeds the cloud point temperature of the reaction solution. The oxidative coupling occurs in the presence of a metal complex catalyst, and when the catalyst includes an amine ligand, the method facilitates incorporation of the amine ligand into the poly(arylene ether) resin. The amine-incorporated poly(arylene ether) resins prepared by the method are useful in the preparation of higher molecular weight poly(arylene ether) resins and compatibilized blends of poly(arylene ether) resins with other thermoplastics.

The present invention provides metal-containing compounds that include at least one β-diketiminate ligand, and methods of making and using the same. In certain embodiments, the metal-containing compounds include at least one β-diketiminate ligand with at least one fluorine-containing organic group as a substituent. In other certain embodiments, the metal-containing compounds include at least one β-diketiminate ligand with at least one aliphatic group as a substituent selected to have greater degrees of freedom than the corresponding substituent in the β-diketiminate ligands of certain metal-containing compounds known in the art. The compounds can be used to deposit metal-containing layers using vapor deposition methods. Vapor deposition systems including the compounds are also provided. Sources for β-diketiminate ligands are also provided.

The present invention provides metal-containing compounds that include at least one β-diketiminate ligand, and methods of making and using the same. In some embodiments, the metal-containing compounds are homoleptic complexes that include unsymmetrical β-diketiminate ligands. In other embodiments, the metal-containing compounds are heteroleptic complexes including at least one β-diketiminate ligand. The compounds can be used to deposit metal-containing layers using vapor deposition methods. Vapor deposition systems including the compounds are also provided. Sources for β-diketiminate ligands are also provided.

The present invention provides for substituted metal chelating compounds in which at least two of the chelating atoms are nitrogen which are directly attached to aromatic rings and one or more of those nitrogen atoms has attached thereto a substituent other than hydrogen, and methods for making and using these compounds.

The invention provides a method for preparing chlorinated-2-acetyl-1,10-phenanthroline amine iron (II) complex with the structural formula of formula (I) and an application of the obtained complex as an ethylene oligomerization catalyst, wherein variables in the formula (I) are defined in the specification. According to the method, triethyl aluminum which is adopted as an initial raw material in the process of the preparation of 2-acetyl-1,10-phenanthroline from 1,10-phenanthroline is hydrolyzed and undergoes an oxidation reaction with nitrobenzene to obtain 2-acetyl-1,10-phenanthroline, 2-acetyl-1,10-phenanthroline is condensed with substituted aniline to obtain a 2-acetyl-1,10-phenanthroline amine ligand, and the ligand is reacted with iron dichloride to obtain the complex. The synthetic method of the invention, which has the advantages of less step, simple technology, and catalyst preparation cost reduction, and adopts nontoxic triethyl aluminum to replace potassium cyanide used in routine preparation methods, has a wide industrialization prospect.

An aqueous coating composition comprises a metal oxide selected from the group consisting of bismuth oxide, vanadium oxide, manganese oxide, cobalt oxide, zinc oxide, strontium oxide, yttrium oxide, molybdenum oxide, zirconium oxide, lanthanum oxide, oxides of the lanthanide series of elements and combinations thereof and an electrodepositable binder, the binder comprising (a) a phosphorous-containing groupin which X is a hydrogen, a monovalent hydrocarbon, an alkyl group such as an aminoalkyl group, or an oxygen atom having a single covalent bond to the phosphorous atom, and each oxygen atom has a covalent bond to a hydrogen atom, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, or the resin, with the caveat that at least one oxygen atom has a covalent bond to resin; (b) a carboxylate group separated by from 2 to 4 carbons from an ester group; and (c) a tridentate amine ligand. The coating composition can be electrodeposited on a metal substrate to provide superior corrosion resistance.

The invention provides a method of preparing a complex represented by formula (I) of 2-n-butyryl-1,10-phenanthroline condensation amine ferric chloride (II) and application of the prepared complex as a catalyst for ethylene oligomerization, wherein variables in formula (I) are defined in the specification. According to the method, in the process of preparing 2-n-butyryl-1,10-phenanthroline from 1,10-phenanthroline, tri-n-butylaluminum is used as a starting material, then hydrolysis and an oxidation reaction with nitrobenzene are sequentially carried out so as to obtain 2-n-butyryl-1,10-phenanthroline, 2-n-butyryl-1,10-phenanthroline and substituted aniline undergo a condensation reaction so as to prepare 2-n-butyryl-1,10-phenanthroline condensation amine ligand, and the ligand reacts with ferrous chloride so as to obtain a target product. The synthetic method comprises a few procedures, is a simple process, enables preparation cost for the catalyst to be reduced and uses nontoxic tri-n-butylaluminium to substitute potassium cyanide used in normal preparation methods, thereby having a wide industrial prospect.

The present invention concerns novel platinum complexes in which at least one of the amine ligand is a non-planar heterocyclic aliphatic amine. The platinum complexes may be in a trans or cis configuration and were found to posses therapeutic activites. Thus, the present concerns novel platinum complexes, pharmaceutical compositions comprising them and other uses thereof.

The invention discloses a catalyst precursor and its preparation method, a catalyst and its application, and an ethylene polymerization method. The catalyst precursor is a bimetallic catalyst precursor which has an open structure shown as a formula I and is based on a salicylaldehyde imine ligand, the preparation method of the catalyst precursor is as follows: under complexation reaction conditions, contacting a compound having a structure shown as a formula IV with a compound with a molecular structure general formula of MCl4 (THF) 2 in an organic solvent; the catalyst provided by the invention comprises the catalyst precursor and alkyl aluminoxane; the invention also provides the application of the catalyst in olefin polymerization, the invention also provides the ethylene polymerization method which is as follows: under olefin polymerization conditions, in the presence of an organic solvent, contacting ethylene with the catalyst precursor and the alkyl aluminoxane for polymerization. The preparation method of the catalyst precursor is simple, and the catalyst is high in catalytic efficiency. The formula I and the formula IV are shown in the specification.

New ligands, compositions, metal-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. Certain of these catalysts with hafnium metal centers have high performance characteristics, including higher comonomer incorporation into ethylene / olefin copolymers, where such olefins are for example, 1-octene, isobutylene or styrene. Certain of the catalysts are particularly effective at polymerizing propylene to high molecular weight isotactic polypropylene in a solution process at a variety of polymerization conditions.

The invention provides a method for preparing a chlorinated 2-benzoyl-1,10-phenanthroline condensed amine iron (II) complex shown in formula I, and its catalytic application in ethylene oligomerization. The preparation method comprises the following steps: orderly performing hydrolysis and an oxidation reaction with nitrobenzene of initial reaction raw materials of 1,10-phenanthroline and benzyl lithium to obtain 2-benzoyl-1,10-phenanthroline, then performing condensation of 2-benzoyl-1,10-phenanthroline with substituted aniline to obtain 2-benzoyl-1,10-phenanthroline condensed amine ligand, and reacting the ligand with ferrous chloride to obtain a target product I. The synthetic method provided by the invention is few in steps, and simple in process, substitutes nitrobenzene for selenium dioxide in the prior art for the oxidation reaction, substitutes nontoxic benzyl lithium for hypertoxic potassium cyanide in the prior art, reduces the preparation cost of the catalyst, and has wide industrialization prospects.

The invention provides a perovskite film, a perovskite electroluminescence device and a preparation method and a display device and belongs to the technical field of display. The perovskite film comprises a crystallized perovskite material on a substrate and an amine ligand material which is grafted on the crystallized perovskite material. As the crystallized perovskite material in the perovskitefilm is grafted with the halogenated amine ligand material, the perovskite film has a smooth surface, the crystallized perovskite material has a high surface cover rate and has no conspicuous pore defect, and meanwhile, as the halogenated amine ligand material is additionally used in the perovskite film, the perovskite film provided by the invention has a very high fluorescence quantum yield.

The invention discloses a preparation method of a supercritical carbon dioxide (CO2) foaming nucleating agent. The preparation method comprises the steps that porous silica or porous titania and a modifying reagent are subjected to a modification reaction in a toluene solvent under the condition of heating reflux, and modified powder is obtained after the reaction is completed; the modified powder reacts with an initiator and triethylamine in an anhydrous dichloromethane solvent at a normal temperature in a nitrogen atmosphere for 12 to 24 hours, and powder loaded with the initiator is prepared after the reaction is completed; a CuBr catalyst and a pentamethyl diethylene triamine ligand are added to the powder loaded with the initiator and ionic liquid in an anhydrous acetonitrile solvent to conduct a graft polymerization reaction at a temperature of 110 to 120 DEG C in a nitrogen atmosphere for 24 to 36 hours; and after the reaction, a reaction solution is post-processed to obtain the supercritical CO2 foaming nucleating agent. Material of the nucleating agent prepared according to the preparation method has a certain CO2-friendly substance loading amount, so that the CO2 adsorption capacity is improved, nucleation energy can be well reduced, the nucleation efficiency is improved, the cell size of a polymer foaming material is reduced, and the cell density is increased.

The invention relates to a hybrid organic-inorganic chiral perovskite single crystal and a synthesis method thereof. According to the invention, a chiral organic amine ligand is used as a raw materialto prepare a novel non-centrosymmetric hybrid organic-inorganic chiral perovskite single crystal. The preparation method comprises the following steps: dissolving a mixture of PbBr2 and chiral aminein a molar ratio of 2: 1 in HBr and N, N-dimethylformamide, stirring for 20 minutes at room temperature, gradually clarifying the solution, standing in a toluene atmosphere for several days to obtaincolorless bulk monocrystals, and drying in a drying oven to obtain the hybrid organic-inorganic chiral perovskite monocrystals. The hybrid organic-inorganic chiral perovskite single crystal synthesized by the method disclosed by the invention has relatively strong second-order nonlinear optical properties. The preparation method provided by the invention is simple and efficient, the product stability is high, the environmental pollution is small, and a foundation is laid for the development and application of the novel hybrid organic-inorganic perovskite material in the photoelectric field.

A coating layer prepared from an aqueous electrodeposition coating composition comprising an electrodepositable binder, the binder comprising a tridentate amine ligand-containing resin, and optionally further comprising a metal oxide selected from the group consisting of bismuth oxide, vanadium oxide, manganese oxide, cobalt oxide, zinc oxide, strontium oxide, yttrium oxide, molybdenum oxide, zirconium oxide, lanthanum oxide, and oxides of the lanthanide series of elements provides corrosion protection to a metallic substrate.

The invention discloses a method for preparing aromatic alkynes through cross-coupling of nitroaromatic hydrocarbons and aryl-terminated alkynes under the catalysis of transition metal. The method comprises a step of subjecting nitroaromatic hydrocarbons and aryl-terminated alkynes to a cross-coupling reaction in a solution system of a palladium-containing catalyst, a copper-containing catalyst, aphosphine ligand and an amine ligand in a protective atmosphere so as to obtain aromatic alkynes. According to the method, the cheap, easily available and polar nitroaromatic hydrocarbons are used asan electrophilic reagent for synthesis of the aromatic alkynes, so a series of advantages in traditional Sonogashira coupling can be compensated. The method of the invention has the following advantages: (1) usage of expensive halogenated hydrocarbons hard to prepare can be avoided; (2) in the process of multiple coupling reactions, the polarity of nitro groups allows coupling products to have polarity different from the polarity of raw materials and by-products, so the coupling products can be easily separated through column chromatography; and (3) the transition metal is employed for homogeneous catalysis, so cross-coupling is expected to be smoothly carried out under mild conditions, and the tolerance range of function groups is wide.

The invention provides a method for preparing a coordination compound chlorination2-formoxyl-1, 10-phenanthroline condensation amine and iron (II) in a formula (I) and application of the coordination compound as an ethylene oligomerization catalyst. Variants in the formula (I) are defined in the specification. In the process for preparing 2-formoxyl-1, 10-phenanthroline by 1, 10-phenanthroline, the method adopts trimethyl aluminum as a starting material and then conducts hydrolysis and oxidizing reaction with nitrobenzene to obtain 2-formoxyl-1, 10-phenanthroline, then the 2-formoxyl-1, 10-phenanthroline is condensed with substitution aniline to obtain 2-formoxyl-1, 10-phenanthroline condensation amine ligand, and the ligand reacts with ferrous chloride to obtain the target product. The preparation method is few in step and simple in process, reduces catalyst preparation cost, adopts non-toxic trimethyl aluminum to replace potassium cyanide used in a routine preparation method, and is wide in industrial prospects.

A method for producing alcohols which comprises reducing esters or lactones with hydrogen gas in the presence of a catalyst comprising (i) a ruthenium compound, (ii) a monodentate monophosphine or a bidentate bisphosphine, and (iii) an amine. Examples of the catalyst include a ruthenium (Ru) complex represented by the formula:RuX1X2(LP)m(LN)n [X1 and X2 each represent an anionic ligand, LP represents a phosphine ligand, m is 1 when LP is bidentate, while m is 2 when LP is monodentate, LN represents an amine ligand, and n is 1 when LN is bidentate, while n is 2 when LN is monodentate.] and a catalyst comprising an amine and a ruthenium (Ru) complex of the formula: RuX1X2(LP1)r [LP1 represents a monophosphine ligand and r is 3 or 4.].

The present invention relates to a process for preparing palladium complexes. In particular, the present invention relates to a process in which ammoniacal complexes of palladium (hydrogen)carbonate are converted into complexes with oligoamine ligands.

The invention discloses a pincerlike bi-N-heterocyclic carbene biphenyl amine rare earth metal catalyst, a preparation method and an application thereof and belongs to the field of catalysts. The catalyst has one structural formula. The preparation method comprises the following steps: firstly heating bromoiodobenzene, 2-bromobenzenamine and the like to react in a dark place in a nitrogen or an argon atmosphere, so as to obtain a first-step product by column chromatography, heating with imidazole to react, so as to obtain a second-step product by virtue recrystallization; reacting with alkyl iodides while heating, filtering, washing and drying to obtain a pincerlike bi-N-heterocyclic carbene biphenyl amine ligand; and dropwise adding a hydrogen-pulling reagent into a ligand liquid to react in a low-temperature, nitrogen or argon atmosphere, then dropwise adding a liquid with a metal source dissolved to react, and filtering and recrystallizing to obtain the pincerlike bi-N-heterocyclic carbene biphenyl amine rare earth metal catalyst. The raw materials are easily available and the catalyst can be used for homopolymerization or copolymerization of olefins, alkynes and polar monomers or copolymerization with CO2, respectively. The preparation method is simple in process, economic and environment-friendly and suitable for industrial production.

Disclosed are tris(triazolylmethyl)amine ligands, and kits and methods for labeling and / or imaging a biomolecule of interest in a subject or living system.

Process for preparing optically active beta-amino alcohols represented by a general formula (2): Ra-C*H(OH)-C*H(Rb)-Rc wherein Ra and Rc are each independently hydrogen, optionally substituted alkyl, optionally substituted cycloalkyl, Rb is one member selected from among groups represented by the following general formulae; (3) R1CO(R2)N-, and (4) R1CO(R1'CO)N-, and C* is an asymmetric carbon atom, characterized by reacting a racemic alpha-aminocarbonyl compound represented by the general formula (1): Ra-CO-CH(Rb)-Rc, with hydrogen in the presence of an optically active transition metal compound represented by a general formula (7): MaXY(Px)m(Nx)n wherein Ma represents a metal atom belonging to VIII-group of the periodic law, X and Y represent each independently hydrogen, halogeno, Px represents a phosphine ligand, Nx represents an amine ligand, at least one of Px and Nx is optically active, and m and n each independently represent 0 or an integer of 1 through 4 and a base.

An aqueous electrodeposition coating composition comprising a cathodically electrodepositable binder, the binder comprising a phosphorylated resin and a carboxyl group separated by from 2 to 4 carbons from an ester group, provides corrosion protection equivalent to that obtained by the conventional phosphate pretreatment-electrodeposition coating process. The aqueous coating composition may comprise a metal oxide selected from the group consisting of bismuth oxide, vanadium oxide, manganese oxide, cobalt oxide, zinc oxide, strontium oxide, yttrium oxide, molybdenum oxide, zirconium oxide, lanthanum oxide, oxides of the lanthanide series of elements and combinations thereof. The phosphorylated resin may comprise a phosphorous-containing group in which X is a hydrogen, a monovalent hydrocarbon, an alkyl group such as an aminoalkyl group, or an oxygen atom having a single covalent bond to the phosphorous atom, and each oxygen atom has a covalent bond to a hydrogen atom, an alkyl group, an aryl group, an alkylaryl group, an arylalkyl group, or the resin, with the caveat that at least one oxygen atom has a covalent bond to resin. The aqueous coating composition may comprise a tridentate amine ligand.

The invention discloses a preparation method of pyridoxal or pyridoxal hydrochloride. The preparation method comprises: taking pyridoxine or pyridoxine hydrochloride shown in formula (III) as the starting material and water as the reaction solvent, conducting selective oxidation on the pyridoxine or pyridoxine hydrochloride in water under the effect of a catalytic oxidation system, thus obtaining the pyridoxal or pyridoxal hydrochloride shown in formula (I). The catalytic oxidation system includes an oxygen source, a catalyst, an inorganic salt and an amine ligand. The preparation method of the invention has the advantages of high conversion rate, good selectivity, mild reaction condition, easy operation, low cost, and environmental friendliness, thus boasting good industrial application value.

New compositions, titanium-ligand complexes and arrays with pyridyl-amine ligands are disclosed that catalyze the polymerization of monomers into polymers. These catalysts with titanium metal centers have high performance characteristics, including high styrene incorporation into ethylene / styrene copolymers.