852results about "Group 3/13 organic compounds without C-metal linkages" patented technology

A compound which has thermal stability and moderate vaporizability and is satisfactory as a material for the CVD or ALD method; a process for producing the compound; a thin film formed from the compound as a raw material; and a method of forming the thin film. A compound represented by the general formula (1) is produced by reacting a compound represented by the general formula (2) with a compound represented by the general formula (3). The compound produced is used as a raw material to form a metal-containing thin film. [Chemical formula 1] (1) [Chemical formula 2] (2) [Chemical formula 3] M_p(NR⁴R⁵)_q(3) (In the formulae, M represents a Group 4 element, aluminum, gallium, etc.; n is 2 or 3 according to cases; R¹ and R³ each represents C_1-6 alkyl, etc.; R² represents C_1-6 alkyl, etc.; R⁴ and R⁵ each represents C_1-4 alkyl, etc.; X represents hydrogen, lithium, or sodium; p is 1 or 2 according to cases; and q is 4 or 6 according to cases.)

Methods and compositions for depositing a film on one or more substrates include providing a reactor and at least one substrate disposed in the reactor. At least one lanthanide precursor is provided in vapor form and a lanthanide thin film layer is deposited onto the substrate.

A single source precursor for depositing ternary I-III-VI₂ chalcopyrite materials useful as semiconductors. The single source precursor has the I-III-VI₂ stoichiometry “built into” a single precursor molecular structure which degrades on heating or pyrolysis to yield the desired I-III-VI₂ ternary chalcopyrite. The single source precursors effectively degrade to yield the ternary chalcopyrite at low temperature, e.g. below 500° C., and are useful to deposit thin film ternary chalcopyrite layers via a spray CVD technique. The ternary single source precursors according to the invention can be used to provide nanocrystallite structures useful as quantum dots. A method of making the ternary single source precursors is also provided.

The subject invention pertains to metal organic frameworks (MOF) having zeolite-net-like topology, their methods of use, and their modes of synthesis. The ZMOFs are produced by combining predesigned tetrahedral building, generated in situ using heterochelation, with polyfunctional ligands that have the commensurate angle and the required donor groups for the chelation. Each molecular building block is contrasted of a single metal ion and ligands with both heterochelation functionality and bridging functionality. Advantageously, zeolite-net-like MOFs of the subject invention are porous and contain large functional cavities, which is useful for encapsulating large molecules.

A method of solvating metal ions in an aromatic organic liquid. The method includes adding an ammonium salt having an organic acid reagent to the aromatic organic liquid. The organic acid reagent comprises a carboxylate having eight (8) or less carbon atoms. Thereafter, an aqueous solution comprising a metal salt is added to the aromatic organic liquid comprising the ammonium salt and the organic acid reagent. As a result, at least 10% by weight of metal ions is solvated in the aromatic organic liquid.

An organic electroluminescence element including at least one organic layer including a light emitting layer, between an anode and a cathode, wherein at least one layer of the at least one organic layer contains at least one selected from specific nitrogen-containing heterocyclic derivatives, and at least one layer of the at least one organic layer contains a specific electron-transporting phosphorous light emitting material.

A purified cannabidiol (CBD) extract and/or cannabidiolic acid (CBDA) extract is isolated from industrial hemp and comprises less than 0.5 wt % organic impurities as measured by HPLC and ¹H NMR spectroscopy exhibits no detectable peak at 4.07 ppm as measured by ¹H NMR spectroscopy. The CBD and/or CBDA extract is in crystalline form. The CBD extract exhibits a melting point as measured by differential scanning calorimetry (DSC) of 69-70° C. Dry powder compositions comprise such extracts. Additional dry powder compositions comprise polyvinylpyrrolidone and an amorphous CBD extract. An adduct comprises CBD and/or CBDA bonded to a paramagnetic trivalent lanthanide (III) metal chelate.

The purpose of the invention is providing a micro-channel chemical preparation method of porous metal-organic framework material. The method comprises the following steps: respectively injecting a liquid medium containing one or more organic compounds with at least one unidentate ligand, a liquid medium containing one or more metal ions, a liquid medium containing a deprotonation assistant and an inert gas into a micro-channel reactor through different inlets, carrying out a coordination reaction on the above obtained mixed material liquid in the micro-channel at a certain temperature under a certain pressure to form a coordination compound, crystallizing, filtering, washing, and drying to prepare the porous metal-organic framework material, wherein the micro-channel reactor has at least two inlets and one outlet; the addition amount of the deprotonation assistant is 0-50% of the mole number of all metal ions; a ratio of the volume velocity of inert gas added into the micro-channel reactor to the bulk volume velocity of the liquid phase is 0-100:1; and the crystallization process can be omitted. The method has the characteristics of simple and safe operation, high efficiency, large throughput and easy amplification.

The invention discloses a baicalin metal complex of which the molecular formula is (C21H17O11) xM (H2O) y, wherein M in the formula is Cu (II), x is 1 and y is 2; or M is Fe (III), x is 2 and y is 0; or M is La (III) or Y (III), x is 3 and y is 0. The preparation method comprises the following steps: adding aqueous alkali into baicalin until the baicalin and alkali (sodium bicarbonate, potassium bicarbonate, sodium formate, potassium formate, sodium acetate, potassium acetate, disodium hydrogen phosphate, dipotassium hydrogen phosphate, sodium phosphate or potassium phosphate) are just completely reacted, then adding metal salt (copper salt, ferric salt, lanthanum salt or yttrium salt) for reaction to obtain the baicalin metal complex. The baicalin metal complex has obviously stronger antibacterial and antitumor activities than the baicalin, can be used for preparing antibacterial drugs and antitumor drugs, and has good development and application prospects. In the preparation method, an organic solvent is not used, a strong basic condition is not adopted, and the method is simple and feasible, is green and environment-friendly and has the advantages of low cost, high product purity and high yield.

Methods of forming metal alkoxides and methods of forming precursor solutions of metal alkoxides suitable for the coating of glass in the manufacture of electrochromic devices are disclosed. The method of forming metal alkoxides involves dissolving the metal halide in an anhydrous solvent and reacting it with an alcohol and (together with the addition of the alcohol or subsequently) adding an epoxide, and then evaporating-off the volatile components of the reaction product to leave a solid metal alkoxide that is substantially free of halide. The alkoxide may then be dissolved in a solvent including an alcohol (preferably ethanol) containing a small proportion of water to produce a precursor solution suitable for coating glass, the coating then being hydrolyzed to form a sol-gel and then baked to remove volatile components and to yield a thin layer of metal oxide.

The invention discloses a rare earth organic framework material for fluorescence detection of trace water and a preparation method of the rare earth organic framework material. The rare earth organic framework material is an orderly microporous crystalline material, and the general structural formula of the material is [(CH3)2NH2]2[Ln6(mu3-OH)8(L-NH2)6(H2O)6]*(G)7, wherein Ln in the formula is Eu<3+>, Tb<3+> or Gd<3+>, L-NH2 is a chainlike phthalic acid organic ligand with an amino group function group and G represents a solvent in pores. The rare earth organic framework material is synthesized with a solvothermal method, the synthesis method adopts a simple process, the condition is mild, the yield is higher, and the product stability is good. The rare earth organic framework material has the properties of characteristic emission of rare earth and fluorescence of the ligand, the specific value of two emission peaks and the content of water in the solvent are in a better linear relation, and ratio type detection of trace water can be realized; the light color remarkably changes with the change of the water content, and the material can be used for colorimetric type detection of trace water. The sensitivity of a probe is high, the response speed is high, the detection limit is low, and the material can be recycled and is expected to be used practically in fields of detection and monitoring of trace water.

The invention relates to an InIII-based metal organic anion framework and application thereof. The technical scheme is as follows: the preparation method comprises the following steps: adding 2,3',5,5'-biphenyltetracarboxylic acid, N,N'-dimethylformamide, ethanol, water and concentrated nitric acid into a container, and stirring at room temperature for 20 minutes; sealing the container, putting in a drying oven, and keeping at the temperature of 100-110 DEG C for 2-4 days; slowly cooling to room temperature to obtain a colorless transparent rod-like crystal; and washing, filtering and drying to obtain the target product. The InIII-based metal organic anion framework can sensitize rare earth ions to emit light when being used as an adsorption matrix, and can efficiently and selectively separate cationic organic dyes.

A compound represented by the following general formula (I):

{R¹, R³, R⁶ and R⁸ are methyl groups and the like, R² and R⁷ are cyano groups and the like, R⁴ and R⁵ are fluorine atoms and the like, and X is a group represented by the formula (A) [R¹¹ is a monocarboxy-substituted C_1-8 alkoxy group and the like, R¹², R¹⁴ and R¹⁵ are hydrogen atoms and the like, and R¹³ is hydroxy group and the like],

provided that the combination of the aforementioned substituents is such a combination that the compound represented by the formula (I) can be substantially non-fluorescent before reacting with peroxynitrite, and the compound represented by the formula (I) in which the group represented by the formula (A) is nitrated after reacting with peroxynitrite can be substantially highly fluorescent}, or a salt thereof, which is useful as a fluorescent probe for peroxynitrite measurement.

The invention relates to a microporous rare earth cluster metal organic anion framework and a preparation method and application thereof. According to the technical scheme, the preparation method comprises the steps that RE(NO<3>)<3>/4, 4'-diphenyldicarboxylic acid, o-fluorobenzoic acid, N, N-dimethyl formamide and ethanol are added into a container and stirred at the normal temperature; the container is sealed and then placed into a drying oven, and the container is maintained for 1-2 days at the temperature of 300-400 K; the mixture is cooled slowly to the room temperature and left standing for 20-30 hours, and crystals are obtained; N, N-dimethyl formamide is used for washing the mixture, filtration and drying are conducted, and a target product is obtained. The microporous rare earth cluster metal organic anion framework prepared through the preparation method can serve as an adsorption base material for adsorbing cation type organic dyestuff, and the cation organic dyestuff is separated in an efficient and selective mode.

The invention discloses a dysprosium complex constructed with a 8-hydroxyquinoline acylhydrazone derivative as a ligand, and a synthesis method and an application of same. The chemical formula of the complex is [Dy(HL)(L)].2H2O, wherein the L refers to 2-formyl-8-hydroxyquinoline benzoylhydrazone with a hydrogen atom on a hydroxyl group and a hydrogen atom on acylhydrazone nitrogen eliminated and with two units of negative charges; and the HL refers to 2-formyl-8-hydroxyquinoline benzoylhydrazone with a hydrogen atom on a hydroxyl group eliminated and with one unit of negative charge. The synthesis method of the complex includes the steps of: dissolving Dy(NO3)3.6H2O and the 2-formyl-8-hydroxyquinoline benzoylhydrazone in a mixed solvent, regulating the pH of the solution to 7.5-8.1; carrying out a reaction to the mixed solution under a heating condition, cooling a reaction product until a crystal is separated out to obtain the product, wherein the mixed solvent is a composition of methanol/water. The complex, at low temperature, shows a field-induced slow-relaxation magnetic behavior.

A naphthalocyanine dye of formula (I) is provided:

wherein M is a metal group or is absent;

• R¹ and R² are independently selected from hydrogen or C_1-12 alkoxy; X is selected from O, S or —NH—;
• Ar¹, Ar², Ar³, Ar⁴, Ar⁵, Ar⁶, Ar⁷ and Ar⁸ are selected from phenyl, naphthyl, pyridyl, furanyl, pyrollyl, thiophenyl, each of Ar¹, Ar², Ar³, Ar⁴, Ar⁵, Ar⁶, Ar⁷ and Ar⁸ being optionally substituted with 1, 2, 3, 4 or 5 groups, the or each group being independently selected from C_1-12 alkyl, C_1-12 alkoxy, C_1-12 arylalkyl, C_1-12 arylalkoxy, —(OCH₂CH₂)_dOR^d, cyano, halogen, amino, hydroxyl, thiol, —SR^v, —NR^uR^v, nitro, phenyl, phenoxy, —CO₂R^v, —C(O)R^v, —OCOR^v, —SO₂R^v, —OSO₂R^v, —NHC(O)R^v, —CONR^uR^v, —CONR^uR^v, sulfonic acid, sulfonic acid salt and sulfonamide; d is an integer from 2 to 5000;
• R^d is H, C_1-8 alkyl or C(O)C_1-8 alkyl; and
• R^u and R^v are independently selected from hydrogen, C_1-12 alkyl, phenyl or phenyl-C_1-8 alkyl. Dyes of this type are especially suitable for use in netpage and Hyperlabel™ systems.