The invention discloses an
imide metal naphthyanine derivative as well as preparation and photovoltaic application thereof, and belongs to the field of
perovskite solar
photovoltaics. The
metal naphthyanine derivative forms a larger pi
conjugated system, and the pi-
pi interaction between molecules can be enhanced by the extension of pi conjugation, so that the charge transfer capability is favorably improved. According to the Lewis acid-alkali theory, molecules containing
electron-donating atoms such as
nitrogen and
oxygen can be used as a passivator to reduce defects in
perovskite. According to the invention, an
imide group with multiple coordination sites is introduced to the periphery of naphthyanine, and the obtained derivative is used as a passivator to be added into a
perovskite thin film in a bulk phase
doping manner, so that not only can non-coordinated ions (such as Pb < 2 + >) be efficiently passivated, but also the perovskite
crystallization process can be regulated and controlled. Finally, the method is beneficial for forming a perovskite
active layer with better
crystallinity, larger grain size and more uniform morphology, and higher
photoelectric conversion efficiency is obtained.