The invention relates to a one-dimensional pyrenyl organic framework
nonlinear optical material as well as preparation and application thereof. The material is prepared from a pyrenyl amino
monomer (Py) and different dialdehyde monomers (PTDE, PTBE and PDA) through direct
Schiff base condensation reaction under a solvothermal condition, a series of one-dimensional linear organic framework material (COF) chain segments are constructed, and a thin
film material is further prepared. The obtained material has highly ordered
crystallinity, an expanded pi-conjugated skeleton and an obvious donor-
acceptor (D-A) charge transfer channel. The one-dimensional pyrenyl D-A COF (Py-PTDE, Py-PTBE and Py-PDA) has the advantages that the one-dimensional pyrenyl D-A COF (Py-PTDE, Py-PTBE and Py-PDA) has the obvious RSA (Reverse Saturated Absorption) effect under the excitation of
femtosecond laser (800 nm and 1550 nm) for the first time; compared with the prior art, in particular to a Py-PTDE material, the effective
nonlinear absorption coefficient (beta eff) of the Py-PTDE material reaches 116.89 cm. GW <-1 > and 337.03 cm. GW <-1 > at 800 nm and 1550 nm respectively, so that the Py-PTDE material is obviously superior to a precursor material and another two COF materials, and shows a lower
optical limiting threshold value at a near-
infrared band. The excellent performance is mainly derived from more effective D-A interaction, narrower optical
band gap and more efficient intramolecular charge transfer channel in the material. The material disclosed by the invention is simple in preparation method and high in
repeatability, and the obtained COF film has excellent
thermal stability and
optical stability, can be directly used for preparing
optical limiting devices and ultrafast optical response devices and can be applied to other three-order
nonlinear optical fields.