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609 results about "Metal chelate" patented technology

Method for catalytic polymerization of alpha-olefin monomers using an ultra-high activity non-metallocene pre-catalyst

A method for catalytic polymerization of alpha-olefin monomers using an ultra-high activity non-metallocene pre-catalyst featuring an amine bis(phenolate) ligand-metal chelate, having general formulas of [{(O)1R1R2R3R4(C6)1(CH2)1(RnY-T)N(CH2)2(C6)2R5R6R7R8(O)2}MX1X2] and [{(O)1R1R2R3R4(C6)1(CH2)1(RnY-T)N(CH2)2(C6)2R5R6R7R8(O)2}MX3], where, M, O, and N, are metal, oxygen, and, nitrogen; X1, X2, and X3, are ligands bonded to M; R1 through R8 are radicals; (RnY-T) is an optional non-donor or donor group bonded to N. The relatively stable and simply synthesized pre-catalyst is activated by a co-catalyst under mild reaction conditions, producing exceptionally reactive polymerization of a wide variety of alpha-olefin monomers, and forming a variety of poly(alpha-olefin) products, having high molecular weight and low molecular weight distribution (PDIs close to 1). Living polymerization is performed at or above room temperature, along with achieving block co-polymerization of alpha-olefin monomers at room temperature, and producing polymers and oligomers having a wide range of molecular weights. The catalyst formed during reaction remains "alive' for as long as 31 hours, for producing a polymer with a molecular weight as high as 450,000 grams/mole.
Owner:RAMOT UNIV AUTHORITY FOR APPLIED RES & INDAL DEVMENT

Soil remediation method

The invention relates to a soil remediation method, which comprises the following steps that: 1) a liquid injecting well for injecting chitosan leacheate through a pump is arranged in a soil polluted area, the chitosan leacheate enters the inside of polluted soil through the liquid injecting well, soil percolate seeps through underground water, and heavy metal active ingredients in the soil and the underground water are eluted by the chitosan leacheate to form stable chitosan-metal chelate; and 2) a permeable reactive barrier filled with active substances is constructed in a direction which is vertical to the flow direction of the underground water at the periphery of the liquid injecting well, the soil percolate and the polluted underground water flow through the permeable reactive barrier filled with the active substances, and polluted substances such as the chitosan-metal chelate and the like in the soil and the underground water are removed. Through the soil remediation method, heavy metals in the soil can be effectively removed, a polluted underground water system can be remediated, and most of the heavy metals contained in the soil and the underground water can be gathered in the active substances of the permeable reactive barrier, so that the heavy metals can be recycled. The heavy metal content of the remediated soil and the water quality of the percolate passing through the reactive barrier meet the corresponding national standard.
Owner:JIANGXI JDL ENVIRONMENTAL PROTECTION CO LTD
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