The invention belongs to the field of functional materials and
water treatment, and provides a preparation method of organic phosphonic acid functionalized super-
crosslinked chitosan hydrogel, which comprises the following steps: dissolving
chitosan in an alkali solution to obtain a
chitosan suspension; adding
benzaldehyde into the
chitosan suspension, and carrying out
condensation reaction to obtain a modified chitosan suspension; reacting the modified chitosan suspension with a quinary organic phosphonic acid solution to obtain an organic phosphonic acid functionalized chitosan solution; adding a
potassium tripolyphosphate solution into the organic phosphonic acid functionalized chitosan solution, carrying out a cross-linking reaction, carrying out
alcohol precipitation after the reaction is completed, carrying out
solid-liquid separation, and collecting a precipitate; dispersing the precipitate in water to obtain a suspension; and uniformly mixing the suspension with a
sodium alginate solution and a
calcium salt solution, and carrying out a cross-linking reaction to obtain the quinary organic phosphonic acid functionalized super-
crosslinked chitosan hydrogel. An organic phosphonic
acid group and a C-P
covalent bond are successfully introduced into a chitosan molecular chain, the morphology structure of original chitosan
powder is greatly improved, adsorption sites on the chitosan molecular chain are enriched, and efficient application of chitosan in
uranium-containing
wastewater is remarkably improved.