2267results about How to "Improve mass transfer efficiency" patented technology

The invention discloses a device and technique for producing cyclohexane by benzene hydrogenation. The device for producing cyclohexane by benzene hydrogenation comprises a reactor, a superfine bubble generator and a bubble breaker, wherein the reactor is provided with a first containing cavity; the wall of the first containing cavity is provided with a feed port, a circulation discharge port, a circulation return port and a gas phase outlet; the superfine bubble generator is provided with a second containing cavity; the wall of the second containing cavity is provided with a return port and a gas phase outlet; the return port of the superfine bubble generator communicates with the circulation return port of the reactor; the bubble breaker is arranged in the second containing cavity; the bubble breaker is provided with a gas phase inlet and a liquid phase inlet which communicates with the circulation discharge port of the reactor; and the gas phase inlet of the bubble breaker communicates with the gas phase outlet of the reactor. The device disclosed by the embodiment of the invention has the advantages of high mass transfer efficiency, high reaction rate, short reaction time, low material consumption and energy consumption, simple structure, low manufacturing cost and low maintenance cost.

The invention discloses a tower-type super fine bubble reactor. The tower-type super fine bubble reactor comprises a body, a primary bubble breaker and a secondary bubble breaker, wherein a reaction cavity is formed in the body, a through hole, a liquid inlet, a circulating liquid outlet, an air inlet and a circulating air outlet are formed in the wall of the reaction cavity, one part of the primary bubble breaker penetrates through the through hole and extends into the reaction cavity, the primary bubble breaker is provided with a circulating liquid inlet, a circulating air inlet and an air-liquid mixture outlet, the circulating liquid inlet is communicated with the circulating liquid outlet, and the circulating air inlet is communicated with the circulating air outlet. The secondary bubble breaker is provided with a feeding port and a discharging port, and the feeding port is communicated with the air-liquid mixture outlet. The tower-type super fine bubble reactor has the advantages of being high in mass transfer efficiency, high in reaction rate, low in energy consumption and the like, the reaction time can be remarkably shortened, and reactor size can be decreased.

The invention discloses a high-specific-surface-area boron-doped diamond (BDD) electrode which comprises an electrode substrate. A boron-doped diamond layer is arranged on the surface of the electrode substrate. Or, a transition layer is arranged on the surface of the substrate, and then a boron-doped diamond layer is arranged on the surface of the transition layer. Metal particles are distributed in the diamond layer, and tiny holes and / or pointed cones are distributed on the surface of the diamond layer. Compared with a traditional plate electrode, the boron-doped diamond electrode contains a large number of tiny holes and pointed cones and has the extremely high specific surface area, and the large current intensity is provided through the low current intensity; and meanwhile, due to the different electrode configurations of the substrate and modification of surface graphene and / or carbon nano tubs (CNT), the mass transfer process can be greatly improved, the current efficiency and the electrochemical property are greatly improved, and the BDD electrode with high electrocatalytic activity and high using efficiency is prepared. The electrode can be widely applied in the fields of electrochemical wastewater purification treatment, electrochemical biosensors, strong oxidant electrochemical synthesis, electrochemical detection and the like.

The present invention is related to hemodialysis, and more particularly, to a dialyser with improved efficiency of mass transfer across a dialysis membrane utilizing microchannel separation provided in accordance with embodiments of the present invention. In accordance with an embodiment, a dialyzer is provided comprising a plurality of semipermeable membrane sheets and a plurality of flow separators. The membrane sheets and flow are arranged in alternating configuration and coupled into a laminae stack defining a plurality of parallel microchannel layers. Each microchannel layer comprises a plurality of first microchannels and a plurality of second microchannels. The first and second microchannels of each microchannel layer are in fluid communication with each other via one of the plurality of membrane sheets therebetween. The MECS dialyzer is characterized as having a high surface to volume ratio and a high mass transfer coefficient.

A manufacturing method of an LED array device uses LED devices with a vertical structure and a mother board, wherein the LED device is provided with a first magnetic part composed of soft magnetic metal; the mother board is provided with a second magnetic part composed of a hard magnetic material, and a base layer without magnetic insulation is arranged on a first plate surface; a driving circuitlayer including a plurality of welding pads arranged on the base layer, and the welding pads are corresponding to the second magnetic part; the LED devices are distributed on the driving circuit layer, the first magnetic part of the LED device is subjected to the acting force of the magnetic field of the welding pad on the second magnetic part, so that the LED device is arranged on the welding padin a positioning way; so that the LED device and the welding pad are bonded with each other; the base layer and the mother board are separated from each other to obtain an LED array device. This approach can quickly and efficiently transfer large amounts of LED devices to the driving circuit layer.

The invention relates to the field of porous materials, in particular to a hollow foam material as well as a preparation method and an application thereof. The hollow foam material is formed by three-dimensional connective support framework networks from the macroscopic angle, the support frameworks are microchannels with hollow structures in three-dimensional connection, the walls of the microchannels are compact or contain nano-scale pores and / or micro-scale pores. The hollow foam material with three-dimensional connective networks is prepared from a polymer resin foam material with three-dimensional connective networks with the structure design and the preparation method. The hollow foam material has three types of pores with adjustable sizes: macroscopic three-dimensional connective open meshes, three-dimensional connective hollow microchannels and nano-scale pores and / or micro-scale pores in microchannel wall bodies. The innovative structure characteristic of the three-dimensionalconnective hollow microchannels of the hollow foam material lays a foundation for application of the hollow foam material.

Disclosed is amultichannel reactor with microstructure. Continuous phase inlet pipe and distribution chamber, discontinuous phase inlet pipe and distribution chamber, mixture phase buffer chamber and fluid outlet pipe connects separately, and they compose the lower cavity. Porous distribution medium is sealed in the upper distribution chamber of discontinuous phase. A parallel channel plate of continuous phase is located above the lower cavity and the upper is sealed. The continuous phase liquid flows into the reactor from the distribution chamber of inlet pipe; the discontinuous liquid flows into the parallel channel of continuous phase following through the distribution medium, distributes into minute drop or air bubble with the floating shearing force of continuous phase liquid, and then connects with the continuous phase liquid to realize the rapid mixture and reaction of the two- phase liquid; then the liquid flows out of the reactor. With the invention, the area of mass transfer is big, the reaction conversion rate is high, and large scale production can be realized.

The adsorbent for adsorbing and separating paraxylene includes active adsorbing component in mass fraction 85-95 % and adhesive in mass fraction 5-15 %. The active adsorbing component is selected from BaX zeolite and BaKX zeolite, and the adhesive is selected from kaolin, silica and alumina, with the crystal grain size of X zeolite in the adsorbent being 0.5-1.0 micron. The adsorbent is suitable for adsorption and separation of paraxylene from C8 arene and has high adsorption selectivity.

The invention relates to a carrier-type TIO2 photo-catalyst, it's preparing method, and a high-absorbability photo-catalysis water purifier made from said material. Said carrier-type TIO2 photo-catalyst uses active carbon fiber base as substrate, which carries 100-600mgTIO2 / g active carbon fiber to form the TIO2 film in 100-300nm thick and the specific surface area in 150-400m2 / g. Said catalyst can be attained by powder plating method, liquid deposition method and sol-gel method of adhesive agent. The invention can keep the former space between active carbon fibers with the advantages that the liquid can freely enter the inner part of photo-catalyst and the ultraviolet light can radiate the inner part of photo-catalyst. The photo-catalysis water purifier with aforementioned carrier-type TIO2 photo-catalyst is in the shape of rectangle, while several photo-catalyst elements with said catalyst are inserted into the slot of purifier, the aeration system on the bottom can mix the treating liquid with air to reduce the mass transfer limit. Said purifier can effectively absorb the action bottom material; and improve the photo-catalysis process to apply the deeply-purification treatment of micro-pollution water.

The invention discloses a method for enhancing the gas-liquid mass transfer of an ebullated bed hydrogenation reactor, which comprises the following processes of: introducing fresh raw oil, circulating oil and hydrogen into a microbubble generator arranged in front of the reactor, fully mixing to make the hydrogen dispersed in a liquid-phase material in the form of microbubbles, and performing hydrogenation and cracking reaction in the ebullated bed reactor. The method can improve the utilization rate of the hydrogen, reduce the volume ratio of the hydrogen to the oil, save operating cost andpromote the depth of the hydrogenation and cracking reaction.

The grating type pneumatic triphase fluidizing comprehensive absorption tower includes one housing, one gas inlet channel and gas outlet channel in the top of the tower, one rotary defogging and dewatering unit, one stuffing assembly comprising support boards, hold-down boards and stuffing, one coaxial tubular grating member, one liquid distributor with ring sprinkler pipe, one large caliber reverse sprayer inside the gas inlet channel, and one absorbing slurry pond in the bottom of the tower. It features the special grating structure, the regularly arranged stuffing for cyclic fluidizing, the combined foam absorption and stuffing absorption, etc, and has high absorption efficiency, great gas treating amount and other advantages.

Horizontal polar plate multi-dimensional electrode electrocatalysis reactor wastewater treatment equipment comprises a shell, a cathode plate and an anode plate which are relatively parallel, a particle electrode filled between the cathode plate and the anode plate, a water distributor, a water inlet pipe, an aerator, an air inlet pipe, an effluent weir trough, a water outlet pipe and a power supply; the cathode plate and the anode plate are respectively connected with the cathode and the anode of the power supply; a plurality of through holes are distributed on the cathode plate and the anode plate which are horizontally positioned in the shell of the equipment; the water distributor, the water inlet pipe, the aerator and the air inlet pipe are positioned at the lower part of the shell of the equipment; and the effluent weir trough and the water outlet pipe are arranged at the upper part of the shell of the equipment. After being evenly distributed by the water distributor, the wastewater flows across a reactor from bottom to top; the horizontal polar plate structure design not only avoids the short circuit of water flow and improves the mass transfer effect, but also ensures that the wastewater can alternatively flow across the cathode plate and the anode plate and the oxidation reaction of the anode plate and the reduction reaction of the cathode plate coexist in a system, and causes different organic pollutants in wastewater which can be degraded by the oxidation reaction and the reduction reaction to be degraded and treated.

The efficient sequencing batch type air lifting circular flow waste water treating bioreactor in alternative anoxia-anaerobic-aerobic process includes one squared or cylindrical reactor unit, one water inlet unit and one water outlet unit as well as one aerating system. The reactor unit includes one reactor body, one triphase separator, conic bottom, air lifting circular flow guide tube and upper deflecting baffle. The present invention also discloses corresponding technological process. By means of the sequencing batch type air lifting circular flow waste water treating bioreactor and the corresponding technological process, double target of oxidizing non-degradable organic pollutant and biological denitrification may be reached in the same reactor, the treated high concentration non-degradable nitrogenous industrial organic waste water may reach the drainage standard, and the residual sludge amount may be reduced by over 80%.

The invention provides equipment and a method for treating nondegradable wastewater by utilizing catalytic oxidation of ozone. The equipment comprises a feeding system, an ozone catalytic reaction tower and a spray absorbing tower; the feeding system comprises a wastewater pH regulation device, a wastewater feeding pipeline, a hydrogen peroxide aqueous solution feeding pipeline, an ozone feeding pipeline and a pH regulator feeding pipeline; the wastewater pH regulation device is communicated with the wastewater feeding pipeline and the pH regulator feeding pipeline respectively; the ozone feeding pipeline is communicated with the wastewater feeding pipeline; the ozone catalytic reaction tower is communicated with the wastewater feeding pipeline and the hydrogen peroxide aqueous solution feeding pipeline respectively so that wastewater undergoes once catalytic reaction in the presence of a first catalyst to generate a liquid flow and an ozone tail gas flow which are subjected to initial treatment; and the spray absorbing tower is communicated with a catalytic reaction system, is used for spraying at least one part of the liquid flow which is subjected to the initial treatment, and is contacted with the ozone tail gas flow in the presence of a second catalyst to undergo second catalytic reaction.

A paracorporeal respiratory assist lung is configured with an annular cylindrical hollow fiber membrane (fiber bundle) that is rotated at rapidly varying speeds. Fluid (for example, blood) is introduced to the center of the device and is passed radially through the fiber bundle. The bundle is rotated at rapidly changing velocities with a rotational actuator (for example, a motor or magnetic coupling). The rotation of the fiber bundle provides centrifugal kinetic energy to the fluid giving the device pumping capabilities and may create Taylor vortexes to increase mass transfer. Rotation of the fiber bundle increases the relative velocity between the fluid and the hollow fibers and increases the mass transfer. The porosity of the fiber bundle may be varied to enhance gas exchange with the blood. Alternatively, a rotating core may be used with a stationary fiber bundle.

Improved contacting modules and apparatuses containing the modules, for carrying out vapor-liquid contacting, are described. In representative contacting modules, liquid (and possibly vapor) are discharged into co-current flow channels in a non-uniform manner (e.g., from only one side of the channels). Particular contacting modules comprise at least one liquid downcomer and a demister, wherein the liquid downcomer and an inlet surface of the demister define a co-current flow channel and wherein liquid is discharged from an outlet of the downcomer. The use of one or more added liquid distribution devices to more uniformly distribute the discharged liquid improves vapor-liquid contacting efficiency in the co-current flow channel and consequently vapor-liquid mass transfer and approach to equilibrium for the contacting stage.

The invention provides a concentric circularity counter-flow type super-gravity rotating packed bed, which comprises a shell, a liquid-phase inlet and a gas-phase outlet arranged on the upper end surface of the shell, a gas-phase inlet and a liquid-phase outlet arranged on the lower end of the shell, a rotating body arranged on the center of the shell, and a rotor connected with the rotating body, wherein the rotor comprises a rotating disc permanently connected with the rotating body and a static disc permanently connected with the shell, the two sides of the lower end of the rotor are provided with first access points, the center of the upper end of the rotor is provided with a second access point, the second access point is communicated with the gas-phase outlet and the liquid-phase inlet, and the first access points are communicated with the gas-phase inlet and the liquid-phase outlet; the rotor also comprises a concentric mesh moving coil, the concentric mesh moving coil is composed of a group of rotating coils which are concentric with different diameters and have meshes, the bottom end thereof is permanently connected on the rotating disc, the upper end is rotationally connected with the static disc, and the first access points and the second access point are communicated with the channel of the concentric mesh moving coil. The invention proposes the concentric circularity counter-flow type super-gravity rotating packed bed with low pressure drop, small rotor liquid holdup and better application effect.

The invention discloses a method for preparing a polymer by micro-scale photo-induced organic catalysis. The method comprises the following steps: using alkyl halide as an initiator in a microreactor; and using an organic small molecule as a catalyst to catalyze atom-transfer radical-polymerization, so as to prepare the polymer. Compared with the prior art, the method provided by the invention has advantages of high reaction speed, controllable molecular weight and molecular weight distribution of a polymerization product, no residue, and wide application in fields of optoelectronic materials and biomedical materials.

The invention relates to a sound absorption material preparation method and a sound absorption material. The method comprises the following steps: S1, preparing non-foaming material slurry, and uniformly mixing; S2, forming the non-foaming material slurry by adopting an oil column forming method, and forming wet particles; S3, drying the wet particles to form dry particles; S4, roasting the dry particles to form sound absorption material particles. The method has the characteristics of simplicity in operation and high reliability, and the formed particles are uniform in size, smooth in surface and good in sphericity degree; particles mutually contact one another in a point-to-point manner and are uniformly stacked, and the bed-process resistance is small. The invention also provides the sound absorption material. The sound absorption material is prepared from a non-foaming material and is of spherical particles. The sound absorption material has the characteristics of high mass transfer efficiency, good sound absorption effect and uneasiness in dusting when in use.

The invention relates to a method for improving the pore structure of a kaolin microsphere in-situ crystallization product. The method comprises the following steps of: preparing kaolin spray microspheres with the particle sizes of between 20 and 110 mu m by using mixed kaolin grout by spray drying, wherein the mixed grout comprises kaolin, deionized water, a dispersant and an organic pore cannelforming template agent; the dispersant is sodium silicate or sodium pyrophosphate; and the organic pore cannel forming template agent is polyvinyl pyrrolidone or polyvinyl alcohol; baking the spray microspheres at the temperature of between 900 and 1,100 DEG C for 1 to 3 hours so as to obtain kaolin baked microspheres; mixing the kaolin baked microspheres with the mullite content of between 2 and12 percent, sodium silicate, a directing agent, solution of sodium hydroxide and deionized water; crystalizing the mixture at the temperature of between 90 and 95 DEG C for 16 to 36 hours; and filtering and drying so as to obtain a crystallization product which has a medium / large-pore structure and comprises a NaY molecular sieve. The crystallization product has a well-developed large-pore structure and the abrasion index of not more than 1.5 percent and comprises 20 to 50 percent of NaY molecular sieve.

The invention essentially relates to a filter material for treating sewage, in particular to relate to a filtering material used in the sewage process technique of aeration biology filtering pool. The filtering material of sewage process of the aeration biology filtering pool is characterized in that the components of the raw material of the filtering material consists of by fly ash of 60 to 75 percent, portland cement of 10-20 percent, quick lime of 10-20 percent, gypsum 3-5 percent and degreasing aluminum powder of 0.06-0.08 percent. The preparation includes the following steps of pulping, stirring, pouring, cutting forming and ball milling. Under the optimal proportion of the air and water and the optimal water force load, the life sewage is treated by the aeration biology filtering pool with adding the fly ash to the gas concrete particle. When the average concentration of the water inlet is 176mg / L, the average removal rate of the CODis 75.3 percent, the average concentration of water inlet is 42.7mg / L, the average removal rate of the NH3-N is 96.4 percent, the average concentration of the water outlet is 0.87mg / L which meets the GB18918-2002 grade A standard of the sewage discharging.

The invention discloses a gas-liquid distributor, belonging to the field of petrochemical equipment. The gas-liquid distributor comprises gas-phase cofferdams, liquid guide pipes, mixed components, a non-return ball, an end cover, etc, wherein the mixed components are formed by contraction sections, throat pipes, extension sections and straight pipe sections from bottom to top; the walls of the throat pipes are provided with a plurality of gas inlets; gas-liquid runners are arranged on the straight pipe sections; the non-return ball is arranged in the extension sections and the straight pipe sections; and the end cover is sealed at the upper ends of the straight pipe sections. The gas-liquid distributor has simple structure, small volume, low pressure drop and high mass transfer efficiency, is especially suitable for realizing gas-liquid distribution with gas-solid-liquid phases in fluidized state in a fluidized bed reactor and can be widely applied to the fields of petrochemical industry and environmental protection.

This invention discloses cyclohexane air dioxide prepare cyclohexanol, cyclohexanone and adipic acid technique and equipment. Its technique is that in series connecting reaction system in a 4-8 grade kettle reactor that contains agitator, or series connecting reaction system in a 3-7 bubbling column reactor that contains outer cycle, or series connecting reaction system in 2-6 different type reactor, cyclohexane that added catalyst of 1-100PPM metalloporphyrin and 0.1-2.0 PPM air, or oxygen or oxygen enriched air or oxygen denubed air is let in. temperature is 120-160 degree centigrade, reaction for 45-120 minutes. Corresponding equipment is also included in this invention. This invention can restrain train side reaction and reduce generating of depthoxide, so cyclohexane conversion, reaction selectivity and oxidation products yield can be improved.

The invention discloses a low-pressure-drop nano / microstructure filler revolving bed supergravity device and application thereof and belongs to the technical field of supergravity. The supergravity device comprises a rotating part formed by arranging a rotor and a filler in a closed shell, wherein the shell and an upper cover have a liquid inlet, a liquid outlet, a gas inlet and a gas outlet; and a liquid distributor extending into a central cavity of the rotor is arranged in the liquid inlet. In the device, the filler in the rotating part is a structuralized SiC, sintered ceramic and powder sintered titanium-based alloy filler with a nano / microstructure, the runner diameter of the structuralized filler is 0.1 to 5mm, the porosity is 55 to 97 percent, the surface of the filler has a 0.01 to 3-micrometer convexoconcave nano / microstructure, and the specific surface area of the filler is 200 to 2,000m<2> / m<3>. When the device is used for deeply removing sulfur dioxide from industrial gases such as sulfuric acid industrial tail gas with low-pressure-drop requirement, the pressure drop of the supergravity device is lowered by 40 to 80 percent, and the harmful gas content after treatment is lower than 20 to 100ppm.

The invention belongs to the technical field of solid waste treatment and resource recovery, and relates to an apparatus for pyrolyzing solid wastes through molten salt, and a method thereof. The method uses the molten salt as a pyrolysis medium, the solid wastes are immersed in the molten salt and are effectively dissociated and decomposed under preset pyrolysis conditions, and various resource substances can be recovered. Pyrolysis products of organic components in the solid wastes are recycled as energy and resource substances. The method has the advantages of short process flow and simple operation. The apparatus allows the above raw material to be sent into or moved out of a molten salt reactor through a pyrolysis basket, and comprises a gas inlet, a gas outlet, and a feeding and discharging gate. The method uses the high heat accumulation capability and high heat conduction rate of the molten salt, effectively improves the decomposition rate of organic matters and the energy utilization rate, traps or converts acidic gases and harmful substances by using the characteristic of reaction of the molten salt with the acidic gases and the harmful substances, reduces secondary pollution to environment, and improves the cleanliness and resource of products.

The invention discloses an advanced oxidative coupling device and process for treating organic wastewater difficult to degrade. A main device body comprises an ozone oxidation-multi-dimensional electro-catalysis / microelectrolysis area, an ozone oxidation-microelectrolysis / Fenton area, a coagulation area and an inclined plate sedimentation area, wherein the ozone oxidation-multi-dimensional electro-catalysis / microelectrolysis area comprises a multi-dimensional electrolysis / microelectrolysis area at the upper part and an ozone oxidation area at the lower part; the ozone oxidation-microelectrolysis / Fenton area comprises a microelectrolysis / Fenton area at the upper part and an ozone oxidation area at the lower part. The device combines four levels of advanced oxidation systems, and electrocatalytic oxidation, ozone oxidation, Fenton oxidation and a microelectrolysis reaction are mutually coupled in function, so that an organic matter difficult to degrade is subjected to multi-level oxidation to realize complete oxidative cracking; when the device is used for treating the organic wastewater difficult to degrade, the yield and the production rate of *OH are increased, the liquid phase transfer process is accelerated, the overall current efficiency of the device is increased, operation expenses are saved, flexible regulation and control of a process unit are realized, and the device can be used for treating various kinds of organic wastewater difficult to degrade.

The invention discloses a method for preparing polymethoxy dimethyl ether through reaction and rectification of a fixed bed. The method comprises the following steps: (1) preheating trioxymethylene, uniformly mixing the preheated trioxymethylene and methylal, and feeding the trioxymethylene and the methylal which are uniformly mixed into a fixed bed reactor for an etherification reaction; (2) feeding materials after the etherification reaction into a reaction rectifying tower for the reaction and the rectification, and discharging PODE2-8 from the tower bottom of the reaction rectifying tower; (3) transporting the PODE2-8 to a dewatering tower loaded with a 3A molecular sieve for dehydration, then transporting the dehydrated PODE2-8 into a first refining tower, transporting materials which are discharged from the tower bottom of the first refining tower into a second refining tower, discharging PODE3-5 from the tower top of the second refining tower, and discharging PODE6-8 from the tower bottom of the second refining tower. When the method disclosed by the invention is used for preparing the PODE3-8, the yield of the polymethoxy dimethyl ether can reach 95%, wherein the products of the PODE3-8 can reach 80%-95%, and after refinement, the PODE3-5 of which the quality purity reaches 99.9% can be obtained.

The invention provides a system for enriching denitrified anaerobic methane oxidized microorganisms and a method thereof. The system comprises a hollow fiber membrane reactor which comprises a shell, an upper flange arranged at the top end of the shell and a lower flange arranged at the bottom end of the shell. A water inlet is arranged on the lower part of the shell, a sampling opening is arranged in the middle, and a water outlet is arranged on the upper part. The upper flange is provided with an air outlet and the lower flange is provided with an air inlet. The shell is internally provided with a hollow fiber membrane beam which is closed at the upper end and opened at the lower end and is connected with the air inlet. A methane supply device is connected with the air inlet of the hollow fiber membrane reactor. A water supply device is connected with the water inlet of the hollow fiber membrane reactor. Through the system provided by the invention, inoculums are added. The system operates according to a sequence mode and a continuous flow mode, so that the utilization ratio of methane is improved, and the enriching time of denitrifying anaerobic methane oxidation microorganisms is shortened.

The invention discloses a three dimension electrode reaction unit, which is characterized in that short flow of wastewater is avoided by arranging plate-type main electrodes placed in a parallel staggered manner, insulation baskets with holes and particle electrodes filled therein, aerator pipes, insulation frames of which the surfaces have fine wire screens, support pins and tees, so that the wastewater is more uniformly mixed and the retention time is simultaneously reduced; the aeration is more uniform, the degree of mixedness of the wastewater is deepened, and the mass transfer efficiency is greatly improved; the partitioning design of the particle electrodes can omit a discharge opening of a traditional device, so that loading and unloading of the particle electrodes are more convenient and cleaner, and the partitioning design of the particle electrodes also can block a short-circuit current difficult to overcome in a traditional three dimension electrode reaction unit, and economy, green and high efficiency are realized; a gas-liquid mixture can be removed while mixing and effluent discharging are performed; the occurrence of a siphon problem can be avoided; the height of the wastewater can be controlled through the length of a discharging tube, thus a basic parameter, namely the filling amount of the particle electrodes, is controlled, and a better treatment effect is further obtained.