4666results about "Fractional distillation" patented technology

The invention discloses a dynamic intelligent control method and system for improving the efficiency of a rectifying tower, particularly relates to the technical field of chemical process control, and is used for solving the technical defect that an operation variable is mismatched with a physical state due to the fact that an existing distributed control system cannot recognize a hidden degradation state of equipment. The method comprises the following steps: acquiring temperature gradient distribution of each tower plate of a rectifying tower, thermal load of a reboiler and tower top condensation load parameters in real time, calculating a mass transfer efficiency offset by combining the temperature gradient distribution to generate a scaling trend index, and synchronously calculating a local entropy yield based on the thermal load and the condensation load to generate a thermodynamic irreversibility index. When the double indexes exceed a preset threshold value, it is judged that a recessive degradation state is entered, then a backflow ratio correction coefficient is reversely derived through a dynamic correlation model, and the correction coefficient is input into a distributed control system to dynamically adjust backflow ratio operation parameters; the product purity is maintained, the tower plate scaling process is obviously delayed, and long-term efficient operation of the rectifying tower is guaranteed.

A method for producing a tin compound represented by formula (A1) with a purity of 95 mol % or higher, involves a step of distilling the tin compound, in which the number of plates of the distillation is 10 or more, and the reflux ratio is 30 or less.RSnX3  (A1)In formula (A1), R is an organic group with 1 to 30 carbon atoms, and may be substituted with halogen, oxygen atoms, or nitrogen atoms. X is selected from OR′ and NR′2. R′ is an organic group with 1 to 10 carbon atoms, and part may be substituted with halogen, oxygen atoms, or nitrogen atoms. When there are multiple R′ groups in the molecule, they may have the same or different structures, and they may be bonded to each other to form a cyclic structure.

The invention discloses preparation equipment and a preparation process for preparing high-purity electronic-grade thionyl fluoride, and the preparation equipment comprises a mixer, the mixer is communicated with a first preheating device, the first preheating device is communicated with a first rectifying tower, the top of the rectifying tower is connected with a condenser, the condenser is communicated with a crude product tank, the crude product tank is communicated with a second preheating device, and the second preheating device is communicated with a second rectifying tower. The second preheating device is communicated with a second rectifying tower, the second rectifying tower is communicated with a third rectifying tower, the third rectifying tower is connected to a storage tank, the storage tank is connected with a vaporization device, the vaporization device is pressurized and then stored in a high-pressure buffer tank, the high-pressure buffer tank is connected with at least three adsorption towers, and the adsorption tower at the rearmost end is connected with a high-pressure product tank. According to the invention, the purity of the finished product is improved, and all raw material components are fully utilized.

The utility model relates to the technical field of heat pump rectification, and particularly discloses a heat pump rectification system which comprises a rectification tower; the tower top gas liquefaction system comprises a compressor connected with a gas phase at the top of the rectifying tower, and a reboiler, a throttling device, a condenser and a flow divider which are sequentially connected with the compressor; liquid phase connection at the bottom of the rectifying tower is communicated with the reboiler, the tower bottom reboiling system comprises an auxiliary reboiler and a flash evaporator which are sequentially communicated with the reboiler, and the flash evaporator is communicated to the rectifying tower; and the gas phase at the top of the rectifying tower is heated by the compressor and then enters the reboiler to exchange heat with the liquid phase at the bottom of the rectifying tower, so that the rectifying energy consumption can be reduced, and the energy-saving effect is achieved.

The invention discloses an electronic-grade nitric acid preparation device and method capable of controlling the filtering speed based on temperature difference, and relates to the technical field of nitric acid preparation.The electronic-grade nitric acid preparation device comprises a first-stage rectifying tower and a second-stage rectifying tower, and a first-stage evaporator and a second-stage evaporator are arranged on the outer sides of the bottoms of the first-stage rectifying tower and the second-stage rectifying tower respectively; compared with an existing filtering part, the temperature control assembly is arranged, the temperature control assembly has double functions, on one hand, liquefied nitric acid entering the filter is preheated, and on the other hand, the filtering speed of the filtering assembly on nitric acid is changed according to needs; in addition, a filling disc is accurately rotated through a reversing motor, so that a target material storage cavity is isolated from the rectifying tower main body, and the risk of negative pressure damage or harmful gas leakage in the tower in the traditional dismounting process is avoided.

The invention belongs to the technical field of chemical production, and particularly relates to an efficient energy-saving refining system for producing cyclohexanone through dehydrogenation, which comprises an alcohol tower, a dehydrogenation heat exchanger, a dehydrogenation reactor, an alcohol tower feeding heat exchanger, a dehydrating tower, a light tower I, a light tower II, a ketone tower and an alcohol recovery tower which are connected in sequence, a middle feeding port of the alcohol tower is communicated with a tube pass discharging port of the alcohol tower feeding heat exchanger, a top discharging port of the alcohol tower is communicated with a tube pass feeding port of the dehydrogenation heat exchanger, a bottom discharging port of the alcohol tower is communicated with a middle feeding port of the alcohol recovery tower, and an alcohol ketone drying tower is additionally arranged between the alcohol tower feeding heat exchanger and the dehydration tower. A feed port of the alcohol ketone drying tower is communicated with a shell pass discharge port of the alcohol tower feed heat exchanger, and a liquid phase discharge port of the alcohol ketone drying tower is communicated with an upper feed port of the dehydrating tower. The alcohol tower adopts a process that raw materials directly enter the tower top, tower top reflux is cancelled, steam consumption is reduced, and the purpose of saving energy is achieved.

The invention relates to the technical field of chemical engineering, in particular to a method and a device for removing heavy components from cyclohexanol. Comprising the following steps: a, rectifying a cyclohexanol-containing material from a cyclohexene hydration reaction to obtain a first solution containing cyclohexanol and heavy components in a tower kettle; b, carrying out heavy component removal operation on the first solution to obtain a third solution containing a catalyst and heavy components, a first gas phase and a second gas phase; and c, rectifying the first gas phase and the second gas phase to obtain a fourth solution subjected to heavy component removal, namely cyclohexanol subjected to heavy component removal. The entrained catalyst and heavy components are removed together, and the fluidity required by the catalyst waste liquid is maintained by using the heavy components, so that the loss of cyclohexanol is reduced.

The invention discloses a rectification mechanism and a carbon disulfide production system containing the same. The rectification mechanism comprises an integrated rectification tower, and an inner cavity of a shell of the integrated rectification tower is sequentially divided into a function-integrated pre-separation and sulfur removal area, a main rectification and hydrogen sulfide removal area and a condensation reflux area from bottom to top in the vertical direction; the pre-separation and sulfur removal area comprises a settling tank arranged at the lower part of the shell, a gathering cover arranged above the inner wall of the settling tank, and a gas rising pipe I arranged above the gathering cover; the invention belongs to the technical field of chemical separation, and achieves the technical effects that multi-stage functions of pre-separation, main rectification, precise purification, final condensation and the like are innovatively integrated in a single tower, so that the fundamental simplification and compactness of the equipment structure are realized; in the traditional process, separate coarse removal, fine removal and finished product towers are replaced by unique expanded settling tanks in the towers, filler layers of integrated plate heat exchangers, tower tops with spiral condensation channels and side-draw systems.

The invention relates to the technical field of chemical separation, in particular to a cyclohexanone rectification and purification method based on high-tower segmented packing, which comprises the following steps: step 1, filtering a cyclohexanone raw material containing impurities to remove solid particles, and dynamically adjusting the filtering precision according to the viscosity of the raw material; 2, arranging a bottom section, a middle section and a top section in the vertical high tower; the temperature gradient of each section is regulated and controlled through an independent temperature control unit, so that the temperature gradient of the middle section is matched with the relative volatility of the cyclohexanone-light component; 3, dynamically adjusting the reflux ratio based on the real-time detection result of the purity of the tower top distillate, and controlling an intermittent discharge valve according to the density change of the tower bottom heavy component enrichment liquid so as to continuously remove the heavy components; and 4, recycling the waste heat of the steam at the top of the tower for preheating the raw materials, and inhibiting the tower pressure fluctuation through a buffer tank. Through the innovative design of sectional packing of the high tower, the separation efficiency is improved, the energy consumption is reduced, and meanwhile, the equipment reliability is improved.

The invention discloses a preparation method of phosphorus oxyfluoride based on reaction separation equipment, which comprises the following specific steps: S1, a heat exchange medium enters a driving pipe fitting through a heat exchange medium inlet pipe of the reaction separation equipment, is pressurized at a discharge end of the driving pipe fitting and then is sprayed out in a horizontally outward inclined manner, a heat exchange mechanism and a second filler layer of the reaction separation equipment are driven to integrally rotate, so that a circulating heat source circularly passes through the whole reaction area; s2, respectively feeding liquid industrial phosphoric acid and gaseous anhydrous hydrogen fluoride when the reaction temperature of the reaction zone reaches a set value; s3, liquid industrial phosphoric acid and gaseous anhydrous hydrogen fluoride are in contact on the surface of the rotating second filler layer and react to generate phosphorus oxyfluoride gas; and S4, extracting phosphorus oxyfluoride gas generated by the reaction along the top of the reaction separation tower body. The controllability of the reaction process can be effectively ensured, and the reaction effect is obviously improved.

This application relates to the field of rectification equipment, and particularly to a rectification column with an anti-blocking structure, including: a tray, on which sieve holes are formed; a floating ball, arranged above the sieve holes, the diameter of the floating ball being larger than the diameter of the sieve holes, and a plurality of concave grooves being formed on the peripheral wall of the floating ball; a plurality of elastic arc plates, symmetrically fixed above the sieve holes, the upper ends of the plurality of elastic arc plates forming an open end with a diameter smaller than the diameter of the floating ball, a spacing being formed between adjacent elastic arc plates, and a gap being formed between the inner wall of the elastic arc plate and the peripheral wall of the floating ball. This application has the effect of reducing the probability of tray blockage.

The utility model provides a compound device for providing feed gas for preparing green ammonia from new energy and a green ammonia synthesis system. The composite device comprises a deep cooling air separation nitrogen generation subsystem, a hydrogen supply subsystem and a main heat exchanger, and the hydrogen supply subsystem comprises a water electrolysis hydrogen generation unit, a first hydrogen compressor, a second hydrogen compressor, a hydrogen storage tank and a hydrogen conveying pipeline. The hydrogen conveying pipeline comprises a first hydrogen conveying pipeline, a second hydrogen conveying pipeline and a third hydrogen conveying pipeline; the main heat exchanger is a multi-channel heat exchanger and comprises a first flowing channel used for flowing of a first medium and a second flowing channel used for flowing of a second medium, the second hydrogen compressor is connected with the hydrogen storage tank through the first flowing channel, and the hydrogen storage tank is connected with the third hydrogen conveying pipeline through the second flowing channel. The composite device provided by the utility model can ensure the supply stability of the raw material hydrogen of the ammonia production subsystem, and solves the technical problem that the hydrogen supply is unstable in the existing green ammonia synthesis process.

The invention relates to the technical field of chemical engineering, in particular to a simple and safe ammonia residual gas recovery system which comprises a liquid ammonia storage tank (1), an accident ammonia absorption tower (2), a circulating pump set, a gas phase pipeline and a liquid phase pipeline, the circulating pump set comprises a circulating water pump, a compression pump and a waste heat recovery pump, the waste heat recovery pump is connected with a steam valve, and the liquid ammonia storage tank (1) is connected with a gasifier (11). The vaporizer (11) is connected with the buffer tank (12), the buffer tank (12) and the accident ammonia absorption tower (2) circulate pure ammonia gas through a gas phase pipeline, the accident ammonia absorption tower (2) and the liquid ammonia storage tank (1) circulate pure liquid ammonia through a liquid phase pipeline, the absorption tank (21) adsorbs exhaust gas detected by the accident ammonia absorption tower (2), and recovered nitrogen is used for purging the liquid ammonia storage tank (1), so that escape-free environment-friendly treatment and recycling of ammonia are realized.

Embodiments of the present disclosure relate to a method and system for producing refined hydrocarbons from waste plastic pyrolysis oil. The method and system for producing refined hydrocarbons from waste plastic pyrolysis oil according to the embodiments of the present disclosure may minimize formation of an ammonium salt (NH4Cl) and may prevent an adhesion phenomenon of impurity particles in a reactor in a refining process of waste plastic pyrolysis oil containing impurities including chlorine and nitrogen. In addition, the method and system for producing refined hydrocarbons according to the embodiments of the present disclosure may have excellent refining efficiency and may implement a long-term operation of a process because deactivation of a catalyst used in the process is prevented, and may produce refined hydrocarbons having a low content of impurities and a low content of olefins from waste plastic pyrolysis oil.

The invention relates to the technical field of chemical waste liquid rectification separation, in particular to a solvent rectification device for chemical waste liquid treatment, which comprises a frame, two mounting boxes, a tower body and the like, the frame is connected with the two mounting boxes, the tower body is mounted on the two mounting boxes, and the mounting boxes are communicated with the tower body. Chemical waste liquid can be injected into the tower body through the waste liquid pipe, a high-boiling-point solvent can be injected into the tower body through the solvent pipe, the original azeotropic condition is broken, and the relative volatility among components is changed, so that rectification separation is realized, the filler can be conveyed upwards through the spiral conveyor, the filler is conveyed into the tower body for loading, and the production efficiency is improved. The sliding plate can be driven by the lead screw motor to move rightwards, so that the discharge hole corresponds to the tower body, old filler falls onto the material guide plate through the discharge hole and rolls leftwards to be discharged, the filler is automatically cleaned and replaced, manpower and material resources can be saved, and the safety can be improved.

The invention discloses an efficient purification method of rBHET, and belongs to the technical field of waste polyester recycling. A reaction raw material obtained after premixing of waste PET polyester raw material particles and a catalyst and ethylene glycol are jointly and continuously introduced into a depolymerization reactor, the reaction raw material and ethylene glycol in the depolymerization reactor are mixed and pass through a plurality of rotating discs, and the materials form a flowing film on the rotating discs rotating at a high speed to promote depolymerization; depolymerization reaction liquid generated in the depolymerization reactor enters a temporary storage tank to be stored after being subjected to impurity removal, the depolymerization reaction liquid in the storage tank is introduced into a rectifying tower to be primarily concentrated and purified, obtained concentrated liquid enters an evaporator to be secondarily concentrated and purified, obtained secondary concentrated liquid enters a cooler to be cooled and then enters a product tank to be crystallized; and drying the crystallized solid to obtain a high-purity rBHET product. According to the method, the production efficiency is improved, and the purity of rBHET is effectively improved.

The utility model discloses a heat source optimizing device for a reboiler of a methanol pre-rectifying tower, which comprises the pre-rectifying tower and the reboiler, and is characterized in that a branch pipeline is separated from the crude methanol discharge of a tower kettle and is connected with a negative pressure flash tank, and the crude methanol in the negative pressure flash tank is subjected to gas-liquid separation through flash evaporation; the bottom of the negative-pressure flash tank is connected with a methanol circulating pump, and a liquid-phase material is conveyed to a first heat exchanger at the top of the tower and returns to the negative-pressure flash tank after exchanging heat with steam at the top of the tower; a gas-phase material in the negative-pressure flash tank enters a compressor, is compressed and heated and then returns to the tower kettle of the pre-rectifying tower; according to the utility model, the process is improved by combining flash evaporation of a tower kettle discharge part with heat pump rectification, and meanwhile, the flash evaporation liquid is recycled to recycle steam heat at the top of the tower, so that the steam consumption of a reboiler of the methanol pre-rectifying tower and the use amount of circulating water at the top of the tower are effectively reduced, meanwhile, the reboiler does not need to be added, and the compression ratio of a heat pump compressor can be reduced.

The invention provides an NMP (N-Methyl Pyrrolidone) purification process based on an NMP rectification system, the process is completed by matching a tail gas desorption tower, the space in the tower is divided into an adsorption bin and a desorption bin by arranging a middle box body, two groups of adsorption devices capable of alternately entering the two bins are mounted, and automatic switching of the adsorption devices is realized by utilizing a driving mechanism; when the adsorption efficiency of one group of adsorption devices is reduced, the adsorption devices are automatically transferred to the desorption bin for regeneration treatment, meanwhile, the other group of adsorption devices enter the adsorption bin to continue working, and in the desorption process, low-pressure saturated steam and hot nitrogen are adopted for purging, so that residual moisture is effectively removed, and the adsorption activity is recovered; compared with the prior art, the process has the advantages that gas exchange in the adsorption and desorption process is reduced, the sealing performance and the air pressure balance control capability of the system are improved, the process ensures continuous production, meanwhile, the energy consumption and the discharge pressure are remarkably reduced, and the NMP purification efficiency and the product quality are improved.

The utility model relates to a supergravity bed cylinder and a supergravity bed, the supergravity bed cylinder comprises a cylinder body shell and a cylinder body bottom plate which is arranged in the lower end of the cylinder body shell and divides the interior of the cylinder body shell into a lower cavity and an upper cavity, the lower surface of the cylinder body bottom plate is provided with a reinforcing ring located in the lower cavity, and the upper surface of the cylinder body bottom plate is provided with a reinforcing ring located in the lower cavity. A plurality of radial reinforcing ribs which are circumferentially distributed are further arranged on the lower surface of the barrel body bottom plate, the outer ends of the radial reinforcing ribs are connected with the inner wall of the barrel body shell, and the inner ends of the radial reinforcing ribs are connected with the outer wall of the reinforcing ring; and the lower end part of the cylinder body shell is connected with a reinforcing ring plate connected with the bottom sides of the radial reinforcing ribs. The large-size rotating bed has the advantages that the strength of the bottom of the barrel is improved, the structural strength of the barrel is improved by the aid of the reinforcing rings, the radial reinforcing ribs, the reinforcing ring plates and other components, deformation of the barrel is prevented, and the problems of structural strength and production safety of the large-size rotating bed are solved.

The invention provides a device and a method for removing MIBK (methyl isobutyl ketone) in raffinate for extracting and separating zirconium and hafnium, the device comprises a tank body, a liquid distribution ring is fixedly connected in the tank body, one side of the liquid distribution ring penetrates through the tank body and is outwards communicated with a feeding pipe, a plurality of spray heads are arranged below the liquid distribution ring in a penetrating manner, the outer end of the tank body is fixedly connected with a bracket, and the bracket is fixedly connected with a rotating shaft. According to the device, raffinate can be quickly conveyed into the tank body by arranging a liquid distribution ring and a spray head, rotation of a rotating shaft and a rotating plate can be completed in cooperation with a gear assembly, the fallen raffinate is scattered, it is ensured that the raffinate can uniformly fall on a steam heating pipe, and the raffinate is uniformly heated; meanwhile, the contact area of the gas phase and the liquid phase can be increased in cooperation with the condensation assembly, the phase splitting barrel and the grid plate, the MIBK separation efficiency is improved, and the purpose of rapidly removing oil is achieved through the principle that the volatility is affected by factors such as liquid diffusion and temperature.

A method is provided for synthesizing bio-based LPG from renewable sources via a bio-based synthetic gas feedstock, using a solvent absorption process and a solid adsorption process for recovering LPG in high yield while providing for high recovery and reuse, with low pressure drop, of unreacted synthesis gas components.

The invention relates to the field of heavy water production, and discloses an energy-saving rectification heavy water separation process which comprises the following steps: (1) heating feed water, and carrying out primary rectification; (2) compressing steam at the top of the first-stage rectifying tower, then supplying heat to a first reboiler, performing heat exchange condensation on the compressed steam to form tower top produced liquid for first-stage rectification, enabling one part of the tower top produced liquid to flow back to the first-stage rectifying tower, and discharging the other part of the tower top produced liquid as first-stage rectification distillate; (3) a stripping section base solution of the first-stage rectifying tower flows into a first reboiler, and a part of the stripping section base solution is boiled to form rising steam; the rest part enters a tower kettle and is extracted as heavy water or used as feeding water for next-stage rectification; and (4) carrying out N-stage rectification and purification until the heavy water meets the purity requirement. According to the scheme, the boiling difference between water and heavy water is extremely small, tower top condensation heat is equivalent to a heat source required by a tower kettle, tower top steam is used for providing heat for the tower kettle, latent heat of steam is fully utilized, energy consumption is greatly reduced, and a large number of heat sources can be obtained with a small amount of power consumption.

The invention discloses a multi-stage distillation control method and system for fatty acid ester refining, and the method comprises the steps: collecting the temperature, pressure, component concentration and flow data of each tower of a multi-stage distillation system in real time, and obtaining a real-time operation state vector representing the overall operation situation of the current system; according to the real-time operation state vector, obtaining a global optimization instruction set containing optimal set temperature, set pressure, reflux ratio and inter-tower energy flow instructions of each tower; according to the inter-tower energy flow instruction, obtaining a real-time energy flow map for realizing cross-tower energy cascade matching; according to the global optimization instruction set and the real-time energy flow atlas, obtaining a stable rectification operation state matched with the optimization target and the energy flow atlas; and obtaining a system self-healing state for maintaining continuous and stable output of the high-purity fatty acid ester according to abnormal disturbance characteristics continuously monitored in a stable rectification operation state. By utilizing the embodiment of the invention, global cooperative control of multi-stage distillation can be realized, and the separation purity and the energy efficiency ratio are improved.

It has been discovered that heat energy may be captured from various process streams in a chemical recycling facility, such as the pyrolysis effluent streams, pyrolysis gas streams, and pyrolysis flue gas streams. More particularly, it has been discovered that residual heat energy from various process streams in a chemical recycling facility may be used to preheat waste plastic streams and provide heat for waste plastic pyrolysis. Consequently, the pyrolysis processes and systems described herein may obtain a lower carbon footprint.

The invention discloses a storage medium, and an optimization method, device and equipment for a multi-effect rectification process flow. The method comprises the following steps: constructing a mechanism model comprising each rectification tower in a multi-effect rectification system; respectively constructing a first correlation function and a second correlation function; generating a data set of a preset group number of process parameters; the data set serves as input, and the reboiler thermal load of the highest-pressure rectifying tower is obtained through mechanism model calculation and serves as theoretical output; taking the data set of the process parameters and theoretical output as modeling data, and generating a prediction model capable of predicting the thermal load of the reboiler of the highest-pressure rectifying tower according to the process parameters through deep learning; and obtaining predicted parameter values of the controllable process parameters when the maximum pressure rectifying tower reboiler has the minimum energy consumption through the prediction model. According to the method, the number of process parameters participating in calculation and the solving difficulty in subsequent optimization calculation can be greatly reduced, and the calculation efficiency of obtaining the optimal solution can be effectively improved.

The utility model relates to the technical field of chemical separation, and provides a dividing wall column and a rectification device.The dividing wall column comprises a column body, a partition plate, a first distributor and a first liquid collection tray, the partition plate is arranged in the column body and extends in the height direction of the column body, and the top face of the partition plate and the inner top wall of the column body are arranged at intervals in the height direction of the column body; the bottom surface of the partition plate and the inner bottom wall of the tower body are arranged at intervals; in the height direction intersecting with the tower body, one side wall face of the partition plate and a part of the inner wall of the tower body define a feeding section, the other side wall face of the partition plate and the other part of the tower body define a discharging section, the first distributor is arranged in the feeding section and connected with the tower body and the partition plate, and the first liquid collecting disc is arranged in the discharging section and connected with the tower body and the partition plate. According to the invention, the problems of high energy consumption and large occupied area when silicate ester is separated in a double-tower rectification mode can be solved.

The invention provides an NMP waste liquid rectification system and process for a lithium battery, and relates to the technical field of NMP waste liquid treatment. The rectification system comprises a dehydrating tower and a product tower which are connected in series, the dehydrating tower is connected with the raw material tank, a condenser 1 is arranged at the top of the dehydrating tower, a reboiler 1 is arranged at the bottom of the dehydrating tower, and the bottom of the dehydrating tower is connected with the product tower; a condenser 2 is connected to the top of the product tower, a reboiler 2 is arranged at the bottom of the product tower, a concentrator is connected to the bottom of the product tower, and a kettle residue discharge outlet is formed in the bottom of the concentrator; a condenser 3 is arranged at a side line extraction opening of the product tower and is connected with a finished product storage tank; and a plurality of layers of tower plates are arranged in the dehydrating tower and the product tower, and are filled with structured packing. The preparation process comprises the following steps: dehydrating and removing amine, extracting a main product from a side line, and recycling a high-boiling residue. According to the invention, double towers are used together, and the product is extracted from a side line and has high quality; and more heat sources are saved, the production cost is low, and operation is easy and safe.

The invention discloses gamma-butyrolactone single-tower rectification equipment and a treatment process thereof, and relates to the technical field of gamma-butyrolactone preparation.The gamma-butyrolactone single-tower rectification equipment comprises a feeding pump, a rectification tower, a first cooler, a second cooler, a hazardous waste storage tank, a finished product storage tank and a vacuum pump, the rectification tower comprises a tower shell, and tower plates are evenly arranged in the tower shell in the height direction; an overflow weir is arranged on one side of the tower plate, and a downflow plate is connected below the overflow weir; bubble cap assemblies are uniformly distributed above the tower plate, and each bubble cap assembly comprises a breather pipe, a rotary steam distribution component and a cyclone structure; the bottom end of the ventilation pipe is fixed at the top of the tower plate and forms a ventilation channel penetrating through the tower plate; the top end of the ventilation pipe is higher than the highest point of the overflow weir. Through structural innovation and process optimization, high purity of the product is guaranteed, energy consumption and material consumption are reduced, high efficiency, intelligence and environmental friendliness are achieved, and an advanced solution is provided for rectification production of gamma-butyrolactone.

The invention discloses methylamine rectification equipment, a separation and purification assembly and a purification process, and relates to the technical field of methylamine processing.The methylamine rectification equipment comprises a tower body, a skirt is arranged at the bottom of the tower body, a manhole is formed in the side face of the skirt, a drain pipe is arranged at the bottom of the tower body, a ventilation hole is formed in the side face of the skirt, and a steam ingress pipe is arranged at the bottom of the side face of the tower body; a liquid inlet pipe is arranged on the side face of the tower body, a backflow pipe and a tower body top hanging column are arranged on the two sides of the top of the side face of the tower body respectively, a steam guide-out pipe is arranged at the top end of the tower body, a gas-liquid separator is arranged on the top side of the interior of the tower body, and tower plate assemblies are vertically arranged in the tower body in a staggered mode. Moreover, when the tower plate leaks liquid, monitoring is carried out in time, process parameters are adjusted in time, in addition, the flow speed of liquid on the tower plate can be adjusted conveniently according to production requirements, and blockage clearing can be intervened in time conveniently when the tower plate is blocked.

The invention provides an electronic-grade hydrofluoric acid rectification heat exchange device, and relates to the field of heat exchange devices.The electronic-grade hydrofluoric acid rectification heat exchange device comprises a cold recovery box, the surface of the cold recovery box is provided with a hot backflow pipe and a hot circulation box, a plurality of mass transfer boxes are arranged above the cold recovery box, a plurality of mass transfer bottles are fixedly connected to the interiors of the mass transfer boxes, and the tops of the mass transfer boxes are fixedly connected with a top plate; a plurality of adjusting holes are uniformly formed in the surface of the top plate, adjusting boxes are arranged in the mass transfer boxes, high-corrosion-resistance air bags are symmetrically arranged on the surfaces of the adjusting boxes, adjusting blocks are arranged in the adjusting boxes, rotating pipes are arranged in the mass transfer bottles, and stirring paddles are arranged on the surfaces of the rotating pipes. The efficiency and the stability of the hydrofluoric acid rectification heat exchange device are improved, the adaptability of the device to the production scale and different raw materials is improved, and the energy consumption is reduced.