The invention discloses a
lithium negative
electrode with a multi-layer composite artificial SEI film and a preparation method and application of the
lithium negative
electrode, and relates to the technical field of
lithium batteries. Comprising a porous material, a lithium-loving layer,
lithium metal and an inorganic
composite material, a lithium-loving layer and
lithium metal are sequentially deposited on one side of the porous material, and an inorganic
composite material is deposited on the other side of the porous material; the porous material is at least one of a
porous carbon material and a
porous silicon material; the inorganic
composite material is at least five of LiF, Li2O, Li3N, Li2CO3, Li2S, Li10GeP2S12 and Li3PO4, and the inorganic composite material is at least five of Li2CO3, Li2S, Li10GeP2S12 and Li3PO4. According to the invention, the lithium-loving
sponge-like porous structure is constructed, the lithium deposition space is increased, the growth of lithium dendrites is effectively inhibited, the SEI layer is prevented from being punctured, and meanwhile, the artificial SEI layer with high stability, excellent
ionic conductivity and
mechanical strength is constructed by adopting the multifunctional inorganic composite material, so that the cycle performance, the safety and the
overall efficiency of the
lithium battery are improved.