The invention discloses an anti-static alloy composite material and belongs to the technical field of high polymer materials. The anti-static alloy composite material comprises the following components of, by weight, 100 parts of polypropylene (PP)/ linear low density polyethylene (LLDPE), 3-7 parts of elastomers, 10-60 parts of inorganic fillers, 5-15 parts of conducting materials, 3-10 parts of dispersing agents and 0.1-1.0 parts of coupling agents, wherein the PP is 30-70 parts. The invention further discloses a preparation method of the anti-static alloy composite material, which includes the following steps of mixing the PP, the LLDPE, the elastomers, the inorganic fillers, the dispersing agents and the coupling agents in a mixer, and adding the mixtures into a hopper of an extruder; adding the conducting materials into a feed barrel of the extruder form a side feeding port of the feed barrel of the extruder; subjecting the mixtures to plasticization, vacuum-pumping exhausting, extruding, cooling and granule-cutting, and obtaining the anti-static alloy composite material. According to the anti-static alloy composite material and the preparation method thereof, the problems that prepared products are not provided with performances of warpage prevention, low temperature resistance and anti-stativity on the premise of having basic mechanical properties and heat resistance when the PP, the LLDPE and the elastomers are mutually added in prior art are solved.