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Graphene formaldehyde-resisting paint and preparing method thereof

An anti-formaldehyde and graphene technology, applied in antifouling/underwater coatings, coatings, paints containing biocide, etc., can solve the problems of poor decomposition effect and low decomposition efficiency of anti-formaldehyde coatings, and increase visible light absorption efficiency, reducing recombination, and improving utilization

Inactive Publication Date: 2016-02-10
QINGDAO REALEADER ADVANCED MATERIALS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0008] The present invention aims at the above-mentioned technical problems such as poor decomposition effect and low decomposition efficiency of the anti-formaldehyde coating, and proposes a graphene anti-formaldehyde coating with reasonable formula, simple process, good decomposition effect and high decomposition efficiency and a preparation method thereof

Method used

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  • Graphene formaldehyde-resisting paint and preparing method thereof
  • Graphene formaldehyde-resisting paint and preparing method thereof
  • Graphene formaldehyde-resisting paint and preparing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Embodiment 1. This embodiment provides a graphene anti-formaldehyde coating with a ratio of nanometer TiO2 and graphene of 10:1: 18 parts of water; 0.1 part of sodium carboxymethyl cellulose; 0.1 part of alkyl aryl polyether; 0.5 part of propylene glycol; 0.2 part of associative alkali swelling thickener (CHECOATVT-183); 0.2 part of polyurethane thickener (CHECOATVT-903); 0.1 part of mineral hydrocarbon defoamer (CHECOATDF6684); titanium white slurry 5 Parts; 50 parts of heavy calcium carbonate slurry; 0.1 parts of multifunctional amine additives (AMP-95); 10 parts of acrylic copolymer emulsion; 0.2 parts of film-forming additives (TEXANOL ester alcohol); fungicides (Clariant HF-I ) 0.1 part; 0.1 part of polydimethylsiloxane; 0.1 part of anti-formaldehyde additive (the ratio of nano-TiO2 and graphene is 10:1).

[0027] First put 13 parts of water into the mixing tank, and then add 0.1 part of carboxymethyl cellulose sodium salt, 0.2 part of film forming aid (TEXANOL ester ...

Embodiment 2

[0034] Embodiment 2. This embodiment provides a graphene anti-formaldehyde coating with a ratio of nano-TiO2 and graphene of 8:2: 20 parts of water; 0.2 parts of sodium carboxymethyl cellulose; and diisooctyl boperonic acid 0.2 part of salt; 1 part of ethylene glycol; 0.1 part of associative alkali swelling thickener (CHECOATVT-183); 0.4 part of polyurethane thickener (CHECOATVT-903); non-ionic alkyl copolymer defoamer (CHECOATDF9000) )0.1 part; 10 parts of titanium dioxide; 60 parts of diatomaceous earth; 0.2 parts of multifunctional amine additives (AMP-95); 10 parts of pure acrylic polymer; 1 part of film-forming aids (TEXANOL ester alcohol); fungicides (Clariant HF-I) 0.2 parts; alkyl-modified organosiloxane 0.2 parts; anti-formaldehyde additives (the ratio of nano-TiO2 and graphene is 10:1) 0.2 parts.

[0035] First put 14 parts of water into the mixing tank, then add 0.1 part of carboxymethyl cellulose sodium salt, 1 part of film-forming aid (TEXANOL ester alcohol), non-ion...

Embodiment 3

[0043] Embodiment 3, this embodiment provides a graphene anti-formaldehyde coating with a ratio of nano TiO2 and graphene of 5:5: 15 parts of water; 0.2 parts of sodium carboxymethyl cellulose; and diisooctyl boperonic acid 0.2 part of salt; 1 part of propylene glycol; 0.2 part of associative alkali swelling thickener (CHECOATVT-183); 0.2 part of polyurethane thickener (CHECOATVT-903); non-ionic alkyl copolymer defoamer (CHECOATDF9000) and A total of 0.4 parts of mineral hydrocarbon defoamer (CHECOATDF6684); 10 parts of titanium dioxide; 55 parts of ultrafine calcite powder; 0.2 parts of multifunctional amine additives (AMP-95); 10 parts of styrene-acrylic emulsion; 1 part of agent (TEXANOL ester alcohol); 0.2 part of bactericide (Clariant HF-I); 0.5 part of fluorine-modified acrylate; 0.2 part of anti-formaldehyde additive (ratio of nano-TiO2 and graphene is 5:5).

[0044] First put 12 parts of water into the mixing tank, then add 0.2 parts of carboxymethyl cellulose sodium salt...

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Abstract

The invention belongs to the field of chemical engineering paint and particularly relates to graphene formaldehyde-resisting paint and a preparing method thereof. The graphene formaldehyde-resisting paint is prepared from water, cellulose, a wetting agent, an anti-freezing agent, a thickening agent, a defoaming agent, titanium dioxide pulp, padding pulp, a multifunctional amine assistant, emulsion, a coalescing agent, a sterilizing agent, a flatting agent and a formaldehyde resisting agent, wherein the formaldehyde resisting agent is a mixture of graphene and nanometer titania. According to the graphene formaldehyde-resisting paint and the preparing method thereof, a traditional formulation is improved, graphene serves as a photocatalytic carrier by means of the light transmittance of graphene, and thus the efficiency of a photocatalytic reaction is greatly improved. Meanwhile, graphene is added to nanoscale titania, the absorption rate of visible light is increased, and the electron conduction efficiency is improved. In addition, due to the addition of graphene, the wear-resisting property of the water-based emulsion paint is improved.

Description

Technical field [0001] The invention belongs to the field of chemical coatings, and particularly relates to a graphene anti-formaldehyde coating and a preparation method thereof. Background technique [0002] Formaldehyde, also known as formic aldehyde, is the simplest aldehyde. It is usually a combustible, colorless and irritating gas. Formaldehyde is an important organic raw material, mainly used in the plastic industry, synthetic fibers, leather industry, medicine, dyes, etc. [0003] However, formaldehyde is also toxic. Long-term exposure to low-dose formaldehyde can cause chronic respiratory diseases, causing nasopharyngeal cancer, colon cancer, brain tumors, menstrual disorders, and gene mutations in the nucleus. Among all contacts, children and pregnant women are particularly sensitive to formaldehyde, and the harm is even greater. [0004] Due to the improvement of living standards, more and more people like to decorate their houses. However, when decorating houses, they co...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D133/00C09D133/04C09D125/14C09D5/14
Inventor 郑逸群吕艳红王霄飞孟良
Owner QINGDAO REALEADER ADVANCED MATERIALS TECH
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