1935 results about "Formic Aldehyde" patented technology

A fibrous insulation product comprising a plurality of randomly oriented glass fibers and a cross-linked formaldehyde-free binder composition at least partially coating the fibers is disclosed. The cross-linked formaldehyde-free binder composition is formed from an aqueous binder composition comprising 5.0% by weight to 37.0% by weight of at least one monomeric polyol having at least four hydroxyl groups and at least 50.0% by weight of a cross-linking agent comprising a polymeric polycarboxylic acid having at least two carboxylic acid groups, based on the total solids content of the aqueous binder composition. The glass fibers have an average fiber diameter in the range of 8 HT to 12 HT. The fibrous insulation product, after curing, has a density, when uncompressed, in the range of 0.30 pcf to 2.7 pcf.

The invention provides a redox imidazole covalent organic framework material as well as a preparation method and application thereof, belongs to the technical field of material preparation and photocatalytic preparation of hydrogen peroxide, and aims to solve the technical problem of low activity of a current covalent organic framework in preparation of hydrogen peroxide. The preparation method of the imidazole-connected redox type imidazole covalent organic framework material comprises the following steps: respectively reacting a reactant 2, 7-di-tert-butylpyrene-4, 5, 9, 10-tetraketone monomer with 4, 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ', 4', 4 ' The preparation method comprises the following steps: mixing 4, 4 '-(pyridine-2, 4, 6-triyl) tribenzaldehyde and a tri (4-formylphenyl) amine monomer, adding a solvent and a catalyst, uniformly stirring, and reacting to obtain the redox type imidazole covalent organic framework material after the reaction is finished. The application comprises the following steps: adding the covalent organic framework, oxygen and the sacrificial agent into water, and reacting under the irradiation of visible light. The preparation method is green, environment-friendly, simple and easy to implement, the prepared material has good thermal stability, and efficient visible light photocatalysis preparation of hydrogen peroxide can be achieved; meanwhile, the catalyst can be recycled and has good photocatalytic stability.

The invention relates to a crown ether covalent organic framework material as well as a preparation method and application thereof. The preparation method comprises the following steps: dissolving a crown ether monomer and an amino monomer in an o-dichlorobenzene solvent, adding a catalyst acetic acid aqueous solution, and uniformly dispersing to form a reaction solution; the method comprises the following steps: freezing a reaction solution through a liquid nitrogen bath, vacuumizing, filling nitrogen, carrying out a heating reaction, and carrying out post-treatment operations such as washing and drying on a reaction product, so as to obtain the crown ether covalent organic framework material BADT-DB18C6-COF. The crown ether covalent organic framework material is formed by condensation of a crown ether aldehyde monomer and an amino monomer, the crown ether monomer is 4, 4 ', 4' ', 4 '''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde, and the crown ether monomer is 4, 4 ', 4' ', 4'''-(6, 7, 9, 10, 17, 18, 20, 21-octahydrodibenzo [B, K] [1, 4, 7, 10, 13, 16] hexaoxacyclo octadecene-2, 3, 13, 14-tetrayl) tetrabenzaldehyde. The amino monomer is 4 ', 5'-bis (4-aminophenyl)-[1, 1 ': 2', 1 ''-terphenyl]-4, 4''-diamine. The crown ether covalent organic framework material BADT-DB18C6-COF prepared by the invention is mainly used as an adsorbent, is used for adsorbing and recovering uranium, thorium and americium ions from a solution, shows good adsorption capacity on radionuclides U-238, Th-232 and Am-243, and is particularly suitable for the field of spent fuel post-treatment in the nuclear industry.

The invention provides an anti-aging flame-retardant epoxy resin coating and a preparation process thereof, and belongs to the technical field of coating preparation. The preparation process comprises the following steps: preparing the flame-retardant additive; preparing a coated modified black phosphorus nanosheet; preparing modified hollow glass beads; preparing the epoxy resin coating. The preparation method comprises the following steps: dissolving 3, 4-dihydroxy benzaldehyde and 2-amino-4-methylphenol in absolute ethyl alcohol, carrying out a heating reflux reaction, carrying out dehydration condensation on an aldehyde group in the 3, 4-dihydroxy benzaldehyde and an amino group in the 2-amino-4-methylphenol to generate an imine bond-containing intermediate, respectively dissolving the intermediate and phosphonitrilic chloride trimer, and carrying out a reaction to obtain the phosphonitrilic chloride trimer. The preparation method comprises the following steps: firstly, adding phosphonitrilic chloride into an intermediate, then mixing for reaction, enabling phenolic hydroxyl groups in the intermediate and phosphonitrilic chloride trimer to be subjected to nucleophilic substitution reaction to generate the flame-retardant additive containing phosphorus and a Schiff base structure, and the flame-retardant additive has relatively good compatibility with an epoxy resin matrix, is not easy to separate out and can effectively improve the flame-retardant property of the epoxy resin coating.

The invention discloses an antibacterial packaging material and a preparation method thereof, and relates to the field of high polymer materials. When the antibacterial packaging material is prepared, polyethylene sequentially reacts with 3-bromo-1-propylene and amino trimethylene phosphonic acid, and modified polyethylene is prepared; the preparation method comprises the following steps: etching a halloysite nanotube with a hydrochloric acid solution, loading tea polyphenol into the halloysite nanotube, reacting 4-(3-thienyl) benzaldehyde and pyrrole on the surface of the halloysite nanotube, and finally polymerizing with 3-aminothiophene and thiophene to prepare the functionalized halloysite nanotube. And mixing the functionalized halloysite nanotube and the modified polyethylene, heating, and preparing a film, thereby obtaining the antibacterial packaging material. The antibacterial packaging material prepared by the invention has the capabilities of flame retardance, static electricity resistance, degradability and oxidation resistance.

The invention discloses a high-temperature-resistant power tube and a production process thereof, and belongs to the technical field of power tube preparation. The high-temperature-resistant electric power tube is prepared from, by weight, 60-80 parts of a high-temperature-resistant base material, 10-30 parts of carbon fibers and 1-5 parts of a modified anti-aging agent, the high-temperature-resistant base material is prepared from 2, 3, 4-trifluorobenzaldehyde, malonic acid, oxynaphthalene propionic acid, trifluoroacetic anhydride and 2, 2-bis [4-(4-aminophenoxy) phenyl] propane, and the modified anti-aging agent is prepared from 2, 3, 4-trifluorobenzaldehyde, malonic acid, oxynaphthalene propionic acid, trifluoroacetic anhydride and 2, 2-bis [4-(4-aminophenoxy) phenyl] propane. The modified anti-aging agent is prepared from absolute ethyl alcohol, paeonol, sodium hydroxide and 2-methoxybenzaldehyde. The power tube prepared by the method has excellent high temperature resistance, mechanical property and aging resistance.

The invention discloses unsaturated polyester resin for an unmanned aerial vehicle fuselage and a preparation method of the unsaturated polyester resin, and relates to the field of high polymer materials. When the unsaturated polyester resin for the unmanned aerial vehicle fuselage is prepared, a flame-retardant monomer reacts with 2-hydroxy-5-(hydroxymethyl) benzaldehyde to prepare a modified flame-retardant monomer; reacting cellulose with acrylic acid to obtain pre-modified cellulose; the pre-modified cellulose, 1-allyl-1, 1, 3, 3-tetramethyldisiloxane and chloroplatinic acid are subjected to a reaction, and modified cellulose is prepared; maleic anhydride, 5-(1H-imidazole-1-yl)-1, 3-phthalic acid, propylene glycol and the modified flame-retardant monomer are subjected to a reaction, and pre-polyester is prepared; and stirring the pre-polyester, zinc chloride, modified cellulose, benzophenone peroxide and styrene to obtain the anti-aging coating. The prepared unsaturated polyester resin for the unmanned aerial vehicle fuselage has good anti-aging, self-repairing, flame-retardant and self-cleaning performance.

The invention relates to the field of cables, and discloses a modified polyvinyl chloride composite material for cables and a preparation method thereof.The composite material comprises low-density polyethylene, polyvinyl chloride, ethylene-vinyl acetate copolymer, nitrile rubber, modified graphene oxide, modified nano calcium carbonate and auxiliaries; the modified graphene oxide is prepared by reacting acylating chlorination of graphene oxide with an anti-aging derivative, the anti-aging derivative is prepared by reducing a benzoxazole-containing intermediate generated by a reaction of 2-amino-4-bromophenol and 4-cyanobenzaldehyde to obtain an aminated benzoxazole-containing intermediate, then the aminated benzoxazole-containing intermediate reacts with p-phenylenediamine, and then the product reacts with 3-(3, 4-dichlorophenyl)-1, 2, 3-triazole-3-one to obtain the anti-aging graphene oxide. 2, 5-di-tert-butyl-4-hydroxyphenyl) propionyl chloride is subjected to a reaction to prepare the product. And the modified nano calcium carbonate is prepared by reacting phosphonitrilic chloride trimer with an amino silane coupling agent and 2-amino benzoxazole-5-borate and then grafting on the surface of the nano calcium carbonate. The composite material prepared by the invention has excellent flame retardance, heat resistance and long-acting oxidation resistance.

The invention relates to a polyorganosilicone cyclophosphazene modified epoxy resin and a preparation method thereof, and belongs to the field of flame retardant materials, and the preparation method of the polyorganosilicone cyclophosphazene flame retardant comprises the following steps: taking hexachlorotripolyphosphazene, p-hydroxybenzaldehyde, p-aminobenzoic acid, DOPO and diphenyl silanediol as raw materials, and carrying out four-step reaction to prepare the polyorganosilicone cyclophosphazene modified epoxy resin. The preparation method comprises the following steps: by taking m-phenylenediamine as a curing agent, adding the series gradient polyorganosilicone cyclophosphazene flame retardant into the epoxy resin, and curing twice to obtain the modified epoxy resin. The preparation method is mainly used for preparing the polyorganosilicone cyclophosphazene flame retardant and the polyorganosilicone cyclophosphazene modified epoxy resin.

The invention discloses a preparation method of second-generation denitrified flavin TND1128, which comprises the following steps: S1, by taking 1-methylbarbituric acid and o-aminobenzaldehyde as raw materials and a mixture of water and alcohol as a solvent, heating and reacting to generate an intermediate I; s2, taking the intermediate I as a raw material, and performing ethylation under the combined action of inorganic alkali and an ethylation reagent to generate a TND1128 crude product; s3, the TND1128 crude product is purified, and a TND1128 pure product is obtained; according to the invention, 1-methylbarbituric acid and 2-nitrobenzaldehyde are taken as raw materials for cyclization synthesis of an intermediate I, then ethylation and pulping purification are carried out under the combined action of inorganic base and an ethylation reagent, and high-purity TND1128 is synthesized in a high-yield, high-specificity and high-selectivity manner; the method has the advantages of simple process route, good reaction selectivity, high yield, cheap and easily available raw materials, low equipment requirement, easy realization of industrial production and the like.

The invention discloses a modified phenolic resin-based hard carbon material as well as a preparation method and application thereof, and belongs to the technical field of phenolic resin-based hard carbon materials. According to the method, glucurolactone containing aldehyde groups and rich oxygen is creatively used for replacing formaldehyde in a traditional method, 1, 2, 4-hydroxybenzene containing three phenolic hydroxyl groups and having two phenolic hydroxyl groups at ortho positions is used for replacing phenol in the traditional method, and the provided method is easy to prepare the thermosetting phenolic resin and has the advantages of being low in cost, free of toxicity and free of pollution; the prepared modified phenolic resin-based hard carbon material has proper specific surface area, abundant micropores and larger graphitization interlayer spacing, the specific surface area of the modified phenolic resin-based hard carbon material is 451.51 m < 2 > / g, and the micropore volume is 0.217 cm < 3 > / g; the prepared modified phenolic resin-based hard carbon material is used as a sodium-ion battery negative electrode material, has the initial coulombic efficiency of 86.44%, has the platform capacity of 232.8 mAh / g under the current density of 0.05 A / g, and still has the capacity retention ratio of 83.71% after stable circulation for 1000 circles at the coulombic efficiency of 99.97% under the current density of 1A / g.

The invention provides formaldehyde lyase as well as a mutant and application thereof. The amino acid sequence of the formaldehyde lyase mutant is shown as SEQ ID NO.1, SEQ ID NO.4 or SEQ ID NO.6 and contains at least one of the following sites: S26, W86, N87 or Y87, L109 or M109, L110, H281, Q282 or E282 and A460, and the amino acid sequence is subjected to amino acid mutation and has a formaldehyde lyase activity function. The amino acid sequences of the formaldehyde lyase and the mutants of the formaldehyde lyase have at least 99% of sequence identity with SEQ ID NO.1-7. The formaldehyde lyase and the mutant thereof can catalyze formaldehyde to synthesize 1, 3-dihydroxyacetone, and a new way for converting formaldehyde into 1, 3-dihydroxyacetone is provided.

The invention discloses a preparation method of 3, 4-dihydroxy benzaldehyde / gelatin carbon nanomaterial-based adhesive hydrogel, and belongs to the technical field of hydrogel. According to the invention, 3, 4-dihydroxy benzaldehyde and gelatin are adopted as carbon sources, the synthesized nano-filler has amphiphilic surface characteristics, uniform dispersion of the nano-filler in a hydrogel network can be promoted, meanwhile, a mechanically firm and deformable nano-composite structure is established by utilizing the interaction of multivalent interfaces, and 3, 4-dihydroxy benzaldehyde and gelatin are added into the hydrogel network. The surface chemical property of the 1, 4-dihydroxybenzaldehyde / gelatin nano-filler not only can relieve phase separation, but also can promote synergistic energy dissipation through hydrogen bond reconstruction under the action of stress. According to the design, the inherent flexibility of the hydrogel is reserved, meanwhile, the electromechanical response capacity of the hydrogel is greatly improved, and the obtained hydrogel material has the dual functions of structural supporting and active sensing media and can be seamlessly integrated with biological tissue without sacrificing the fidelity of interface signals.

The invention provides a triphenylamine derivative as well as a preparation method and application thereof in killing gram-positive bacteria. The preparation method comprises the following steps: firstly, synthesizing an intermediate molecule 4-di-p-methoxyanilino benzaldehyde (s); the s respectively reacts with 3-pyridylacetonitrile and 4-pyridylacetonitrile to generate intermediate molecules a and b; the intermediate molecules a and b respectively react with methyl iodide to generate triphenylamine derivatives 1 and 2, and the intermediate molecules a and b respectively react with 9-bromomethyl anthracene to generate triphenylamine derivatives 3 and 4. The prepared triphenylamine derivative has a donor-acceptor structure and is a D-pi-A structure, the modified triphenylamine is used as a donor, a carbon-carbon double bond is used as a covalent bridge, and cyano and N positive ions have electron withdrawing property. As all the components contain positive ions, the components can be anchored on a bacterial membrane to kill bacteria; and the compound has a short alkyl chain and can be combined with gram-positive bacteria, so that the bacteria are killed.

The invention belongs to the technical field of preparation of polyurethane elastomers, and discloses a water-resistant self-repairing polyurethane elastomer, a preparation method thereof and application of the water-resistant self-repairing polyurethane elastomer in a humidity sensor. The method comprises the following steps: S1, dissolving 4, 4 '-diaminodiphenylmethane and p-hydroxybenzaldehyde in absolute ethyl alcohol, and carrying out a Schiff base reaction to generate micromolecular MDOH with an imine bond structure, which is used as a chain extender of polyurethane; s2, reacting hydroxyl-terminated polybutadiene with isophorone diisocyanate at 60 DEG C to generate a prepolymer, and adding MDOH and glyceryl monostearate into the obtained prepolymer for chain extension; mDOH is introduced, so that the material has excellent self-repairing capability, and glyceryl monostearate is beneficial to further improving the self-repairing capability and water resistance. In addition, the humidity sensor based on the polyurethane elastomer can show good sensing performance.

The invention discloses a high-impact material prepared from recycled polypropylene and a preparation method of the high-impact material, and relates to the field of materials. When recycled polypropylene is used for preparing the high-impact material, firstly, polypropylene is grafted with vinyl diphenylphosphine, then the grafted polypropylene is reacted with 1-(3-chlorphenyl)-2-propyn-1-ol, and then the reacted polypropylene is reacted with 6-(methyl formate) pyridine-3-boric acid to obtain modified polypropylene; secondly, the calcium carbonate pretreated by 3-aminopropyltrimethoxysilane reacts with 3-thiophenecarboxaldehyde, thiophene, 6-(thiophene-2-yl) pyridine-2-carboxylic acid and 6-(3-thienyl) pyridine-2-formaldehyde are polymerized on the surface of the calcium carbonate, and modified calcium carbonate is obtained; and finally, carrying out melt blending on recycled polypropylene, modified polypropylene, modified calcium carbonate, sodium cyanide and bismaleimide, and carrying out extrusion granulation to obtain the high-impact material. The high-impact material prepared by the invention has good impact resistance, aging resistance and antibacterial property.

The invention relates to the technical field of organic synthesis, in particular to a synthesis method and application of functional caprolactam and functional nylon-6. The synthesis method comprises the following steps: in the presence of a catalyst and a solvent, enabling amino caprolactam and / or a derivative thereof to contact and react with benzaldehyde, so as to obtain functional caprolactam which is bis (benzyl) amino caprolactam, wherein the reaction conditions are as follows: the temperature is 150-350 DEG C; the hydrogen pressure is 0.1 to 10 MPa; the time is 5-15 hours. The synthesis method not only has the advantages of high reaction efficiency, high catalytic efficiency, adjustable target product selectivity and the like, but also simplifies process conditions, and realizes green large-scale production.

The invention relates to the technical field of materials and advanced oxidation, and discloses a covalent organic framework catalyst with a benzothiadiazole structure, a preparation method of the covalent organic framework catalyst and application of the covalent organic framework catalyst in peroxymonosulfate (PMS) activation and organic pollutant degradation. The preparation method of the covalent organic framework catalyst comprises the following steps: adding precursors 1, 3, 6, 8-tetra-(p-aminophenyl)-pyrene and 2, 7-dibenzaldehyde-benzothiadiazole into a mixed solvent composed of o-dichlorobenzene and n-butyl alcohol, carrying out a reaction by using acetic acid as a catalyst through a solvothermal method, and after the reaction, carrying out multiple times of centrifugal washing and drying to obtain the covalent organic framework catalyst. The catalyst shows excellent performance in the aspect of activating PMS to degrade organic pollutants, the degradation rate constant of bisphenol A reaches 1.68 min <-1 >, and 100% removal can be achieved within 5 minutes. Meanwhile, the catalyst has the advantages of no secondary pollution, strong anti-interference performance, reusability and the like. Compared with a traditional method, the catalyst has high PMS activation efficiency, the catalysis process is energy-saving and environment-friendly, the operation is simple and convenient, the preparation process is simple and feasible, and a new solution is provided for efficient degradation of organic pollutants in water.

The invention discloses a preparation method and application of a photo-thermal dual-response membrane material, and relates to the field of membrane materials. When the photo-thermal double-response membrane material is prepared, a photo-thermal material firstly reacts with 4-(triethoxysilyl) aniline and then reacts with 2, 4, 6-trihydroxy-1, 3, 5-benzenetricarboxaldehyde and p-phenylenediamine, and a modified photo-thermal material is prepared; the preparation method comprises the following steps: sequentially reacting benzaldehyde with 2-hydroxyacetophenone and 3-N, N-dimethylamino methacryloyl chloride to prepare a photo-initiation monomer; the preparation method comprises the following steps: mixing N-isopropylacrylamide, a photo-initiation monomer, N, N '-methylene bisacrylamide and a modified photo-thermal material, combining with a hydrophobic substrate membrane, preparing a membrane, and finishing the surface by using 2-bromo-1-[3, 5-di (tert-butyl)-4-hydroxyphenyl] ethanone, thereby obtaining the photo-thermal dual-response membrane material. The photo-thermal dual-response membrane material prepared by the invention has the characteristics of pollution resistance, easiness in cleaning, durability, antibacterial property, metal ion recovery and low energy consumption.

The invention relates to the technical field of petrochemical proppants, and discloses a high-performance phenolic resin material which comprises the following components in percentage by weight: 60%-75% of modified phenolic resin, 5%-15% of a curing accelerator, 10%-20% of a flexibilizer, 5%-20% of a filler and 3%-10% of a multifunctional additive, the modified phenolic resin is prepared by the following steps: mixing a phenolic compound and a formaldehyde solution in a reaction kettle, adding a basic catalyst, and reacting to obtain a phenolic prepolymer; gradually adding a modifier containing a hydroxyl group, an epoxy group and a carboxyl group into the phenolic prepolymer, and simultaneously stirring to obtain a mixture; heating the obtained mixture for reaction to complete crosslinking modification reaction to obtain modified phenolic resin; and cooling the modified phenolic resin to room temperature for later use. By adopting the design of the multifunctional flexibilizer and the composite filler, the toughness and thermal conductivity of the material are improved, meanwhile, the curing efficiency is accelerated through the curing accelerator, and the industrial cost is reduced.

The invention discloses a mechanical force-induced fluorescence discoloration sensor material as well as a preparation method and application thereof, and relates to the technical field of organic synthesis and fine chemical engineering. The preparation method comprises the following steps: step 1, carrying out heating reaction on 4-(1, 2, 2-triphenyl vinyl) benzaldehyde, 3-(2, 2-dicyano-1-(3, 4-diaminophenyl) vinyl) benzene-1-yl and a catalyst to prepare a compound 1-1; and 2, carrying out heating reaction on the obtained compound 1-1 and methyl iodide under the action of alkali and a solvent, and analyzing and purifying to obtain a compound 1-2. The compound disclosed by the invention is low in preparation cost, simple and convenient to operate and simple in method, the compound shows the material characteristic of mechanical force-induced fluorescence discoloration and can be applied to the fields of sensors, dyes, anti-counterfeiting and the like, and meanwhile, the synthesis method can be used for synthesis in the fields of fine organic chemical engineering such as luminescent materials, printing and dyeing technologies and the like.

The present invention discloses an infrared-shielding polyurethane glass film and a preparation method thereof, relating to the field of polymer materials technology. When preparing the infrared-shielding polyurethane glass film, the present invention comprises reacting an organic nickel complex and 3-imidazole-1-propionic acid to produce a functionalized crosslinker; sequentially reacting 4-aminophenylacetonitrile with 3-hydroxypropyl acrylate and quinoline-4-carboxaldehyde to produce a UV-absorbing monomer; reacting polypropylene glycol, a UV-absorbing monomer, 1,4-butanediol, and 4-chloromethyl-1,3-phenylenediisocyanate to polymerize to produce polyurethane; reacting tungsten-doped titanium dioxide and chloropropyltriethoxysilane to produce modified titanium dioxide; and uniformly mixing the polyurethane, modified titanium dioxide, the functionalized crosslinker, and acetone, followed by coating and curing to produce the infrared-shielding polyurethane glass film. The infrared-shielding polyurethane glass film prepared by the present invention has excellent infrared shielding, anti-aging, antibacterial, and mechanical properties.

The invention relates to a [NN] bidentate coordination metal catalyst based on a quinoline skeleton as well as a preparation method and application of the [NN] bidentate coordination metal catalyst. According to the preparation method, quinoline-8-formaldehyde and aniline are directly subjected to aldehyde-amine condensation under the catalysis of p-TsOH, and a quinoline-imino ligand is synthesized. The [NN] bidentate coordination metal catalyst based on the quinoline skeleton is prepared by carrying out one-pot reaction on the obtained ligand and in-situ synthesized MMe4 (M is Ti, Zr or Hf). The quinoline skeleton [NN] bidentate coordination metal catalyst is used for polyolefin synthesis. The preparation method has the advantages of simple synthesis process, easily available raw materials, high product yield and high temperature resistance, is suitable for high-temperature solution polymerization, and can be used for preparing high-performance polyolefin elastomers.

The invention relates to the technical field of concrete materials, and discloses a hydrophobic antibacterial material, a preparation method and environment-friendly hydrophobic antibacterial concrete. The preparation method of the hydrophobic antibacterial material comprises the following steps: enabling 2, 3-dihydroxy terephthalic dihydrazide to react with 3-hydroxy-4-methoxybenzaldehyde to obtain an intermediate product, and then enabling the intermediate product to react with terephthaloyl chloride and 1, 2-epoxyoctane in sequence to obtain a multifunctional agent; carrying out load modification on the multifunctional agent to obtain a modified multifunctional agent; performing surface treatment on the modified multifunctional agent to obtain an aminated modified multifunctional agent; the amination modified multifunctional agent is treated with functionalized polydimethylsiloxane, and a composite multifunctional agent is obtained; the composite multifunctional agent and the modified composite nano material are combined to obtain a hydrophobic antibacterial material, and the hydrophobic antibacterial material is added into concrete to obtain the environment-friendly hydrophobic antibacterial concrete. The environment-friendly hydrophobic antibacterial concrete disclosed by the invention has good antibacterial performance, hydrophobic anti-seepage performance and self-repairing performance.

The invention discloses a phenanthridine-6-formaldehyde derivative and a preparation method and application thereof.The preparation method comprises the steps that 2, 4, 5, 6-tetra (9-carbazolyl)-isophthalonitrile serves as a photocatalyst, 1-azabicyclo [2.2. 2] octane serves as a hydrogen atom transfer catalyst, a biphenyl isocyanide compound, the photocatalyst, the hydrogen atom transfer catalyst and an alkali additive are jointly dissolved in 1, 3-dioxolane, the mixture is stirred to be uniform, and the phenanthridine-6-formaldehyde derivative is obtained. And carrying out free radical tandem cyclization and acid-catalyzed hydrolysis reaction to obtain the phenanthridine-6-formaldehyde derivative. The invention also provides a specific reaction equation. According to the developed synthesis method of the phenanthridine-6-formaldehyde derivative, the compound can be efficiently and conveniently prepared, the technical bottlenecks of harsh reaction conditions and tedious steps in a traditional process are successfully overcome, raw materials which are low in price and easy to obtain are adopted, operation is carried out under mild conditions, the synthesis method has the outstanding advantages of being high in yield, safe and simple to operate, environmentally friendly and the like, and the method is suitable for industrial production. Good industrial application potential is shown.

The invention relates to the technical field of synthesis of photosensitive organic compounds, and discloses a novel hydroxyl-containing dihydropyridine photosensitizer and a preparation method and application thereof.The method comprises the steps that 5-hydroxy-2-nitrobenzaldehyde serves as an initial raw material and reacts with 3-aminocrotonic acid methyl benzoate under the catalytic action of trifluoroformic acid, and a reaction product is obtained; precipitating, filtering and recrystallizing the product to obtain a photosensitive dihydropyridine monomer; the preparation method comprises the following steps: by taking 3, 5-dibromophenol as an initial raw material, introducing halogenated straight-chain alkyl of which the tail end is halogen into a hydroxyl position on the 3, 5-dibromophenol; dissolving a photosensitive dihydropyridine monomer and the intermediate A, and carrying out substitution reaction under the action of alkali to prepare an intermediate B; and carrying out Suzuki coupling reaction on the intermediate B and 4-hydroxymethyl phenylboronic acid to finally obtain the novel dihydropyridine photosensitizer containing hydroxyl. The novel hydroxyl-containing dihydropyridine photosensitizer (DHPDO) is good in compound stability, the preparation process is simple and convenient, the stability of an intermediate product is high, and after-treatment purification is low in toxicity and harmless.

The invention discloses a temperature change resistant glass material and a preparation method thereof, and relates to the field of glass. When the temperature change resistant glass material is prepared, crystal whisker silicon is soaked in an aluminum hydroxide solution, and then the crystal whisker silicon, nano silicon dioxide, lithium oxide, sodium carbonate and titanium dioxide are heated, mixed and annealed to prepare glass; the preparation method comprises the following steps: sequentially reacting aluminum oxide with 3-aminopropyltrimethoxysilane, 4-bromo-2-hydroxybenzaldehyde and 4-aminopyridine, so as to prepare functionalized aluminum oxide; the preparation method comprises the following steps: carrying out a reaction on polyaspartic acid ester resin, a hexamethylene diisocyanate-based polyisocyanate tripolymer, a functional monomer and an end-capping reagent to prepare modified polyurea; and mixing the modified polyurea with the functionalized aluminum oxide to prepare a coating material, spraying the coating material on the surface of glass, and drying to prepare the temperature-change-resistant glass material. The temperature-change-resistant glass material prepared by the invention has the capabilities of fouling prevention, heat conduction, impact resistance, coating self-repairing and aging resistance.

The present invention relates to the technical field of organic synthesis, particularly to a daphnetin preparation method, which comprises: adopting 2, 3, 4-trihydroxybenzaldehyde and Meldrum's acid as starting raw materials, and carrying out a first-step reaction under the action of a first catalyst to obtain an intermediate 7, 8-dihydroxycoumarin-3-carboxylic acid; the intermediate 7, 8-dihydroxycoumarin-3-carboxylic acid is subjected to a second-step reaction under the action of a second catalyst, and daphnetin is obtained. The method has the remarkable advantages that firstly, the reaction process is easy to control, the generation amount of byproducts is low, and the product is excellent in appearance quality and extremely high in purity; and secondly, the use of chemicals with high risk and high toxicity is avoided, meanwhile, a large amount of acid waste liquid is not generated, and the environmental pollution is effectively reduced. In addition, the recycling of the solvent and the catalyst further reduces the production cost. The yield and the purity are remarkably improved, the total yield can reach 90% or above, the purity exceeds 99%, and the method is very suitable for industrial large-scale production.

The invention belongs to the technical field of oilfield development, and relates to an oilfield high-temperature-resistant discharge aiding agent and a synthesis method and application thereof. The preparation method comprises the following steps: sequentially adding diaza 18-crown ether-6, ethanol and benzaldehyde-2, 4-sodium disulfonate into a reactor, stirring and dissolving, continuously adding sodium cyanoborohydride, stirring and dissolving, adjusting the pH value to 3-4 by using hydrochloric acid, heating at 70-80 DEG C, and keeping the temperature to react for 2-4 hours; cooling to below 20 DEG C, slowly dropwise adding hydrochloric acid, adjusting the pH value to 0-1, stirring for 20-30 minutes, and destroying the residual sodium cyanoborohydride; adjusting the pH value to 9-10 by using sodium hydroxide, adding dodecyl bromide, and heating and refluxing for 24-48 hours; and carrying out reduced pressure distillation to obtain a viscous solid, recrystallizing, and drying to obtain the product high-temperature discharge aiding agent. The high-temperature-resistant discharge aiding agent has the advantages of low surface tension, low interfacial tension, low critical micelle concentration and high flowback rate.

The invention relates to the technical field of flame retardants, and discloses a halogen-free flame retardant, a preparation method and application of the halogen-free flame retardant in plastics. The preparation method comprises the following steps: synthesizing modified DOPO by taking DOPO, p-hydroxybenzaldehyde and phenol as raw materials, and mixing the modified DOPO with propargylamine and paraformaldehyde for reaction to obtain dialkynyl benzoxazine; the preparation method comprises the following steps: grafting dialkynyl benzoxazine and 1-azido adamantane through a click chemical reaction to obtain flame-retardant benzoxazine; the halogen-free flame retardant is obtained by carrying out in-situ polymerization on flame-retardant benzoxazine on the surface of the ammonium polyphosphate / molecular sieve composite material. The halogen-free flame retardant is excellent in flame retardant effect and good in compatibility in a matrix material, can effectively improve the flame retardant property and the mechanical property of the matrix material, and can be applied to plastic materials.