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Method for comprehensively recycling valuable metals from spent lithium ion battery

The invention discloses a method for comprehensively recycling valuable metals from a spent lithium ion battery. The method comprises the following steps: carrying out electric discharge treatment on a spent battery, crushing, pre-roasting at 300-400 DEG C, adding a reducing agent, and carrying out reduction roasting at 450-700 DEG C; carrying out water extraction and evaporative crystallization on fine aggregates obtained through the reduction roasting, so as to obtain a high-purity lithium product, leaching copper, nickel and cobalt from leached slag and roasted lump materials by virtue of ammonia oxide, carrying out magnetic separation and sieving on ammonia leaching slag so as to obtain iron and aluminum enriched products, and carrying out reduction acid leaching, purification and edulcoration on sieved products, so as to obtain a high-purity manganese sulfate solution; and carrying out extraction and selective reverse extraction on ammonia leaching liquid, so as to obtain a high-purity nickel sulfate solution and a high-purity copper sulfate solution, and carrying out vulcanization cobalt precipitation, oxidation acid leaching and extraction purification on raffinate, so as to obtain a high-purity cobalt sulfate solution. The method is high in extraction rate of valuable metals and applicable to the treatment of multiple waste lithium ion battery raw materials and efficient utilization of multiple elements, and sorting is not required.
Owner:GUANGDONG GUANGHUA SCI TECH

Preparation method of high-performance anti-corrosion repairing mortar

A preparation method of high-performance anti-corrosion repairing mortar including following components, by weight: 150-250 parts of cement, 280-725 parts of quartz sand, 50-200 parts of mineral powder, 50-150 parts of fly ash, 0-50 parts of silicon ash, 5-10 parts of barium nitrate, 0.1-1 part of an early strength agent, 1-4 parts of PP fibers, 0.5-20 parts of latex powder, 0.5-5 parts of cellulose ether, 0.5-2 parts of a water repellent agent, 0.001-0.1 parts of an air entraining agent, 0.1-2 parts of a water reducing agent, 0-1 part of a defoaming agent, and 100-250 parts of water. The invention, aiming to the characteristic of sulphate attack and the performance requirement of repairing mortar, discloses the repairing mortar which can repair the surface of damaged concrete with a protective film formed thereon to prevent the concrete form being corroded again. The repairing mortar is good in construction performance, can be used for coating the surface of the damaged concrete or filling damaged positions of the concrete. The repairing mortar is high in bonding strength and strength, is good in anti-permeability and flexibility, is simple in preparation process, is especially suitable for repairing the concrete subjected to sulphate attack, is great in market prospect and is good in practicability.
Owner:潍坊德霖建材科技有限公司

Other transitional metals doped ferrotitanium composite oxides catalyst for selectively reducing nitrous oxides by ammonia

The invention relates to a catalyst for selectively deoxidizing oxides through ammonia, which mainly solves the problems that in the prior commercial NH3-SCR catalyst system, V2O5-WO3(MoO3)/TiO2 has high operating temperature and a narrow temperature window, N2 has low generation selectivity at high temperature, vanadium as an active composition has toxicity and harmfulness on environment and human body and the like. On the basis of a ferrotitanium composite oxide catalyst prepared in prior period, environment-friendly raw materials with cheap prices are continuously adopted; and other transition metal oxides are added into a ferrotitanium composite oxide catalyst system through a simple and feasible coprecipitation method to prepare a catalyst system with improved low-temperature activity. The catalyst is subjected to physicochemical property characterization by using a plurality of methods to show that an active phase of the catalyst is the same as that of a ferrotitanium composite oxide catalyst which is not doped with other transition metals, and is still in a microcrystal state, thereby forming a composite oxide microcrystal system with a Fe-O-Ti, M-O-Ti and Fe-O-M (M is a doped transition metal element) structure; and the composite oxide microcrystal system has special catalytic activity in SCR reaction. The catalyst has high NH3-SCR activity, selectivity and stability at a middle-low temperature period (between 150 and 300 DEG C), is unobvious in the poisoning effect of SO2; and if the catalyst is prepared into slurry and is coated on a honeycomb ceramic carrier, the catalyst is expected to be applied to the denitration and purification process of flue gas produced after desulfuration and dedusting in a coal-fired power plant or tail gas of a diesel engine.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI
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