The invention discloses a blue light-excited white light fluorescent powder and its use and its manufacture process and device. Its molecular formula is aY2O3.bGd2O3. (1.5-a-b)Re2O3.2.5Al2O3.xSiO2, where Re is two or above of Ce, Eu, Tm and Tb; 0<a<1.5, 0<=b<1.5, 0<x<3; it can be used to manufacture white LEDs. Its process steps include preparing precursor solution, aerating, atomizing, reacting, collecting and after-processing. Its manufacture device includes a liquid fillingdevice, an atomization generating device, a gas supplying device, a gas flux control device, a reaction furnace, a powder collecting device, and a purifying processing device. The invention has simple process, high efficiency, good quality, and suitable for industrial production; and low-cost.