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410results about How to "Lower iron levels" patented technology

Method for enriching niobium by high-temperature roasting and low-intensity magnetic separation

The invention relates to a method for enriching niobium by high-temperature roasting and low-intensity magnetic separation and belongs to the technical field of mineral extraction metallurgy. The method comprises the following steps: performing solid-state reduction of a niobium ore concentrate to obtain a reduced ore containing the niobium and metal iron; ball-milling the reduced ore containing the niobium and the metal iron and then performing low-intensity magnetic separation to obtain a niobium-rich material. According to the method disclosed by the invention, iron oxide in the niobium ore concentration is selectively reduced in a solid state, so that the metal transformation rate is above 90%; by reduction of the iron oxide, a mineral structure of niobium-iron rutile in the original ore is damaged; subsequently niobium oxide can be separated from the metal iron by low-intensity magnetic separation; finally the content of iron in the obtained niobium-rich material is lower than 8%; compared with the original 'solid-state iron reduction-high-temperature melt separation-smelting' method, the method disclosed by the invention can be used for preparing the niobium-rich material of which the iron content is basically the same and also has the advantages of saving power consumption, reducing emission and improving the efficiency.
Owner:包钢集团矿山研究院(有限责任公司)

Method for concentrating and purifying titanium dioxide waste acid by using complex acid

The invention discloses a method for concentrating and purifying titanium dioxide waste acid by using complex acid. The method comprises the following specific steps of: titanium recovery: primarily concentrating waste acid produced in a titanium dioxide production process by using waste heat of calcining tail gas of a ring kiln to achieve the mass concentration being 25-32%, and then recovering titanium; acid mixing: uniformly mixing the waste acid subjected to titanium recovery and concentrated sulfuric acid in an acid mixing tank according to a mass proportion of (1.2-4):1 to obtain mixed acid; and crystallization: carrying out gradient cooling, crystallizing, curing and filtering on the mixed acid gradually in the acid mixing tank, and when the temperature of the mixed acid is reduced to 60-65 DEG C, pumping the mixed acid into a filter press for solid-liquid separation to obtain concentrated sulfuric acid and ferrous dregs. The method disclosed by the invention has the advantage of changing the traditional method for concentrating the titanium dioxide waste acid by depending on natural gas, steam, fire coal hot gas and other heat sources, is free from consuming a large amount of energy sources and capable of reducing the cost in waste acid concentration, and is high in recovery rate of the waste acid.
Owner:SICHUAN LOMON TITANIUM IND CO LTD

Process for recovering lithium phosphorous from lithium phosphate crude product to prepare battery-level lithium carbonate and iron phosphate

The invention provides a process for recovering lithium phosphorous from a lithium phosphate crude product to prepare battery-level lithium carbonate and iron phosphate, and belongs to the technical field of resource recycling. The process comprises: lithium phosphate slurrying: adding pure water or washing water to the lithium phosphate crude product to prepare slurry, and performing high-speed dispersion and grinding dispersion to obtain uniform lithium phosphate slurry; iron solution preparation: filtering an iron solution to obtain a refined iron solution; iron orthophosphate preparation:adding inorganic acid into a pure water base solution to regulate pH to 2-3, adding the lithium phosphate slurry and the refined iron solution after temperature rise, performing solid-liquid separation after reaction is completed, initially washing a solid by the pure water, re-washing the solid by slurry mixing, and drying and crushing the solid, so as to obtain iron orthophosphate; battery-levellithium carbonate preparation: purifying a lithium-containing mother solution obtained by preparing the iron orthophosphate, and inputting into a mixed solution of sodium carbonate and EDTA to perform lithium deposition reaction, and performing separation, washing, drying and crushing to obtain lithium carbonate. The lithium phosphate crude product is treated by means of the process of the invention, so that iron orthophosphate and lithium carbonate products meeting quality requirements of a lithium battery can be obtained.
Owner:CHENGDU CHEMPHYS CHEM IND

Method for collecting nickel and cobalt from laterite-nickel ore lixivium by using sulfide precipitation

The invention provides a method for enriching nickel and cobalt from lateritic nickel ore lixivium. The method comprises the steps of concentration and pH value adjustment of pickle liquor, precipitation through adopting composite vulcanizing agent, solid-liquid separation, washing and filtrate processing. The composite vulcanizing agent consists of vulcanizing agent A containing hydrogen ions and vulcanizing agent B without the hydrogen ions. The method uses 1 to 95 percent of the vulcanizing agent A and 5 to 99 percent of the vulcanizing agent B in the composite vulcanizing agent. The pH value of the pickle liquor can be maintained or changed slowly through adjusting the pH value of the pickle liquor of the lateritic nickel ore to be a set value and slowly adding the composite vulcanizing agent, thereby acquiring a sulphide product enriched with nickel-cobalt. The mass ratio of nickel and the vulcanizing agent is between 1 to 1.6 and 5. A buffer system formed by the vulcanizing agent A and the vulcanizing agent B in the invention adjusts and controls changes of the pH value during the process of sulphuration precipitation, prevents iron chloride and magnesium chloride from being hydrolyzed into hydroxide and entering a sulphide, and improves the separation rate of nickel and cobalt and the separation rate of iron and magnesium; the acquired precipitation of the sulphide can be easily filtered; and the dosage of the vulcanizing agent is small.
Owner:CENT SOUTH UNIV

High-performance stainless steel surfacing nickel-based special welding wire and preparation method thereof

The invention belongs to the field of welding materials and particularly relates to a high-performance stainless steel surfacing nickel-based special welding wire and a preparation method thereof. Thewelding wire comprises chemical elements including, by mass, not greater than 0.04% of C, 0.1-0.5% of Mn, not greater than 0.001% of P, not greater than 0.001% of S, 0.05-0.1% of Si, 20-25% of Cr, 8-12% of Mo, 2-6% of Nb, 0.2-0.5% of Ti, not greater than 0.001% of Cu, 0.1-0.3% of Al, not greater than 1% of Fe, 0.03-0.08% of Co, 0.05-0.1% of the rare earth element RE, 30-80 ppm of N and the balance Ni and inevitable impurity elements. The preparation method comprises the steps of (1) vacuum electric-furnace smelting; (2) VOD external refining; (3) horizontal continuous casting; (4) tandem rolling; and (5) tandem drawing. The welding wire provided by the invention has the good properties of active gas resistance and reducing acid medium corrosion resistance, the electric arc stability and slag stripping performance are excellent during welding, and welding metal with high strength, good tenacity, flaw resistance, high temperature cracking resistance and corrosion resistance is obtained;and the preparation technology is simple, the raw material and manufacturing cost is low, environmental friendliness is achieved, no pollution is generated, and the welding wire and the preparation method are suitable for industrial volume production and remarkable in economic benefit.
Owner:DANYANG HUALONG SUPERIOR STEEL

Method for preparing high-purity low-chlorine electroplating-grade cupric oxide

The invention discloses a method for preparing high-purity low-chlorine electroplating-grade cupric oxide. According to the method, copper, liquid ammonia and high-purity carbon dioxide are taken as raw materials, stronger ammonia water is prepared firstly, carbonated ammonia water is obtained through introducing the high-purity carbon dioxide into the stronger ammonia water and controlling carbonization degree, the carbonated ammonia water reacts with the copper under certain air pressure so as to prepare copper-ammonia complexation liquid, the copper-ammonia complexation liquid is then subjected to heating, ammonia distilling, separating, washing, drying and sieving so as to prepare high-purity heavy basic copper carbonate, and the heavy basic copper carbonate is then subjected to heating calcination and decomposition, thereby preparing the high-purity low-chlorine electroplating-grade cupric oxide. According to the method, the carbon dioxide is directly used as a raw material, so that the problems of the traditional method that impurities, such as heavy metal ions and chloride ions, are introduced by raw materials used in the production of basic copper carbonate are solved, the rate of reaction is increased, the production cycle is shortened, the production efficiency is greatly increased, and products are low in impurity content, high in purity, high in activity and wider in application; and meanwhile, the method is high in yield, low in energy consumption, and low in cost and hardly causes pollution.
Owner:TAIXING SMELTING PLANT

Method for preparing double-acid ferro-aluminum flocculating agent

The invention discloses a method for preparing a double-acid ferro-aluminum flocculating agent, which relates to a process for preparing the double-acid ferro-aluminum flocculating agent by using calcium aluminate powder. The method comprises the following steps of: taking the calcium aluminate powder of which the particle size is smaller than 60 meshes, putting the calcium aluminate powder into a hydrochloric acid solution in a part mass ratio of the hydrochloric acid solution to the calcium aluminate powder of 3-5:1, reacting the two materials at a temperature of 98 DEG C for 1 to 1.5 hours, standing the mixture for 30 minutes, and then taking a supernatant to obtain AlCl3 liquid; adding ferrous sulfate to the mixture in a part mass ratio of the calcium aluminate powder to the ferrous sulfate of 9-11:1 at a temperature of between 80 and 90 DEG C, dropwise adding a sodium hydroxide solution of which the concentration is 0.5 mol/L into the mixture after 15 minutes, dropping oxyful into the mixture in a part mass ratio of the ferrous sulfate to the oxyful of 1:1-1.5 when the basicity is 30 to 40 percent, stirring the mixture continuously for 15 to 20 minutes, and then curing the mixture at a temperature of between 50 and 60 DEG C for 12 hours to obtain a liquid product of the double-acid ferro-aluminum flocculating agent; and drying the liquid product of the double-acid ferro-aluminum flocculating agent to obtain a double-acid ferro-aluminum solid product. Tests show that in the solid product, Al2O3 is over 30 percent, the total iron is over 1 percent, the insoluble substances is less than 1 percent, and other indexes accord with the national standards. The method has a simple process and a low cost, and the prepared product has a good coagulation effect and high economic and social benefits.
Owner:TONGJI UNIV
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