1152 results about "Iron chloride" patented technology

The invention relates to the technical field of biocatalysts, in particular to a FeCo-NC bimetallic monatomic nano-enzyme as well as a preparation method and application thereof. The preparation method of the nano enzyme comprises the following steps: preparing Co-ZIF-8 from zinc nitrate, cobalt nitrate and 2-methylimidazole; the Co-ZIF-8 and ferric chloride are used for preparing the FeCo-NC bimetallic monatomic nano-enzyme, the molar ratio of the zinc nitrate to the cobalt nitrate is (20-30): 1, and the molar ratio of the cobalt nitrate to the ferric chloride is (2-6): 1. The nano-enzyme prepared by the embodiment of the invention is of a monatomic structure, has double-enzyme activity, can simultaneously simulate catalase and NADH oxidase, and has the capability of removing active oxygen.

The invention discloses a preparation method of antistatic modified chinlon filaments, and relates to the field of chinlon filaments. When the antistatic modified chinlon filament is prepared, (formylmethyl) diethyl phosphate and 1-aminopyrrole react to prepare pyrrole diethyl phosphate; reacting the hydroxylated multi-walled carbon nanotube with pyrrole diethyl phosphate to obtain a modified multi-walled carbon nanotube; the preparation method comprises the following steps: reacting 2, 2 '-bipyridine-5, 5'-dicarboxylic acid with 2-amino-5-nitrophenol, and then reducing to obtain a benzoxazole diamine monomer; then, adipic acid, 1, 5-diaminopentane and a benzoxazole diamine monomer are subjected to a reaction, and modified polyamide is prepared; uniformly mixing the modified polyamide, the modified multi-walled carbon nanotubes, pyrrole, ferric trichloride and copper chloride, and performing melt spinning to obtain the antistatic modified polyamide filament. The antistatic modified chinlon filament prepared by the invention has excellent antistatic, flame-retardant, anti-aging and mechanical properties.

This invention discloses a method for leaching lithium iron phosphate mixed powder with iron salts and recovering all components, belonging to the field of battery recycling. The invention uses an iron salt solution to leach the mixed powder, obtaining a lithium-containing leachate and leaching residue. Ferrous ions in the leachate are regenerated into ferric iron through acidification and oxidation, and recycled for leaching the next batch of mixed powder. After reaching a preset number of cycles, the leachate is used for re-leaching multiple batches of leaching residue to improve the lithium leaching rate. Ultimately, a enriched solution containing Li, Fe, Cu, and Al and graphite-containing iron phosphate residue are obtained. Copper is recovered from the enriched solution through iron powder replacement, and a high-purity lithium chloride solution is obtained through extraction and separation, while ferric chloride (recycled) and aluminum chloride crystals are also recovered. The leaching residue is treated with hydrochloric acid to obtain regenerated graphite, and the pH is adjusted with alkali to obtain high-purity iron phosphate. This method achieves full component recovery under mild conditions, reducing separation steps and chemical consumption through a "leaching-regeneration-leaching" cycle mechanism, thus achieving both environmental and economic benefits.

The invention discloses a heavy metal chelating agent for industrial wastewater and a preparation method of the heavy metal chelating agent, and belongs to the technical field of sewage treatment.The preparation method comprises the steps that 2-hydroxyphenylboronic acid is subjected to graft modification through acrylic acid and polymerized on the surface of activated biomass porous carbon powder with acrylic acid, boron-containing polymer modified porous carbon is obtained, and then ferric chloride hexahydrate serves as an iron source; a boron-containing polymer modified porous carbon surface and aminated magnetic adsorption nanospheres are obtained, B-N coordination is formed between the aminated magnetic adsorption nanospheres and the boron-containing polymer modified porous carbon surface, boron element fixation is achieved through modified copolymerization, loss caused by long-time use of the boron element is avoided, lasting and stable chelation is guaranteed, activated biomass porous carbon serves as a carrier, and macromolecular resin serves as a coating layer. The environment-friendly biochar has the advantages of favorable degradability, greenness, degradability, safety and high efficiency, and avoids the problem of secondary pollution caused by the use of a chelating agent.

The invention provides a leakage point pressure difference response high-strength blocking agent based on iron ion dynamic cross-linked latex and a preparation method thereof, and the raw materials comprise the following components in parts: 60-120 parts of latex, 60-120 parts of deionized water, 5-15 parts of an activator, 5-10 parts of a defoamer, 100 parts of a terminator, 100 parts of a stabilizer, 10 parts of a 20% ferric chloride solution, and the balance of water. Rubber particles are dynamically crosslinked through ferric ions, and the plugging strength is remarkably improved. Compared with a traditional differential pressure plugging agent, the plugging strength for small holes with the diameter of 0.5 mm reaches 35.67 MPa and is improved by about 238%, and the plugging strength for large holes with the diameter of 1 mm reaches 9.68 MPa and is improved by about 428%. And the plugging device is suitable for plugging conditions with higher leakage point pressure difference. In addition, the plugging agent can realize rapid and high-strength plugging of an underground pipe column, and provides a more efficient and more reliable solution for well site construction.

The invention belongs to the technical field of pollutant detection, and relates to an iron-based nano enzyme and application thereof in quinolone antibiotic detection. The preparation method comprises the following steps: adding ferric trichloride hexahydrate and cerium nitrate hexahydrate into water, uniformly mixing to obtain a mixed solution A, uniformly mixing the mixed solution A with an organic polyacid ligand solution, and then carrying out a reflux reaction to prepare a Ce / Fe-MOF precursor; and adding the Ce / Fe-MOF precursor and sodium hypophosphite into a tubular furnace, and calcining in a nitrogen atmosphere to prepare Ce / Fe-P. According to the present invention, the synthesized material has the nanometer prism mesoporous structure, the contact area with the substrate is effectively increased, the visual detection of the NOR can be achieved based on the principles of low-concentration NOR activity improving and high-concentration Ce / Fe-P activity inhibition, and the high sensitivity, the low detection limit, the wide linear response range and the good selectivity and the good stability are provided.

The invention provides a material for removing sodium ions in saline-alkali soil and a preparation method, and relates to the field of sodium ion adsorbents, the preparation method comprises the following steps: (1) lignin modification: under a water bath condition, dissolving sulfate lignin in a mixed solution of analytically pure acetic acid and 30% hydrogen peroxide, then adding ferric chloride, reacting for 1.5-2.5 hours, diluting with distilled water by 7-8 times, centrifuging and washing to obtain modified lignin; drying to obtain oxidized lignin; (2) hydrogel synthesis: mixing and stirring the oxidized lignin and analytically pure acrylic acid, adding a cross-linking agent and an initiator, and reacting in a drying oven at 65-75 DEG C for 1.5-2.5 hours to form a sodium ion adsorption material with a porous interpenetrating network structure; by modifying the lignin, particularly introducing more hydroxyl and carboxyl groups, the performance of the lignin in the application of adsorbing ions, preparing hydrogel and the like can be improved.

The invention discloses a high-pressure belt conveyor low-cost sludge dewatering technology, and relates to the technical field of sludge dewatering, the technology comprises the following steps: S1, in a pretreatment stage, adding a ferric chloride agent and destroying a sludge colloid structure; s2, in the conditioning stage, lime powder is added to adjust the pH value, and a porous skeleton structure is constructed; s3, adding a polyacrylamide medicament in a flocculation stage to form a compact floc; s4, a high-pressure belt filter press is used for mechanical dehydration in the dehydration stage; s5, recovering the filtrate for redissolving the medicament; s6, performing dynamic linkage optimization of chemical dosing and filter pressing parameters through a dynamic chemical dosing algorithm of the control system; the dosage of chemicals is effectively reduced, the sludge dewatering effect is improved, the sludge dewatering treatment cost is reduced, and the cyclic utilization of resources is realized; the technical problems that an existing sludge dewatering technology is too high in agent cost, low in agent matching and combination reliability and insufficient in technology adaptability are solved.

The invention relates to a sludge biochar modified layered bimetallic oxide, and a preparation method and application thereof. The modified layered bimetallic oxide is prepared from the following main raw materials: domestic sewage aeration tank sludge, NaOH, Na2CO3, FeCl3. 6H2O and MnCl2. 4H2O. The domestic sewage aeration tank sludge is used for preparing dry sludge, the ferric chloride solution and the manganese chloride solution are used for preparing sludge composite layered double hydroxides, and the final layered bimetallic oxide composite sludge biochar catalyst can be prepared by calcining the sludge composite layered double hydroxides. The modified layered bimetallic oxide prepared by the scheme of the invention can effectively degrade bisphenol A, has relatively strong reusability, and still keeps good degradation ability in a relatively wide pH environment.

According to the method, phosphomolybdic acid, copper chloride and ferric chloride serve as precursors, copper and iron-containing phosphomolybdic acid nano-enzyme (Cu, Fe-PMs) with peroxidase-like activity is synthesized through a microwave method, under the acidic condition, on one hand, the surface of Cu and Fe-PMs carries negative charges, high affinity is generated between Cu and Fe-PMs and a substrate TMB with positive charges, and on the other hand, the surface of Cu and Fe-PMs has negative charges; on the other hand, Cu / Fe / Mo three-metal redox couple accelerates the regeneration of Fe < 2 + > and plays an important role in the activity of peroxidase, and meanwhile, due to the introduction of sodium dehydroacetate, Cu and Fe in Cu and Fe-PMs and pyranoid ring and keto O in sodium dehydroacetate interact through coordinate bonds to cause electron interaction, so that the peroxidase-like activity of Cu and Fe-PMs is enhanced, and the peroxidase-like activity of Cu and Fe-PMs is improved. And the Fenton reaction is enhanced through transfer of electrons among the sodium dehydroacetate, the Cu and the Fe-PMs. When Cu and Fe-PMs oxidize TMB and H2O2, sodium dehydroacetate enhances the absorbance of the system, and on the basis, a novel colorimetric rapid detection method of sodium dehydroacetate is established.

The invention discloses a preparation method for selectively oxidizing thioether into sulfoxide through photo-initiation, and belongs to the field of synthesis of medical compounds. The preparation method comprises the following steps that in the air atmosphere, a thioether compound is dissolved in an acetonitrile-water mixed solvent, inorganic metal salt catalysts such as ferric chloride and copper sulfate are added, the mixture reacts for 8-48 h at the temperature of 0-45 DEG C under illumination with the wavelength of 295-405 nm, selective oxidation is carried out, and the sulfoxide product is obtained, and the molar ratio of thioether to the catalysts is 5: 1. The method overcomes the problems of excessive oxidation risk, complicated operation, environmental pollution and the like caused by dependence of a noble metal catalyst and use of a strong oxidant in the existing thioether oxidation method, has the advantages of high catalytic efficiency, high yield and excellent selectivity, can greatly reduce the production cost, is suitable for later industrial synthesis and amplification, and has wide application prospects. The method has the advantages of no expensive metal catalyst or oxidant, simple preparation process, high efficiency, environmental protection, safety and cost saving.

The invention discloses a chlorobenzene wastewater continuous stripping purification recovery device and an implementation method, the chlorobenzene wastewater continuous stripping purification recovery device comprises an aeration tank, an alkali water washing system, an acid water washing system, an acid-base neutralization system and a ferric hydroxide separation system, the aeration tank is connected with the alkali water washing system, the acid water washing system is connected with the alkali water washing system, and the acid water washing system is connected with the ferric hydroxide separation system. The acid-base neutralization system is connected with the alkali-water washing system, the acid-water washing system and the ferric hydroxide separation system, and the alkali-water washing system and the acid-water washing system are both in two-stage steam stripping, and have the following advantages: alkali washing water and acid washing water generated in the chlorobenzene production process are subjected to two-stage nitrogen steam stripping, so that the content of organic matters is greatly reduced; ferric hydroxide is generated through neutralization of acid-alkali wastewater, the total amount of the wastewater is reduced, then the ferric hydroxide reacts with hydrochloric acid in the pickling water to generate ferric trichloride, hydrochloric acid is neutralized, the neutralization product ferric hydroxide is consumed, the wastewater amount is reduced, and recycling of wastewater resources is achieved.

The invention discloses a solar photovoltaic cable sheath material and a tear-resistant photovoltaic cable, and belongs to the field of photovoltaic cable manufacturing. The sheath material comprises the following components in parts by weight: 70-120 parts of ethylene propylene rubber, 10-13 parts of crosslinked polyethylene, 3-7 parts of zinc oxide, 1-4 parts of stearic acid, 1-2 parts of paraffin, 2-5 parts of an anti-aging agent RD, 8-12 parts of zinc borate, 150-200 parts of a reinforcing agent, 10-12 parts of high abrasion furnace black, 9-13 parts of tricresyl phosphate, 9-13 parts of red phosphorus, 0.5-1 part of an accelerant TMTD, 3-5 parts of DCP and 1-2 parts of HVA-2. The reinforcing agent composed of sodium silicate, ferric chloride and aluminum hydroxide is added into the sheath material, so that when the sheath material is damaged, sodium silicate and ferric chloride react under the influence of air moisture to generate colloidal silicic acid carrying ferric hydroxide and aluminum hydroxide, and the damaged part is filled with the colloidal silicic acid; and meanwhile, the aluminum hydroxide can promote the colloidal silicic acid to be dried, so that the damaged part is repaired, and the situation that the tear resistance of the cable is remarkably worsened due to damage is avoided.

The invention provides a composite polyaluminum ferric chloride water purifying agent as well as a preparation method and application thereof, and belongs to the technical field of waste resource recycling and municipal sewage treatment. The industrial hazardous waste aluminum ash is subjected to innocent treatment and then reacts with the pickling steel waste liquid of the steel mill, and the polyaluminum ferric chloride meeting the industrial standard is prepared. The polyaluminum ferric chloride and a cationic adsorbent are compounded according to a specific proportion to obtain the composite polyaluminum ferric chloride water purifying agent. According to the method provided by the invention, the resource recycling of hazardous wastes is realized, and the composite polyaluminum ferric chloride water purifying agent obtained by the method is used for treating municipal sewage, so that the treated water quality can reach the first-grade discharge standard A.

The invention discloses a coagulant material, a preparation method and application, and the method comprises the following steps: adding a silane coupling agent into water for pre-hydrolysis to obtain a pre-hydrolysis solution; secondly, a mixed solution of aluminum chloride and ferric chloride is prepared and stirred to be completely dissolved and evenly mixed, and the mass ratio of aluminum chloride to ferric chloride is 9: 1-5: 5; the pre-hydrolysis solution and a mixed solution of aluminum chloride and ferric chloride are mixed and stirred evenly, and the ratio of the total substance mass of silicon to ferro-aluminum in the silane coupling agent is 0.1-0.5; dropwise adding a sodium hydroxide solution into the mixed solution, and adjusting the alkalization degree until the mass ratio of [OH] to [Al + Fe] is 1-2; and standing and curing the solution of which the alkalization degree is adjusted to obtain the aluminum-iron covalent composite coagulant. The coagulant has the advantages of efficient fluorine removal capability, rapid floc growth, good settling performance, low aluminum residue and the like, and is suitable for wide pH range and water quality conditions.

The present invention relates to the technical field of preparation of adsorbent materials for removing heavy metals from acidic wastewater, specifically a method for preparing a resin-based magnetic composite adsorbent material, comprising the following steps: using waste expanded resin as a base carrier, ferric chloride as an added magnetic auxiliary substance, mixing magnesium sulfate and aluminum sulfate evenly, stirring at high speed and ultrasonic dispersion, then adding sodium phosphite and sodium hypophosphite and placing them in a microwave reactor, adjusting the pH of the sodium phosphite and sodium hypophosphite in the reactor to precipitate, while the phosphite intercalates into the precipitate, finally filtering the precipitate and washing and drying to obtain a novel adsorbent material for excellent adsorption of heavy metals in acidic mine wastewater. The material prepared by the present invention can effectively adsorb various heavy metal ions such as cadmium, chromium, zinc, lead, manganese, copper, etc. in acidic mine wastewater, has a large adsorption capacity, and the adsorbent material has magnetism and can be regenerated by solid-liquid separation through magnetism.

The present invention discloses a method for synthesizing 9-bromoanthracene. Anthracene and potassium bromide are used as raw materials. The final product, 9-bromoanthracene, is obtained by reacting anthracene and potassium bromide in the presence of ferric chloride and 1-acetoxy-1,2-benzidoxyl-3-(1H)-ketone. The method has the advantages of being inexpensive and readily available, easy to produce, and readily purifiable, and can be developed into an industrialized production method.

The invention aims to provide a device and method for extracting iron from red mud and preparing iron oxide red, and belongs to the technical field of resource utilization, hydrochloric acid is adopted to leach iron element in the red mud, and a ferric chloride solution is separated from leachate through an extraction process. And then, carrying out alkali precipitation, washing and firing to prepare the high-purity iron oxide red. By using the method disclosed by the invention, the iron resource in the red mud can be recycled, so that the dual purposes of resource utilization and environment-friendly treatment are achieved.

The invention belongs to the field of membrane pollution control, and particularly relates to a modification method for prolonging the service life and performance of a pervaporation membrane in seawater. According to the method, the pervaporation membrane is soaked in deionized water for treatment, so that anticorrosive substances on the surface of the membrane are stripped, the soaked pervaporation membrane is pasted in a membrane assembly, then the membrane assembly is soaked in a tannic acid solution for 60 s, and after soaking is finished, the membrane assembly is taken out. The membrane assembly is taken out, the surface of the membrane is washed with deionized water and then moved into a ferric chloride solution to be soaked for 60 s, finally, the surface of the membrane is washed with deionized water, so that the polyphenol coating is successfully attached to the surface of the membrane, and the unique property of the polyphenol coating becomes the key for prolonging the service life of the membrane; when the PH is lower than 3, most-OH groups in the tannic acid are protonated, so that the polyphenol coating is disintegrated and separated from the pervaporation membrane, and pollutants accumulated on the surface of the membrane are removed at the same time. And subsequently. The surface of the pervaporation membrane is coated with a new polyphenol coating again, so that the service life of the pervaporation membrane is prolonged, and the method also has important significance in reducing the treatment cost of desalinated seawater.

The invention relates to the technical field of electro-catalysis, in particular to a modified iron monatomic catalyst based on biomass carbon as well as a preparation method and application of the modified iron monatomic catalyst. The preparation method comprises the following steps: mixing and stirring chitosan, an acetic acid solution, thiourea and ferric chloride, adjusting the pH value to 7.5-8.5, and freeze-drying to obtain an aerogel precursor; pre-carbonizing the aerogel precursor to obtain a pre-carbonized product; mixing the pre-carbonized product with an alkali reagent, and calcining to obtain a metal nanoparticle doped monatomic catalyst; and carrying out ultrasonic treatment on the metal nanoparticle doped monatomic catalyst by using a mixed acid solution, washing to be neutral, and drying to obtain the modified iron monatomic catalyst. By adopting the modified iron monatomic catalyst provided by the invention, non-polar CO2 molecules and NO3 <-> are efficiently converted into urea under mild conditions, the yield of the urea is up to 2978.6 mu g h <-1 > mgcat <-1 >, and the maximum Faraday efficiency is up to 30.4%.

The invention provides a wide pH applicable multi-biomolecule detection MOF probe, a preparation method, a detection method and application, the probe is an MIL-53 (Fe) (at) AA (at) EZ probe, and comprises a metal organic framework MIL-53 (Fe), amino acid and enzyme; the preparation method comprises the following steps: weighing terephthalic acid and ferric chloride hexahydrate, adding into N, N-dimethylformamide, mixing and stirring, pouring the mixed solution into a stainless steel autoclave, heating and reacting, naturally cooling to room temperature, centrifugally separating a product, and washing with N, N-dimethylformamide and absolute ethyl alcohol to obtain the metal organic framework MIL-53 (Fe). The preparation method comprises the following steps: mixing a metal organic framework MIL-53 (Fe) with an amino acid solution, and carrying out ultrasonic treatment and stirring to obtain an MIL-53 (Fe) coated AA solution; the method comprises the following steps: dissolving enzyme in an MIL-53 (Fe) (at) AA solution, uniformly mixing, stirring, centrifugally separating a product, taking precipitate, and drying in vacuum to obtain the MIL-53 (Fe) (at) AA (at) EZ probe. The pH application range is wide, one-step detection can be achieved, and the method has the advantages of being rapid in reaction, high in sensitivity, low in detection limit and easy and convenient to operate.

The invention provides a preparation method of apixaban, and belongs to the technical field of raw material medicine synthesis. The intermediate product 5 is prepared by adopting continuous flow equipment, so that the defect of low heat and mass transfer efficiency of an intermittent reaction kettle is overcome, the reaction danger coefficient is reduced, the reaction time is shortened, the product quality is improved, and the product yield is increased; a ferric trichloride / activated carbon-hydrazine hydrate system is adopted for nitro reduction, so that the selectivity is good, and the product purity and yield are improved; the ethanol solution of ammonia is adopted to replace ammonia water, CH3ONa / HCOONH2, mixed anhydride-ammonia water and the like in the prior art, the defects that in the prior art, the content of acid impurities is high, and the amount of post-treated ammonia-containing wastewater is large are overcome, and the environmental protection pressure is reduced while the product quality is improved.

The invention belongs to the technical field of photocatalytic materials, and particularly relates to a manganese ferrite / bismuth tungstate heterojunction photocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: 1) dissolving sodium tungstate dihydrate, bismuth nitrate pentahydrate and hexadecyl trimethyl ammonium bromide in deionized water, and obtaining bismuth tungstate by using a hydrothermal method; 2) dissolving ferric chloride hexahydrate and manganese chloride tetrahydrate in water, then adding a sodium hydroxide solution, and obtaining manganese ferrite by using a hydrothermal method; and 3) dissolving bismuth tungstate and manganese ferrite into a sodium hydroxide solution, stirring, and drying to obtain the manganese ferrite / bismuth tungstate heterojunction photocatalyst. The formation of the heterojunction can greatly improve the activity of the manganese ferrite / bismuth tungstate in photocatalytic reduction of carbon dioxide.

The invention discloses an antistatic modified polyamide fiber and a preparation method thereof, and relates to the field of fibers. When the antistatic modified polyamide fiber is prepared, nano-silver is loaded on halloysite powder nanotubes in situ to prepare pre-modified halloysite powder nanotubes; grafting 9H-carbazole-9-formaldehyde to chitosan, and uniformly mixing the chitosan with the pre-modified halloysite powder nanotube and silver nitrate to obtain a modified halloysite powder nanotube; the preparation method comprises the following steps: reacting diethyl (hydroxymethyl) phosphate with carbazole-N-formyl chloride to obtain a functional monomer; reacting hexamethylenediamine, adipic acid, pyromellitic dianhydride and a functional monomer to prepare a modified polyamide slice; uniformly mixing the modified polyamide slices, the modified halloysite powder nanotubes, carbazole and ferric trichloride, spinning, and grafting 4-aminomethyl-2, 2, 6, 6-tetramethylpiperidine to obtain the antistatic modified polyamide fiber. The antistatic modified polyamide fiber prepared by the invention has excellent antistatic property, antibacterial property, flame retardance and aging resistance.

The invention provides a resource utilization method of iron-aluminum-chromium waste acid, and belongs to the field of waste acid resource treatment. According to the hydrochloric acid type iron-aluminum-chromium waste acid, firstly, high-valence metal in the waste acid is reduced through iron powder, the acidity of a system is reduced, and the iron content is increased; secondly, high-efficiency separation of iron, aluminum and chromium is realized by accurately controlling the sodium phosphate amount, the pH value, the reaction temperature and the stirring rotating speed; and then, oxidizing an iron solution obtained by solid-liquid separation to prepare ferric chloride, and carrying out hydrothermal crystallization on aluminum phosphate and chromium phosphate precipitates to prepare chromium-containing aluminum phosphate which can be used as a catalyst. The method realizes thorough step-by-step separation of metals in the iron-chromium-aluminum hydrochloric acid type waste acid, realizes resource utilization, is free of waste gas and waste residues in the process, meets the green and environment-friendly requirements, and has remarkable environmental and social benefits.

The invention discloses a preparation method of a CoMnFe-PBA hollow superstructure material, which combines seed induced self-assembly with an in-situ ligand / metal ion exchange growth method, and comprises the following steps: dissolving MOF-74 and potassium ferricyanide in deionized water, and carrying out ultrasonic treatment to form a solution A; dissolving polyvinylpyrrolidone, ferric chloride and manganese chloride tetrahydrate in a mixed solvent of ethanol and deionized water, and stirring for a certain time to obtain a solution B; dropwise adding the solution B into the solution A, stirring, carrying out centrifugal collection, ethanol washing and freeze drying on a reaction product, and collecting a sample to obtain the CoMnFe-PBA hollow superstructure material. According to the CoMnFe-PBA hollow superstructure material prepared through the method, a construction unit of a self-assembly superstructure is expanded to PBA nanoparticles, and the synthesis strategy, the construction unit, the structural level and the application range of the self-assembly superstructure can be further expanded.

The invention discloses ferric chloride and calcium chloride combined modified biochar, a preparation method thereof and a method for enhancing phosphate adsorption, and the preparation method comprises the following steps: (1) mixing and dipping original biochar with a ferric chloride and calcium chloride solution, and fully shaking and shaking up the mixed solution; (2) carrying out suction filtration on the mixed solution to remove supernate, and drying residual solid substances to obtain a modified biochar material; and (3) putting the modified biochar material into a tubular furnace, continuously introducing nitrogen into the tubular furnace, carrying out high-temperature carbonization at 600 + / -5 DEG C for 2 + / -0.1 h, cooling the tubular furnace to room temperature, taking out, cleaning, and drying to obtain the biochar jointly modified by ferric chloride and calcium chloride. Adsorption active sites of the biochar can be increased after joint modification of ferric chloride and calcium chloride, the specific surface area of the biochar is increased, the structure of the biochar is looser, and the adsorption effect is enhanced.

The invention discloses a method for catalyzing and photo-initiating nitro reduction through ferric trichloride, and belongs to the field of pharmaceutical compound synthesis. According to the method, transition metal salt is mainly used as a catalyst for reaction, inorganic acid and organic acid are used as additives, nitryl is reduced into amino under the condition of air or nitrogen, the catalytic efficiency is high, the yield of reduction products is high, the production cost is greatly reduced, and the method is suitable for synthesis and amplification of later compounds and has good application prospects. The method has the advantages of no expensive metal catalyst or reducing agent, simple preparation process, high efficiency, environmental protection, safety and cost saving.

A method of producing a mesoporous chitosan / sodium iron silicate (NaFeSi2O6) nanocomposite includes hydrothermally treating a mixture of sodium metasilicate pentahydrate (Na2SiO3·5H2O) with iron(III) chloride hexahydrate (FeCl3·6H2O) to obtain NaFeSi2O6 nanoparticles. The method further includes combining the NaFeSi2O6 nanoparticles with a solution of chitosan to generate a precursor mixture; treating the precursor mixture with sodium hydroxide (NaOH), resulting in a nanocomposite where chitosan coats and aggregates the NaFeSi2O6 nanoparticles into rod-like structures. The resulting nanocomposite exhibits unique textural properties with mesopores larger than 15 nm, is ideal for adsorption, separation, and catalysis, and can be produced under mild conditions without complex procedures or hazardous chemicals.

The invention belongs to the field of organic synthetic chemistry, and relates to a preparation method of melatonin and meerythrine indole derivatives and compounds. Specifically, the indole derivative is efficiently synthesized by taking arylamine and carboxylic acid as raw materials through a one-pot two-step reaction in the presence of catalysis of ferric chloride hexahydrate (FeCl3. 6H2O), a ligand, a diazotization reagent, an additive and a solvent under the conditions of visible light irradiation, inert atmosphere and room temperature. According to the method, visible light induced iron-based LMCT catalysis and iron lewis acid catalysis functions are integrated, and efficient integration of diazotization, decarboxylation, free radical coupling and cyclization reaction is achieved. The method has the advantages that raw materials are cheap and easy to obtain, reaction conditions are mild, substrate applicability is wide, functional group compatibility is good, operation is easy, convenient and safe, and environment friendliness is achieved, gram-level scale preparation can be achieved, and a green and efficient synthesis path is provided for indole compounds with biological activity such as melatonin and meerythrine.