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92results about How to "Reduce the effective content" patented technology

Microorganism passivator for repairing heavy metal pollution of soil and preparation and application thereof

The invention discloses a microorganism passivator for repairing heavy metal pollution of soil and preparation and application thereof. A preparing method comprises the steps of fermentation and adsorption of strains. Specifically, bacteria solutions obtained after fermentation of bacillus megateriumvar.phosphaticum and bacillus subtilis LVLE-14 are mixed in proportion, then adsorption is conducted by means of a special adsorption carrier, and then mixing and smashing are conducted to obtain the microorganism passivator. The adsorption carrier comprises hydrolysis residues and biochar which are mixed and smashed according to a certain mass ratio. By the adoption of the microorganism passivator for repairing heavy metal pollution of soil, the content of available heavy metals in soil can be effectively reduced, and the number of microbial populations and plant yield are increased greatly. The method for repairing heavy metal pollution of soil by means of the microorganism passivator is in-situ repair, operation is easy, the cost is low, and industrialized implementation can be easily achieved; furthermore, the repairing effect is good, soil fertility can not be damaged, and the utilization rate of resources can be increased.
Owner:SHANGHAI LVLE BIO TECH

Fixed enrichment method for city life compost heavy metals through modified nanocarbon

The invention discloses a fixed enrichment method for city life compost heavy metals through modified nanocarbon. The fixed enrichment method comprises the following steps: modifying the modified nanocarbon with the grain diameter of 20-70nm before being applied so as to obtain various types of modified nanocarbon; then sealing a layer of cotton cloth and a nylon net at the lower end of a PVC (polyvinyl chloride) tube, uniformly and proportionally mixing garbage compost with the modified nanocarbon, wherein each tube is filled with150g of a mixed material; setting the temperature during experiments to be 19-27 DEG C and the relative humidity to be 60% to 72%, and supplementing water for the compost every day, so that the content of water of the compost reaches about 70% of field moisture capacity; sampling 45d for cultivation later, and carrying out morphological analysis on the heavy metals, wherein the addition of the modified nanocarbon is 1-5%(w/w) of the weight of the garbage compost. Experimental results show that the modified nanocarbon is added so that the contents of the heavy metals in a residual form are increased, the conversion of the compost heavy metals from a plant easily-absorbed state to a difficultly-absorbed state is promoted, and the method provides a basis for the application of the modified nanocarbon on passivation and plant enrichment of the heavy metals in garbage compost.
Owner:TIANJIN NORMAL UNIVERSITY

Cross-linked polymer system heat stabilizer for water shutoff and profile control, and preparation method and application thereof

InactiveCN103113702AReduce the number of re-constructionLow costDrilling compositionCross-linkPolymer science
The invention discloses a cross-linked polymer system heat stabilizer for water shutoff and profile control, and a preparation method and application thereof, wherein the heat stabilizer is composed of the following components in parts by weight: 2-8 parts of sodium thiosulfate, 30-50 parts of polyethylene glycol, 10-30 parts of urea, 1-5 parts of formaldehyde and 800-1200 parts of de-ionized water. All of the components are evenly mixed to obtain the heat stabilizer which is used as a cross-linked polymer system common in water shutoff and profile control or profile control and displacement of the oil field; and the cross-linked polymer system is composed of polyacrylamide aqueous solution and a phenolic resin cross-linking agent or organic chromium cross-linking agent. The thiourea or sodium thiosulfate of the heat stabilizer provided by the invention serves as the deoxidant, the polyethylene glycol or the urea serves as the complexing stabilizer, and the formaldehyde serves as the complexing stabilizer and the bactericide; the method for preparing the cross-linked polymer system heat stabilizer is simple and the use cost is also low; therefore, the strength and the stability of the cross-linked system both can be well improved.
Owner:CHINA PETROLEUM & CHEM CORP +1

Passivating agent used for treating lead-cadmium compound contaminated soil as well as preparation method thereof and using method thereof

The invention relates to the technical field of repair of heavy metal contaminated soil, in particular to a passivating agent used for treating lead-cadmium compound contaminated soil as well as a preparation method thereof and a using method thereof. The passivating agent is prepared by compounding sepiolite and phosphor-containing substances. The preparation method for the passivating agent comprises the following steps: mixing acidic modified sepiolite, calcium dihydrogen phosphate and phosphorite powder, and uniformly mixing to obtain the passivating agent. The using method for the passivating agent comprises the following steps: pre-treating the lead-cadmium compound contaminated soil, performing air-drying on the contaminated soil, grinding the contaminated soil, enabling the grinded contaminated soil to pass through a 20-mesh sieve, adding the passivating agent into the pre-treated contaminated soil, adding water to uniformly mix, maintaining the uniformly mixed soil in situ, and enabling the passivating agent to sufficiently react with heavy metals in the soil. The passivating agent provided by the invention is low in raw material cost, is high in passivating efficiency, is stable in effect, and is suitable for farmland treatment with great Pb and Cd contaminated area and light contamination degree.
Owner:WUHAN UNIV OF SCI & TECH

Method for reducing bioavailability of soil with combined heavy metal pollution

The invention discloses a method for reducing the bioavailability of soil with combined heavy metal pollution. The method comprises the following steps: subjecting the soil with combined heavy metal pollution to air drying, sieving and preservation; with agricultural and forestry residues as raw materials, preparing biochar particles, and carrying out crushing, screening, air drying or stoving, and preservation; mixing the screened dried biochar particles and the soil with combined heavy metal pollution in a weight ratio of 1: 20 to 1: 100 under stirring, adding distilled water to allow the water content of the obtained mixture to reach 50 to 70% of field moisture capacity, and subjecting the mixture to standing for 5 to 7 days to allow the mixture to be fully decomposed so as to prepare achar-soil mixture with combined heavy metal pollution; and transplanting tobacco seedlings into the char-soil mixture by using a well cellar seedling transplanting method, uniformly filling the wellcellar with the mixture and allowing the growing points of the tobacco seedlings to main exposed. The method provided by the invention substantially reduces the available contents of Cd and Pb in thesoil with combined heavy metal pollution and lower absorption and enrichment of the heavy metals Cd and Pb by the roots, stems and leaves of crops; and the method has the advantages of low cost, highefficiency, simple operation and easy promotion and application.
Owner:INST OF GEOCHEM CHINESE ACADEMY OF SCI

Micro-nano structure hydroxyapatite and preparing method and application thereof

The invention discloses micro-nano structure hydroxyapatite and a preparing method and application thereof. The hydroxyapatite is of a microsphere structure, and the surfaces of the hydroxyapatite microspheres are provided with nanorods. The specific surface area of the hydroxyapatite microspheres with the surfaces provided with the nanorods is larger than or equal to 192 m<2> / g, the spherical diameter of the microspheres ranges from 3 microns to 5 microns, the diameter of the nanorods ranges from 5 nm to 15 nm, and the length of the nanorods ranges from10 nm to 100 nm. The preparing method includes the steps that after a calcium solution and a phosphorus solution are stirred and mixed according to the molar ratio (please see the specification) of 1:(1.4-1.8), adjustment is carried out through hydrochloric acid or nitric acid to obtain clear liquid; after a chelating agent and urea are added into the clear liquid, a surface active agent is added into the obtained mixed liquid to obtain precursor liquid; the precursor liquid is reacted at the temperature of 80-95 DEG C and subjected to standing and aging, and reaction liquid with sediments is obtained; the reaction liquid with the sediments is subjected to solid-liquid separation and washing treatment, and a target product is obtained. The micro-nano structure hydroxyapatite can be widely used for governing and repairing soil polluted by heavy metal.
Owner:HEFEI INSTITUTES OF PHYSICAL SCIENCE - CHINESE ACAD OF SCI

Biochar-based bacterial composite soil conditioner as well as preparation and application thereof

The invention discloses a biochar-based bacterial composite soil conditioner as well as preparation and application thereof. A preparation method comprises the following steps: (1) domestication of bacteria: sequentially inoculating bacillus cereus, ochrobactrum sp. and arthrobacter sp. into a Cd-containing inorganic salt culture solution with a gradient concentration respectively for domestication and cultivation; and mixing the domesticated and cultured bacterial solutions to prepare a bacterial suspension for later use; and (2) preparation of the biochar-based bacterial composite soil conditioner: taking biochar to be mixed with the bacterial suspension, adding antagonistic elements of heavy metals in soil, then performing shaking cultivation, filtering and washing. The biochar-based bacterial composite soil conditioner provided by the invention is simple in preparation method and low in cost; microorganisms in the preparation have high tolerance to the heavy metal Cd, so that the preparation has good remediation effect on the heavy metals in the soil, and is stable, long-acting, and less affected by the environment; the invention is an in-situ chemistry-combined microbial passivation remediation technology effectively applied to heavy metal-contaminated soil in farmlands.
Owner:HUNAN HENGKAI ENVIRONMENT TECH INVESTMENT CO LTD

Amendment agent and preparation method and application thereof

The invention belongs to the technical field of soil protection, and particularly relates to a cadmium-arsenic compound contaminated soil restoration amendment agent and a preparation method and application thereof. The provided amendment agent comprises modified vermiculite, modified bio-char and modified sepiolite, has simple composition and good adsorption effect, can maintain the pH of the soil in a relatively stable range, and can effectively reduce the variation amplitude of the soil pH, the comprehensive restoration of the cadmium-arsenic compound pollution can be achieved through the compounding of the three materials, and the soil fertility is not affected. The modified vermiculite has relatively high pH buffering ability, so that the problem that sepiolite tends to increase the pH value of the soil and the iron-modified bio-char tends to lower the pH value of the soil can be slowed down. The bio-char is rich in functional groups, and the iron-modified bio-char has relativelygood curing and stabilizing effects on arsenic. The sepiolite is a chain-like transition structure composed of parallel crystal layers, the adjacent crystal layers are arranged alternately to form micro-porous channels, so that the sepiolite has strong adsorption, decolorization, dispersion and other properties.
Owner:BCEG ENVIRONMENTAL REMEDIATION CO LTD

Method using catalytic oxidation of sulfur dioxide tail gas for PH adjustment agent of phosphate rock ore dressing

ActiveCN103949150ARealize flotation mineralization coupling technologyRealize the coupling technology of beneficiation and mineralizationDispersed particle separationChemical industryO-Phosphoric Acid
The invention discloses a method using catalytic oxidation of sulfur dioxide tail gas for a PH adjustment agent of phosphate rock ore dressing. According to the method, soluble iron (III), germanium (IV) and other metal ions in raw phosphate rock pulp are used as catalysts, copper (II) ions play a synergistic effect, a trace buffer is added; countercurrent contact, in a dynamic wave desulphurization tower, with the sulfur dioxide tail gas out from an absorption tower is realized, and after sulfur dioxide is absorbed, a sulfuric acid solution is formed for decomposition of the phosphate rock pulp; phosphoric acid formed by the decomposition of the phosphate rock pulp can be used as the PH adjustment agent in phosphate rock ore flotation selection, and a mineralization coupling technology of phosphorus chemical industry and phosphate rock ore dressing can be achieved. The tail gas processed by desulphurization can reach an emission standard of less than or equal to 400mg/m<3> of tail gas of the new national standard. The purification method of the sulfur dioxide tail gas in sulfuric acid production has the advantages of simple process and strong applicability, can achieve the mineralization coupling technology of phosphorus chemical industry and phosphate rock ore dressing, and has great significance in the points of view of both resources and environmental protection.
Owner:YUNNAN PHOSPHATE CHEM GROUP CORP

Polycrystalline silicon reduction furnace raw material gas feeding amount controller

The invention discloses a polycrystalline silicon reduction furnace raw material gas feeding amount controller. A polycrystalline silicon reduction furnace comprises an air inlet and a gas outlet. The fed raw material gas comprises tail gas discharged by the polycrystalline silicon reduction furnace, newly fed trichlorosilane and newly fed hydrogen. The tail gas comprises tail gas trichlorosilane, tail gas hydrogen chloride and tail gas hydrogen. The controller comprises a detection mechanism for detecting mole content of hydrogen chloride in tail gas, a raw material gas feeding mechanism and a master controller. The detection mechanism for detecting mole content of hydrogen chloride in tail gas is electrically connected to the master controller. The raw material gas feeding mechanism is electrically connected to the master controller. The controller realizes on-line automatic control of a mole amount of tail gas fed into the reduction furnace, is free of personnel monitoring, keeps a ratio of trichlorosilane to hydrogen chloride in the reduction furnace in a normal high efficiency production reasonable scope by timely change of a used tail gas amount in polycrystalline silicon reduction furnace production so that the tail gas is reasonably used to a highest degree.
Owner:XINTE ENERGY

Heavy metal contaminated soil remediation agent and preparation method thereof

The invention belongs to the technical field of soil remediation agents, and discloses a heavy metal contaminated soil remediation agent. The heavy metal contaminated soil remediation agent comprises,by weight, 30-50 parts of modified fly ash, 20-30 parts of modified kaolinite, 10-20 parts of oxidized nanometer carbon black, 10-15 parts of biochemical fulvic acid, 3-8 parts of sodium thiosulfateand 5-10 parts of a microbial agent. The invention also discloses a preparation method of the heavy metal contaminated soil remediation agent. The preparation method comprises the following steps: (1)uniformly mixing weighed modified fly ash, modified kaolinite, oxidized nanometer carbon black, biochemical fulvic acid and sodium thiosulfate, feeding the obtained mixture into a granulator, addinga proper amount of water vapor, granulating, and drying for later use; and (2) adding the microbial agent into obtained particles, uniformly mixing, feeding the obtained mixture into a granulator, adding a proper amount of water vapor, granulating, and drying to obtain the soil remediation agent. An inorganic passivator and microorganisms are combined for use, and heavy metal ions are rapidly andefficiently fixed through the inorganic passivator; and the microbial agent is added, so that the leaching concentration of heavy metals is reduced, and the heavy metal contaminated soil is improved.
Owner:湖南本农环境科技有限公司 +1

Soil remediation method based on modified attapulgite clay

The invention discloses a soil remediation method based on modified attapulgite clay. The method comprises the following steps of S1, sampling attapulgite clay raw materials, smashing the attapulgiteclay through a smashing device, and then, adding diluted ammonium hydroxide, a dioctyl sebacate solution, a carbon base material and a remediation solution, wherein the addition mass percentage of diluted ammonium hydroxide is 0.8-1.0%, the addition mass percentage of the dioctyl sebacate solution is 1.0-1.2%, the addition mass percentage of the carbon base material is 0.8-1.5%, and the addition mass percentage of the remediation solution is 0.2-0.3%. The invention relates to the technical field of soil remediation. According to the soil remediation method based on modified attapulgite clay, the modified attapulgite clay is adopted as a soil remediation agent, a layer which is high in adsorption capability, high in adoration rate and capable of effectively adsorbing heavy metal ions in soil can be formed below a contaminated soil layer, the soil remediation solution is sprayed, plants grow to have deep roots and luxuriant leaves, chlorophyll is enhanced, nutrients are abundant, and normal juice and normal taste are recovered; soil contaminations are reduced, and the method is low in carbon and environmentally friendly and no water or fertilizer soil is lost.
Owner:HUAIYIN INSTITUTE OF TECHNOLOGY
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