1572 results about "Liquid ammonia" patented technology

The invention relates to the technical field of risk analysis, in particular to a dangerous chemical transportation risk prediction system and method based on big data analysis, and the system comprises a multi-dimensional data acquisition module which is used for collecting human-machine-ring-pipe four-dimensional data in the liquid ammonia water transportation process, and carrying out the standardization processing and time-space synchronization, and obtaining a multi-source heterogeneous data set; the risk level acquisition module is used for constructing a man-machine-ring-management collaborative risk assessment model and analyzing the multi-source heterogeneous data set to obtain a risk assessment result; the human-machine-environment-management collaborative risk assessment model comprises a human-machine interaction key node identification layer, a management behavior-equipment response association analysis layer, an environment-material interaction dynamic risk assessment layer and a multi-dimensional factor risk cascade assessment layer; and the emergency disposal scheme acquisition module constructs an emergency disposal scheme intelligent recommendation model to perform grading and classification analysis on the risk assessment result, generates a multi-level risk early warning and emergency disposal scheme, and optimizes the emergency disposal scheme.

The invention discloses a device and a method for producing oxamide, and relates to the field of chemical production. The method for producing oxamide specifically comprises the following steps: mixing a methanol solution of liquid ammonia and a methanol solution of dimethyl oxalate, carrying out ammonolysis reaction, carrying out flash evaporation, filtration and drying on first slurry obtained after the reaction is finished to obtain solid oxamide, and refining a liquid phase obtained by solid-liquid separation of the first slurry to obtain a byproduct methanol, ammonia in the tail gas is washed and absorbed by dimethyl oxalate and then returns to a reaction system. In the oxamide production process, dimethyl oxalate reacts with ammonia gas in mixed gas generated in the reaction process, and the obtained product is continuously subjected to subsequent ammonolysis reaction, so that the utilization rate of reaction materials is increased; meanwhile, a condenser is not used for condensing ammonia gas and methanol and then separating alcohol and ammonia, so that condensing equipment and cooling water are saved, the production cost is reduced, and industrial production is facilitated.

The invention discloses a plasma-enhanced direct-injection type liquid ammonia atomizing nozzle and a liquid ammonia combustor, and belongs to the field of liquid fuel combustion. The plasma-enhanced direct-injection type liquid ammonia atomizing nozzle comprises a liquid ammonia channel, a compressed air channel, an atomizing channel, a secondary air channel and a heating assembly, wherein the outlet end of the compressed air channel and the outlet end of the liquid ammonia channel are both communicated with the atomizing channel; the heating assembly comprises a high-voltage electrode, a ground electrode and a central air channel, the ground electrode is arranged on the outer side of the high-voltage electrode, and an outlet of the central air channel faces a discharge area formed by the high-voltage electrode and the ground electrode; a discharge area formed by the high-voltage electrode and the ground electrode is close to the liquid ammonia channel; a ground electrode hole is formed in the position, close to the liquid ammonia channel, of the ground electrode. Self-evaporation of preheated liquid ammonia is achieved through small plasma flames, efficient atomization of large-flow liquid ammonia is achieved, and consumption of atomization media is reduced while stable combustion is achieved.

The invention discloses a process and a device for producing oxamide, and relates to the field of chemical production. The invention provides a process for producing oxamide, which specifically comprises the following steps: mixing a methanol solution of liquid ammonia and a methanol solution of dimethyl oxalate, carrying out ammonolysis reaction, carrying out flash evaporation, filtration and drying on first slurry after the reaction is finished to obtain solid oxamide, and carrying out liquid phase refining to obtain a byproduct methanol, ammonia in the tail gas is washed and absorbed by dimethyl oxalate and then returns to a reaction system. The methanol solution of dimethyl oxalate is used for absorbing excessive ammonia in the reaction process, and the reaction product is continuously used for producing oxamide, so that methanol and ammonia can be thoroughly separated, the conversion rate of ammonia can be greatly improved, and the economical efficiency of the production process is improved; meanwhile, tail gas containing ammonia is not discharged, and the environmental protection property of the production process is improved.

The invention relates to the technical field of industrial process control, and discloses a denitration intelligent monitoring method and system based on data analysis and a storage medium. The method comprises the following steps: performing working condition identification by using an improved K-means algorithm to obtain stable operation, fire change preparation, fire change proceeding and fire change recovery modes; matching a segmented control strategy according to an identification result, and carrying out weighted fusion on feedforward and predictive control in a fire exchange preparation stage to generate a differentiated liquid ammonia regulation instruction; the disturbance feed-forward compensation amount is calculated in combination with the combustion state of the kiln, the adjusting instruction is restrained, and a liquid ammonia control instruction is obtained; the execution effect is monitored in real time through standardized deviation detection, manual intervention is switched in case of abnormity, and control parameters are fed back and updated in case of normal. The problems that NOx control lags behind and liquid ammonia consumption is not economical under the fire exchange working condition are solved, and the control precision and the self-adaptive capacity of the denitration system are improved.

The invention belongs to the field of pollutant control, and particularly discloses a method and system for reducing generation of nitric oxide in the ammonia coal combustion process. The method specifically comprises the steps that liquid ammonia is gasified and then subjected to a thermocatalytic reaction to generate hydrogen and nitrogen, and ammonia-doped mixed gas is obtained; and judging whether the ratio of the concentration of hydrogen to the concentration of ammonia in the ammonia-doped mixed gas is greater than or equal to a threshold value or not, if so, discharging the ammonia-doped mixed gas for blending combustion, and if not, carrying out thermal catalytic reaction on the ammonia-doped mixed gas again. According to the method, the ratio of the concentration of hydrogen to the concentration of ammonia in the ammonia-doped mixed gas serves as the judgment standard for whether blending combustion can be conducted or not, the calculation formula of the threshold value is provided by balancing the influence of H2 and NH3 on NOx generation in the combustion process, then flexible regulation and control can be conducted on the raw material side according to the actual blending combustion condition, and the blending combustion efficiency is improved. The method effectively reduces the generation of nitrogen oxides in the ammonia coal combustion process, does not need to regulate and control the combustion side, does not affect the combustion stability and the boiler thermal efficiency, and has the advantages of simple operation and low cost.

The invention discloses a high-temperature ammonia burner based on ammonia catalytic cracking hydrogen production and liquid ammonia atomization combustion and an operation method thereof, high-temperature air generated by a grate cooler is introduced into a catalytic cracking device, heat of the high-temperature air is utilized to promote liquid ammonia gasification, activate a catalyst and promote ammonia catalytic cracking to generate hydrogen, and ammonia, nitrogen and hydrogen mixed gas is formed; the reaction activity of the fuel is improved; medium-temperature air and mixed gas generated by the catalytic cracking device are supplied to the first to fifth gas inlets respectively, stable on-duty flames are formed under the action of a sliding arc, then the mixed gas introduced into the fourth gas inlet is ignited to form main combustion flames, high-temperature and active components generated by the main combustion flames promote liquid ammonia atomization, and the liquid ammonia atomization effect is improved. And the liquid ammonia is ignited to form axial graded flames. According to the invention, ammonia catalytic cracking hydrogen production and high-temperature air are fully utilized, the flame stability and temperature are improved, stable combustion of large-flow liquid ammonia can be maintained, and the problems of low flame temperature, difficult ammonia ignition, unstable combustion and the like are effectively solved.

The flexible ammonia synthesis process comprises the following steps: raw material gas is preheated and heated, then enters a temperature-controlled ammonia synthesis tower and reacts under the action of a catalyst, the reacted gas is subjected to heat energy recovery through an outlet waste heat boiler and then enters an ammonia separation tank after being subjected to multi-stage cooling, and a liquid ammonia product is obtained at the bottom; the top non-condensable gas is pressurized by a circulating compressor and then returns to an inlet of the temperature control ammonia synthesis tower; in the temperature-controlled ammonia synthesis tower, raw material gas enters the tower through a raw material gas inlet and sequentially penetrates through the distribution plate, the catalyst bed I section, the distribution plate and the catalyst bed I section from outside to inside in the radial direction, reaction is carried out while heat exchange is carried out, and reaction gas is led out from a reaction gas outlet in the bottom after being converged in the center. The method is simple in process, easy to control, low in equipment investment and operation cost, energy-saving, consumption-reducing, high in reaction efficiency and loose in reaction condition, temperature runaway or temperature loss of a bed layer is not easily caused under high load, and stable operation of the system can still be kept under 0-120% fluctuation of feed gas flow.

The invention provides an ammonia / kerosene dual-fuel precooling engine and a fuel cell power generation system, and belongs to the technical field of aviation systems. The problems of poor variable working condition performance of an engine, difficulty in matching of a gas compressor and a turbine, low working efficiency, fuel waste and the like due to the fact that working of the gas compressor is limited by overhigh total temperature of flying incoming flow air under the high Mach number of an aircraft are solved. According to the invention, the electric energy generated by the solid oxide fuel cell system is supplied to the aircraft load and the motor, and the motor drives the secondary gas compressor to do work in a manner of coaxial installation with the secondary gas compressor, so that the previous single-pole compression is changed into multi-stage compression. A dual-fuel pre-cooling propulsion method is adopted, liquid ammonia and aviation kerosene are selected as dual fuels of the system, the heat sink requirement for incoming flow air pre-cooling can be met, the fuel heat value requirement needed when the aircraft flies at the high Mach number can also be met, and therefore stable and safe flight of the aircraft at the hypersonic speed becomes possible.

The invention discloses a high-power sliding arc igniter based on a gas-liquid cooling electrode and an operation method of the high-power sliding arc igniter, and relates to the field of high-end equipment, a high-voltage electrode is located at the tail end of an inner-layer sleeve, and insulation between the high-voltage electrode and a low-voltage electrode is achieved through a first cyclone and an insulation interface. Sliding arc discharge is generated by the high-voltage electrode and the low-voltage electrode, a rotary sliding arc is formed under the action of strong rotational flow, and large-area discharge is generated; meanwhile, liquid ammonia is introduced into the high-voltage electrode and the low-voltage electrode, the surface temperature of the electrodes is reduced, the service life of the electrodes is prolonged and higher discharge power is allowed in the liquid ammonia gasification heat absorption process, and gasified ammonia is sprayed out through small-diameter holes and mixed with sliding arc plasmas to form flames. The defects that a high-power sliding arc electrode is high in temperature, short in service life and the like are overcome, and the sliding arc power, the electrode service life and the ignition performance can be greatly improved within the limited size.

The invention discloses an electricity ammonia heat multi-energy conversion system adapting to offshore wind power fluctuation and a control method of the electricity ammonia heat multi-energy conversion system. The electric ammonia heat multi-energy conversion system comprises a green hydrogen preparation system, a green ammonia synthesis system, a green ammonia power generation system and a green ammonia heat supply system, the electric ammonia heat multi-energy conversion system is controlled by adopting the wind power absorption module and the power generation heat supply module. According to the invention, offshore wind power is utilized to prepare green hydrogen and synthesize green ammonia, offshore new energy consumption and medium-and-long-term storage of electric power are realized, low-cost long-distance flexible transportation of energy is realized through a liquid ammonia mode, the problem of storage and transportation of hydrogen energy is solved, and the construction investment of offshore transmission channels is reduced; energy supply diversification can be achieved through green ammonia power generation and green ammonia heat supply; meanwhile, through the unique control method, the method can effectively adapt to the strong volatility of offshore wind power, and economical and efficient preparation and diversified utilization of the green ammonia are achieved.

The invention discloses an efficient ammonia decomposition hydrogen production system based on the Joule heating effect and belongs to the technical field of clean energy. The system is composed of an ammonia supply module, a Joule thermally driven ammonia decomposition reaction module and a hydrogenation module. Wherein the ammonia supply module consists of a liquid ammonia storage device, a vaporizing chamber and an ammonia gas storage device; the Joule thermally-driven ammonia decomposition reaction module consists of an ammonia gas flow control valve, a reaction tube gas inlet, a reaction tube gas outlet, a Joule heating electrode tip, a direct-current power supply, a temperature sensor, a thermal insulation layer, a reaction tube, a catalyst and a stainless steel alligator clip; the hydrogenation module is composed of a hydrogen purifying and drying device, a hydrogen compressor, a hydrogen cooling unit, a high-pressure hydrogen storage tank, a hydrogen flow control valve and a hydrogenation machine. The whole process can be started and stably output within one second, the conversion rate and the electrothermal conversion efficiency both exceed 90%, low energy consumption, quick response and safe operation are achieved, the system is particularly suitable for hydrogen refueling station construction in a future hydrogen energy network, and green hydrogen energy economy development is promoted.

The ammonia decomposition hydrogen production system comprises a first molten salt tank, a second molten salt tank, a molten salt electric heater, a reactor, a heat exchanger and a liquid ammonia tank, the first molten salt tank is filled with a molten salt medium, and the first molten salt tank communicates with the molten salt electric heater; the fused salt electric heater is also communicated with the second fused salt tank; the reactor comprises a heating inlet, a heating outlet, an ammonia gas inlet, an ammonia gas outlet, a heating top plate, a heating bottom plate and a plurality of wall pipes which are sleeved from inside to outside, a shell of the heat exchanger is provided with a hot fluid inlet, a hot fluid outlet, a cold fluid inlet and a cold fluid outlet, and a plurality of heat exchange plates of rectangular structures are arranged in the shell in a stacked mode; the cold fluid inlet is communicated with the liquid ammonia tank, the cold fluid outlet is communicated with the ammonia gas inlet, the hot fluid inlet is communicated with the heating outlet, and the hot fluid outlet is communicated with the first molten salt tank. The ammonia decomposition hydrogen production system adopting fused salt heat supply is high in energy utilization rate, can realize low-temperature, energy-saving and efficient hydrogen production, and can continuously and effectively operate.

The invention relates to the technical field of chemical engineering, in particular to a simple and safe ammonia residual gas recovery system which comprises a liquid ammonia storage tank (1), an accident ammonia absorption tower (2), a circulating pump set, a gas phase pipeline and a liquid phase pipeline, the circulating pump set comprises a circulating water pump, a compression pump and a waste heat recovery pump, the waste heat recovery pump is connected with a steam valve, and the liquid ammonia storage tank (1) is connected with a gasifier (11). The vaporizer (11) is connected with the buffer tank (12), the buffer tank (12) and the accident ammonia absorption tower (2) circulate pure ammonia gas through a gas phase pipeline, the accident ammonia absorption tower (2) and the liquid ammonia storage tank (1) circulate pure liquid ammonia through a liquid phase pipeline, the absorption tank (21) adsorbs exhaust gas detected by the accident ammonia absorption tower (2), and recovered nitrogen is used for purging the liquid ammonia storage tank (1), so that escape-free environment-friendly treatment and recycling of ammonia are realized.

The invention relates to the technical field of ship engine tail gas treatment, and discloses a denitration system and a denitration method for ammonia fuel engine tail gas. The denitration system comprises an ammonia fuel engine and a denitration device, the liquid ammonia fuel supply device is connected with the ammonia fuel engine through a supply pipeline and is used for supplying ammonia fuel to the ammonia fuel engine; a gas inlet of the ammonia gas buffer tank is connected with the supply pipeline, and the ammonia gas buffer tank is used for collecting unburned ammonia gas generated in the supply pipeline; the ammonia water preparation device is connected with a gas outlet of the ammonia gas buffer tank; and the tail gas denitration device is connected with an outlet of the ammonia water preparation device and an exhaust port of the ammonia fuel engine. The ammonia water is prepared from the unburned ammonia gas, and the prepared ammonia water is used for subsequent reduction of nitrogen oxides in tail gas of an ammonia fuel engine, so that the treatment problem of the unburned ammonia gas can be solved, and meanwhile, the consumption of a reducing agent is reduced. In addition, the ammonia water can replace part of the reducing agent, so that the storage amount of the reducing agent can be reduced, and the ship space occupied by the reducing agent is reduced.

The utility model relates to a system for treating tail gas produced during preparation of germane / silane in a liquid ammonia system. The system comprises an inert gas cylinder, an anti-suck-back tank and a tail gas absorption tank which are communicated through pipelines, a gas inlet of the tail gas absorption tank is communicated to a germane / silane tail gas outlet of a germane / silane synthesis device in the liquid ammonia system through an anti-suck-back tank; a top gas inlet of the anti-suck-back tank is connected to a germane / silane tail gas outlet of a germane / silane synthesis device in the liquid ammonia system, and a bottom gas outlet of the anti-suck-back tank is inserted into the bottom in the tail gas absorption tank from the top gas inlet of the tail gas absorption tank through a first pipeline; and the inert gas cylinder is connected to the gas inlet pipeline at the top of the suck-back prevention tank. The system is simple in structure, convenient to operate and high in germane / silane tail gas treatment efficiency, and can effectively prevent the suck-back of the absorption liquid and ensure that the germane / silane tail gas is discharged after reaching the standard after being treated.

The invention relates to the technical field of liquid ammonia liquid level meters, in particular to a liquid ammonia liquid level meter capable of automatically cleaning impurities and a method thereof.The liquid ammonia liquid level meter comprises a sampling pipe and a floating ball liquid level sensor installed in the sampling pipe, the floating ball liquid level sensor is used for detecting the position of a floating ball and the height of the liquid level, and the floating ball liquid level sensor transmits detection data to a processor; a heat tracing pipe is arranged on the outer wall of the sampling pipe, a flow meter for introducing inert gas is arranged at the upper end of the sampling pipe, and a blow-down valve is arranged at the lower end of the sampling pipe. Whether the floating ball is stuck or not is judged by automatically detecting the position of the floating ball, then cleaning is achieved by heating and nitrogen introduction for purging under the condition that the floating ball is stuck, and due to the integrated automation technology, the accuracy of liquid level measurement of liquid ammonia and the stability of the system are remarkably improved. According to the device, impurities attached to the liquid level meter can be removed in time, the floating ball is prevented from being jammed, and accuracy and reliability of liquid level measurement data are ensured.

The invention discloses a high-whiteness and high-non-ironing short-flow processing technology for polyester-cotton fabric, and belongs to the technical field of textile printing and dyeing. According to the technical scheme, the processing flow comprises singeing, desizing and scouring, chlorine bleaching, oxygen bleaching, mercerizing, liquid ammonia treatment, polyester whitening and non-ironing one-bath treatment, cotton whitening and softening. Wherein in the polyester whitening non-ironing one-bath process, a polyester whitening agent 1 is 3-5 g / L, a polyester whitening agent 2 is 2-4 g / L, a penetrating agent is 3-5 g / L, and resin is 80-120 g / L, and in the cotton whitening process, a cotton whitening agent is 10-20 g / L, and a penetrating agent is 3-5 g / L; in the softening process, the formaldehyde catching agent is 10-30 g / L, the penetrating agent is 2-5 g / L, and the softening agent is 10-30 g / L. According to the method, the technological process is simplified, the production cost is saved, the production efficiency is improved, the requirements of the current market can be well met under the condition that the quality is guaranteed, and the requirements of printing and dyeing processing of the future polyester-cotton fabric are met.

A method for continuously producing m-xylylenediamine belongs to the technical field of organic synthesis and comprises the following steps: (1) mixing isophthalonitrile, toluene and liquid ammonia according to a mass ratio of 1: (3-5): (13-17) in a nitrogen atmosphere to form a reaction mixture; (2) heating the interior of a reaction bed containing a catalyst to 90-95 DEG C, continuously introducing hydrogen into the reaction bed, introducing the reaction mixture after the pressure intensity of the reaction bed is stable, and carrying out a catalytic hydrogenation reaction to generate a reaction product; and (3) carrying out gas-liquid separation on the reaction product, removing liquid ammonia from the liquid-phase product through an ammonia distillation process, and separating toluene and m-xylylenediamine through a rectification process to obtain m-xylylenediamine. According to the method, isophthalonitrile and hydrogen are used as raw materials, liquid ammonia and methylbenzene are used as reaction solvents, the raw materials and the reaction solvents are heated to 90-95 DEG C under the catalytic action of a catalyst for an exothermic reaction, m-xylylenediamine is generated through the reaction, and the reaction yield is larger than 99%.

The invention relates to a tail gas denitration system and method for an ammonia fuel ship, an ammonia supply pipeline of an ammonia fuel engine in the system adopts a double-wall pipe, the inner pipe of the double-wall pipe is used for conveying liquid ammonia, and the outer pipe of the double-wall pipe is connected with an ammonia treatment system through a fan so as to suck leaked ammonia gas to the ammonia treatment system; the ammonia treatment system is connected with the buffer tank through a fan and is used for conveying the discharged gas to the buffer tank after pressurizing the discharged gas through the fan; the ammonia treatment system is connected with a reducing agent tank through a pump; the reducing agent tank receives ammonia water of the ammonia treatment system through the pump; the SCR reducing agent supply system is connected with the reducing agent spray gun through the reducing agent tank and the buffer tank and used for conveying the discharged gas to the reducing agent spray gun through the SCR reducing agent supply system to assist in atomizing ammonia water. According to the ammonia fuel ship tail gas denitration system and method, ammonia water generated in the ammonia treatment system is used as a reducing agent of the SCR system, and discharged gas of the ammonia treatment system is used as auxiliary atomization gas of the reducing agent, so that waste is recycled, and the denitration efficiency is improved.

The invention belongs to the field of scramjet engines, and particularly relates to an ammonia-hydrogen power wide-speed-range scramjet engine and a combustion method thereof. The ammonia-hydrogen power wide-speed-range scramjet engine comprises a combustion chamber, a liquid ammonia storage device and a hydrogen storage device; a concave cavity is formed in the combustion chamber, a fuel injection section upstream injection hole is formed in a fuel injection section of the concave cavity, the concave cavity is located at the downstream of the fuel injection section, a fuel injection section upstream micro-jet injection hole is formed in the upstream of the fuel injection section upstream injection hole, and a concave cavity inner micro-jet injection hole is formed in the concave cavity; the liquid ammonia storage device is connected with an upstream injection hole of the fuel injection section through a cooling structure; and the hydrogen storage device is connected with the upstream micro-jet injection hole of the fuel injection section and the micro-jet injection hole in the concave cavity. According to the invention, liquid ammonia and hydrogen are introduced as fuels to realize wide-range combustion organization, so that wide-range efficient combustion is realized, the fuel heat absorption requirement of high-Mach-number active cooling thermal protection is met, and zero carbon emission can be realized in the whole process.

The invention provides an ammonia flash steam reliquefaction system for realizing cold energy supply, the reliquefaction system comprises an ammonia fuel cabin, an ammonia gas storage tank, a compressor, a condenser pipe, a cooling tank and other devices which are connected in sequence, ammonia gas flowing out of the ammonia fuel cabin is converted into high-pressure liquid ammonia after being compressed and condensed, and the high-pressure liquid ammonia is divided into three branches after flowing out through a cold heat exchanger, the first branch flows into the cooling tank after being depressurized and cooled by the high-pressure throttle valve, so that the interior of the cooling tank is cooled; the second branch is depressurized and cooled by a refrigeration storage throttle valve and then enters a liquid ammonia evaporator in the refrigeration storage, so that the refrigeration storage is cooled; and the third branch flows back to the ammonia fuel cabin after being depressurized and cooled by a back-to-cabin throttle valve. And meanwhile, the liquid ammonia in the cooling tank is also used for cooling the refrigerant water, so that the refrigeration of a user room is realized. According to the reliquefaction system, cold energy contained in high-pressure liquid ammonia in the reliquefaction process is fully utilized, different refrigeration schemes are made according to the refrigeration house and the user room, and the whole pipeline design is more reasonable.

The invention belongs to the technical field of clean energy, and particularly relates to an ammonia-hydrogen fusion engine system and a control method thereof.The ammonia-hydrogen fusion engine system comprises an engine, a liquid ammonia vaporization device and an ammonia reaction hydrogen production device, the engine is provided with an intake manifold and an exhaust manifold, and the exhaust manifold penetrates through the ammonia reaction hydrogen production device; the liquid ammonia vaporization device is communicated with the ammonia reaction hydrogen production device through a first pipeline and is communicated with the intake manifold through a second pipeline, and the second pipeline is communicated with the first pipeline so as to convey ammonia gas to the ammonia reaction hydrogen production device and the intake manifold respectively; and a gasoline injector is further arranged on the intake manifold, and when the water temperature of the engine is smaller than a first temperature threshold value or the temperature of a catalyst in the ammonia reaction hydrogen production device is smaller than a second temperature threshold value, the gasoline injector is used for injecting gasoline into the intake manifold so as to start the engine. The cold start problem of the engine can be solved, and the ignition reliability is improved.

The invention discloses a condenser and flue gas waste heat utilization system for an ammonia power plant, which belongs to the technical field of power generation and comprises a condenser, a condensate pump, a circulating water regulating valve, a liquid ammonia regulating valve, an ammonia regulating valve, a primary flue gas heat exchanger, a secondary flue gas heat exchanger, a water collector, a steam extraction heater, a pure ammonia burner, a boiler, an air pre-heater, a chimney and a steam turbine. A condenser and a liquid ammonia evaporator are integrally designed, the condenser comprises a liquid ammonia cooling area and a circulating water cooling area, liquid ammonia gasification cold energy of an ammonia power plant is used for cooling steam exhausted by a low-pressure cylinder of a steam turbine, the heat exchange efficiency is improved, and the load of a cooling tower is reduced; the tail of the pure ammonia boiler is free of dust removal and desulfurization facilities, waste heat of high-temperature and high-humidity flue gas at the outlet of the air pre-heater is used for replacing steam extraction of a steam turbine to heat condensed water and low-temperature ammonia gas, the generating power of a unit can be increased, secondary condensation of the ammonia gas can be prevented, the combustion stability of the ammonia gas can be improved, and meanwhile a large amount of water in the flue gas can be recycled.

The utility model provides dry denitration equipment for a rotary cement kiln. The dry denitration equipment for the rotary cement kiln comprises a device body, a circulating box is fixedly connected to the device body, a circulating base is fixedly connected to the interior of the circulating box, a circulating pump is fixedly connected to the circulating base, a circulating pipe is fixedly connected to the circulating pump, a circulating output pipe is fixedly connected to the circulating pump, and the circulating output pipe is fixedly connected to the device body. A circulating pump is fixedly connected to the device main body, a circulating electromagnetic valve is arranged on the circulating pump, a water tank is fixedly connected to the device main body, a cooling distillation box is fixedly connected to the device main body, an ammonia gas input pipe is fixedly connected to the cooling distillation box, a condenser is fixedly connected to the ammonia gas input pipe, a liquid ammonia input pipe is fixedly connected to the condenser, and a liquid ammonia outlet pipe is fixedly connected to the liquid ammonia input pipe. A liquid ammonia box is arranged on the device main body, and an exhaust pipe is fixedly connected to the device main body. The dry denitration equipment for the rotary cement kiln has the effect of reducing environmental pollution.

The ammonia fuel supply system comprises a liquid ammonia supply assembly, an ammonia injection assembly and a pumping assembly, the pumping assembly comprises a liquid ammonia pump, the liquid ammonia pump is provided with a liquid ammonia pressurization cavity and a cooling expansion cavity which have a dividing wall heat exchange relation, and the liquid ammonia pressurization cavity is provided with a liquid ammonia inlet and a liquid ammonia outlet; the liquid ammonia inlet is connected with the liquid ammonia supply assembly, the liquid ammonia outlet is connected with the ammonia injection assembly, the cooling expansion cavity is provided with an expansion inlet and an expansion outlet, and an expansion valve is connected between the expansion inlet and the liquid ammonia supply assembly. Part of liquid ammonia is adopted as a refrigerant, normal-temperature ammonia can be filled, the liquid ammonia tank does not need heat insulation, liquid ammonia in the tank flows out automatically, a single-stage pump scheme can be adopted, the liquid supply amount can be accurately adjusted, oil return is not needed, and the system is simple, low in cost and high in efficiency.

The invention relates to a vehicle-mounted high-pressure liquid ammonia supply and liquid return control system and an engine, the vehicle-mounted high-pressure liquid ammonia supply and liquid return control system comprises a liquid ammonia tank, a liquid ammonia pump is mounted at a liquid outlet of the liquid ammonia tank, the output end of the liquid ammonia pump is communicated with a high-pressure plunger pump through a liquid inlet pipeline, the first output end of the high-pressure plunger pump is communicated with a high-pressure liquid ammonia rail, and the second output end of the high-pressure plunger pump is communicated with a low-pressure liquid ammonia rail; the output end II of the high-pressure plunger pump is communicated with a liquid return pipeline; the liquid return pipeline is communicated with a liquid return opening of the liquid ammonia tank; the first-stage liquid inlet heat exchanger is mounted on the liquid inlet pipeline; the liquid return heat exchanger is mounted on the liquid return pipeline; and the vehicle-mounted water cooling machine is thermally coupled with the primary liquid inlet heat exchanger and the liquid return heat exchanger. In-cylinder direct injection is adopted, the combustion process is optimized, and the combustion efficiency is improved. Heat exchange temperature control is carried out during liquid feeding, it is guaranteed that ammonia supply is in a liquid state, the temperature of liquid ammonia is prevented from rising to form a gas-liquid mixed phase during liquid returning, and a stable and reliable liquid ammonia supply and liquid returning system is provided for an engine.

The invention provides an ammonia fuel cracking supply system of a gas turbine. The system comprises a liquid ammonia storage tank, a liquid ammonia supply pump, an air vaporizer, a heat exchanger, a first ammonia cracker, a compression and expansion all-in-one machine, the gas turbine and the like. Wherein liquid ammonia is supplied to the air vaporizer through the liquid ammonia supply pump; one end of the heat exchanger is communicated with the air vaporizer, and the other end is communicated with the first ammonia cracker; one end of a compression-expansion all-in-one machine introduced by the system is communicated with the heat exchanger, and the other end is communicated with the gas turbine. The air vaporizer adopts an exhaust heat source to gasify liquid ammonia into ammonia gas. Ammonia gas discharged from the air vaporizer enters the heat exchanger, exchanges heat with cracked gas after cracking to be heated, and then is guided into the first ammonia cracker. Ammonia gas is decomposed into mixed gas of hydrogen and nitrogen in the first ammonia cracker, the mixed gas can enter the heat exchanger, and the mixed gas enters the compression and expansion all-in-one machine after being subjected to heat exchange and cooling in the heat exchanger, and is conveyed to the gas turbine after being pressurized and cooled.

The invention provides a liquid ammonia in-cylinder direct injection engine combustion system and method with an active pre-combustion chamber, and relates to the technical field of internal combustion engines, the liquid ammonia in-cylinder direct injection engine combustion system comprises a cylinder cover and a cylinder sleeve arranged below the cylinder cover, the pre-combustion chamber is vertically arranged in the center of the cylinder cover, a liquid ammonia injector is arranged on one side of the pre-combustion chamber, and the active pre-combustion chamber is arranged in the cylinder sleeve. A hydrogen ejector and a spark plug are arranged on the pre-combustion chamber; and spraying holes are formed in the pre-combustion chamber and located in the bottom of the pre-combustion chamber, and the spraying holes of the pre-combustion chamber face one side of the liquid ammonia ejector. According to the liquid ammonia in-cylinder direct injection engine combustion system and method with the active pre-combustion chamber, the effect that diffusion combustion is promoted through premixed combustion of ammonia fuel is achieved, accurate control over the combustion initial point and the heat release rate is achieved, and the requirements for the low hydrogen energy ratio, high ignition efficiency and high heat efficiency of an ammonia fuel engine in the full working condition range are met.

The invention discloses an automotive liquid ammonia supply system which comprises a liquid ammonia storage tank, a liquid outlet and a gas outlet are formed in the liquid ammonia storage tank, the liquid outlet is connected with one end of a filling pipeline and one end of a liquid outlet pipeline, a stop valve and an electromagnetic valve are connected to the liquid outlet pipeline in series, the other end of the liquid outlet pipeline is connected with a first medium inlet of a water bath type vaporizer, and a second medium inlet of the water bath type vaporizer is connected with a second medium inlet of the water bath type vaporizer. A first medium outlet of the water bath type vaporizer is connected with an inlet of the buffer tank, an outlet of the buffer tank is used for providing ammonia gas, one end of the gas return pipeline is connected with the gas outlet, a pressure gauge, a stop valve and a safety valve are connected to the gas return pipeline in series, and a second medium inlet and a second medium outlet of the water bath type vaporizer are used for being connected with an engine cooling liquid outlet and an engine cooling liquid inlet respectively. And a saturation pressurization pipeline is further arranged, an electromagnetic valve and a heat exchange pipe located in the liquid ammonia storage tank are connected to the saturation pressurization pipeline in series, and two ports of the saturation pressurization pipeline are used for being connected with an engine cooling liquid inlet and an engine cooling liquid outlet respectively. The liquid ammonia gas supply system for the vehicle can stably supply gas to the vehicle.