2531 results about "Sodium sulfate" patented technology

The invention discloses high-purity hafnium oxide and a preparation method thereof, and relates to the technical field of hydrometallurgy. The preparation method of the high-purity hafnium oxide comprises the following steps: crushing a hafnium oxide raw material to obtain hafnium oxide powder; sequentially carrying out alkali fusion, water immersion and filtration treatment on the hafnium oxide powder to obtain a hafnium hydroxide filter cake; dissolving the hafnium hydroxide filter cake in a sulfuric acid solution to obtain a hafnium sulfate solution; adding sodium sulfate into the hafnium sulfate solution to obtain hafnium-containing double salt; dissolving the hafnium-containing double salt in a sulfuric acid solution, heating, evaporating, cooling and crystallizing to obtain hafnium sulfate crystals; dissolving the hafnium sulfate crystal in concentrated hydrochloric acid to obtain a hafnium oxychloride solution, heating, evaporating, cooling and crystallizing to obtain a hafnium oxychloride crystal; dissolving the hafnium oxychloride crystal in pure water, adding an oxalic acid solution, and precipitating to obtain hafnium oxalate; and calcining hafnium oxalate to obtain high-purity hafnium oxide. The preparation method of the high-purity hafnium oxide is green, environment-friendly, simple and efficient.

The invention discloses a yellow phosphorus tailing-based mine filling material and application thereof. The yellow phosphorus tailing-based mine filling material comprises aggregate and a cementing material, the cementing material comprises the following components in parts by mass: 5-20 parts of red mud, 20-40 parts of yellow phosphorus slag, 10-30 parts of slag, 5-10 parts of fly ash, 5-10 parts of a compound exciting agent, 1-3 parts of an early strength agent and 2-5 parts of a water-retaining agent; wherein the compound exciting agent comprises the following components in parts by mass: 10-20 parts of sodium metasilicate, 30-40 parts of gypsum powder, 20-30 parts of sodium sulfate, 5-10 parts of carbide slag and 5-10 parts of silica fume; according to the invention, the raw materials are compounded and the specific exciting agent is subjected to depolymerization-polycondensation reaction to obtain a cementing material containing Aft (ettringite), C-S-H gel (hydrated calcium silicate gel) and C-A-S-H gel (hydrated calcium aluminosilicate gel), and finally, the mine filling material with high fluidity, low bleeding rate and high strength is obtained while yellow phosphorus tailing solid waste is treated.

The invention discloses an organic plugging agent, a preparation method thereof and application of the organic plugging agent to inhibition of SAGD steam cavity edge water invasion. The organic plugging agent is prepared from the following raw materials: epoxy resin, a curing agent, nano aerogel, mineral fibers, plant fibers, a reactive diluent, a heat stabilizer and water, the epoxy resin is at least one of glycidyl amine epoxy resin and alicyclic epoxy resin; the curing agent is at least one of amino resin, dicyandiamide and hydrazide; the heat stabilizer is at least one of thiourea, sodium thiosulfate and cobalt chloride. The organic plugging agent is excellent in high temperature resistance, mineralization resistance and plugging performance, the organic plugging agent, nitrogen and an inorganic plugging agent are injected into a water plugging system of an SAGD steam cavity edge well in a slug mode, the organic plugging agent is applied to SAGD high-temperature and high-leakage well conditions, and the SAGD production effect can be effectively improved.

According to the invention, biomass rice hull ash and a sodium hydroxide solution are reacted to obtain water glass and carbon mud. And reacting the water glass with CO2 generated by calcining the limestone to produce a white carbon black product and a mixed waste liquid of sodium carbonate and sodium bicarbonate. Meanwhile, quick lime obtained by calcining limestone is digested and then reacts with sodium carbonate and sodium bicarbonate mixed waste liquid to generate a light calcium carbonate product and dilute sodium hydroxide waste liquid. And finally, the dilute sodium hydroxide waste liquid is concentrated and reused for water glass production, so that the waste liquid is recycled, and a complete process closed loop is formed. According to the process method disclosed by the invention, two leading-edge innovative processes, namely production of white carbon black by renewable resource biomass rice hull ash and production of white carbon black by a carbonization method, are organically combined and are coupled with production of light calcium carbonate by a limestone calcination process, so that the problem that a large amount of sodium sulfate-containing wastewater is discharged in a traditional process is solved; meanwhile, the carbon footprint of white carbon black and calcium carbonate products is greatly reduced.

The invention discloses a film coating agent for accelerating stabilization of a weathering resistant steel rust layer in a severe atmospheric environment. The film coating agent comprises a film-forming agent and a spraying agent, the film-forming agent comprises a gel agent and a transforming agent; the gel is prepared from one or more of tannic acid, carbomer, chitosan and gelatin; the transforming agent comprises one or more of magnesium sulfate, zinc sulfate and sodium molybdate; the spraying agent comprises an accelerant and an aggressive agent; the accelerant comprises one or more of sodium sulfate, potassium sulfate and chromium sulfate; the aggressive agent comprises one or more of sodium chloride, aluminum chloride and sodium fluoride. The film coating agent provided by the invention can form a stable and uniform rust layer on the surface of the weathering resistant steel, so that the corrosion resistance of the weathering resistant steel is improved.

The invention belongs to the technical field of sewage treatment, and particularly relates to a demulsifier for eliminating an oil-water interface emulsion layer in oilfield produced liquid treatment and a preparation method of the demulsifier. The preparation method comprises the following steps: adding acrylamide, 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, allyl tributyl phosphonium chloride and deionized water into a first reactor, and heating and dissolving the acrylamide, the 1-allyl-3-methylimidazolium bis (trifluoromethanesulfonyl) imine salt, the allyl tributyl phosphonium chloride and the deionized water; adding allyl (diisopropylamino) dimethylsilane, butyl acrylate, deionized water, octylphenol polyoxyethylene ether-10, lauryl sodium sulfate and monopotassium phosphate into the second reactor, and stirring to obtain an emulsion; adding an initiator and sodium hydrogen sulfite into a second reactor, carrying out heating and heat preservation reaction, pouring the mixed solution in the first reactor, and continuously carrying out reaction, heating and heat preservation to obtain a viscous liquid; and drying and granulating the viscous liquid to obtain the demulsifier. The demulsifier provided by the invention has the characteristics of simple synthesis process and high demulsification rate.

A method including pretreating ground lithium-containing ceramics to form alkali coated ceramics, leaching the alkali coated ceramics to form a leachate comprising a filtrate and a solid residue, preferentially extracting lithium from the filtrate to form a lithium rich solution and a raffinate, precipitating a crude lithium carbonate from the lithium rich solution and purifying the crude lithium carbonate to produce a battery grade lithium carbonate. A method including leaching a slurry comprising lithium-containing ceramics, water, a strong base, and an alkaline earth metal oxide / hydroxide at a pressure ranging from 0 to 1450 psi and at a temperature ranging from 100 to 500°C to form a leached slurry comprising a liquid filtrate and a solid residue, processing the liquid filtrate to recover a lithium-rich organic solution, and processing the lithium-rich organic solution to produce a battery-grade lithium compound and sodium sulfate.

The invention provides a method and system for salt separation, evaporation and crystallization of printing and dyeing wastewater, and the method comprises the following steps: sequentially carrying out multi-stage synergistic pretreatment on textile printing and dyeing wastewater to remove suspended solids, degrade organic matters and reduce hardness; the pretreated wastewater is subjected to membrane salt separation treatment, and preliminary separation of salt is achieved through reverse osmosis pre-concentration and nanofiltration salt separation; and respectively carrying out evaporative crystallization treatment on the separated high-concentration salt solution to obtain high-purity sodium sulfate and sodium chloride products. According to the method, the salt recovery rate and the product purity are remarkably improved, the energy consumption and the operation cost are reduced, meanwhile, the problems that in traditional printing and dyeing wastewater treatment, salt is difficult to separate, and the crystallization purity is low are solved, and an innovative solution is provided for high-valued resource recovery of industrial wastewater.

The invention discloses high-toughness ultrathin flexible glass and a preparation method thereof, and relates to the technical field of glass manufacturing. The ultrathin flexible glass is prepared from the following raw materials: silicon dioxide, aluminum oxide, lithium oxide, sodium oxide, magnesium oxide, a modified nano reinforced phase, a high-temperature melting regulator and cerium dioxide. The modified nano reinforced phase is prepared by the following steps: pre-treating silicon carbide and silicon nitride with hydrochloric acid, and mixing with nano zirconium oxide to obtain a mixture; and modifying the mixture with a silane coupling agent to obtain the modified nano reinforced phase. The high-temperature melting regulator is a mixture of lithium borate, sodium sulfate and lithium fluoride. The preparation method of the ultra-thin flexible glass comprises the following steps: preparing the modified nano reinforced phase, melting and homogenizing the glass, forming the glass substrate, and preparing the ultra-thin flexible glass. The ultra-thin flexible glass prepared by the invention has relatively high fracture toughness and structural rigidity, excellent flexibility and bending fatigue durability, and excellent thermal shock resistance.

The invention provides an impurity removal and recovery method of electrodeposited nickel anolyte, which comprises the following steps: (1) mixing the electrodeposited nickel anolyte with liquid caustic soda, carrying out solid-liquid separation to obtain nickel hydroxide and filtrate, and evaporating the filtrate to obtain sodium sulfate; mixing the electrodeposited nickel anolyte with a nickel source to obtain a mixed solution; (2) mixing the mixed solution with barium salt, and carrying out lead removal treatment; (3) adjusting the pH value of a material obtained after lead removal treatment by using nickel hydroxide to obtain a solution to be subjected to arsenic removal, and mixing the solution to be subjected to arsenic removal with polyferric sulfate for arsenic removal treatment; and (4) a material obtained after arsenic removal treatment is mixed with an oxidizing agent, a solution to be subjected to iron removal is obtained, solid-liquid separation treatment is conducted on the solution to be subjected to iron removal, catholyte with lead, arsenic and iron removed and iron-containing slag are obtained, sodium sulfate is supplemented into the catholyte with lead, arsenic and iron removed, and the catholyte is reused in the nickel electrodeposition process. According to the method, lead, arsenic and iron in the electrodeposited nickel anolyte can be efficiently and rapidly removed and recycled.

The invention belongs to the technical field of solid waste resource utilization, and discloses an activity-enhanced solid waste-based sludge curing agent as well as a preparation method and application thereof. The sludge curing agent comprises the following raw materials in percentage by mass: 30-40% of cement, 15-25% of S95 mineral powder, 15-23% of steel slag powder, 16-26% of an activity enhancing component and 0.5-3% of a composite exciting agent, wherein the activity enhancing component is prepared from the following raw materials in percentage by mass: 35 to 40 percent of desulfurized gypsum, 35 to 40 percent of carbide slag and 20 to 30 percent of biomass ash; the composite exciting agent comprises the following raw materials in percentage by mass: 30-35% of metakaolin, 30-35% of sodium sulfate, 15-20% of sodium silicate and 15-20% of sulfonated oil. According to the sludge curing agent, the industrial solid waste accounts for 57% or above, the desulfurized gypsum, the carbide slag and the biomass ash form an activity enhancing component, the activity enhancing component is matched with the composite exciting agent to jointly enhance and excite the activity of the metallurgical slag solid waste, and therefore the excellent curing effect is achieved, and when the sludge curing agent is used for sludge curing, the 3d unconfined compressive strength of a sludge curing body is larger than or equal to 0.5 MPa; and the 28d unconfined compressive strength is greater than or equal to 1.4 MPa.

The invention discloses a method for comprehensively recovering valuable elements from a waste lithium iron phosphate battery material. The method comprises the following steps: carrying out alkali leaching on black powder and / or pole piece materials of the waste lithium iron phosphate batteries, and then carrying out solid-liquid separation to obtain alkali leaching residues and an alkali leaching solution; carrying out acid leaching on the alkaline leaching residues, and then carrying out solid-liquid separation to obtain an iron oxide powder product and an acid leaching solution; the alkali leaching liquid is cooled and crystallized to obtain a sodium phosphate product and crystallization mother liquor, and the crystallization mother liquor can be circularly used for the alkali leaching process; adjusting the pH value of the acid leaching solution, precipitating and separating to obtain a lithium phosphate product and a lithium precipitation mother solution, wherein the lithium precipitation mother solution can be used for preparing a sodium sulfate product. The method can effectively separate iron, phosphorus and lithium products, and is high in recovery rate, simple, short in process, low in cost and suitable for industrial application.

The invention relates to the technical field of expansive soil treatment, and particularly discloses an expansive soil rapid hardening material as well as a preparation method and application thereof. The invention discloses an expansive type rapid hardening material for soil. The expansive type rapid hardening material is prepared from the following components: high belite sulphoaluminate cement clinker, ordinary Portland cement, gypsum, solid waste high-activity superfine powder, a nano crystal nucleus induction activating agent, a nano modified complexing agent and a modified early strength agent, the nano crystal nucleus induction activating agent is prepared from nano Al2O3, sodium dodecyl benzene sulfonate, NaOH and Na2SiO3; the nano modified complexing agent is prepared from nano SiO2, lauryl sodium sulfate and silane; the modified early strength agent is prepared from modified graphene oxide, Na2SiO3 and water. According to the technical scheme, the solid waste can be recycled, the expansive soil treated by the hardening material can achieve the effects of high hour strength and good water stability, and the curing speed and the production efficiency are greatly improved.

The invention relates to blue high borosilicate glass and a preparation method thereof, and belongs to the technical field of glass manufacturing, and the blue high borosilicate glass comprises the following raw materials in parts by weight: 50-60 parts of silicon dioxide, 10-15 parts of boron oxide, 2-3 parts of aluminum oxide, 6-8 parts of alkali metal oxide, 3-4 parts of a compound clarifying agent and 1-3 parts of a modified coloring agent. According to the technical scheme, the cobalt blue pigment is coated with mesoporous silica, and the composite material is obtained; combining the composite material with a silane coupling agent to obtain a silanized composite material; combining the silanized composite material with boric acid ester to obtain a modified coloring agent; the prepared modified coloring agent enables the high borosilicate glass to have remarkable blue color and to be stable in color and not prone to volatilization under high-temperature and high-pressure conditions, the added composite clarifying agent is formed by mixing cerium dioxide, sodium sulfate and tin oxide, the clarity of the glass is improved, volatilization of boron is effectively reduced, and the service life of the glass is prolonged. The mechanical property and the stability of the high borosilicate glass are generally improved, and the quality of the glass is improved.

The invention discloses a printing and dyeing wastewater advanced treatment and salt control recycling process and system, and belongs to the technical field of wastewater treatment. According to the process, the printing and dyeing wastewater is sequentially subjected to pretreatment of grating interception, adjustment and homogenization, and coagulating sedimentation; carrying out hydrolytic acidification and biochemical treatment in a membrane bioreactor; softening treatment of ozone oxidation complex breaking and fluidization crystallization softening; carrying out nanofiltration separation to obtain a permeate and a concentrated solution; carrying out seed crystal fluidization descaling on the concentrated solution; respectively carrying out membrane concentration on the nanofiltration permeate and the descaled concentrated solution through reverse osmosis to obtain sodium chloride and sodium sulfate concentrated solutions; and finally, carrying out evaporation curing treatment on the sludge and the crystallized waste residues. Through multi-step cooperative treatment, deep purification of the printing and dyeing wastewater and efficient separation and recycling of salt are realized, and the problems of impure nanofiltration salt separation and high system scaling risk in the prior art are solved.

The invention provides a purification and impurity removal method of a crude nickel-cobalt-manganese sulfate solution. The purification and impurity removal method comprises the following steps: (1) adding sodium thiosulfate into the crude nickel-cobalt-manganese sulfate solution to remove copper; (2) phosphate is adopted, the pH value is regulated, and titanium, iron, aluminum and the like are removed; (3) ferric sulfate is added, the pH value is regulated, and phosphorus and silicon are removed; (4) adding a bismuth agent and regulating the pH value to remove chlorine; (5) adding a fluorine agent to remove calcium and magnesium; and (6) adding a tillite mineral adsorbent to remove fluorine. According to the method, iron, aluminum, copper, fluorine, phosphorus, titanium, calcium, magnesium, chlorine, silicon and other elements can be efficiently removed from the rough nickel-cobalt-manganese sulfate solution, the loss of main metal is low, the prepared high-purity nickel-cobalt-manganese sulfate solution can directly meet the requirement of a precursor solution of a battery preparation level, the process is simple, the operation difficulty is low, industrial large-scale production is easy to achieve, and the method is suitable for industrial production. And the defects of the current preparation method of the high-purity nickel-cobalt-manganese sulfate solution are overcome.

The invention provides a sulfonator for preparing fatty alcohol polyoxyethylene ether sodium sulfate and a production process of the sulfonator, relates to a novel falling film sulfonator, and belongs to the technical field of manufacturing of reaction devices for producing anionic surfactants by sulfating gas SO3. The invention provides a novel falling film sulfonator capable of being used for producing fatty alcohol polyoxyethylene ether sodium sulfate with ultralow dioxane content, the sulfonator improves the structure of a reaction tube, and a separation layer is formed between SO3 diluted gas and an organic material liquid film by introducing a balance wind concept, so that the content of the dioxane in the organic material liquid film is reduced, and the content of the dioxane in the organic material liquid film is reduced. According to the falling-film sulfonation tube, the sharp temperature interval at the upper part of the falling-film reactor tends to be mild, and the sulfonation / sulfation reaction rate in the length of the whole falling-film sulfonation tube tends to be balanced, so that the output of dioxane is reduced, the product quality is improved, the subsequent post-treatment of AES products is avoided, and the production energy consumption is reduced; the device is easy to operate and has certain practicability.

The invention provides a method for preparing sodium carbonate and co-producing ammonium sulfate from sodium sulfate waste salt, and relates to the technical field of chemical engineering. The method comprises the following steps: mixing sodium sulfate waste salt with water for dissolution, mixing the obtained sodium sulfate waste salt solution with an impurity removal agent for impurity removal, and mixing the obtained impurity removal solution with ammonium bicarbonate for double decomposition reaction to obtain a reaction feed liquid; carrying out primary cold separation on the reaction feed liquid to obtain first filtrate and primary sodium bicarbonate; sequentially washing, drying and roasting the primary sodium bicarbonate to obtain a sodium carbonate product; carrying out secondary cold separation on the first filtrate, carrying out solid-liquid separation to obtain a second filtrate and mixed salt, and reusing the mixed salt in the metathesis reaction; and mixing the second filtrate with an acid adjusting agent to adjust the acid, and carrying out evaporative crystallization on the obtained solution to obtain an ammonium sulfate product and an evaporation mother solution. Industrial-grade sodium carbonate and ammonium sulfate are co-produced by using sodium sulfate waste salt, sodium carbonate and ammonium sulfate meet national standard requirements, and the recovery rate of sodium sulfate is greater than or equal to 90%.

The invention belongs to the technical field of lithium-containing waste treatment, and particularly discloses a method for preparing lithium carbonate by recycling lithium through cooperative treatment of lithium-containing waste. The method specifically comprises the following steps: mixing a lithium amide waste material, a lithium sulfide waste material and water, then mixing with a hydrogen peroxide solution and a sulfuric acid solution, and carrying out an acid dissolution reaction to obtain a lithium-containing acid solution and an insoluble substance; mixing the lithium-containing acid solution with alkali liquor, and carrying out alkalization reaction to obtain insoluble impurities and alkalized feed liquid; concentrating the alkalized feed liquid to obtain concentrated alkalized feed liquid, and mixing the concentrated alkalized feed liquid with a sodium carbonate solution for lithium precipitation reaction to obtain lithium precipitation mother liquor and lithium carbonate; extracting the lithium element in the lithium precipitation mother liquor, and evaporating and concentrating the raffinate to separate out sodium sulfate and ammonium sulfate; ammonium sulfate and the lithium iron phosphate waste are mixed and then sequentially subjected to roasting and leaching, and a leaching solution and a lithium-containing acid solution are mixed for alkalization. The method has the characteristics of high process integration level, high economic value and less environmental pollution, and conforms to the new concept of chemical green atom economy.

The invention provides a method for removing arsenic in water through sacrificial iron anode electrocoagulation, and belongs to the technical field of feed water treatment. According to the method for removing arsenic in water through sacrificial iron anode electrocoagulation, arsenic-containing underground water is electrolyzed through electrocoagulation treatment, an iron sheet serves as an anode in the electrocoagulation treatment, a sodium sulfate solution serves as electrolyte, and arsenic in water is removed after electrolysis is finished. The current of the electrocoagulation treatment is 5-10 mA, the treatment time is 8-15 min, and the concentration of the sodium sulfate solution is 5-20 mM. According to the invention, an electric coagulation technology is adopted, ferrous iron is generated by electrolysis of an iron anode to promote oxidation of arsenite and adsorption of arsenic on iron precipitates, so that the purpose of separating arsenic from water is achieved, and the method has the advantages of high treatment efficiency, environmental friendliness, flexibility, controllability and the like.

The invention relates to the technical field of cables, and provides a flexible corrosion-resistant robot cable, which sequentially comprises a cable core, a shielding layer, an inner sheath layer and an outer sheath layer from inside to outside, and is characterized in that the cable core sequentially comprises a conductor and an insulating layer from inside to outside; the outer sheath layer comprises the following raw material components in parts by weight: 60-70 parts of high-density polyethylene, 15-25 parts of an ethylene-tetrafluoroethylene copolymer, 0.5-1.5 parts of an antioxidant, 1-3 parts of a plasticizer, 8-12 parts of a flame retardant, 10-20 parts of polyethylene glycol diacrylate composite barium sulfate and 1-2 parts of a lubricant; the polyethylene glycol diacrylate composite barium sulfate is prepared from the following raw materials: polyethylene glycol diacrylate, barium chloride and sodium sulfate. According to the technical scheme, the problem of poor corrosion resistance of the robot cable in the prior art is solved.

The invention discloses a low-temperature multi-effect evaporation-based impurity salt treatment process method, and relates to the technical field of industrial waste salt treatment in the chemical industry. According to the scheme, firstly, impurity salt is dissolved and then pretreated by a fluorine removal tank and a multi-medium filter, and pretreated saline water is obtained; then, organic matters and dissolved substances are removed through a catalytic oxidation and nanofiltration device, and a monovalent salt solution and a divalent salt solution are separated out; then, the monovalent salt solution is subjected to reverse osmosis concentration and then enters a low-temperature multi-effect evaporation system for sodium chloride crystallization, and the divalent salt solution is subjected to catalytic oxidation and then enters low-temperature multi-effect evaporation for sodium sulfate crystallization. And finally, the mother liquor subjected to low-temperature multi-effect evaporation is refluxed and retreated, and resources are further concentrated. According to the invention, the waste salt treatment efficiency is effectively improved by optimizing the chemical addition of the sedimentation tank. By adopting a low-temperature multi-effect evaporation technology, the energy efficiency is optimized, the energy loss is reduced, the crystallization efficiency is improved, and the resource recovery rate is increased. And a mother liquor backflow retreatment mechanism reduces waste liquid discharge and reduces environmental burden.

The invention relates to the technical field of soil remediation, in particular to a biochar-humic acid-calcium alginic acid composite saline-alkali soil modifier and a preparation and application method thereof. The modifier adopts a multi-layer structure design: biochar is pre-adsorbed by calcium chloride, compounded with sodium humate, and then crosslinked with sodium alginate to form a gel to form a composite inner core; secondly, sulfobetaine methacrylate and vinyl phosphonic acid are introduced into a sodium alginate molecular chain through graft polymerization, and modified sodium alginate is obtained to serve as an outer layer coating material; and finally, dipping the composite inner core into the outer layer solution, and carrying out graded recalcification by calcium chloride and short-time treatment by sodium sulfate to obtain a final product. Through the synergistic effect of calcium ion slow release of the inner core and zwitterionic characteristics of the outer layer, efficient replacement and long-term stable regulation and control of soil sodium ions are achieved, the pH value, the conductivity and the alkalization degree of soil are remarkably reduced, the water holding capacity is effectively improved, and the soil conditioner is suitable for sustainable improvement of moderate and severe saline-alkali soil.

The invention discloses a quick-absorption type adult paper diaper and a preparation method thereof, and relates to the field of hygienic products, the quick-absorption type adult paper diaper comprises a surface layer, a flow guide layer, an absorption core layer and a leakage-proof bottom film which are arranged in sequence, the absorption core layer comprises an upper layer non-woven fabric, a first liquid absorption layer, deodorization fibers, a second liquid absorption layer and a lower layer non-woven fabric which are stacked in sequence, the first liquid absorption layer and the second liquid absorption layer are formed by mixing SAP and fluff pulp according to the mass ratio of (40-70): (30-60), and the SAP is prepared from the following raw materials in parts by weight: 100-120 parts of acrylic acid; 70-90 parts of a 30% sodium hydroxide solution; 4-8 parts of polyvinyl alcohol sodium sulfate; 10 to 14 parts of starch; 2-4 parts of an initiator; 0.5 to 1 part of a cross-linking agent; and 180 to 220 parts of deionized water. The liquid absorption performance and the deodorization and antibacterial performance of the absorption core layer of the adult paper diaper can be improved.

The invention discloses a fluidized collision type bioelectric reaction device suitable for high-carbon sewage treatment. The device comprises a reactor body, a capacitive electroactive biofilm carrier, an anode plate and a cathode plate. The reactor body is a cylinder, the bottom of the reactor body is provided with a water impeller, and the areas are separated by grids; the capacitive electroactive biofilm carrier is a sphere formed by stacking round sheets and is made of polyethylene plated with an ITO (Indium Tin Oxide) film, and stainless steel spikes are arranged on the surface of the capacitive electroactive biofilm carrier; the cathode plate is made of graphite and is cylindrical; the anode plate is made of stainless steel compounded by lauryl sodium sulfate and graphene-multi-walled carbon nanotubes and is cylindrical, the plate wall is hollow, and the anode and the cathode are connected through a circuit. Electron transfer is completed through flowing and collision of the capacitive electroactive biofilm carrier, the mass transfer efficiency and activity of the electroactive biofilm are enhanced, the high-carbon wastewater treatment capacity is improved, and meanwhile the device has the advantages of being high in impact load resistance and low in site area requirement.

The invention relates to the technical field of building material modification, in particular to an anti-freeze thawing-sulfate composite modifier and application thereof in a water-stable base layer. In road engineering, a water-stable base layer often faces the problems of freeze-thaw cycle and sulfate erosion damage. The key point of the technical scheme of the invention is as follows: on the basis of the mass of cement, a composite modifier is composed of the following components in percentage by mass: 2%-5% of sodium sulfate, 0.02%-0.05% of sodium gluconate, 0.4%-0.6% of polypropylene fiber, 0.1%-0.2% of steel fiber, 1%-3% of butadiene styrene rubber emulsion, 0.05%-0.5% of sodium carboxymethyl cellulose, 0.05%-0.1% of triethanolamine, 0.1%-0.5% of naphthalene water reducer, 0.005%-0.02% of air entraining agent, 8%-10% of silica fume and the like. The composite modifier is mainly used for the water-stabilized base, can effectively improve the freeze-thaw resistance and sulfate erosion resistance of the water-stabilized base, and prolongs the service life of a road.

The invention discloses an HPVC power cable protection pipe and a preparation method thereof, and relates to the technical field of cable protection pipes. The HPVC power cable protection tube is at least prepared from the following raw materials in parts by weight: 100 parts of high-strength polyvinyl chloride, 35 to 45 parts of epoxy acrylate rubber, 5 to 8 parts of vinyl chloride-g-acrylate copolymer, 8 to 12 parts of epoxidized soybean oil, 3 to 5 parts of calcium-zinc composite stabilizer, 5 to 15 parts of modified hydrotalcite, 0.1 to 0.5 part of beta-diketone, 0.8 to 1.5 parts of calcium stearate and 10 to 20 parts of flame retardant. 12 to 15 parts of modified nano calcium carbonate, 5 to 8 parts of talcum powder, 0.6 to 1.2 parts of antioxidant, 1 to 2 parts of anti-aging agent 4010 and 0.5 to 1.5 parts of ultraviolet light absorber UV531; the modified hydrotalcite is obtained by adding a mixed solution of calcium nitrate and lanthanum nitrate, a sodium hydroxide solution and a sodium bicarbonate solution into a lauryl sodium sulfate solution, mixing and aging, and then carrying out a post-treatment process. The HPVC power cable protection tube prepared by the invention has relatively high strength, good mechanical properties, weather resistance and cold resistance, and long service life.

The invention relates to the field of emulsions for grainy paper coatings, and discloses a preparation method of a water-based environment-friendly emulsion for a grainy paper coating. The preparation method comprises the following steps: S1, preparing an acrylic carbamate modified monomer from hydroxyethyl acrylate, 2, 4-toluene diisocyanate and diethanol amine; and S2, preparing to obtain the emulsion. S3, obtaining the initiator. S4, deionized water, lauryl sodium sulfate, the emulsion and an initiator are subjected to a polymerization reaction, and an emulsion A is obtained. S5, transferring the emulsion A into a degassing kettle, adding tert-butyl hydroperoxide and vitamin C, and performing oxidation-reduction reaction to obtain emulsion B; and S6, carrying out steam degassing on the emulsion B to obtain the water-based environment-friendly emulsion. The water-based environment-friendly emulsion which is good in stability, glossiness, adhesion fastness, water resistance and weather resistance and low in volatile organic compound content can be prepared, and the preparation method is simple, efficient and environmentally friendly and has wide application prospects and market value.

The invention discloses modified cement-water glass slurry and a preparation method thereof, and belongs to the technical field of building material preparation. The preparation method comprises the following steps: weighing the following raw materials in parts by weight: 50-70 parts of Portland cement, 20-35 parts of a water glass solution, silica fume, modified nano-silica, an early strength agent and the like, carrying out dry mixing on solid powder, stirring with part of deionized water to form base slurry, adding the water glass solution and the rest deionized water, and carrying out high-speed dispersion to obtain a slurry; and finally, carrying out ultrasonic treatment for 10-15 minutes at the frequency of 20-40 kHz and the power of 300-500 W. Wherein the early strength agent is compounded by triethanolamine and sodium sulfate according to the ratio of 1: 2-1: 3. According to the method, through raw material compounding and process optimization, the dispersity, the early strength and the crack resistance of the slurry are improved, and the method is mainly used for grouting operation in the field of construction engineering such as foundation reinforcement and water prevention and leakage stoppage.

The invention relates to a method for separating sodium sulfate and sodium thiocyanate from a mixed waste salt solution, which comprises the following steps: carrying out catalytic oxidation, decoloration treatment and first solid-liquid separation on the mixed waste salt solution, and carrying out first evaporation concentration, first cooling crystallization and second solid-liquid separation on the obtained pretreated solution to obtain a sodium sulfate crude product and a filtrate, washing the sodium sulfate crude product, and carrying out third solid-liquid separation to obtain sodium sulfate; carrying out second evaporation concentration on the filtrate, adding sodium thiocyanate seed crystal, carrying out second cooling crystallization and fourth solid-liquid separation to obtain a sodium thiocyanate crude product and residual liquid, washing the sodium thiocyanate crude product, and carrying out fifth solid-liquid separation to obtain sodium thiocyanate; and circulating the washing waste liquid and the residual liquid to the pretreatment solution for mixing and recycling. According to the method, evaporation concentration is combined with cooling crystallization, sodium sulfate and sodium thiocyanate which are high in purity and extraction rate can be obtained through separation, and the whole preparation process is low in energy consumption and more environmentally friendly and integrally has good economic benefits.