1167 results about "Sodium sulfate" patented technology

The invention relates to the technical field of soil remediation, in particular to a biochar-humic acid-calcium alginic acid composite saline-alkali soil modifier and a preparation and application method thereof. The modifier adopts a multi-layer structure design: biochar is pre-adsorbed by calcium chloride, compounded with sodium humate, and then crosslinked with sodium alginate to form a gel to form a composite inner core; secondly, sulfobetaine methacrylate and vinyl phosphonic acid are introduced into a sodium alginate molecular chain through graft polymerization, and modified sodium alginate is obtained to serve as an outer layer coating material; and finally, dipping the composite inner core into the outer layer solution, and carrying out graded recalcification by calcium chloride and short-time treatment by sodium sulfate to obtain a final product. Through the synergistic effect of calcium ion slow release of the inner core and zwitterionic characteristics of the outer layer, efficient replacement and long-term stable regulation and control of soil sodium ions are achieved, the pH value, the conductivity and the alkalization degree of soil are remarkably reduced, the water holding capacity is effectively improved, and the soil conditioner is suitable for sustainable improvement of moderate and severe saline-alkali soil.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a pretreatment method for improving the leaching rate and the carbon adsorption rate of high-sulfur-arsenic gold ore. Comprising the following steps that the high-sulfur-arsenic gold ore is ground and then prepared into ore pulp; a green oxygen activating agent and hydrogen peroxide are sequentially added into the ore pulp, oxidation pretreatment is conducted on the high-sulfur-arsenic gold ore, ore pulp activating liquid is formed, and the green oxygen activating agent is a mixture of calcium oxide, sodium persulfate and soluble bivalent iron salt; and adding a gold leaching agent into the ore pulp activation solution, adjusting the pH value of the ore pulp to 9-12, carrying out stirring gold leaching treatment, filtering to obtain a leaching solution, and then adding activated carbon to adsorb and extract gold. According to the method, a stronger oxidation environment is provided, meanwhile, the residual concentration of arsenate radicals in the solution is effectively reduced, the leaching rate of gold and the adsorption rate of activated carbon are greatly increased, excellent oxidation performance and environment friendliness are shown, and a more sustainable high-sulfur-arsenic gold ore pretreatment process is provided.

The invention discloses a hollow fiber nanofiltration membrane based on interfacial polymerization regulation and a preparation method thereof. The method comprises the following steps: preparing a water phase system and an oil phase system, and sequentially injecting the water phase system and the oil phase system into a hollow fiber ultrafiltration membrane; performing interfacial polymerization reaction on the water phase system and the oil phase system on the surface of the hollow fiber ultrafiltration membrane; and drying to obtain the hollow fiber nanofiltration membrane. By adopting the method, the interception performance and flux of the nanofiltration membrane can be effectively adjusted, and the stability and applicability of the nanofiltration membrane are improved. The nanofiltration membrane is low in water contact angle and high in oil contact angle. Particularly, the surface porosity, the effective aperture, the sodium sulfate retention rate, the sodium chloride retention rate, the flux of sodium sulfate, the flux of sodium chloride and other properties of the nanofiltration membrane can be designed and accurately controlled according to requirements, and the properties of the nanofiltration membrane can be accurately designed and customized by adopting the method disclosed by the invention; the performance of the green and natural modified hollow fiber ultrafiltration membrane is realized, and an innovative solution is provided for high-salt resource recovery.

The invention discloses a composite mineral admixture prepared from heat-stewed steel slag and a preparation method of the composite mineral admixture, and the mineral admixture is prepared from the following raw materials in parts by weight: 40-50 parts of heat-stewed steel slag powder, 20-30 parts of granulated blast furnace slag powder, 20-40 parts of fly ash, 0.01-0.1 part of a grinding aid and 0.5-4.0 parts of an exciting agent, wherein the grinding aid comprises glycerol and diethanol isopropanolamine, and the exciting agent comprises diphenyl phosphate, sodium sulfate and ammonium bicarbonate. The preparation method comprises the following steps: mixing calcium bicarbonate and water, spraying the mixture on high-temperature steel slag at 600-800 DEG C, carrying out hot braising under the condition of steam pressure of 0.2-0.5 MPa for 8-12 hours to pulverize the steel slag until the particle size is less than 5-10 mm, and carrying out vertical milling on the pulverized steel slag and a grinding aid for 20-40 minutes to obtain hot-braised steel slag powder; uniformly mixing the heat-stewed steel slag powder, granulated blast-furnace slag powder, fly ash, a grinding aid and an exciting agent in proportion to obtain mixed powder; and finally, grinding the mixed powder for 30-50 minutes by adopting a high-energy planetary ball mill to obtain the cement concrete composite mineral admixture with the specific surface area being greater than or equal to 600m < 2 > / kg. According to the invention, the potential hazard of poor stability of a cement concrete material caused by high f-MgO content in the steel slag is broken through, the steel slag is efficiently utilized to prepare a low-carbon green building material, a composite mineral admixture is developed, and the performance meets the II type requirement in JG / T 486-2015 Composite Admixture for Concrete.

The invention belongs to the technical field of chemical engineering and secondary resource utilization, and particularly discloses a collaborative utilization process of sodium sulfate and ammonium-containing waste salt. The high-value utilization method of sodium sulfate provided by the invention comprises the following steps: mixing sodium sulfate, organic ammonium salt and sulfuric acid, and adding water to prepare a mixed solution; extracting the mixed solution by using an extracting agent, and separating a water phase from an organic phase; adding a pH regulator into the water phase to regulate the pH to alkalescence, introducing carbon dioxide gas to fully react, cooling, crystallizing, and filtering to obtain filtrate and sodium bicarbonate precipitate; heating the filtrate for evaporative crystallization to obtain ammonium sulfate; and recovering the organic acid in the organic phase. The invention provides a subversive solution for sodium sulfate by-product accumulation and ammonium-containing wastewater treatment, has double values of resource circulation and carbon emission reduction, and has the advantages of full-flow closed-loop design, wide applicability, high product purity and high economical efficiency in process.

The invention relates to the technical field of paint removers, and particularly discloses a paint removal composition, a paint stain cleaning agent and application of the paint stain cleaning agent. The paint stain cleaning agent provided by the invention is prepared from the following components in parts by weight: 30 to 40 parts of EDTA-2Na (Ethylene Diamine Tetraacetic Acid), 200 to 300 parts of caustic soda flakes, 140 to 170 parts of sodium alcohol ether sulphate, 160 to 180 parts of sodium xylene sulfonate, 400 to 450 parts of monoethanolamine, 1100 to 1300 parts of diethylene glycol monobutyl ether, 250 to 300 parts of limonene, 40 to 100 parts of saponin extract and 3700 to 3900 parts of water, the saponin extract is selected from one or more of soapnut saponin, fenugreek saponin and aescin; the invention further provides a paint stain cleaning agent prepared from the paint removal composition and application of the paint stain cleaning agent to cleaning of protective clothing. The paint stain cleaning agent provided by the invention can quickly permeate into paint and the contact surface of the paint and protective clothing, so that the paint on the surface of the protective clothing is dissolved and effectively stripped.

The invention relates to a recycling method of chemical polishing waste liquid, which comprises the following steps: (1) carrying out first pH regulation treatment on the chemical polishing waste liquid containing phosphate radicals, sulfate radicals, aluminum ions and + 3 valent iron ions to obtain aluminum mud and aluminum-removed liquid; (2) sequentially carrying out second pH regulation treatment, third pH regulation treatment and dealumination treatment on the aluminum mud to obtain a hydrated calcium aluminate product; (3) the aluminum-removed liquid is subjected to phosphorus removal treatment, and first phosphorus mud and phosphorus-removed liquid are obtained; sequentially carrying out fourth pH regulation treatment and first evaporative crystallization treatment on the first phosphorus sludge to obtain a sodium phosphate product; and sequentially carrying out fifth pH regulation treatment and second evaporative crystallization treatment on the dephosphorized liquid to obtain a sodium sulfate product. According to the method disclosed by the invention, phosphorus, sulfur and aluminum in the chemical polishing waste liquid are completely separated by utilizing different solubility of different substances in the solution when the pH value is the same, and a sodium phosphate product, a sodium sulfate product and a hydrated calcium aluminate product are respectively obtained, so that complete recycling of elements in the chemical polishing waste liquid is realized, and no byproduct waste is produced.

The invention belongs to the technical field of fine chemical engineering, and discloses hydroxypropyl crosslinked starch as well as a preparation method and application thereof. The preparation method of the hydroxypropyl crosslinked starch comprises the following steps: mixing starch and water to prepare starch milk; adding sodium phytate and urea; adding sodium sulfate and sodium hydroxide after cooling; adding epoxypropane for reaction; and adding sodium trimetaphosphate to react to prepare the hydroxypropyl crosslinked starch. The hydroxypropyl crosslinked starch prepared by the preparation method disclosed by the invention has excellent shear resistance, acid resistance and oxidation resistance.

The invention relates to a preparation method of a biomass-based degradable dust suppressant and a spraying device. The biomass-based degradable dust suppressant is prepared from the following components in percentage by weight: 0.78% of a biological matrix, 20.7% of a salting-out salt solution and the balance of an acetic acid solution diluted by deionized water, the method comprises the following specific steps: adding biological matrix powder into an acetic acid solution; the salting-out salt solution powder is poured into a biological matrix acetic acid solution, magnetic stirring is conducted for 30 min under the conditions that the rotating speed is 200 r / min and the temperature is 30 DEG C, and then ultrasonic treatment is conducted for 10 min for full reaction; a salting-out method and a dust suppression technology are combined, high-concentration salt solutions such as sodium citrate and sodium sulfate are selected, physical and chemical effects between salt ions and biomass material molecules are utilized, and the limitation of a traditional cross-linking mode is broken through the synergistic effect of salting-out auxiliary precipitation and weak ion cross-linking net forming; according to the present invention, the long-acting and safe dust suppression agent can be simply and conveniently prepared, the dust suppression efficiency can be effectively improved, and the dust suppression cost can be effectively reduced.

The invention relates to a selective nanofiltration membrane as well as a preparation method and application thereof. The selective nanofiltration membrane comprises a support layer and a separation layer, the separation layer is obtained through interfacial polymerization of an oil-phase reactant and a water-phase reactant; the water-phase reactant comprises a negatively charged monomer and a positively charged monomer; the positively charged monomer comprises any one or a combination of at least two of polyvinylamine, polyethyleneimine, diethylenetriamine, water-soluble chitosan, quaternized polyethyleneimine, polyallylamine or triethylene tetramine. According to the method, monomers with different charges are added into a water phase, so that the nanofiltration membrane is wholly charged and neutral, the interception of sodium sulfate can be effectively reduced, the interception of antibiotics is increased, and the separation of the antibiotics and inorganic salts can be efficiently promoted.

The utility model relates to the technical field of wastewater retreatment, and provides an ion exchange water production regeneration wastewater pretreatment device. The ion exchange water-making regenerated wastewater pretreatment device comprises a normal-temperature crystallization reactor, a sedimentation tank, a filtering assembly, an ion exchange assembly and a strong oxidizer. The normal-temperature crystallization reactor is used for crystallizing and separating part of impurities in the regenerated wastewater; the settling pond is communicated with the normal-temperature crystallization reactor and is used for settling and purifying the crystallized regenerated wastewater; the filtering assembly is communicated with the settling pond and is used for filtering the settled and purified regenerated wastewater; the ion exchange assembly is communicated with the filtering assembly and is used for removing calcium and magnesium ions in the regenerated wastewater; the strong oxidizer is communicated with the ion exchange assembly and is used for killing microorganisms in the regenerated wastewater. The device disclosed by the utility model can be used for treating and separating most impurity ions except sodium chloride and sodium sulfate in the ion exchange water-making regeneration wastewater.

The application discloses a lithium mica floating agent, a preparation method thereof and a lithium mica floating method. The lithium mica floating agent has a formula mass ratio of amine 8-35%, ether 10-40%, sodium dodecyl sulfate 8-35%, sodium sulfonate 5-30%, alcohol 10-35% and inorganic alkali 2-15%. The lithium mica floating agent can greatly improve the recovery rate of lithium metal, has very high selectivity to lithium mica, has high floating yield, good purity of the extract and low cost.

The invention discloses a method for preparing battery-grade lithium phosphate and iron phosphate by recycling waste lithium iron phosphate batteries, and belongs to the technical field of lithium ion battery recycling. The method comprises the following steps: mixing and calcining black powder recovered from the waste lithium iron phosphate battery and sodium persulfate; adding water for dissolving, filtering to obtain a water leaching solution A and leaching residues, washing the leaching residues with water, and calcining at high temperature to obtain battery-grade iron phosphate; adding a sodium hydroxide solution into the water extract A, and reacting to obtain a water extract B; adding a trisodium phosphate solution into the water immersion liquid B, performing suction filtration after reaction to obtain lithium phosphate and filtrate, and cleaning and drying the lithium phosphate to obtain battery-grade lithium phosphate; and freezing and denitrifying the filtrate to obtain a denitrified solution, and adding the denitrified solution into the sodium hydroxide solution for recycling. The filtrate is recycled in the whole production process, zero loss of the lithium element is theoretically realized, the iron element is prevented from entering the solution, the preparation steps of the lithium phosphate are simplified, and the method has the advantages of economy and environmental protection.

The invention relates to the technical field of aluminum oxide preparation, in particular to a method for preparing flaky aluminum oxide by using electrolyte waste liquid and flaky aluminum oxide. The method comprises the following steps: carrying out carbonation reaction on the electrolyte waste liquid by using carbon dioxide to obtain aluminum hydroxide precipitate; washing the aluminum hydroxide precipitate for the first time by using a washing agent to obtain a washed aluminum hydroxide solid-phase substance with a preset sodium content; calcining the washed aluminum hydroxide solid-phase substance to obtain a gamma-type aluminum oxide precursor; carrying out molten salt reaction on the composite molten salt system and the gamma-type aluminum oxide precursor to obtain a flaky aluminum oxide crude product; wherein the composite molten salt system is a mixture of sodium chloride, potassium chloride and sodium sulfate; and carrying out secondary washing on the sheet-shaped aluminum oxide crude product to obtain a sheet-shaped aluminum oxide product. According to the method, the flaky alumina with the high radius-thickness ratio is prepared under fluoride-free and strong acid conditions through a three-step core strategy of resource utilization of waste electrolyte, accurate sodium content control and directional induction of composite molten salt.

The invention discloses a clean, efficient and low-cost lithium extraction slag utilization method which comprises the following steps: mixing lithium extraction slag with a fluxing agent, and sequentially carrying out roasting treatment, solid-liquid separation treatment, aging treatment and water leaching treatment to obtain a second solid-liquid mixture; carrying out solid-liquid separation treatment on the second solid-liquid mixture to obtain a second filter residue and a second filtrate; performing carbon separation method treatment on the first filtrate to obtain a third solid-liquid mixture; carrying out solid-liquid separation treatment on the third solid-liquid mixture to obtain a third filter residue and a third filtrate; the main component of the second filter residue and the third filter residue is white carbon black; performing heat treatment on the second filtrate and the third filtrate to obtain a fourth solid-liquid mixture; performing solid-liquid separation treatment on the fourth solid-liquid mixture to obtain fourth filter residues and fourth filtrate; the main components of the fourth filter residue are aluminum hydroxide and ferric hydroxide; and separating the fourth filtrate to obtain a sodium sulfate crystal substance and a potassium sulfate crystal substance.

The invention relates to the field of separation and purification, in particular to an anti-pollution nanofiltration membrane for magnesium-lithium separation, the anti-pollution nanofiltration membrane comprises a base membrane and a functional layer, and the functional layer is prepared from the following raw materials in parts by weight: a water phase: 1.5-2.5 parts of piperazine, 0.1-1 part of lauryl sodium sulfate, 0.5-2 parts of glycerol, 1-2 parts of triethylamine, 0.6-2 parts of ionic polymer, and the balance of water for supplementing the total amount of the water phase to 100 parts; the ionic polymer comprises at least one of sulfobetaine metacrylic acid ester, sulfobetaine and carboxyl betaine metacrylic acid ester; and an oil phase: 0.1-1 part of trimesoyl chloride, and the total amount of the oil phase is supplemented to 100 parts by normal hexane or isoparaffin. The ionic polymer is added, and a compact hydration layer is formed on the surface of the membrane by using a betaine group of the ionic polymer, so that the membrane pollution probability is reduced, and common inorganic scaling and organic pollution in the high-salt brine are remarkably inhibited; in addition, the ionic polymer enables the membrane surface to have strong negative electricity, and the magnesium ion rejection rate is improved; and the ionic polymer can also reduce the lithium ion transmission energy barrier and reduce the rejection rate.

The utility model discloses a coal chemical industry wastewater crystal salt resource recycling system which comprises a pretreatment softening device, a waste water recycling device and a waste water recycling device, an evaporation concentration device; a first evaporative crystallization system; a first freezing crystallization device; a second evaporative crystallization system; and a second freezing crystallization device. According to different properties of sodium sulfate, sodium chloride and sodium nitrate, the sodium sulfate, the sodium chloride and the sodium nitrate are crystallized and separated through the pretreatment softening device, the evaporation concentration device, the first evaporation crystallization system, the first freezing crystallization device, the second evaporation crystallization system and the second freezing crystallization device, so that the obtained sodium sulfate, the sodium chloride and the sodium nitrate reach industrial recycling standards; therefore, zero discharge and resource utilization of the wastewater are realized.

The invention discloses a microcapsule phase change cement material, which is prepared by compounding a microcapsule with phase change performance and a cement matrix, the microcapsule is of a core-shell structure, the raw materials of the shell are melamine, urea and formaldehyde, the raw material of the core material is octadecane, and Tween 80 and lauryl sodium sulfate are used as emulsifiers. The preparation method comprises the following steps: 1, preparing an MUF resin prepolymer; 2, preparing a core material O / W emulsion; 3, polymerization reaction of the microcapsules; and 4, preparing the microcapsule phase change cement material. When the composite material is used as a cement-based composite material, the melting temperature ranges from 25 DEG C to 29 DEG C, the crystallization temperature ranges from 19 DEG C to 23 DEG C, the melting enthalpy ranges from 13.47 J / g to 29.78 J / g when the mixing amount is 10%-30%, the crystallization enthalpy ranges from 12.94 J / g to 28.41 J / g, and the coating efficiency is 67.5%. The initial decomposition temperature ranges from 386.13 DEG C to 390.96 DEG C, the finishing temperature ranges from 399.49 DEG C to 406.42 DEG C, and the maximum degradation temperature ranges from 438.78 DEG C to 443.64 DEG C; the heat conductivity coefficient is 0.3216 to 0.3949, and is improved by 39.4 percent compared with that of standard cement.

The invention relates to the technical field of textile double-sided printing, in particular to a high-permeability and double-sided positioning printing method for all-cotton towel products, which comprises the following steps: pre-treating all-cotton towel gray cloth, including desizing, scouring and bleaching procedures; padding the treated gray cloth in slurry containing urea, sodium bicarbonate, anhydrous sodium sulphate and a penetrant, and then drying and sizing; printing on the front surface of the towel by adopting a digital printing machine, and spraying a penetrating agent with the surface tension of 25-35mN / m to a printing area through an independent jet printing channel, so as to promote the dye to fully permeate to the back surface of the fabric and form a clear pattern outline; according to the invention, an image acquisition system composed of an industrial camera, an annular LED coaxial light source and a polarization filter captures fabric back pattern contour features in real time, and generates a translation, rotation and zooming transformation matrix based on an image registration algorithm; in combination with closed-loop feedback control of the digital printing machine, the positioning precision is improved by more than 75% compared with a traditional method.

The invention discloses a preparation method of polyurethane leather with electric conduction, infrared stealth and ultraviolet aging resistance functions, and relates to a textile material technology. The preparation method comprises the following steps: firstly, weighing 50g of waterborne polyurethane, adding a dispersing agent, and stirring in a dispersing machine at the rotating speed of 1,000 rpm for 10 minutes; sequentially adding a certain amount of graphene, carbon black, carbon fiber powder and copper powder into the dispersion system to serve as functional particles, adding one kind of functional particles every 5 minutes, and stirring for 5 minutes after adding one kind of functional particles; then adding 0.12 g of lauryl sodium sulfate and 1.2 g of a flatting agent, and continuously stirring for 10 to 20 minutes until the viscosity of the system reaches 30000 Pa.s; and finally, a heating scraper and winding bar integrated coating testing machine is used for coating to manufacture the leather. The polyurethane leather with the conductive, infrared stealth and ultraviolet aging resistant functions is prepared, the polyurethane leather has the conductive, infrared stealth and ultraviolet aging resistant functions, the flexibility and mechanical performance of the material can be kept, and the polyurethane leather can adapt to various complex application environments.

The invention discloses a fly ash washing dechlorination and resource utilization method. The method comprises the steps of fly ash pretreatment, size mixing treatment, enhanced washing and solid-liquid separation, filter cake treatment and mixed washing liquid purification and salt separation crystallization. Through a multi-dimensional synergistic strengthening means, the fly ash dechlorination efficiency is remarkably improved, resource utilization is achieved, the sodium citrate and lauryl sodium sulfate composite additive is adopted, Zeta potential real-time monitoring and pulse type supplementing are combined, fly ash particles are effectively dispersed, mass transfer resistance is destroyed, dissolution of chloride ions is promoted, and the dechlorination effect of the fly ash is improved. Moreover, gradient heating, electric field assistance and redox potential regulation are introduced, so that heavy metal dissolution is inhibited while efficient dechlorination is performed.

The invention relates to the technical field of roadbed materials, in particular to a composite filling material and a preparation method and application thereof. The composite filling material provided by the invention is prepared from the following raw materials in parts by weight: 18 to 26 parts of pretreated phosphogypsum, 30 to 45 parts of pretreated household garbage incineration bottom ash, 8 to 18 parts of alkaline excitation material, 6 to 20 parts of aluminum-silicon material, 5 to 25 parts of aggregate and 1 to 4 parts of sodium sulfate aqueous solution, the pretreatment of the phosphogypsum comprises lime milk aging treatment; the pretreated household garbage incineration bottom ash comprises gelation active fine powder and structural aggregate. The composite filling material formed by taking the ardealite, the household garbage incineration bottom ash, the alkaline excitation material and the aluminum-silicon material as main raw materials is high in industrial solid waste mixing amount, stable in performance and environment-friendly, reduces the pollutant leaching risk, is suitable for roadbed structures such as an embankment filling layer, a semi-rigid base layer and a flexible subbase layer, and has a wide application prospect. And the benefit is obvious.

The invention discloses a preparation method of an organic-inorganic composite microcapsule as well as an obtained product and application of the organic-inorganic composite microcapsule. The preparation method comprises the following steps: firstly, preparing a MoS2-metal composite material by adopting pulse laser irradiation, mixing the MoS2-metal composite material, PAO5 oil, polysulfone and an organic solvent to obtain an organic phase, and dissolving lauryl sodium sulfate and polyvinyl alcohol in water to obtain a water phase; and mixing the organic phase and the water phase, and obtaining the microcapsule by adopting a solvent evaporation method. The method disclosed by the invention is simple to operate and low in cost, and the obtained microcapsule can automatically store a lubricant and has excellent tribological performance in the friction process.

The invention discloses a hyperspectral inversion method for the concentration of sodium sulfate in a mural with consideration of temperature and humidity, and belongs to the technical field of cultural relic protection and spectral analysis. According to the method, simulated mural samples with the sodium sulfate concentration of 0%-1% and the temperature and humidity ranges of-14 DEG C to 38 DEG C and 15% RH to 100% RH are manufactured, spectral reflectivity data of 350 nm to 2500 nm are collected through a ground feature spectrometer, and environmental parameters are recorded; after the data are preprocessed, characteristic wave bands are screened based on Pearson correlation analysis, a multivariable data set containing reflectivity, temperature and humidity of the characteristic wave bands is constructed, a training set and a test set are divided, and a prediction model is established by adopting a regression algorithm; and finally, inputting the characteristic wave band reflectivity and the real-time temperature and humidity of the mural to be detected, and outputting a sodium sulfate concentration predicted value. The method can accurately invert the concentration of sodium sulfate in the mural, and provides technical support for salt damage monitoring and protection of the mural.

The invention relates to a method for comprehensively recycling a positive electrode material of a waste lithium iron phosphate battery, which comprises the following steps of: (1) discharging the waste lithium iron phosphate battery: providing a power supply by the waste lithium iron phosphate battery, and electrolyzing a lithium precipitation mother solution by using a three-chamber diaphragm electrolytic bath; (2) crushing and sorting; (3) two-stage leaching: leaching the lithium iron phosphate positive electrode powder with a sulfuric acid solution generated by electrolysis of a lithium precipitation mother solution, and adding an aeration disc at the bottom of a reaction kettle for aeration; adding a dilute sulfuric acid solution generated by electrolysis of lithium precipitation mother liquor into first-section leaching residues for leaching; (4) two-stage impurity removal; and (5) preparing lithium carbonate. According to the method, the lithium precipitation mother liquor for the waste lithium iron phosphate battery is discharged to prepare the sulfuric acid and sodium hydroxide-lithium hydroxide mixed solution for production, so that residual electricity is utilized, a production reagent is saved, and the problems of high energy consumption, large lithium loss and poor sale of a byproduct sodium sulfate in evaporative crystallization of sodium sulfate are solved; and the aim of circularly and comprehensively utilizing the waste lithium iron phosphate battery is fulfilled.

The invention discloses a high-salinity wastewater resource utilization method and device, belongs to the technical field of chemical engineering, and relates to wastewater treatment. The invention relates to a high-salinity wastewater resource utilization method which comprises the following steps: (1) deep removal of organic matters in a high-salinity system: realizing selective separation and removal of the organic matters in wastewater by using a synergistic effect of a flocculating agent and a catalyst; (2) mixed salt separation and recycling: realizing stable separation of sodium chloride and sodium sulfate through the design of MCR-nanofiltration-reverse osmosis multi-membrane coupling synergistic gradient coupling and reflux nesting; and (3) stable control of evaporative crystallization of a complex system: a scale inhibitor, humic acid and a defoaming agent are used, and fractional crystallization and purification are realized through high-temperature firing. According to the method, recycling circulating water can be saved, a large amount of sodium chloride and sodium sulfate are recycled as byproducts, COD and ammonia nitrogen are reduced, the recycling rate of sodium sulfate and sodium chloride is larger than 85%, and the water recycling rate is larger than 95%.

The utility model discloses a pesticide wastewater advanced treatment device which comprises a first-stage oxidation tower, a second-stage main reaction tower and a third-stage delay reaction tower which are sequentially arranged, a water outlet of the first-stage oxidation tower is communicated with a water inlet of the second-stage main reaction tower, and a water outlet of the second-stage main reaction tower is communicated with a water inlet of the third-stage delay reaction tower; the primary oxidation tower comprises a first tower body, a water inlet pipe, a first hydrogen peroxide adding pipe and an ozone jet device, the water inlet pipe is communicated with the first tower body, the first hydrogen peroxide adding pipe is communicated with the water inlet pipe, and the ozone jet device is mounted on the first tower body to introduce ozone into the first tower body; the secondary main reaction tower comprises a second tower body, a sodium persulfate dosing pipe and an ozone aeration disc; the sodium persulfate dosing pipe is communicated with a water inlet of the second tower body; the ozone aeration disc is arranged at the bottom in the second tower body; the third-stage delay reaction tower comprises a third tower body and a second hydrogen peroxide adding pipe, and the second hydrogen peroxide adding pipe is communicated with a water inlet of the third tower body.

This application discloses a curing agent for fluidized solidified soil and its preparation method. The curing agent comprises the following raw materials by weight: 30-45 parts of sulfoaluminate cement, 15-30 parts of gypsum, 10-15 parts of steel slag, 15-25 parts of mineral powder, 3-4.5 parts of carboxymethyl cellulose, 10-15 parts of attapulgite, 5-10 parts of sodium sulfate, 5-10 parts of silane coupling agent modified glass microspheres, and 60-80 parts of water. The curing agent for fluidized solidified soil provided in this application can improve the compressive strength and stability of the solidified soil.

The present application belongs to the technical field of waste incineration fly ash treatment, and particularly relates to a low-carbon treatment process for waste incineration fly ash water washing wastewater, which comprises the following steps: A1: water washing of waste incineration fly ash to wash and remove heavy metals in the fly ash; A2: water washing wastewater is removed of heavy metals by ferrous chloride and sulfide; A3: water washing wastewater after removal of heavy metals is mixed with sodium sulfate to remove calcium ions; A4: residual calcium ions are removed by sodium carbonate, and sodium carbonate removal liquid is subjected to plate and frame pressure filtration and then enters an ultrafiltration and nanofiltration membrane system, and concentrated liquid of the membrane system is returned to configure a sodium sulfate solution; A5: fresh water from the membrane system enters an evaporation system, and mother liquor of the evaporation system is first subjected to diatomite reaction and then enters a raw ash pre-slurry reaction tank for raw ash slurry, so that the above low-carbon process is used to reduce the amount of sodium carbonate and the amount of mother liquor treatment, and efficient and low-carbon treatment of waste incineration fly ash water washing wastewater can be realized.

The present application relates to the technical field of ammonia compound preparation, in particular to a method for preparing ammonium sulfate and co-producing sodium bicarbonate by using sodium sulfate, comprising the following steps: mixing industrial-grade liquid ammonia with deionized water to prepare ammonia water with a free ammonia concentration of 60-120 ti (ti is the abbreviation of titer, which is 1 / 20 mol / L), controlling the temperature of the mixing process to be less than or equal to 40 DEG C to avoid ammonia volatilization, pre-carbonizing by passing in CO2 under the conditions of 20-70 DEG C and a carbon dioxide pressure of 0.1-0.6 MPa, and adding sodium sulfate or a mixture of sodium bicarbonate and mirabilite to obtain a pre-carbonized liquid. The present application adopts an integrated process of pre-carbonization, clarification, carbonization, ammonia separation and low-temperature crystallization, and ammonia evaporation circulation, and can be operated continuously or intermittently, has low industrial implementation difficulty, strong running stability, separates ammonium sulfate by using ammonia separation and low-temperature crystallization technology, replaces the traditional evaporation and concentration process, combines material recycling design, and reduces the energy consumption per unit product compared with the traditional process.