The invention relates to a method for producing
polyferric sulfate by using mine waste liquid, which comprises the following steps: S1, adding a certain amount of
iron powder into mine leaching waste liquid, adjusting the pH value to 1-2, and filtering to obtain a
stock solution; s2, adding the filtered
stock solution into a reaction kettle, starting stirring, raising the temperature to 70-80 DEG C, and performing negative pressure
evaporation for
volume concentration; s3, stopping concentration when the concentration density of the feed liquid reaches 1.45 g / cm < 3 >, closing the negative pressure vacuum device, and adding a certain amount of catalyst; s4, continuously stirring, introducing air as an
oxidizing agent, converting into
positive pressure operation, controlling the temperature within the range of 40-60 DEG C, and oxidizing the feed liquid; s5, after the oxidation reaches the end point, continuously stirring, maintaining the
positive pressure operation, introducing air, raising the temperature to 80-100 DEG C, and polymerizing for a certain time to obtain liquid polymeric
ferric sulfate; and S6, carrying out
spray drying on the polymerized feed liquid to obtain a
solid polymeric
ferric sulfate product. According to the invention, the production efficiency is improved, the cost is reduced, the generation of pollutants is reduced, and the cooled and recycled
sulfuric acid can be reused in a wet
copper smelting system.