The invention discloses a preparation method of low-
sulfur nano-
iron powder, and belongs to the technical field of
metal powder preparation. The preparation method comprises the following steps that breaking of a waste
zinc-
manganese battery is carried out, concretely, the waste
zinc-
manganese battery is put in a breaker to be broken into
powder with the particle size being below 200 micrometers;the
zinc-
manganese battery
powder is dissolved by adding acid and a
reducing agent; pH is adjusted for removing iron and aluminum; zinc is separated from manganese and zinc
sulfate is prepared, wherein zinc is subjected to extraction separation by adopting a P204 extraction agent;
impurity removal is carried out, concretely, a heavy
metal capturing agent and
fluoride are added so as to remove heavy
metal and
calcium and
magnesium; and preparation of a manganese
sulfate solution is carried out, concretely, manganese is subjected to extraction separation by adopting P507, then an obtained pure manganese solution is condensed and crystallized, and thus battery-grade manganese
sulfate is obtained. With the adoption of the preparation method of the low-
sulfur nano-
iron powder, the battery-grademanganese sulfate and high-purity zinc sulfate crystals can be obtained, the obtained manganese sulfate crystals are granular, an agglomeration phenomenon does not exists, a technology is simple andrecovery of full components is realized.