The invention discloses a primary physicochemical enhanced treatment coagulant for chemical waste water and relates to the technical field of chemical waste water treatment. The coagulant is prepared from, by weight, 10 kg to 18 kg of ferric sulfate, 8 kg to 12 kg of aluminum polysilicate, 4 kg to 9 kg of sodium lignosulfonate, 3 kg to 7 kg of carbon nanotubes, 5 kg to 8 kg of nano-zinc oxide, 3 kg to 6 kg of activated carbon fiber, 2 kg to 5 kg of polyvinyl alcohol, 2 kg to 5 kg of organic montmorillonite, 3 kg to 8 kg of phenolic resin, 1 kg to 4 kg of rapeseed oil, 1.5 kg to 3 kg of gas carbon black, 0.5 kg to 2 kg of propolis, 2 kg to 5 kg of calcium stearate and 8 kg to 12 kg of iron powder. According to the coagulant, chemical waste water is treated jointly by the carbon nanotubes, the nano-zinc oxide, the activated carbon fiber and other physicochemical reagents, the treatment speed is high, COD and BOD of the waste water can be effectively reduced, and organic matter in the waste water can be effectively removed.