461 results about "Copper chloride" patented technology

The invention discloses a nano-copper modified reduced graphene oxide powder preparation method, which comprises: S1, uniformly mixing a reduced graphene oxide dispersion liquid and a copper chloride solution to obtain a mixed liquid A; s2, reducing the mixed solution A by adopting a reducing agent to obtain a mixed solution B; s3, adjusting the pH value of the mixed solution B to 8-9 to obtain a mixed solution C; s4, titrating the mixed solution C with an alkaline solution until the mixed solution C is red, and standing and filtering to obtain a precipitate D; s5, washing the precipitate D until the pH value of supernatant liquid is neutral, and drying to obtain a precipitate E; and S6, sintering the precipitate E in an inert atmosphere to obtain the nano-copper modified reduced graphene oxide powder. The invention further discloses the nano-copper modified reduced graphene oxide powder, the high-strength and high-conductivity graphene copper plating-aluminum matrix composite and a preparation method of the high-strength and high-conductivity graphene copper plating-aluminum matrix composite.

The invention relates to a degradable filter element and a preparation method thereof, and belongs to the technical field of PLA filter elements. The degradable filter element is arranged between an atomizing element shell and a metal heating wire, a plurality of capillary holes are formed in the degradable filter element and used for being filled with tobacco tar, and the degradable filter element is prepared from a degradable composite material through melt spinning. The degradable composite material comprises the following components: polylactic acid and modified silicon dioxide, wherein the modified silicon dioxide is prepared by taking nano silicon dioxide, a silane coupling agent, ferulic acid, amino acid and copper chloride as raw materials, the silicon dioxide is organically modified, so that the dispersity of the silicon dioxide in a polylactic acid system is improved, the interface binding force of the silicon dioxide is improved, and the mechanical property of a polylactic acid material is improved; various antibacterial components are introduced, so that the antibacterial property of the polylactic acid material can be effectively improved.

The invention provides an amorphous copper nanolayer coated spherical porous silicon composite material and a preparation method and application thereof.The preparation method includes the step that the surface of spherical porous silicon is coated with an amorphous copper conductive nanolayer through a simple solution method.On the basis of the principle of replacement reaction, aluminum in aluminum-silicon alloy is replaced with copper to be coated on the surface of silicon, and the amorphous copper nanolayer coated spherical porous silicon composite material is obtained. And meanwhile, the rate of the replacement reaction is slowed down by utilizing different reaction activities of copper chloride in an organic solvent, so that the spherical morphology is kept, and meanwhile, the surface of silicon can be coated with a layer of amorphous copper nano layer with high conductivity. The invention also provides a preparation method of the material. Tests find that the conductivity of the material can be effectively improved due to the excellent conductivity of the copper nano layer, and the volume expansion effect of the material in the electrochemical cycle process can be effectively relieved due to the porous structure. Therefore, the combination of the two effectively improves the problems of poor conductivity and unstable structure of the silicon negative electrode material, and effectively improves the application performance of the silicon negative electrode material in the lithium ion battery negative electrode.

The invention discloses preparation of a bionic copper-based MOF nano-enzyme and application of the bionic copper-based MOF nano-enzyme in hydroquinone detection, and the bionic copper-based MOF nano-enzyme is prepared by the following method: dissolving terephthalic acid H2BDC and L-histidine His in N, N-dimethylformamide DMF to obtain a solution A; adding copper chloride CuCl2. 2H2O into the solution A obtained by C1, and stirring to form a uniform mixed solution; carrying out hydrothermal reaction on the mixed solution obtained from C2 for a certain time, centrifuging to obtain a solid precipitate, cleaning the solid precipitate, and drying to obtain the bionic Cu / His-MOF nano-enzyme; the invention also discloses an application of the sensor in hydroquinone detection. The bionic copper-based MOF nano-enzyme has the advantages of being simple and convenient to synthesize, high in substrate affinity, high in catalytic capacity and the like, and meanwhile, a rapid, sensitive and reliable HQ detection method is provided.

Natural renewable resources are used as raw materials, efficient and environment-friendly catalytic performance is achieved through multi-stage optimization, coconut shells, fruit shells, reeds and wood chips are used as base materials in the process, a channel template is introduced after fine crushing, a graded pore structure is constructed, and the mercury-free catalyst is prepared. Dynamic extrusion forming and program temperature control carbonization-activation technologies are adopted to form an active carbon skeleton with a high specific surface area, a pulsating pressure impregnation system is innovatively designed, ultrasonic vibration is combined to strengthen copper chloride solution permeation, deep and uniform loading of active components is realized, and a mixed pickling process is developed in a matched manner. Metal impurities are efficiently removed through the synergistic effect of hydrochloric acid and citric acid, and the obtained catalyst has three-dimensional through pore channels and high-activity component dispersity, can replace a traditional mercury-containing catalyst to be applied to the fields of vinyl chloride synthesis and the like, remarkably reduces the risk of environmental pollution, improves the reaction selectivity and prolongs the service life of the catalyst, and is suitable for industrial production. And a technical support is provided for green transformation of the chemical industry.

The invention relates to the field of biological functional materials, and discloses a preparation method and application of a Cu-doped W18O49 nano-enzyme with near-infrared two-region photoresponse. The specific method is as follows: a solvothermal method is adopted, the Cu-doped W18O49 (xCu-W18O49) nano-enzyme is prepared by regulating and controlling the molar doping amount of a Cu element, taking tungsten chloride as a tungsten source, taking copper chloride dihydrate as a copper source and taking n-propyl alcohol as a reaction solvent. The crystallinity of the nano enzyme is good, and the nano enzyme shows remarkable glutathione oxidase (GSHOx) activity in a tumor microenvironment. Compared with W18O49, Cu doping enables enzyme activity to be remarkably improved, the problem of low activity generally existing in current cancer treatment nano-enzymes is effectively solved, and meanwhile the nano-enzyme has application potential in the aspect of CT imaging.

The invention discloses a difunctional electrocatalyst for carbon dioxide reduction and PET plastic oxidation and a preparation method and application of the difunctional electrocatalyst, and belongs to the field of application of electrocatalytic materials. The preparation method comprises the following steps: precipitating copper chloride and sodium hydroxide to obtain a precursor of copper hydroxide, and freeze-drying, washing and drying the precursor. The problem that the voltage required by the anode reaction is large when carbon dioxide is electrolyzed is solved. And meanwhile, the material has the advantages of excellent negative and positive electrode bifunctional activity and simultaneous generation of chemicals with high added value at the two electrodes, and has certain commercial application value. Meanwhile, the preparation method is simple, and technical feasibility is provided for large-scale preparation of fine chemicals through carbon dioxide reduction.

The invention discloses a method for producing mRNA (messenger ribonucleic acid) template plasmids by fermenting escherichia coli. When the recombinant escherichia coli is fermented and cultured, a seed solution of the recombinant escherichia coli is inoculated into a basic culture medium to be fermented and cultured until the OD600 value of fermentation liquor is 18-22, then a fed-batch culture medium is continuously added at the feeding rate of 5-15 mL / L / h to be subjected to continuous fed-batch fermentation culture, the basic culture medium contains 0.05-0.2 mmoL / L of ferric salt compound and 0.05-0.2 mmoL / L of copper chloride dihydrate, and the basic culture medium contains 0.05-0.2 mmoL / L of ferric salt compound and 0.05-0.2 mmoL / L of copper chloride dihydrate. The basal culture medium contains 10-15 g / L of copper chloride dihydrate and 100-300 mg / L of p-hydroxybenzoic acid, the carbon source of the basal culture medium contains 0.1-0.3 mmoL / L of a ferric salt compound, 0.1-0.3 mmoL / L of copper chloride dihydrate and 100-300 mg / L of p-hydroxybenzoic acid, the carbon source of the fed-batch culture medium contains 360-480 g / L of glycerol, and the ferric salt compound is one or more of ferrous citrate, ferric ammonium citrate or ferrous sulfate heptahydrate. According to the method, the yield and superhelix content of the mRNA template plasmids are improved by optimizing the culture medium formula and culture conditions, and large-scale production of the high-quality target mRNA template plasmids is facilitated.

The invention provides a chitosan-based hydrogel nano material as well as a preparation method and application thereof, and belongs to the technical field of chemical synthesis and biomedicine. The method comprises the following steps: firstly, dissolving pyropheophorbide A and copper chloride in a solvent, and carrying out heating reflux reaction to obtain PPA-Cu; then, the PPA-Cu is grafted to chitosan (CS), and CS-PPA-Cu is obtained; arginine is added into the prepared CS-PPA-Cu solution, and CS-PPA-Cu (at) Arg is obtained; finally, the CS-PPA-Cu-coated Arg and the prepared PF solution are mixed and stirred, standing is conducted at the room temperature, and the chitosan-based CS-PPA-Cu / PF-coated Arg hydrogel is obtained. The hydrogel nano material has excellent bioluminescence performance, and can specifically recognize the position of wound inflammation. The prepared hydrogel nano material has the combined antibacterial ability of photodynamic, photothermal and NO gas release, and achieves the effect of promoting wound healing.

The invention discloses an antibacterial dressing based on gallic acid-copper coated gamma-polyglutamic acid and a preparation method and application thereof, and belongs to the technical field of biomedicines.The preparation method comprises the steps that gallic acid and copper chloride dihydrate are dissolved in pure water according to the mass ratio of 3: 1, and stirring is conducted to form a solution I; stirring and reacting the solution I at 40 DEG C for 24 hours, centrifuging, collecting precipitate, washing with pure water, and freeze-drying to obtain gallic acid-copper nanoparticles; the gallic acid-copper nanoparticles and gamma-polyglutamic acid powder are mixed and dissolved in pure water according to the mass ratio of 3: 20, and after freeze drying, gallic acid-copper coated gamma-polyglutamic acid hydrogel powder is obtained. The gallic acid-copper coated gamma-polyglutamic acid hydrogel powder disclosed by the invention can absorb exudate near a wound and is subjected to in-situ gelation to form a hydration layer, so that damage to newborn tissues caused by frequent dressing replacement is avoided; it is verified that the healing promoting effect of the hydrogel can be remarkably enhanced through blue light adjuvant therapy, and the healing speed of infected wounds is remarkably increased.

The present invention discloses a nano copper-based catalyst, its preparation method, and its application in the electrocatalytic reduction of carbon dioxide and carbon monoxide. Copper chloride (or copper nitrate, copper acetate) is dissolved in ultrapure water, and a sodium borohydride solution is added dropwise. Stir at room temperature for 5-60 min, filter, and dry to obtain a nano copper catalyst. Further, through a displacement reaction, nano copper-palladium and copper-silver catalysts are obtained. The present invention is applied to the electrocatalytic reduction of carbon monoxide. In a membrane electrode assembly (MEA) electrolyzer, the Faraday efficiency of multi-carbon products (C2+) reaches up to 95%, the partial current density reaches up to 3 A cm-2, and the overall electrolyzer energy efficiency reaches up to 39%. It can stably electrolyze for 30 hours at 1 A cm-2. This nano copper catalyst is applied to the electrocatalytic reduction of carbon dioxide. In an MEA electrolyzer, the Faraday efficiency of C2+ reaches up to 66%, and the partial current density reaches up to 331 mA cm-2.

The application provides a kind of superfine copper powder and its preparation method and application, the preparation method of the above-mentioned superfine copper powder uses two-step liquid phase reduction method to prepare superfine copper powder, and improves process conditions, using dropwise feeding mode. Among them, the first step uses alkaline ascorbic acid solution to reduce copper chloride to cuprous chloride with narrow particle size distribution; the second step uses ferrous sulfate and sodium citrate as mixed reducing agent, and sodium citrate can also be used as a complexing agent, which helps to reduce the cuprous chloride to spherical, well-dispersed, uniform particle size distribution of superfine copper powder. At the same time, the raw materials used by the application are easy to obtain, the reaction process is mild, and organic solvents and toxic and hazardous reagents such as sodium borohydride and hydrazine hydrate are not needed, the preparation process has cost effectiveness, is friendly to the environment, and is suitable for industrial production.

The invention discloses a preparation method of a Cu3Sn alloy electrocatalyst and application of the Cu3Sn alloy electrocatalyst in urea synthesis. The preparation method comprises the specific preparation steps that glucose, dicyandiamide, copper chloride and stannous chloride dehydrate are ground and mixed to be uniform, and a material A is obtained; transferring the obtained material A into a tubular furnace, sintering for 2 hours at 420-500 DEG C in a hydrogen / argon mixed atmosphere, and naturally cooling to room temperature to obtain a material B; and uniformly grinding the obtained material B to obtain the Cu3Sn alloy electrocatalyst. The Cu3Sn alloy electrocatalyst can be used in a reaction system for co-reduction of nitrate and carbon dioxide into urea through electrocatalysis. Compared with a traditional industrial method, the method for preparing urea by catalyzing co-reduction of nitrate and carbon dioxide through the prepared Cu3Sn alloy electrocatalyst consumes greenhouse gas and does not discharge pollutants into air.

The invention provides a neutralization and utilization method of an acidic waste etching solution. The method comprises the following steps: mixing the acidic etching waste liquid with an ammonium bicarbonate solution; in the mixing process, the mixing temperature is controlled to be 40-60 DEG C, the pH value is adjusted to be 3.5-4.5, and slurry is obtained; separating the slurry to obtain copper oxychloride wet crystals and an ammonium chloride crude product solution; carrying out dechlorination treatment on the copper oxychloride wet crystals by using an alkaline solution, and filtering to obtain a copper oxide filter cake and chloride waste liquid; the temperature of the dechlorination treatment is 70-90 DEG C; performing post-treatment on the copper oxide filter cake to obtain copper sulfate; and carrying out precipitation treatment on the ammonium chloride crude product solution to obtain an ammonium chloride finished product solution. Wherein the step S3 and the step S4 have no sequence. According to the method, electroplating-grade copper sulfate and industrial-grade ammonium chloride products are prepared by using ammonium bicarbonate and realizing full utilization of anions and cations in the acidic etching waste liquid.

The invention relates to the field of copper plating solutions, and provides a low-stress chemical copper plating solution for a glass substrate and a preparation method of the low-stress chemical copper plating solution. The invention discloses a copper ion carboxyl chelate, which is composed of copper ion carboxyl chelate, 2, 2 '-bipyridine, polyethylene glycol-8000, lauryl sodium sulfate, a sodium carbonate buffer agent, deionized water and a pretreatment solvent, and the copper ion carboxyl chelate is prepared by chelating a polyacrylate-itaconic acid copolymer with copper chloride and then carrying out stepwise cross-linking with epichlorohydrin and N, N'-methylene bisacrylamide. The copper-bis-salicylaldehyde ethylenediamine complex is obtained by reacting bis-salicylaldehyde ethylenediamine with copper acetate, crystallizing and purifying. The preparation method comprises the steps of solvent premixing, chelating activation, staged additive integration, pH dynamic regulation and control and plating solution purification, through nitrogen protection, high-shear stirring and accurate pH regulation, the problems that a traditional chemical copper plating layer is high in stress and poor in conductivity are solved, and the method is suitable for high-precision glass substrate surface metallization.

The invention provides a carbon-supported platinum-cobalt-copper multifunctional alloy catalyst and a preparation method and application thereof, and belongs to the technical field of energy materials. Wherein the nanocarbon carrier solution is mixed with a chloroplatinic acid solution, a cobalt chloride solution and a copper chloride solution, a sodium hydroxide aqueous solution is added to adjust the pH value, ultrasonic dispersion and stirring are performed to obtain turbid liquid, and the molar ratio of platinum ions to cobalt ions to copper ions is 2: (0.5-1): (0.5-1); then, putting the turbid liquid into a reaction kettle, and reacting at 120-250 DEG C for 1-6 hours to obtain a black colloidal solution; then filtering, washing and drying the black colloidal solution to obtain black powder; and finally, carrying out acid treatment on the black powder, and grinding to obtain the carbon-loaded platinum-cobalt-copper multifunctional alloy catalyst. The catalyst is used for catalyzing an oxygen reduction reaction of a cathode in a hydrogen fuel cell and / or a methanol fuel cell, and / or catalyzing a methanol oxidation reaction of an anode in a direct methanol fuel cell.

The invention relates to the technical field of solar cells, and particularly discloses conductive paste for a solar cell, a preparation method of the conductive paste and an electrode. The conductive paste for the solar cell comprises the following components in percentage by weight: 88%-92% of carbon-based nano-copper particles, 4%-6% of glass powder and 4%-6% of an organic additive, the carbon-based nano-copper particles are prepared by reacting copper chloride with glucose and then calcining, the particle size is 52-100nm, and copper oxidation is inhibited by using a carbon layer; the organic additive is composed of a stabilizer, resin and an organic solvent according to a ratio of 1: 3: 9. The conductive material is prepared by mixing, dispersing, grinding and filtering, and can be prepared into a solar cell conductive material by silk-screen printing and high-temperature sintering. The conductive paste is low in cost, high in oxidation resistance and excellent in conductivity, and can replace silver paste to reduce the manufacturing cost of the solar cell, improve the performance and prolong the service life.

The preparation method comprises the following steps: adding sodium hydroxide into a D / L-cysteine ethyl ester hydrochloride aqueous solution to obtain a mixture, carrying out ultrasonic treatment until the solution is clarified to obtain a mixed solution A, and preparing a copper chloride dihydrate aqueous solution for later use; dropwise adding the mixed solution A into a copper chloride dihydrate aqueous solution in a water bath kettle to obtain a mixed solution B, and continuously stirring for reaction; and after the reaction is finished, centrifugally collecting the precipitate, and washing with water and ethanol. A one-pot self-assembly strategy is adopted, self-assembly is driven based on coordination of D / L-Cys.Oet.HCl and Cu < 2 + >, spherical and spiral supramolecular chiral nano-catalysts are constructed, and compared with the spherical and spiral supramolecular chiral nano-catalysts, the spherical and spiral supramolecular chiral nano-catalysts have obvious spatial asymmetry morphology, and have good application prospects. Therefore, the compound has a higher enantioselective catalytic effect on a chiral substrate dopa, and can be used for selectively catalyzing dopa molecules with specific configurations.

The invention discloses a method for preparing copper sulfate from PCB etching liquid, and belongs to the technical field of PCB etching liquid treatment.The method comprises the following steps that alkaline PCB etching waste liquid and acidic PCB etching waste liquid are mixed to obtain basic copper chloride precipitate; reacting the basic copper chloride precipitate with concentrated sulfuric acid to obtain a copper sulfate crude product; adding a hydrogen peroxide solution into the copper sulfate crude product solution, stirring and reacting for 0.5-2 hours, adding a precipitator to adjust the pH value to 3.5-4, and carrying out solid-liquid separation to obtain an impurity-removed solution; the impurity removal solution is introduced into an adsorption column filled with modified activated carbon, then evaporation concentration, cooling crystallization and reduced-pressure suction filtration are carried out, and copper sulfate is obtained.According to the method, the processes of acid-base neutralization, oxidation impurity removal, adsorption impurity removal and recrystallization are adopted, and the low-cost and efficient recovery and purification technology is achieved; and the recovery efficiency is improved to the maximum extent and the cost is controlled while the high purity of the product is ensured.

The invention is suitable for the technical field of environment and food safety detection, and provides a copper-based compound / graphene oxide nano-enzyme and a preparation method and application thereof.The preparation method comprises the following steps that cysteamine hydrochloride and copper chloride dihydrate are dissolved in deionized water, stirring is conducted under nitrogen protection, the pH is adjusted, then the mixed solution is transferred into an oil bath to be continuously stirred, and the copper-based compound / graphene oxide nano-enzyme is obtained; the preparation method comprises the following steps: preparing a two-dimensional copper-based compound, centrifuging, collecting precipitate, washing and drying to obtain the two-dimensional copper-based compound, dispersing the two-dimensional copper-based compound and graphene oxide in ultrapure water to prepare dispersion liquid, mixing the two-dimensional copper-based compound dispersion liquid and graphene oxide dispersion liquid, stirring at room temperature, and centrifugally drying to obtain the composite nano-enzyme. According to the method, the contradiction that the nano-enzyme activity pH is not matched with the optimal reaction pH of the formaldehyde is solved, the detection sensitivity and the anti-interference capability are remarkably improved, and an efficient technical scheme is provided for rapid and quantitative detection of the formaldehyde in multiple scenes such as food and environment.

The invention relates to a preservative film loaded with antibacterial nanoparticles and a preparation method and application thereof, the preservative film comprises a film substrate and a load loaded on the film substrate, the load is perfume nanoparticles coated with alizarin-copper metal polyquinone, and the film substrate is a carboxymethyl cellulose-gelatin mixed film. The preparation method of the preservative film comprises the following steps: adding a cinnamyl aldehyde ethanol solution and a copper chloride aqueous solution into an alizarin-F127 mixed solution to prepare the alizarin-copper metal polyquinone coated perfume nanoparticles, mixing the perfume nanoparticles into a carboxymethyl cellulose-gelatin mixed film solution, pouring the mixture into a mold, drying, and demolding to obtain the preservative film. Compared with the prior art, the spice nano-particles prepared by the method disclosed by the invention can release the antibacterial spices under the acidic condition and change the color at the same time, so that the purposes of prolonging the shelf life of food and monitoring the environmental change in a package are achieved. The invention opens up a new path for the application of the multifunctional intelligent preservative film.

The invention provides a polyvinyl alcohol / chitosan composite compression hemostatic sponge with an antibacterial function and a preparation method thereof, and belongs to the technical field of medical materials. The polyvinyl alcohol / chitosan composite compression hemostatic sponge with the antibacterial function, provided by the invention, comprises a dual-network hydrogel structure formed by carboxymethyl chitosan and aldehyde polyvinyl alcohol; the double-network hydrogel structure has high stability and fixity, so that the composite compression hemostatic sponge has excellent stability. Raw materials used in the invention comprise carboxymethyl chitosan, formylated polyvinyl alcohol and antibacterial peptide, and the three raw materials are connected through covalent bonds and ionic bonds to form a dual-network hydrogel structure. By introducing gallic acid and copper chloride, a metal-organic network structure can be formed, the mechanical stability of the composite compression hemostatic sponge can be further improved, and the antibacterial performance of the composite compression hemostatic sponge can be further improved.

The invention provides a preparation method of a low-load RuPdPt ternary noble metal electrocatalyst. The preparation method comprises the following steps: etching foamed nickel in a hydrochloric acid solution, and soaking the etched foamed nickel in a mixed solution containing ferric chloride, copper chloride and sodium chloride for 3-12 hours to obtain a NixFeyCuzOOH substrate; ruthenium salt, platinum salt and palladium salt are mixed and then ground, water is added to prepare a mixed solution, then an alcoholic solution of dimethylglyoxime disodium salt octahydrate is added, and a precious metal mixed solution is formed after ultrasonic dispersion; the preparation method comprises the following steps: soaking a NixFeyCuzOOH substrate in a noble metal mixed solution, soaking for 1-6 hours under stirring and heating conditions, washing an obtained product with water, and drying to obtain the RuPdPt-NixFeyCuzOOH composite catalyst. According to the invention, the noble metals Ru, Pd and Pt are combined with the substrate NixFeyCuzOOH nanosheets through M1-M2-O bonds, so that monatomic-cluster sites of the noble metals Ru, Pd and Pt are effectively anchored, and the stability of the catalyst at high current density is greatly improved.

The invention relates to a preparation method of a novel anti-freezing rewarming antibacterial medical gel dressing, belongs to the field of composite material-based hydrogel, and is applied to prevention and treatment of frostbite of field operating personnel in high-cold regions. The preparation method comprises the following step: reacting anhydrous copper chloride, polyvinylpyrrolidone and thiourea to obtain copper sulfide. The preparation method comprises the following steps: dispersing copper sulfide, polymerizing dopamine hydrochloride in an alkaline oxygen-containing environment to gather on the surface of the copper sulfide so as to form polydopamine copper sulfide (PDA-coated CuS), adding N 'N-methylene bisacrylamide and ammonium persulfate, stirring, pouring into a mold, and polymerizing in an environment of 60 DEG C, thereby obtaining PDA-coated CuS / Pro / PAM gel. CuS and PDA are combined, so that the biocompatibility and antibacterial property of CuS are enhanced, the photo-thermal property of dopamine is improved, and proline is used as an antifreeze agent to destroy hydrogen bonds of water molecules and inhibit formation of ice crystals. The medical gel dressing has the beneficial effects that the medical gel dressing with the anti-freezing, rewarming and antibacterial functions can be used in a low-temperature environment of-24 DEG C, and a good rewarming environment is provided for a frostbite part.

The invention relates to the technical field of coatings, in particular to a photo-thermal super-hydrophobic coating as well as a preparation method and application thereof. The invention provides a photo-thermal super-hydrophobic coating. The photo-thermal super-hydrophobic coating is prepared from the following raw materials in parts by weight: 3 to 5 parts of organic silicon polysilazane, 5 to 7 parts of methyl phenyl polysiloxane, 3 to 5 parts of vinyl chloride and vinyl acetate copolymer, 4 to 6 parts of modified ferroferric oxide, 5 to 7 parts of fluorinated multi-walled carbon nanotube, 4 to 6 parts of fluorinated black titanium dioxide, 59 to 82 parts of organic solvent and 0.02 to 0.2 part of defoaming agent. Wherein the modified ferroferric oxide is ferroferric oxide coated with copper chloride. The photo-thermal super-hydrophobic coating provided by the invention has ultrahigh hydrophobic performance and good photo-thermal conversion performance, the water contact angle can reach 155 degrees or above, the rolling angle is less than 10 degrees, the surface hardness of the coating is 4H or above, the adhesive force is grade 0, and the comprehensive performance is excellent.

The invention discloses a process for adsorbing and separating ethane by using catalytic dry gas, and aims to solve the technical problems that in the prior art, the ethane adsorption effect is relatively poor, an adsorbent is not easy to regenerate, the chemical stability is relatively poor, next adsorption can be carried out only after desorption is completed after adsorption saturation, and the working efficiency is low. The process comprises the following steps: S1, pretreating dry gas; s2, preparing an adsorbent; and S3, the dry gas pretreated in the S1 is pressurized to the pressure condition required by the process through a compressor, and then the dry gas is cooled through circulating water and low-temperature refrigerant water in sequence. According to the process, the adsorbent is prepared by loading copper chloride on activated carbon, the prepared adsorbent has a better adsorption effect on ethane, the adsorbent can be regenerated and is good in chemical stability, and through the design of the two adsorption beds, one adsorption bed performs desorption while the other adsorption bed performs adsorption operation; and continuous adsorption and desorption operation can be realized, and the working efficiency is higher.

The invention relates to the technical field of energy systems, in particular to a methane gradient utilization system based on SOFC (solid oxide fuel cell) and copper chloride circulation, comprising a methane reforming and SOFC power generation unit for converting methane fuel into electric energy and combusting anode tail gas to generate high-temperature flue gas; the copper-chlorine circulating hydrogen production unit is connected with a high-temperature flue gas pipeline of the methane reforming and SOFC power generation unit, heat energy of the high-temperature flue gas is used for driving a copper-chlorine thermochemical circulating reaction, and hydrogen is prepared by taking water as a raw material; and the waste heat power generation and recovery unit is connected with a cathode tail gas pipeline of the methane reforming and SOFC power generation unit and a tail gas outlet pipeline of the copper chloride circulation hydrogen production unit, and is used for carrying out power generation and heat supply on waste heat in a cascade recovery system. According to the system, grade alignment and gradient utilization of energy are achieved, high-temperature waste gas of the SOFC system is sequentially used for driving copper-chlorine hydrogen production, ORC power generation and hot water supply, and the comprehensive utilization efficiency of energy is remarkably improved.

The present invention discloses a PVA-nano copper composite material, its preparation method and application, which relate to the detection of amino anthraquinone drugs. The method comprises the following steps: 1) Citric acid and histidine are uniformly mixed in proportion, deionized water is added and dissolved by ultrasonic to obtain a reaction solution, and the reaction is carried out at an oven temperature of 150-250 °C for 3-6 h to obtain histidine-functionalized graphene quantum dots; 2) Weigh PVA and add it to deionized water, stir and boil until completely dissolved to prepare a PVA solution; add the histidine-functionalized graphene quantum dots to the PVA solution; adjust the pH to neutral with NaOH, and dropwise add a copper chloride solution under stirring; stir for 80-120 min, add 3% borax to make the mixture into a gel, and freeze-dry; 3) The freeze-dried gel is calcined in an inert gas atmosphere to obtain a PVA-nano copper composite material. The PVA-nano copper composite material is used for detecting amino anthraquinone, and the detection limit is as low as 3×10<supgt;−9< / supgt; mol / L, with high sensitivity.

A high-entropy nano-array for electrocatalytic nitrate reduction coupling waste plastic conversion is prepared by the following method: (1) immerse the nickel foam into a hydrochloric acid solution to remove the surface oxide layer and oil stains, rinse with deionized water / ethanol three times, and dry for subsequent use; (2) solid powders of sodium chloropalladate, platinum acetylacetate, nickel chloride hexahydrate, copper chloride dihydrate, silver trifluoroacetate and tungsten hexacarbonyl are poured into an N-N dimethylformamide solution, ultrasonic is used to dissolve the solid powders, then glacial acetic acid and the treated nickel foam are added to the above solution, and after ultrasonic, heating in an oven is carried out, after the reaction is completed, water and ethanol solution are used for alternate washing, and drying is carried out, and the high-entropy nano-array catalyst is obtained. A preparation method of a high-entropy nano-array for electrocatalytic nitrate reduction coupling waste plastic conversion is provided. The high-entropy nano-array has excellent electrocatalytic activity and stability.

The invention relates to the technical field of copper powder production, in particular to a method for preparing high-purity low-chlorine copper powder by taking acidic copper chloride etching waste liquid as a raw material. According to the method for preparing the high-purity low-chlorine copper powder by using the acidic copper chloride etching waste liquid as the raw material, hydrazine hydrate is added into the acidic copper chloride etching waste liquid, then a sodium hydroxide solution is used for adjusting the pH value, then heating treatment, suction filtration centrifugation, washing and drying are conducted, a first product is obtained, then first product dispersion liquid is prepared, and the high-purity low-chlorine copper powder is prepared. And adding an alkaline solution into the mixed solution, mixing, carrying out suction filtration, centrifuging, washing and drying to obtain a second product, finally preparing a second product dispersion liquid, and preparing the high-purity low-chlorine copper powder by using the obtained second product dispersion liquid. The high-purity low-chlorine copper powder prepared by the preparation method disclosed by the invention not only has better purity, but also has excellent apparent density, so that the quality of the high-purity low-chlorine copper powder is effectively ensured.