The invention discloses a carbon-based confinement type catalyst as well as a preparation method and application thereof. The catalyst comprises a
sludge carbon substrate, and carbon nanotubes and active metals covering the surface of the substrate, the active
metal comprises Fe and Ni; ni is doped in the
carbon nanotube to form a confinement structure; fe is loaded outside the carbon nanotubes. The active
metal of the carbon-based confinement type catalyst is confined in a
superstructure carbon
nanostructure covering the surface of a
carbon substrate, so that the hydrothermal oxidation efficiency can be effectively improved, the degree of
cracking of
sludge extracellular polymeric substances is improved, deep
cracking of
sludge is realized, and the risk of secondary
pollution caused by loss of the active
metal is reduced; the catalyst can selectively oxidize macromolecular organic matters released by sludge disintegration, the product selectivity of micromolecular
carboxylic acid is improved to be higher than 95% by a confinement structure, the micromolecular
carboxylic acid can be further utilized as a
carbon source, the treated supernate can be used as a composite
carbon source to be applied to the
biochemical process of
sewage treatment, and
resource utilization is realized; the catalyst can realize HTO treatment of sludge at 200 DEG C or below, and does not generate biotoxic by-products in the sludge treatment process, and the treated product can be used as a high-quality
carbon source.