The application provides a waste plastic hydrogenation catalytic
cracking oil refining method and application. The catalyst carrier is ZSM-5
molecular sieve, and the
active center loaded is a
transition metal; in a
hydrogen atmosphere, a high-temperature static
cracking process of plastic and catalyst mixing. The reaction of
polyethylene on the catalyst loaded with
transition metal follows the
carbon ion theory and the free radical
catalytic pyrolysis. The ZSM-5
molecular sieve provides protons for the reaction, the protons are combined with
polyethylene and then short chain olefins are generated through the
carbon ion theory. However, due to the too large molecule, the
polyethylene cannot directly enter the inside of the ZSM-5
molecular sieve channel, so the molten polyethylene will first react under the
catalysis of the
active center on the surface, depolymerize into products with small molecular weight, then enter the channel to react, and after entering the inside of the channel, secondary reactions such as beta-scission,
isomerization, aromatic ring formation and the like occur. The method can relatively safely and environmentally protect convert the plastic into
crude oil, the
reaction temperature is low, and the catalyst effect is remarkable.