486 results about "Nanoporous" patented technology

The invention discloses a photovoltaic POSS (polyhedral oligomeric silsesquioxane)-containing antireflection film coating liquid and a preparation method thereof, the coating liquid comprises the following raw materials in parts by weight: 80-100 parts of modified emulsion, 10-15 parts of modified graphene, 3-5 parts of sodium dodecyl benzene sulfonate, 1-3 parts of triethylene tetramine and 40-60 parts of deionized water, a modified additive in the coating liquid contains a polyhedral oligomeric silsesquioxane structure, the polyhedral oligomeric silsesquioxane structure can form uniformly-distributed nanopores and is matched with a two-dimensional honeycomb lattice structure in the graphene oxide, the surface roughness can be increased, the microstructure can scatter incident light and reduce specular reflection, so that the surface light transmittance is improved, and meanwhile, the modified additive molecule contains a fluoroalkyl structure, so that the surface light transmittance is improved. The fluoroalkane has a high refractive index, so that light reflection can be reduced, and the light transmittance is further improved.

The invention discloses a thermal insulation material with enhanced thermal insulation performance and a processing method, and relates to the technical field of thermal insulation material processing. Comprising the following components in parts by weight: 100 to 200 parts of a nanopore matrix material, 20 to 120 parts of expanded perlite, 10 to 350 parts of polystyrene, 30 to 300 parts of polyurethane, 100 to 500 parts of nano titanium dioxide, 10 to 60 parts of graphene, 10 to 40 parts of silica sol and 1 to 55 parts of ferric oxide. A multi-stage pore structure is constructed through a nanopore matrix and expanded perlite, closed-cell foam of polystyrene and polyurethane is combined, and nano titanium dioxide and graphene functional filler are matched, so that the heat conductivity coefficient is reduced to 0.018 W / (mK) or below, the heat insulation efficiency is remarkably improved, nanoscale homogenization is ensured through high-shear dispersion in the process, the porosity is reserved through freeze drying, and the heat insulation performance is greatly improved. The microcapsule self-repairing layer can repair more than 85% of cracks, the service life is greatly prolonged, and in the aspect of function integration, the material has A-level fireproof, waterproof and weather-proof characteristics and heat preservation and heat insulation performance.

A lightweight radiation shielding material. A carbon nanotube forest is embedded in a matrix comprising nanoparticulates, such as nanoparticles, carbon nanotubes, or graphene nanosheets. The nanoparticulates can be low atomic number (low-Z) or high atomic number (high-Z). The matrix can be a solidified polymer, epoxy, resin, or ceramic precursor, for example silicon carbide. The radiation shield can shield an object from radio frequency interference (RFI), lightning, electromagnetic interference (EMI), an electromagnetic pulse (EMP), gamma rays, X-rays, neutrons, and / or protons. The nanoforest is disposed on a conductive base with sufficient in-plane electrical conductivity to provide an effective conductive path for currents induced by radiation absorption. The base can be a second nanoforest comprising horizontally-oriented carbon nanotubes, which makes the shield particularly lightweight, as low as 10% of the mass of aluminum that provides equivalent shielding. The base can be adhered to an object to be shielded.

A ternary positive electrode material modified with a glassy metal-organic framework, and a preparation method therefor and the use thereof. The ternary positive electrode material modified with a glassy metal-organic framework is obtained by grinding and mixing a ternary positive electrode material and a metal-organic framework, and then subjecting same to a melt quenching treatment under a protective atmosphere. Forming a crack-free glassy metal-organic framework containing nano / sub-nano pores on a surface of the ternary positive electrode material can significantly improve the stability of the ternary positive material, alleviate the dissolution of transition metals, and ultimately improve the electrochemical performance of batteries and prolong the service life of the batteries.

The invention provides a nanometer casting and doping double-strategy improved lanthanum manganese perovskite catalyst, a preparation method thereof and application of the nanometer casting and doping double-strategy improved lanthanum manganese perovskite catalyst in degradation of halogenated organic pollutants. The preparation method of the nanometer casting and doping double-strategy improved lanthanum manganese perovskite catalyst comprises the following steps: taking transition metal salt as a doping agent, and mixing transition metal salt, lanthanum salt, manganese salt and a complexing agent in a solvent to form a mixed solution; then adding nano silicon dioxide, stirring and heating to a gel state, and drying to obtain a solid precursor; calcining the solid precursor to obtain a calcined product which comprises nano silicon dioxide and transition metal doped lanthanum manganese perovskite; and adding the calcined product into an alkaline solution, and etching to remove the nano silicon dioxide to form a nano pore channel structure so as to prepare the nano casting and doping double-strategy improved lanthanum manganese perovskite catalyst. The nano casting and doping double strategies have a synergistic improvement effect on lanthanum manganese perovskite, and the catalytic performance of the obtained catalyst is remarkably superior to that of a single-strategy improved catalyst.

The invention relates to the field of material surface treatment, and discloses a silica gel and metal combined treatment process which comprises the following steps: S1, ultra-short pulse laser is adopted to machine a three-dimensional micro-nano composite structure on the surface of a titanium alloy, the structure comprises a periodic groove array and surface nano holes, and the surface roughness Ra of the titanium alloy is larger than or equal to 5 microns; and S2, a titanium nitride transition layer and a siloxane self-assembly molecular layer are sequentially formed on the roughened titanium alloy surface through atomic layer deposition, and a gradient chemical interface is formed. According to the method, the micro-nano composite structure is processed through ultra-short pulse laser, the interface mechanical embedding area is remarkably increased, the two-dimensional rough limitation of a traditional sand blasting process is broken through, deep barb-shaped anchoring is achieved, the anti-stripping capacity is greatly enhanced, gradient chemical bonding is formed by the atomic layer deposition titanium nitride transition layer and the amino self-assembly molecular layer, and the anti-stripping performance is improved. The thermal expansion difference is effectively buffered, and the interface high-temperature resistance is improved.

The invention discloses a preparation method of a perovskite active layer, a perovskite battery and a perovskite material, and belongs to the technical field of perovskite batteries. According to the invention, bisphosphonate is added when the perovskite active layer is prepared, and the bisphosphonate is obtained by carrying out a deprotonation reaction on 1-aminodecane-1, 1-diphosphonic acid and methylamine, formamidine iodine or cesium carbonate. The bisphosphonate can be anchored on the surface of the substrate and form a self-assembled monomolecular structure, a simple and effective coating process is realized, the bisphosphonate structure of the bisphosphonate is beneficial to anchoring on the substrate, the possibility and effectiveness of anchoring the substrate are increased, the combination of the perovskite active layer and the substrate is enhanced, the formation of nano-pores is reduced, and the photoelectric conversion efficiency is improved. In addition, the introduced cations MA < + >, FA < + > and Cs < + > not only can enhance the self-assembly capability of the bisphosphonate, but also can be used as nucleating agents to promote the growth of perovskite crystals and improve the quality of the perovskite crystals.

The invention discloses a cellulose paper-based diaphragm for a zinc-iodine battery as well as a preparation method and application of the cellulose paper-based diaphragm. The diaphragm is of a three-layer composite structure and comprises a matrix layer formed by paper pulp fibers such as softwood pulp, hardwood pulp, bamboo pulp or straw pulp through a wet papermaking technology, and compact functional layers which cover the two sides of the matrix layer and are formed by oxidized nanocellulose (TOCN). The preparation method mainly comprises the following steps: preparing the paper-based diaphragm matrix through wet papermaking, coating the two sides of the paper-based diaphragm matrix with TOCN aqueous dispersion, and finally carrying out hot-pressing drying treatment to enable the three layers to be tightly combined. According to the invention, the nano aperture and the surface negative electricity functional group of the TOCN layer are utilized, so that physical blocking and electrostatic repulsion of polyiodide ions can be realized at the same time, and the shuttle effect is effectively inhibited; and the uniform pore channels can guide zinc ions to uniformly deposit and inhibit dendritic crystal growth. The diaphragm is green in raw material, simple in process and low in cost, and the cycle life and coulombic efficiency of the battery can be remarkably improved when the diaphragm is applied to the zinc-iodine battery.

The invention belongs to the technical field of battery diaphragms, and provides a composite diaphragm and a preparation method thereof, and a secondary battery, the composite diaphragm comprises a base membrane and a gradient aperture coating arranged on at least one surface of the base membrane; the gradient aperture coating is prepared from a self-polymerized microporous polymer; the gradient aperture coating comprises a nanopore layer and a composite pore layer, and the nanopore layer is located between the base membrane and the composite pore layer; the nanopore layer comprises nanopores, and the composite pore layer comprises micron pores and nanopores which are interspersed with each other. Through the design of the gradient aperture coating, the composite diaphragm has an excellent blocking effect of transition metal cations and large-volume anions, meanwhile, the lithium ion transference number is high, the internal resistance is relatively low, the electrolyte wettability and the heat resistance are excellent, the cycle performance of the secondary battery comprising the composite diaphragm can be improved, and the service life of the secondary battery can be prolonged.

The invention relates to a high-gloss black decorative glass prepared from sludge incineration ash by an all-electric melting method. The high-gloss black decorative glass comprises the following raw material components in percentage by mass: 75-79% of fly ash, 5-7% of calcium carbonate, 9-10% of sodium carbonate, 5-6% of potassium alkali, 1-1.4% of boric acid, 0.03-0.04% of porous carbon, 0.06-0.08% of semi-coke powder, 0.16-0.22% of cobaltosic oxide, 0.1-0.2% of cerium dioxide, 0.04-0.06% of neodymium oxide, 0.5-0.7% of waste zircon brick powder and 0.03-0.05% of yttrium oxide. The dedusting ash is electrostatic dedusting ash collected by incineration of filtered sludge in a municipal sewage treatment plant, and belongs to hazardous waste; the porous carbon is rich in a hierarchical pore structure of sub-nano pores (0.5-1.0 nm). According to the method, a closed-loop production mode that waste is used for treating waste is constructed, high-added-value decorative materials are produced while energy consumption is reduced, and environmental protection investment is converted into economic benefits.

The invention relates to a multilayer double-gradient nanopore resin-based composite material with strong interlayer bonding and a preparation method thereof, and the preparation method comprises the following steps: injecting first high-porosity nanopore resin into a first low-volume-density fiber preform to obtain a first low-density layer; surface tension weakening treatment is conducted on the first low-density layer, then a second low-volume-density fiber prefabricated body is laid on the first low-density layer, second high-porosity nanopore resin is injected, and a double-layer double-gradient nanopore resin-based composite material with strong interlayer combination is obtained; and surface tension weakening, glue injection, curing and drying treatment are cyclically carried out, the nanopore resin with the residual porosity decreasing progressively is injected into the residual fiber prefabricated body with the residual volume density increasing progressively, and finally the multilayer double-gradient nanopore resin-based composite material with strong interlayer combination is prepared. Compared with the prior art, the overall density of the material is reduced, and meanwhile the ablation resistance and the heat insulation performance of the material are improved.

The invention relates to a nanofiber membrane and a preparation method and application thereof, the preparation method comprises the following steps: (1) mixing polyurethane, nano lanthanum oxide, a waterproof agent and a solvent to obtain a spinning solution; (2) performing electrostatic spinning on the spinning solution to obtain an electrostatic spinning membrane; and (3) spraying the after-finishing liquid on the electrostatic spinning membrane, and then carrying out heating treatment to obtain the nanofiber membrane. Polyurethane is stretched into superfine fibers through an electrostatic spinning technology, an ultrahigh porous membrane similar to a spider web is prepared, billions of nanopores are formed in per square centimeter of the porous membrane, so that the porous membrane has high air permeability and waterproof and moisture-permeable performance, fibers are bound through a fiber bonding point technology, and the fiber bonding point technology is adopted, so that the waterproof and moisture-permeable performance of the membrane is improved. Therefore, the fabric has excellent washing resistance. The nano lanthanum oxide heating functional particles are added, so that the nanofiber membrane is endowed with heating and heat storage functions, and the washing resistance of the fabric is further improved.

The invention relates to a high-pressure hydrogen nano-pore permeability testing device and method based on double-chamber pressure balance, and belongs to the technical field of unconventional oil gas. The device comprises a high-pressure gas source, a pressurization module, a double-layer nested core reaction kettle module and a high-frequency data acquisition and safety monitoring module; by constructing a double-layer nested structure that inner cavity hydrogen is actively wrapped by outer cavity nitrogen and cooperating with an all-metal knife edge hard sealing device and a different flow pattern permeability calculation method, accurate measurement of the Ndarcy grade permeability of the compact cover rock is successfully achieved, the industrial pain point that a traditional device is inaccurate in measurement, unstable in measurement and unsafe is thoroughly solved, and the method is suitable for large-scale popularization and application. And key experimental technology guarantee and scientific data support are provided for closure evaluation of underground hydrogen storage engineering and exploration and development of natural hydrogen resources.

The invention relates to a while-drilling anti-collapse plugging agent for fractured stratums and a preparation and application method thereof, and belongs to the technical field of oil and gas drilling. The water-based drilling fluid comprises the following components: an intelligent response type hydrogel material, a nanopore adsorption material, a degradable microcapsule plugging material, an enhanced fiber material, a microencapsulated phase change material, a high-strength inorganic particle reinforcing agent, a rheology control agent and water or water-based drilling fluid. The preparation and application method comprises the following steps: mixing the intelligent response type hydrogel material, the enhanced fiber material and the nanopore adsorption material dry powder; adding the dry powder material into water or a water-based drilling fluid to form a solution; adding a degradable microcapsule plugging material and a microencapsulated phase change material into the solution; and adding the rheology control agent and the high-strength inorganic particles, and uniformly stirring to obtain the anti-collapse plugging agent while drilling. And entering formation fractures while drilling. The plugging agent has remarkable flowability, cohesiveness and durability, can adapt to cracks of different sizes of complex fractured stratums, and is high in plugging success rate.

The invention belongs to the technical field of coatings, and discloses a 600 DEG C heat insulation coating containing In2O3 and rutile type TiO2 aerogel and a preparation method of the 600 DEG C heat insulation coating. The coating is composed of an organic-inorganic compound adhesive, In2O3 at rutile type TiO2 aerogel, hollow glass beads, HAP ultra-long nanowires and auxiliaries, the aerogel is prepared by combining sol-gel with CO2 supercritical drying, and the aerogel is calcined at 800 DEG C to form a rutile crystal form. The compound adhesive is prepared from alkaline silica sol, modified organic silicon emulsion and a silane coupling agent through hydro-thermal synthesis. The coating is prepared by dispersing all the components at a high speed, heat conduction is inhibited by using aerogel nanopores, infrared radiation is reflected synergistically by rutile TiO2 and In2O3, and heat convection is blocked by a lock catch structure formed by hollow glass beads and HAP nanowires. The thermal conductivity of the obtained coating at 600 DEG C is as low as 0.035-0.044 W / (m.K), the coating has excellent temperature resistance, thermal shock resistance and full-wave band heat reflection capacity, and the technical problems of high-temperature phase change, structural collapse and poor thermal stability of a traditional coating are solved.

The invention relates to the technical field of microcosmic measurement, and discloses a morphology construction method, device and equipment of a nanoporous material and a medium, and the method comprises the following steps: obtaining profile data of the nanoporous material; determining a baseline of the profile data based on the profile data; based on the profile data and the base line, pore parameters are obtained, and the pore parameters comprise the pore diameter, the pore depth and the porosity; and based on the pore parameters, constructing the morphology of the nano-pore material. According to the method, the limitation of a traditional measurement method is effectively overcome, the complete three-dimensional shape of the nano-porous material can be constructed, and the method is also suitable for various nano-porous materials including but not limited to porous media such as energy storage materials, catalytic materials, biomedical materials and shale.

The embodiment of the invention discloses a preparation method of a nuclear track membrane with orderly arranged nuclear micropores. The preparation method of the nuclear track membrane with orderly arranged nuclear micropores comprises the following steps: preparing a single-pore membrane; preparing a nuclear track membrane with two holes at a certain interval by utilizing a plurality of single-hole nuclear track membranes; a plurality of two-hole nuclear track membranes are used for preparing a four-hole nuclear track membrane which has a certain hole distance and is arranged in order, and so on, so that the required nuclear track membrane with nanoholes arranged in order is prepared. Nuclear micropores of a nuclear track membrane prepared by a traditional method are uncontrollable in number and disordered in distribution, and the nuclear track membrane plays an important role in multiple fields such as medicine, military industry and nuclear technology, such as production of semi-permeable membranes and wave-absorbing materials. No matter what membrane material is, the production quality of the nuclear track membrane can be improved by the method provided by the invention. A novel probe of a radiation detector can be manufactured by clamping a layer of nuclear track membrane made of an insulating material between two layers of nuclear track membranes made of conductive materials prepared by the method. Or conductive layers are plated on the two surfaces of a film made of an insulating material, and nuclear micropores which are arranged in order are punched on the film by using the method, so that the probe of the radiation detector of the same type can be manufactured. Nuclear track membranes with different pore diameters and pore taper angles are overlaid and arranged in a staggered manner, so that the range of the wavelength of electromagnetic waves absorbed by the wave-absorbing material is expanded.

The invention provides a heterostructure salinity difference energy conversion film based on HOF / two-dimensional mesoporous carbon as well as a preparation method and application of the heterostructure salinity difference energy conversion film. The salinity difference energy conversion film comprises a two-dimensional mesoporous carbon layer serving as a hydrophobic layer and a hydrogen bond organic framework layer which covers one surface of the hydrophobic layer and serves as a hydrophilic layer, wherein the two-dimensional mesoporous carbon layer is formed by compounding a two-dimensional mesoporous carbon material with regular nanopores and aramid nanofibers; the hydrogen bond organic framework layer is formed by compounding a hydrogen bond organic framework material and aramid nanofibers; the heterogeneous Janus structure salinity gradient energy conversion membrane is constructed by adopting a hydrogen bond organic framework and a two-dimensional mesoporous carbon material, and when the heterogeneous Janus structure salinity gradient energy conversion membrane is applied to salinity gradient energy conversion, high ion selectivity, high structural stability and high ion migration flux can be considered.

The invention discloses an organic-inorganic mutually-embedded space structure AAO / PVDF composite coating and a preparation method thereof, based on a hard template-soft modification technology, a hard porous anodic oxidation aluminum oxide layer is obtained on the surface of an aluminum alloy; injecting a polyvinylidene fluoride (PVDF) solution into the nano pore channels of the anodic aluminum oxide layer through a vacuum pressure impregnation process and a solution casting method, curing to form a nano column array structure, and performing high-pressure polarization treatment on PVDF nano columns by adopting a corona polarization mode; and the antibacterial, antifouling and anticorrosive AAO / PVDF composite coating based on environment excitation charge response of the piezoelectric effect can be prepared. The AAO / PVDF coating disclosed by the invention has excellent antibacterial property, strong interface bonding and stable piezoelectric property, and PVDF effectively seals nano pore channels of AAO, so that the anti-corrosion property of the aluminum alloy is remarkably improved, and the anti-corrosion and anti-fouling process has the characteristics of being long-acting, environment-friendly and efficient.