The invention belongs to the field of nano materials, and discloses a method for preparing nano bismuth oxide by using a liquid phase precipitation method in the presence of lignosulfonate serving as a surfactant. According to the technical scheme of the method, lignosulfonate is used as a surfactant and bismuth nitrate and sodium hydroxide are used as raw materials; the concentration of sodium lignosulfonate is adjusted to 2.5-7.5 g/L, and then nano bismuth oxide is prepared by using a liquid phase precipitation method. In the process of precipitation, the addition of different amounts of surfactants can achieve a steric hindrance effect, so that the direct contact between particles is reduced, the surface tension is lowered, and the surface energy is reduced, thereby lowering the aggregation degree of a dispersion system, caused by the action of a hydrogen bond or VDW (Van der Waals' force), keeping the dispersion system stable realtively, and effectively controlling the size and morphology of nanoparticles. The method for preparing nano bismuth oxide by using a liquid phase precipitation method disclosed by the invention is low in cost and simple to operate, and prepared products are uniform in particle distribution, high in particle properties, good in particle size dispersity and good in morphology; therefore the method can be easily industrialized.