554 results about "Polymerization reactor" patented technology

The invention relates to the technical field of aramid fiber production, in particular to a heterocyclic aramid fiber liquid crystal spinning method which comprises the following steps: S1, preparation of heterocyclic aramid polymer powder: carrying out polymerization reaction on a diamine monomer, a third monomer and terephthaloyl chloride in a twin-screw polymerization reactor, after the reaction is finished, neutralizing with an alkaline substance, grinding, washing with water, and drying to obtain heterocyclic aramid polymer powder; s2, preparing the heterocyclic aramid fiber: dissolving the heterocyclic aramid polymer powder with concentrated sulfuric acid, filtering, defoaming to obtain a liquid crystal spinning solution, and performing a dry-jet wet-spinning process, namely spinning, solidifying and forming, washing with water, neutralizing, washing with water, drying and hot drafting to obtain the heterocyclic aramid fiber, a neutralizer used in the neutralization process in the step S2 is a weak base aqueous solution. The heterocyclic aramid fiber obtained by the spinning method has higher mechanical properties, few broken filaments and good flexibility, and can meet the application requirements of aerospace.

Embodiments of the present application are directed to supported catalyst systems that include a metal-ligand complex having the structure of formula (I).

The invention discloses flame-retardant anti-fouling copolymer nylon 6 and a preparation method and application thereof, and the preparation method comprises the following steps: adding a phosphorus-containing flame-retardant monomer, a silicon-containing reaction monomer, lactam, an initiator and a catalyst into a polymerization reaction kettle, and introducing nitrogen to replace air in the kettle; under the protection of nitrogen, firstly raising the temperature to 180-220 DEG C to carry out prepolymerization reaction, and then raising the temperature to 240-260 DEG C to carry out polymerization reaction; and after the polymerization reaction, removing water vapor in the system to react in a normal pressure state, then vacuumizing to react, filling nitrogen to recover to normal pressure after the reaction is finished, and discharging and cooling to obtain the flame-retardant and anti-fouling copolymer nylon 6. The phosphorus-containing comonomer and the silicon-containing comonomer are introduced into the copolymerized nylon, the intrinsic flame-retardant nylon material with high flame-retardant efficiency and permanent flame retardance is prepared through melt copolymerization at a relatively low introduction amount, and the intrinsic flame-retardant nylon material has certain hydrophobic and anti-fouling properties and also retains good mechanical properties and spinnability of the nylon material.

The present invention relates to a polylactic acid waste recovery system and recovery method in the technical field of environment-friendly regeneration. The system comprises a screw extruder, a depolymerization kettle, an intermediate kettle, a cracking kettle, a deacidification tower, a purification system, a pre-polymerization kettle, a polymerization reactor, a first devolatilization device, a second devolatilization device, a pelletizing system, and a vacuum system; an outlet of the screw extruder is connected to an inlet of the depolymerization kettle; the depolymerization kettle is connected to the intermediate kettle; an outlet of the intermediate kettle is connected to a feeding port of the cracking kettle by means of a second conveying pump; a gas phase outlet of the cracking kettle is connected to a gas phase inlet at the lower portion of the deacidification tower; a hammer condenser is arranged at the top of the deacidification tower; an outlet of the deacidification tower is connected to the purification system; the purification system is connected to the polymerization reactor by means of the pre-polymerization kettle; and the polymerization reactor is connected to a pelletizer by means of the first devolatilization device and the second devolatilization device. Such an apparatus is used for polylactic acid waste recovery, has high recovery efficiency, and can be used for obtaining high-molecular-weight polylactic acid. Additionally, a special catalyst is used for depolymerization, such that the depolymerization and cracking temperatures are reduced, the energy consumption is reduced, and racemization by-products in a lactide product are few.

The utility model discloses a polymerization reaction kettle with a dry powder catalyst feeding system. The polymerization reaction kettle comprises a polymerization reaction kettle body, a feeding system, an emptying system, a nitrogen feeding system, a raw material feeding system and a vacuumizing system. The feeding system comprises a catalyst sampler and a catalyst feeder which are communicated through a first catalyst feeding pipe; the catalyst sampler and the catalyst feeder are both communicated with the first catalyst feeding pipe through a first pipeline joint; the catalyst feeder and the polymerization reaction kettle are communicated with a second catalyst feeding pipe through a second pipeline joint; the polymerization reaction kettle and the catalyst feeder are both communicated with the emptying system; the nitrogen feeding system is communicated with the catalyst feeder and the polymerization reaction kettle; the raw material feeding system is communicated with the polymerization reaction kettle and the catalyst feeder; and the vacuumizing system is communicated with the polymerization reaction kettle. According to the polymerization reaction kettle with the dry powder catalyst feeding system, disclosed by the utility model, catalyst residues are reduced, and the catalyst feeding accuracy is improved.

A method for preparing direct melt-spun high-viscosity PBAT / low-viscosity PET two-component elastic fiber and a high-viscosity PBAT polymerization reactor. This method uses two production lines respectively used to produce a high-viscosity PBT melt and a low-viscosity PET melt, which are then spun. The high-viscosity PBAT production line comprises a first esterification reactor, a second esterification reactor, a first prepolymerization reactor, a second prepolymerization reactor, and a high-viscosity PBAT polymerization reactor. The polymerization reactor is designed with a special disc structure in a parallel two-shaft disc reactor, and the two shafts are rotated in opposite directions, improving the devolatilization effect and self-cleaning, significantly increasing the viscosity. By using this method, the cost is low and the production capacity is high, the process flow is shortened, the fiber strength can reach 2.55˜2.85 cN / dtex, the crimp shrinkage rate can reach 25%˜60%, and the crimp stability can reach 58%˜70%.

A continuous process for preparing a multimodal polyolefin composition made from or containing one or more antioxidants, including the steps of: preparing a multimodal polyolefin in form of a polyolefin powder, having a mass-median-diameter D50 in the range from 300 μm to 2500 μm, in a series of polymerization reactors; mixing the polyolefin powder and an organic peroxide without melting the polyolefin powder; melting and homogenizing the mixture within an extruder device; adding one or more antioxidants to the molten polyolefin composition; homogenizing the combination of molten polyolefin composition and antioxidant, thereby forming an antioxidant equipped molten polyolefin composition; and pelletizing the antioxidant equipped molten polyolefin composition.

The invention relates to a nylon 6 polymerization production method capable of fully recycling extractable oligomers, and relates to the technical field of nylon 6 polymerization production processes, the nylon 6 polymerization production method comprises a nylon 6 polymerization section, a nylon 6 slice extraction section, a nylon 6 wet slice drying section, an extract evaporation and concentration section and an extractable oligomer cracking and recycling section; in an extractable oligomer cracking and recycling section, by adjusting process conditions such as temperature, pressure and water content of an oligomer extraction concentrated solution, deep cracking of extractable substances is realized, and all cracking products can be recycled into a polymerization section for recycling, so that rapid accumulation of cyclic dimers in polymers is inhibited, no residues are generated in the polymerization process, and the production cost is reduced. Accumulation of cyclic dimers in a system can be effectively slowed down, the service life of a polymerization reactor is prolonged, and the quality of polymer products is improved.

The invention belongs to the technical field of polydextrose preparation, particularly relates to a polymerization reaction kettle for preparing polydextrose dietary fibers, and aims to solve the problems that raw materials are positioned in the reaction kettle and are not easy to fully and uniformly mix during stirring, so that the mixing effect and heat transfer effect of the raw materials are reduced, the reaction rate is too slow, and the product quality is influenced. According to the scheme, the device comprises a plurality of tool supporting frames, one sides of the tool supporting frames are fixedly connected with the same isolation hood body, one side of the isolation hood body is connected with a kettle body through bolts, one side of the kettle body is movably connected with a kettle body cover plate, and a mixing module is arranged on the kettle body cover plate. The polymerization reaction kettle for preparing the polydextrose dietary fiber has the advantages that raw materials in the reaction kettle are fully and uniformly stirred and mixed, and meanwhile, the fluidity of the raw materials is improved, so that the mixing effect and the heat transfer effect of the raw materials are improved, the reaction rate is increased, and the product quality is improved.

According to the meta-aramid continuous polymerization process and the innovative structure of the first reactor and the second reactor, the technological process of a newly-designed meta-aramid continuous polymerization device is introduced, a fixed tube plate type heat exchanger and the first reactor are combined into an efficient axial flow type polymerization reactor, and a static mixer is directly inserted into the lower part of a stirrer; reactants are quickly scattered and uniformly distributed when entering the reactor, the temperature of the reactor is effectively controlled, reaction heat is removed, and the flowing state in the reaction kettle is changed. A guide cylinder is additionally arranged at the lower part of a tube bundle, and an asymmetric and helical-surface paddle push-type stirrer is selected to push materials to circularly flow upwards in an inner tube nest and downwards in an outer tube nest, so that vertical circulation is formed. The second reaction kettle adopts a stirrer without a through shaft in the center, inner and outer double helical ribbons and a scraper, so that a flowing dead zone is eliminated, and the mixing of high-viscosity materials is solved. The added three-way ball valve and return line are used for cooling during starting and cleaning of the two reactors during stopping.

The invention provides a prepolymerization reactor, a continuous bulk polymerization system and method and PMMA resin. The method comprises the following steps: mixing accurately metered polymeric monomers and auxiliaries, sequentially completing a prepolymerization reaction and a polymerization reaction in serially connected polymerization reactors, and then devolatilizing and granulating a polymerization product to obtain PMMA resin, and comprises the following steps: step 1, purifying and mixing reaction materials; step 2, prepolymerization reaction; step 3, polymerization reaction; step 4, devolatilization; and step 5, granulating. The method overcomes the defects that in the prior art, the polymerization conversion rate is low, the solvent usage amount is large, the molecular weight distribution of the product is wide, light transmittance and other properties cannot meet optical-grade application requirements, and the quality is difficult to accurately regulate and control. Through optimization of a formula and process conditions, a special process system design and combination of polymerization reactors, the contradiction between high conversion rate in the polymerization process and narrow molecular weight distribution of a PMMA product is solved; under the conditions of low solvent addition amount or no solvent, the high conversion rate is obtained, the molecular weight distribution of the polymerization product is narrow, the molecular weight is controllable, and the high-quality optical-grade PMMA resin product is obtained.

The present disclosure relates to a melt-spun high-viscosity PET / low-viscosity PET two-component elastic fiber and a preparation method therefor. The preparation method adopts a six-reactor process. Terephthalic acid and ethylene glycol undergo first and second esterification reactions and first and second prepolymerization reactions, and an obtained ethylene terephthalate prepolymer is respectively introduced into a high-viscosity final polymerization reactor and a low-viscosity final polymerization reactor for polymerization reaction to obtain a high-viscosity melt and a low-viscosity melt, respectively, and then the two melts are spun together. The viscosity of the high-viscosity component can be significantly improved, and a wider range of viscosity difference between the high-viscosity and low-viscosity polyester melts can be obtained. A difference between the intrinsic viscosity of the high-viscosity melt and the intrinsic viscosity of the low-viscosity melt is 0.100-0.550; the prepared PET / PET two-component elastic fiber has high quality and high crimp shrinkage rate.

The invention discloses an olefin polymerization device for producing polyolefin and a method for producing polyolefin. Through flexible combination of fluidized bed reactors and degassing of polyethylene particles discharged from the reactors, a wide molecular weight distribution / multimodal polyethylene or polyethylene block copolymer resin product can be produced. According to the invention, a pipeline for connecting the top of the intermediate tank with the purging gas of the reactor is additionally arranged and is used for conveying polyethylene particles in the intermediate tank to the corresponding polymerization reactor, so that the polymerization environment in the reactor is stabilized, and gas phase components from the previous reactor are effectively removed in the conveying process, for example, 99.9 wt% of hydrogen in the intermediate tank can be removed, and the yield of the polyethylene particles is improved. The production of polyolefin with higher relative molecular mass in the second reactor is ensured, a polyethylene product with target molecular weight and distribution is obtained, the existing production process is simplified, and the energy consumption is reduced.

The invention belongs to the technical field of chemical production reaction equipment, and discloses a polymerization kettle which comprises a polymerization kettle body and an obliquely arranged condenser, the air inlet end of the condenser is communicated with the top of the polymerization kettle body through a pipeline, the polymerization kettle further comprises a driving assembly, the driving assembly comprises two driving discs, the driving discs are arranged in a shell pass of the condenser, and the driving discs are arranged in the shell pass of the condenser. The two driving discs are rotationally arranged at the air inlet end and the air outlet end of the condenser correspondingly, and the two ends of a tube nest of the condenser penetrate through the two driving discs correspondingly and are fixedly connected with the driving discs; the motor is arranged outside the shell pass, and an output shaft of the motor penetrates through the shell pass and is coaxially and fixedly connected with one driving disc; according to the scheme, the driving disc is driven by the motor to drive the tube nests to rotate, so that the tube nests originally located at the upper part and the lower part are alternately contacted with low-temperature circulating water at the water inlet and high-temperature circulating water at the water outlet, and meanwhile, the temperature distribution of the circulating water is more uniform; according to the invention, the problem of insufficient condensation efficiency caused by low top temperature and high bottom temperature of the kettle top condenser is solved.

The utility model discloses an efficient heat exchange polymerization reaction kettle, and belongs to the technical field of reaction kettles. The reaction kettle comprises a kettle body, the kettle body comprises an upper hemisphere head end socket, a lower hemisphere head end socket and a kettle body, the kettle body comprises a material treatment cavity, a discharge port is formed in the surface of the upper hemisphere head end socket, and a feed port, a catalyst inlet and an emptying port are formed in the surface of the lower hemisphere head end socket; the heat exchange mechanism comprises a heat exchange pipe arranged in the material treatment cavity and heat dissipation plates arranged at the two ends of the heat exchange pipe; and the rotating mechanism comprises a stirring piece arranged in the lower hemisphere head sealing head, double mechanical seals, a rotating motor, a speed reducing motor and a lead screw arranged in the advancing direction of the raw materials. The heat exchange tube is additionally arranged in the kettle, the push type paddle pushes the reacted polymer upwards, the polymer passes through the heat exchange tube in the kettle, the temperature is rapidly reduced, a large amount of ordered heat removal is realized, the product conversion efficiency and the product quality can be improved, and the yield and the production safety can be improved.

The invention belongs to the technical field of polymer synthesis, and particularly relates to a preparation method of a methacrylic acid polymer, which comprises the following steps: supplying a polymerization reaction monomer, a chain transfer agent and an initiator to a polymerization reactor, and carrying out polymerization reaction in the polymerization reactor at the temperature of 200-260 DEG C, no gas phase exists in the polymerization reactor, the flow velocity of the reaction liquid in the polymerization reactor is 0.2-0.8 m / s, and the polymer concentration at the outlet of the polymerization reactor is 70-85 wt%. According to the invention, a loop reactor is adopted, and a series of operation conditions are set, so that a product with high polymerization conversion rate is obtained. By controlling the polymerization reaction temperature, the viscosity of the reaction liquid is effectively reduced, and the occurrence probability of the gel effect is reduced, so that the polymerization conversion rate is increased, and the polymer concentration at the outlet of the polymerization reactor is 70-85wt%.

A process for the continuous production of a polyolefin polymer in a gas-phase polymerization reactor in the presence of a polymerization catalyst and an antistatic agent, including the steps of (a) providing a mixture of polyolefin particles and gas, (b) conveying the mixture through a pipe at a gas velocity of greater than or equal to 2 m / s, and (c) introducing an antistatic agent into the mixture.

1. A method for transitioning two different catalysts during the production of a polypropylene homopolymer or copolymer in a sequential multi-stage polymerization reaction, said method comprising: a) polymerizing propylene and optionally a comonomer in the presence of a first catalyst in a multi-stage polymerization reactor system comprising a prepolymerization reactor followed by a slurry reactor and then a gas phase reactor; b) discontinuing the supply of the first catalyst to the prepolymerization reactor; c) subsequently introducing propylene, optionally a comonomer, and a second catalyst into said prepolymerization reactor, and further introducing an aluminum alkyl into said polymerization reactor simultaneously with said introduction of said second catalyst; d) polymerizing propylene and optionally a comonomer in the presence of a second catalyst in said multi-stage polymerization reactor system. The process includes the steps of: wherein the first catalyst is a Ziegler-Natta catalyst and the second catalyst is a single-site catalyst; and wherein the amount of aluminum alkyl supplied in step c) is 0.5 to 10.0 g per ton of total propylene supplied into the prepolymerization reactor and the slurry reactor in steps c) and d). The method.

The utility model discloses a polymerization reaction kettle which comprises a reaction kettle body, a feeding hopper is arranged at the top end of the reaction kettle body, a discharging pipe is arranged at the bottom end of the reaction kettle body, a stirring assembly is arranged on the reaction kettle body, and the stirring assembly is connected with a scraping assembly. The stirring assembly comprises a motor and a stirring shaft connected with the output end of the motor, the motor is fixed at the bottom end of the reaction kettle body, the scraping blades can always abut against the inner wall of the reaction kettle body, raw materials on the inner wall of the reaction kettle body can be scraped more thoroughly, and meanwhile, the raw materials can be scraped more thoroughly. The motor is arranged at the lower end of the reaction kettle body, so that the length of the stirring shaft can be shortened, and the problem that raw materials cannot effectively participate in the reaction due to winding and adhesion on the stirring shaft in the preparation process is avoided.

The invention belongs to the technical field of polyester fibers, and relates to a method for measuring and calculating key parameters based on simulated three-dimensional PET concentration field distribution, which comprises the following steps: firstly, deducing a causal structure in a polyester fiber reactor according to an information theory, secondly, grading and disassembling the causal structure to obtain a disassembled causal structure, and finally, calculating the key parameters of the polyester fiber reactor according to the disassembled causal structure. Driving one stage in the training process through each disassembled causal structure to obtain an output and a sum; the method comprises the following steps of: firstly, carrying out common input, and carrying out weight initialization by using a Caul-guide Init method, constructing a deep neural network (DNN), applying theoretical constraint to a model, and outputting three-dimensional PET concentration field distribution; and finally, measuring and calculating key parameters by utilizing theoretical knowledge of the polyester fibers and combining the output three-dimensional PET concentration field distribution. The method provided by the invention can accurately simulate the three-dimensional PET concentration field in the polyester fiber polymerization reactor, is used for measuring and calculating key parameters, and improves the measurement and calculation precision.

The preparation method is characterized by comprising the following steps: adding D3F and D4 into a polymerization reaction kettle together for dehydration, introducing vinyl by adopting a self-made cross-linking comonomer, adding a vinyl double-end-capping agent for end capping, adding tetramethylammonium hydroxide and an accelerant DMSO (Dimethylsulfoxide), and carrying out polymerization reaction at 120 DEG C for 1-2 hours in a normal-pressure nitrogen environment, so as to obtain the high-molecular-weight fluorosilicone copolymerized raw rubber. And raising the temperature to inactivate the catalyst, and removing the low temperature to obtain the fluorosilicone copolymerized raw rubber. According to the invention, D3F and dimethyl siloxane ring body are copolymerized, so that the cost is saved, vinyl-containing trifluoropropyl siloxane ring body is prepared, vinyl can be effectively connected into the fluorosilicone polymer, the distribution uniformity of vinyl in the main chain of the fluorosilicone polymer is improved, the vulcanization performance is improved, the chain back-bite phenomenon in the polymerization process can be effectively inhibited by adding the accelerant, and the service life of the fluorosilicone polymer is prolonged. The tetramethylammonium hydroxide catalyst is adopted, so that the neutralization step is omitted, polymerization and low molecule removal by heating are carried out in one reaction kettle, the operation is simple, and production and popularization are easier.

This invention relates to the application of hypergravity technology in coordination polymerization, and discloses a method for preparing hyperbranched polyethylene and its application. The method includes: (1) carrying out coordination polymerization of ethylene monomer, solvent, catalyst solution, and auxiliary catalyst solution under hypergravity conditions; and (2) removing the monomer, washing, separating, and drying the reaction product obtained in step (1). By controlling the hypergravity level, reactant ratio, reaction temperature, and pressure, this invention can obtain high-quality hyperbranched polyethylene products with a number-average molecular weight of 1000-1500000 and a molecular weight distribution index of 1.2-2.5. Compared with reactions in ordinary polymerization reactors, the production efficiency is significantly improved, and the product has a higher molecular weight and a narrower molecular weight distribution.

A cooling, condensing and exhausting system of a thermal polymerization reaction kettle comprises a kettle body, an outlet is formed in the middle of the top of the kettle body, an inlet is formed in the top end of the kettle body, one end of a first output pipeline is fixedly installed at the outlet, and the other end of the first output pipeline is communicated with an inlet of a first heat exchanger. An outlet of the first heat exchanger is connected with an inlet of a second heat exchanger through a second output pipeline, an outlet of the second heat exchanger communicates with an inlet of a low-temperature container through a third output pipeline, and an outlet of the low-temperature container communicates with an inlet of a feeding pump through a fourth output pipeline. An outlet of the feeding pump is communicated with an inlet of a high-level tank through a fifth output pipeline, and an outlet of the high-level tank is communicated with the inlet of the kettle body through an input pipeline. Through the heat exchanger and the high-level tank, waste heat carried by the circulating liquid can be eliminated through the heat exchanger, and the high-level tank can ensure that the density of the circulating liquid is uniform and the temperature in the kettle body is maintained within a preset value, so that the yield of finally obtained finished products is effectively improved.

Embodiments of a dual reactor solution polymerization process include: introducing a first feed comprising an ethylene monomer, optionally hydrogen, optionally a C3-C12 alpha-olefin comonomer, and a hydrocarbon solvent into a first polymerization reactor to produce a first reactor product comprising an ethylene-based polymer via solution polymerization at a temperature of 100 DEG C to 225 DEG C; and introducing the first reactor product and a two-phase second feed comprising an ethylene monomer, a hydrocarbon solvent, optionally hydrogen, and optionally a C3-C12 alpha-olefin comonomer to a second polymerization reactor to produce an ethylene-based polymer via solution polymerization, wherein the weight ratio of the sum of hydrocarbon solvent plus comonomer in the two-phase second feed to ethylene monomer is 0.1 to 2.0.

The utility model belongs to the technical field of polymerization reaction kettles, and particularly relates to an anti-yellowing physical foaming PBT copolyester polymerization reaction kettle which comprises a bottom plate, a plurality of supporting frames are symmetrically arranged at the top end of the bottom plate, the supporting frames are L-shaped, mounting rings are arranged at the top ends of transverse frames of the supporting frames, an outer kettle body is arranged in the mounting rings, and the outer kettle body is arranged in the bottom plate. An inner kettle body is arranged in the outer kettle body, a fixing rod is arranged at the top end of the bottom plate, a chassis is arranged at the top end of the fixing rod, a material mixing assembly is arranged in the inner kettle body and comprises a rotating shaft, the rotating shaft is sleeved with a plurality of shaft sleeves, and a plurality of material mixing rods are arranged on the outer side walls of the shaft sleeves in a surrounding mode; a plurality of scrapers are arranged on the top end surface of the chassis, and a plurality of stirring rods are arranged on the outer side walls of the scrapers in parallel, so that materials can be uniformly mixed, the heat of the device can be preserved, and the materials react under proper conditions.

The invention belongs to the technical field of reaction kettles, and discloses a high-efficiency polymerization reaction kettle for producing a polycarboxylic acid water reducer, the high-efficiency polymerization reaction kettle comprises a reaction kettle body, a stirring plate I and a stirring plate II, a composite rotating part is rotatably mounted in the reaction kettle body, the stirring plate I and the stirring plate II are fixedly connected to the outer surface of the composite rotating part, and the stirring plate I and the stirring plate II are fixedly connected to the outer surface of the composite rotating part. A midway injection mechanism is arranged in the composite rotating part, the composite rotating part rotates around the midway injection mechanism in the composite rotating part, and the midway injection mechanism is used for injecting the material liquid into the mixed liquid in the stirring reaction period. According to the invention, the key additive is directly sprayed to the specified depth in the reaction liquid instead of being only added on the liquid surface, so that the problem of over-high local concentration is avoided, the material can be instantly and uniformly dispersed in the reaction system, the stability and controllability of the reaction are greatly improved, the high consistency of the product performance is ensured, and the product quality is improved. Accurate, multi-point and deep injection of materials in the reaction process is achieved.

The application discloses an ethylene and alpha-olefin copolymerization evaluation test device, which comprises an olefin mixed gas distribution device, a polymerization reactor, a temperature control unit, a pressure control unit and a stirring device. The polymerization reactor is connected with the olefin mixed gas distribution device, the temperature control unit is connected with the polymerization reactor, and the pressure control unit is connected with the polymerization reactor. The stirring device comprises a stirring shaft and a stirring paddle. The stirring shaft is a hollow structure with a gas flow pipeline inside. One end of the stirring shaft penetrates through a cover of the polymerization reactor and is provided with a gas inlet. The other end of the stirring shaft is connected with the stirring paddle. The stirring paddle is arranged at the bottom of the polymerization reactor. At least one gas outlet is arranged on the stirring paddle. The ethylene and alpha-olefin copolymerization evaluation test device can increase the contact amount of ethylene and alpha-olefin with a catalyst. The ethylene and alpha-olefin copolymerization evaluation test device can be used for evaluating ethylene polymerization, and the catalyst activity can be accurately evaluated.

Provided is a method for producing a C9 hydrogenated resin by reusing a thermally polymerized liquid resin. The method includes: preheating a polymerization reaction material by a feed heat exchanger using a polymerization liquid as a heat source, and then subjecting a resulting preheated polymerization reaction material to polymerization in a polymerization reactor group; transferring a mixed liquid of unpolymerized C9 and a liquid resin evaporated from a flash evaporation system (11) to a refining tower (9), and performing refining; subjecting a thermally polymerized resin obtained from a bottom of the flash evaporation system (11) to hydrogenation to synthesize a hydrogenated resin; and using a refined liquid resin obtained from the refining tower (9) as a vacuum mother liquor of the vacuum pump (18), and then returning the refined liquid resin to the polymerization reactor group, and making the refined liquid resin to participate in the polymerization.

The invention relates to the technical field of olefin catalyst polymerization, in particular to a preparation method of ethylene propylene diene monomer. The method comprises the following steps: carrying out anhydrous oxygen operation treatment on a polymerization reaction kettle by using a vacuum-gas raw material replacement method, introducing a gas raw material prepared in proportion into the polymerization reaction kettle to achieve the required polymerization original pressure, continuously introducing a main catalyst, a cocatalyst, a hexane solvent and ethylidene norbornene into the polymerization reaction kettle at the same time, starting a polymerization reaction; and introducing circulating cooling water into an outer jacket of the polymerization reaction kettle in the reaction process to maintain the stability of the polymerization reaction temperature, inactivating the polymerization system after the polymerization reaction is finished, removing the solvent, and drying to obtain the ethylene propylene rubber. The prepared ethylene propylene diene monomer is high in stability, the molecular mass of the product is controllable, and the molecular mass distribution is obviously narrowed.

A process for preparing an ethylene polymer in a suspension polymerization including the steps of separating the formed suspension of ethylene polymer particles in a solid-liquid separator into ethylene polymer particles and mother liquor, transferring a first part of the mother liquor into a work-up section including an evaporation unit for producing a wax-depleted portion of the mother liquor, wherein a protic agent is added to the part of the mother liquor which is transferred into the work-up section, and recycling a first part of the wax-depleted portion of the mother liquor to the polymerization reactor or the series of polymerization reactors.