2120 results about "Pelletizing" patented technology

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

The inventive technique process of grainy calcium material for preventing and treating peanut blight primarily includes: adopting the shell powder and weathered coal as raw materials, machining into peanut blight prevention material through agglomeration granulation. The invention has innovative and reasonable design, which not only has simple process, easy implementing, but also has low cost of raw materials, product application convenience, remarkable peanut blight prevention effect, and capability of promoting high-efficient production pf peanut. In particular, the invention applies coastal oyster shell wastes for machining calcium materials for preventing and treating peanut blight, which not only reduces environmental pollution, but also promotes recycling of resources, has very significant economic, social and ecological benefits and greater promotional value.

The invention discloses a double-component reinforced 5Y-PSZ dental ceramic material and a preparation method thereof, and relates to the technical field of ceramic material preparation. The method comprises the following steps: mixing ZrCl4 and deionized water, and dropwise adding an ammonia water solution to prepare m-ZrO2 nano ceramic powder; zrOCl2. 8H2O, Y (NO3) 3.6 H2O and deionized water are mixed, the m-ZrO2 nano ceramic powder and polyethylene glycol 2000 are added, and the material is prepared through calcination, spray granulation, hot-pressing presintering and high-temperature sintering. According to the 5Y-PSZ dental ceramic material disclosed by the invention, the nano-scale m-phase ZrO2 is adopted as a reinforcing material and is dispersed and distributed inside the 5Y-PSZ, and through volume expansion generated by t-m phase change of the m-phase ZrO2, the anti-aging performance is guaranteed, and meanwhile, the reinforcement of the 5Y-PSZ dental ceramic material is realized. The invention solves the problem of insufficient strength of the 5Y-PSZ dental ceramic material in the prior art.

The invention relates to the technical field of plastic molding and treatment, and discloses a molding processing and post-treatment process of low-odor plastic, which comprises the following steps: extruding a plastic melt containing volatile components into a to-be-cut material strip, pelletizing in a pelletizing area by using a pelletizing device, and synchronously adjusting the pulse spraying frequency to adapt to the pelletizing frequency, an alternating stress field is induced on the surface layer of a material strip through periodic cold impact and mechanical vibration, a micro-crack structure is formed on the surface layer of plastic particles by controlling the particle size of atomized liquid drops, an exhaust channel for volatile component escape is constructed, and then the plastic particles are conveyed to post-treatment equipment for volatile component removal. A solid diffusion process blocked by a skin layer is converted into a physical inrush flow along a microcrack channel, so that a mass transfer energy barrier is reduced, efficient removal of peculiar smell components is realized, and thermal degradation and yellowing of particles are avoided.

The invention relates to the technical field of polymer composite materials, and discloses a refining treatment method of a bamboo fiber ultra-nano micro powder and natural polymer blended material, which comprises the following steps: (a) premixing bamboo fiber ultra-nano micro powder and a deep eutectic solvent to obtain a premix and realize in-situ activation; (b) adding the premix and a natural polymer matrix from a main feed port of a double-screw extruder; and (c) in the melt blending process, adding a dynamic interface locking agent through a side feeding port arranged at the downstream of the main feeding port, and then extruding and granulating. A staged dynamic compatibilization process is adopted, a hydrogen bond network of bamboo fibers is destroyed by using a deep eutectic solvent to promote shearing dispersion of the bamboo fibers in the front section, and stable interface bonding is constructed in the rear section through a dynamic interface locking agent after dispersion is completed. The method synergistically solves the conflict between dispersion and interfacial compatibilization, so that the composite material has good comprehensive performance.

The invention discloses a preparation method of a nano silicon dioxide modified high-density polyethylene wear-resistant plate, and belongs to the technical field of polyethylene plates, the method comprises the following steps: firstly preparing an antioxidant PMMA microcapsule, then preparing titanium dioxide and silicon dioxide, and modifying by KH550 to obtain modified nano titanium-silicon composite particles; then, an antioxidant coated PMMA microcapsule, the modified nano titanium-silicon composite particles, POE-g-MAH and HDPE particles are premixed, and the wear-resistant plate is obtained through twin-screw extrusion granulation and pulsating force field assisted molding; through the synergistic effect of the antioxidant coated PMMA microcapsule, the modified nano titanium-silicon composite particles and the compatilizer POE-g-MAH, the problems that the wear resistance of the HDPE plate is insufficient and the antioxidant is easily adsorbed by nano silicon dioxide to cause aging resistance attenuation are solved, and the wear resistance, thermal oxidation / light aging resistance and mechanical property improvement of the plate are realized; and the requirements of high-frequency wear scenes such as mine conveying and outdoor engineering can be met.

The invention provides a recovery device for building waste plastic building materials, and relates to the field of waste recovery devices.The recovery device comprises a feeding mechanism, a crushing mechanism, a separating mechanism and a melting granulation mechanism, and further comprises a crushing system and an electric control system; according to the crushing system, a primary crushing unit is driven by a first variable frequency motor; the secondary crushing unit is arranged at the discharging end of the primary crushing unit and is driven by a second variable frequency motor; the screening unit is arranged below the secondary crushing unit; wherein the electric control system is electrically connected with the first variable-frequency motor and the second variable-frequency motor and used for independently controlling the rotating speeds of the first variable-frequency motor and the second variable-frequency motor so as to drive the primary crushing unit and the secondary crushing unit to do differential relative motion, and the screening unit is used for returning substandard materials to the primary crushing unit to be crushed again. Multi-stage differential crushing and intelligent closed-loop control are adopted, airflow separation and magnetic separation impurity removal are combined, efficient and energy-saving production is achieved through segmented melting and plasticizing, and the treatment efficiency and the purity of a finished product are improved through an automatic system.

The invention belongs to the technical field of high polymer materials, and particularly relates to a PET decorative film and a preparation method thereof. The preparation method comprises the following steps: synthesizing hydroxyl-terminated hyperbranched polyester by taking pentaerythritol and 2, 2-dimethylolpropionic acid as raw materials, and reacting with polyol glycidyl ether to prepare an epoxy-terminated organic modifier; silver-loaded nano silicon dioxide subjected to surface treatment by an amino silane coupling agent is used as inorganic functional particles; pET resin, an organic modifier and inorganic functional particles are subjected to melt blending and extrusion granulation, and modified PET is prepared; the modified PET is prepared into the film through a two-way stretching process. Epoxy groups of the organic modifier chemically react with amino groups at the tail end of a PET molecular chain and on the surfaces of inorganic particles respectively, a stable organic-inorganic hybrid network is constructed, synergistic improvement of reinforcement, toughening and long-acting antibiosis is achieved, and the technical problems that functional particles are not uniform in dispersion, interface bonding is weak, and antibacterial components are prone to migration are effectively solved.

The utility model discloses a polypropylene multi-unit collaborative devolatilization system, which belongs to the technical field of devolatilization in polypropylene production process, and comprises a polypropylene powder solid-phase devolatilization unit, a polypropylene powder solid-phase devolatilization unit, a polypropylene powder solid-phase devolatilization unit, a polypropylene powder solid-phase devolatilization unit and a polypropylene powder solid-phase devolatilization unit, the extrusion granulation devolatilization unit comprises an extruder and a granulator, an outlet of the powder collecting tank is connected with a feed port of the extruder, and an outlet of the extruder is connected with the granulator; the granule devolatilization unit comprises a hot air drying stock bin, and an outlet of the granulator is connected with an inlet of the hot air drying stock bin; an outlet of the hot air drying bin is used for being connected with a packaging production line. According to the melt devolatilization system disclosed by the utility model, the batch-type vacuum dryer is additionally arranged, so that the modification of a core equipment double-screw extruder is reduced, the process complexity of the melt devolatilization system is obviously reduced, the devolatilization efficiency is improved, and volatile components can be completely removed.

The invention discloses a recycled modified polypropylene composite material preparation system and a resource recovery method, and relates to the technical field of high polymer material science and engineering. The raw material pretreatment module adopts near infrared spectrum classification, multi-stage cleaning, drying and crushing, and the moisture content is controlled to be less than 0.5%; the melt blending module melts the materials at 180-220 DEG C, modifiers and additives are added, and vacuum degassing is performed to remove impurities; adding a reinforcing agent into the modification reinforcing module, and performing ultrasonic dispersion and dynamic vulcanization; the molding processing module is used for manufacturing a product through extrusion, injection molding or calendaring; the quality detection module is used for detecting mechanical and thermal properties; the waste recovery module is used for crushing and melting granulation to realize a closed loop; the intelligent control module uses a PLC to coordinate each module. Integrated treatment of waste polypropylene is achieved, the purity of raw materials and the performance of a composite material are improved, the resource utilization rate is increased through closed-loop recycling, manual intervention is reduced through intelligent control, product stability is guaranteed, economic and environment-friendly benefits are achieved, and high-valued circulation of waste plastic is promoted.

The invention relates to preparation of a ZTA composite ceramic material, and belongs to the field of inorganic nonmetal composite materials. The raw material composition formula comprises aluminum oxide, zirconium oxide, zirconium dioxide, yttrium oxide, magnesium oxide and titanium dioxide. The low-sodium microcrystalline alumina powder with the original grain size of 0.40 [mu] m is selected and ground to the original grain size in advance, so that zirconia can be more uniformly distributed between alumina grain boundaries, which is a precondition for obtaining more uniform ZTA. Zirconium dioxide is creatively introduced, and compared with a conventional method in which stable zirconium oxide is directly used, the cost of ZTA is greatly reduced. The pre-calcined granulation powder is adopted, so that a ZTA product which is uniformly mixed in the early stage is cured by adding a stabilizer, and then the uniform and stable ZTA ceramic can be obtained through later-stage forming and firing.

The invention discloses a fracturing proppant using coal gangue and fly ash and a preparation process thereof, and relates to the field of fracturing proppants, the fracturing proppant comprises coal gangue, fly ash, silica fume, nanometer alumina, a composite pore-forming agent and a fluxing agent, and the preparation process comprises raw material pretreatment, mixing granulation, microwave-gradient sintering and post-treatment. The raw material pretreatment comprises the following steps: removing iron and impurities through carbon thermal reduction-magnetic separation; the composite pore-forming agent is enriched on the surface of the green body during mixed granulation; the microwave-gradient sintering is used for cooperatively regulating and controlling growth of mullite crystals through microwave preheating and resistance heating to form an internal acicular mullite interlaced structure and a surface micro-convex structure; a finished product is obtained through post-treatment grading and surface cleaning. Resource utilization of industrial solid waste is achieved, the strength and flow conductivity of the proppant are improved through raw material synergy, crystal structure regulation and control and surface microstructure design, preparation energy consumption is reduced, and the proppant is suitable for oil and gas field fracturing engineering.

The invention discloses a high-wear-resistance modified polypropylene material and a preparation process thereof. The material comprises the following components in parts by weight: isotactic polypropylene, a beta nucleating agent, a heterofunctional hexagonal boron nitride nanosheet, an elastomer, an antioxidant system and a surface migration accelerant, one side of the nanosheet is treated by amino silane, and the other side of the nanosheet is treated by fluorine-containing silane. The material is prepared through twin-screw melt blending granulation and injection molding, in the molding process, variable mold temperature is adopted, contact pressure is applied to the surface of a product to promote directional migration and orientation of nanosheets in a cortex area, and then annealing is conducted. The Janus structure and the surface migration accelerant cooperate to realize a fluorine-containing low-surface-energy self-lubricating surface layer with an outward surface; the beta nucleating agent induces beta crystal formation to improve toughness. The scheme has the advantages of simple process and easily available raw materials, and is suitable for polypropylene products with higher wear resistance requirements, such as automotive interiors and household appliance shells.

The invention discloses a foamed polyphenyl ether bead and a preparation method thereof. The material is prepared by compounding polyphenyl ether, a styrene polymer, a three-dimensional fiber microsphere reinforcement, a CNTs coated SiO2 core-shell nucleating agent, modified resin, a flame retardant and an antioxidant according to a specific ratio. The innovation of the invention lies in that a three-dimensional reinforcement with glass beads as a core and carbon fibers as a network and a composite foaming agent with silicon dioxide coated with carbon nanotubes are introduced to synergistically improve the cellular structure and mechanical properties. The preparation process comprises the key steps of component drying, melt blending granulation, carbon dioxide physical foaming under an autoclave aqueous dispersion system and the like. Through component design and surface modification, the foamed bead has the advantages of light weight, high strength, flame retardance and uniform foam structure, and is suitable for the fields of high-end heat insulation and bearing.

The invention relates to a multi-stage granulation crushing device for ceramics, and belongs to the technical field of ceramic granulation, the multi-stage granulation crushing device comprises a crushing cylinder, a feeding cylinder is fixedly mounted at the top of the crushing cylinder, a feeding hopper is fixedly mounted on one side of the feeding cylinder, and a dustproof dissipation assembly is arranged on the feeding cylinder; and the dustproof dissipation assembly comprises a dust baffle rotationally installed on the inner side wall of the feeding barrel, an air blowing pipe is fixedly installed at the top of the feeding barrel, an air blowing net plate is fixedly installed at the top of the air blowing pipe, air blowing blades are rotationally installed at the bottom of the air blowing net plate, and an air blowing motor is fixedly installed at the top of the air blowing net plate. According to the multi-stage granulating and crushing device for ceramics, a dust baffle is arranged at the joint of a feeding hopper and a feeding barrel, an air blowing pipe is arranged at the top of the feeding barrel, an air blowing motor drives air blowing blades to rotate, air is blown into a crushing barrel, dust is blocked through the dust baffle, and the dust is blown into the crushing barrel through air flow; and dust is prevented from escaping from the feeding hopper.

The invention relates to the technical field of packaging materials, in particular to a manufacturing method of an industrial byproduct semi-hydrated gypsum hollow plastic plate. The plastic plate is prepared from the following components in parts by weight: 60 to 70 parts of superfine modified semi-hydrated phosphogypsum powder, 28 to 35 parts of polypropylene resin, 0.5 to 1.5 parts of slipping agent, 0.5 to 1.5 parts of dispersing agent, 0.5 to 1.5 parts of antistatic agent, 0.3 to 0.8 part of antioxidant, 5 to 10 parts of calcium oxide and 3 to 6 parts of polyolefin elastomer. The gypsum powder subjected to purification, calcination and quaternary ammonium / stearic acid surface treatment has oleophylic and hydrophobic properties, and 65% high-proportion filling can be realized; the light moisture-proof plate with the density of 0.75-0.95 g / cm < 3 > and the thickness of 3-6 mm is obtained by matching with a double-screw granulation process and a single-screw hollow plate extrusion process, the use amount of resin is reduced, the mechanical property and the heat resistance are obviously superior to those of a single surface modifier, and high-value utilization of ardealite resources is realized.

A vacuum induction melting (VIM) furnace and method of using. A VIM is configured for use with metal-containing carbon powders. In operation, the metal-containing carbon powders are formed into a pellet so as to minimize or eliminate ejection of material during introduction of the pellet into the VIM processor. The VIM processor may be substituted or used in combination with a vacuum arc melt processing apparatus, an electron beam melt furnace, an ion plating furnace, a plasma flame source, a smelter, a traditional metal-metal melt furnace, or any equivalent. Pelletizing can be accomplished through use of a press or through application of any pelletizing technique and / or use of any apparatus that is able to generate pellets that have sufficient mass to avoid ejection from a VIM processor.

The invention discloses a composite material polypropylene film and a preparation method thereof, and belongs to the technical field of polymer modification and polymer films. The preparation method of the composite material polypropylene film comprises the following steps: blending 5-10 wt% of maleic anhydride grafted polypropylene (PP-g-MAH), 5-20 wt% of a cycloolefin copolymer or a cyclic block copolymer and 75-90 wt% of isotactic polypropylene, granulating, carrying out melt extrusion at 240-260 DEG C, and carrying out tape casting at 80-95 DEG C to form a sheet; preheating the sheet at the temperature of 145-170 DEG C, synchronously stretching at the temperature of 150-175 DEG C, carrying out heat setting at the temperature of 160-175 DEG C, and cooling; the composite material polypropylene film is prepared through the steps of extrusion, traction, corona treatment, rolling and the like. The composite material polypropylene film not only has good heat resistance and good dielectric strength at a high temperature, but also has a relatively high dielectric constant and relatively low dielectric loss, and is suitable for a film capacitor.

The invention relates to the technical field of solid waste resource utilization and building materials, in particular to magnesium slag-based aggregate and a preparation method thereof. According to the specific technical scheme, the industrial magnesium slag is ground into powder; performing surface activation and organic-inorganic hybrid coating modification on the waste tire rubber powder; grading and mixing the magnesium slag powder, the modified rubber powder and a chemical foaming agent to obtain a composite dry material; mixing and granulating the composite dry material and a special bio-based composite cementing solution; and finally, the raw material balls are placed in an alkaline carbon dioxide-rich atmosphere for low-temperature carbonization maintenance. The bio-based cementing solution is stably cured through mechanisms such as ionic crosslinking, mineralization induction and organic-inorganic network interpenetration. The obtained aggregate has a compact shell structure, the bulk density is 650-850 kg / m < 3 >, the cylinder compressive strength is 6-12 MPa, the water absorption rate is lower than 10%, the impact toughness is excellent, efficient synergistic utilization of various solid wastes is achieved, high-temperature sintering is not needed in the process, and low carbon and energy saving are achieved.

The invention discloses a hydrolysis-resistant reinforced high-temperature nylon composite material and a preparation method thereof, and relates to the technical field of nylon composite materials. According to the composite material, a PA66-PA46 random copolymer, bio-based polyamide 1010 and PA6 resin are used as matrixes, and are matched with a composite reinforcement formed by silane coupling agent modified carbon nanotubes and hydrolysis-resistant alkali-free glass fibers; and a polycarbodiimide and epoxy-terminated polyether compounded hydrolysis-resistant agent, a bio-based composite nucleating agent, an antioxidant complexing agent, a fatty acid amide flowable agent and an inorganic coloring agent are used as auxiliary materials. The preparation method comprises the following steps: raw material synergistic pretreatment, ultrasonic-mechanical shearing synergistic premixing, dynamic pressure-regulating twin-screw extrusion blending, water mist-water cooling-air knife synergistic cooling pelletizing and vacuum pulse drying-crystallization synergistic post-treatment. The composite material is uniform in structure and stable in performance, has excellent hydrolysis resistance and high-temperature resistance, and is suitable for application scenes with relatively high requirements on material environment stability.

The invention discloses a multi-layer composite polypropylene color master batch and a preparation method thereof.The multi-layer composite polypropylene color master batch comprises an inner layer, a middle layer and an outer layer, the inner layer is coated with the middle layer, the middle layer is coated with the outer layer, matrix resin, a composite toughening agent and an interface modifier are subjected to melt blending in a double-screw extruder, nano reinforcing filler is added, extrusion granulation is performed, and the multi-layer composite polypropylene color master batch is obtained. Carrier resin, hyperbranched polyesteramide and a toner pre-dispersion body are mixed at a high speed and then uniformly coated on the outer surface of the inner layer through fluidized bed equipment, and a mixture of a weather-proof additive and a lubricant is attached to the outer surface of the middle layer by adopting an electrostatic spraying process to form the outer layer. According to the multi-layer composite color master batch, the matrix resin and the composite toughening agent have a synergistic effect, so that the impact strength of the color master batch is improved, the cavity structure of hyperbranched polyesteramide is coated with the toner, the silane is used for treating the nano filler to reduce agglomeration and chromatic aberration, the outer layer delays aging, the lubricant reduces the extrusion torque, and the multi-layer composite color master batch is adaptive to a high-speed pipe production line.

The invention discloses an oxygen control process for injection-molded titanium alloy based on oxygen-free solvent degreasing, which belongs to the technical field of powder metallurgy materials and comprises the following steps of: banburying and cooling pre-alloyed titanium powder and a binder matrix, granulating and injection-molding, and degreasing, drying and sintering by using an oxygen-free solvent. According to the method, a full-process oxygen control process chain of vacuum pre-drying of pre-alloyed titanium powder, preparation of an oxygen-free binder, extraction and degreasing of an oxygen-free solvent, vacuum thermal degreasing and graphite furnace temperature control sintering is constructed, invasion of impurity elements such as carbon, oxygen and nitrogen is blocked from the source to a finished product, and the core bottleneck that the oxygen content of the powder metallurgy titanium alloy is difficult to control is solved; and the consistency of the strength and plasticity of the product is guaranteed through stable impurity control, and performance fluctuation caused by out-of-control of the oxygen content is avoided.

The invention relates to the technical field of high polymer materials, and discloses a low-smoke halogen-free irradiation crosslinking polyolefin cable sheath material and a granulation process thereof, the raw materials comprise an ethylene-vinyl acetate copolymer, an ethylene-octylene copolymer, an epoxy group-containing terpolymer and functionalized composite powder, the powder system superfine aluminum hydroxide is subjected to high-temperature grafting through vinyl silane, after cooling, an active coating layer is constructed by zinc methacrylate, active magnesium oxide and a lubricant, and the process adopts matrix resin main feeding, powder side feeding and low-temperature low-shear extrusion, and is subjected to air-cooled die surface hot cutting and electron beam irradiation crosslinking forming. The covalent bond and ionic bond synergistic enhancement mechanism is utilized, the contradiction between mechanical property loss and processing rheological property deterioration is solved under the high filling amount of 137-160 parts, the active components are effectively prevented from being scorched in the early stage, and the material is endowed with excellent tensile strength, elongation at break and surface quality.

The invention provides a ceramsite proppant as well as a preparation method and application thereof. The method comprises the following steps: grinding a coal gangue raw material, pre-sintering, cooling and then grinding again; grinding the tungsten tailing sand, the low-grade bauxite, the carbide slag and the clay; grinding after mixing the raw materials; the raw materials comprise 45-60 parts of low-grade bauxite, 20-35 parts of pre-sintered coal gangue, 15-20 parts of tungsten tailing sand, 1-5 parts of carbide slag and 7-14 parts of clay; the total amount of the low-grade bauxite, the pre-sintered coal gangue and the tungsten tailing sand is 100 parts; granulating and drying; carrying out first sintering at 800-950 DEG C; second sintering is conducted at the temperature of 1050-1200 DEG C; and naturally cooling to obtain the ceramsite proppant. The technical problem to be solved is how to realize high-valued utilization of mine solid waste and low-grade bauxite, reduce dependence on high-quality bauxite and production cost, reduce sintering energy consumption and carbon emission, reduce product body density and improve key performance such as strength and sphericity of the proppant by optimizing raw material combination and a preparation process. And the requirements of oil and gas field fracturing operation are met.

The invention discloses an ABS (Acrylonitrile Butadiene Styrene) material for a vehicle-mounted USB (Universal Serial Bus) interface shell and a preparation method thereof, and belongs to the technical field of polymer processing modification. Aiming at the technical contradiction that the heat resistance is improved and the toughness is reduced when the existing ABS material is applied to the vehicle-mounted USB interface shell, the composite formula of 40-60 parts of styrene-acrylonitrile copolymer (SAN), 10-40 parts of ABS high rubber powder, 0-5 parts of toughening compatilizer, 0-30 parts of heat-resistant agent, 0.2-1.0 part of antioxidant and 0.1-0.5 part of lubricant is adopted; the material is prepared through a high-speed mixing-twin-screw extrusion granulation process (the length-diameter ratio is 40: 1-50: 1, and the temperature is controlled to be 150-200 DEG C). The Vicat softening temperature of the material is greater than or equal to 107 DEG C (the highest temperature is 115 DEG C), the notch impact strength is greater than or equal to 10.5 kJ / m, and the material has ultrahigh heat resistance and excellent mechanical properties, can be directly used for injection molding of a vehicle-mounted USB interface shell, and can also be popularized to other ABS workpieces with high heat resistance requirements. The process is simple, continuous production can be realized, the cost is controllable, and the industrial application value is remarkable.

The invention discloses metal ceramic MAX-phase composite powder for spraying and a preparation method of the metal ceramic MAX-phase composite powder, and belongs to the field of metal ceramic composite materials. The method comprises the following steps: mixing Ni powder, Cr powder and Cr2AlC nano powder with deionized water, a binder and a dispersant according to a specific ratio, and carrying out wet ball milling to prepare uniform slurry; carrying out spray granulation to obtain primary spherical powder; and finally, carrying out spheroidizing treatment on the primary powder by adopting radio frequency plasma under the protection of inert gas to obtain a final product. The core of the preparation method is that through an optimized two-step process, many limitations in the application aspect of an existing MAX phase material are solved, and the composite powder which is high in sphericity degree, good in flowability, compact in interior and stable in MAX phase component is successfully prepared. The powder can be directly used for thermal spraying, and an ideal raw material is provided for preparing a high-performance MAX-phase metal ceramic coating.

The invention discloses a gallium-cerium co-doped ITO target material and a preparation method thereof, and belongs to the field of transparent conductive oxide ceramic target materials, and the preparation method comprises the following steps: weighing indium oxide powder raw materials, tin oxide powder raw materials, gallium oxide powder raw materials and cerium oxide powder raw materials in proportion, and performing pretreatment; the raw material powder is subjected to independent ball milling till the raw materials reach the preset particle size; mixing the four kinds of slurry, and continuously performing ball milling to obtain uniform mixed slurry; adding a binder into the mixed slurry, and carrying out ball milling and mixing to form stable formed slurry; carrying out spray granulation on the formed slurry to obtain spherical precursor powder; pressing and forming the precursor powder to obtain a biscuit, then putting the biscuit into a sintering furnace, carrying out stepped sintering in an oxygen atmosphere, and naturally cooling to obtain the gallium-cerium co-doped ITO target material. According to the gallium-cerium co-doped ITO target material prepared by the method, the relative density is greater than or equal to 99.4%, the resistivity is less than or equal to 99.4%, and the three-point bending strength is greater than or equal to 230MPa.

The invention relates to the field of high polymer material processing, and discloses a high-efficiency low-energy-consumption granulation process and system for a full-biodegradable multiphase composite material, and the process comprises the following steps: feeding raw materials such as polypropylene carbonate, polyester, plant fibers and four-stage activated biomass hydroxyapatite into a double-screw extruder with the length-diameter ratio of not less than 64: 1 in a grading manner according to heat sensitivity; the temperature, the pressure and the shear field are cooperatively controlled, and three-section type temperature distribution of intensified melting, short-time reaction and rapid cooling is established; and carrying out three-stage gradient vacuum devolatilization and underwater pelletizing to obtain a finished product. The four-stage activated biomass hydroxyapatite is prepared by plasma etching, hydrophobic coating, interface coupling and melt pre-dispersion. The problem of degradation of heat-sensitive components is solved through graded feeding and asymmetric temperature control, the dispersity and interface bonding force of the filler are improved by utilizing a four-stage activation technology, closed-loop control is realized by combining online rheology monitoring and an energy consumption model, and continuous production of the full-biodegradable material with low energy consumption, low volatile matter and high mechanical property is realized.

The invention relates to the technical field of 3D printing materials, and belongs to a nanofiber reinforced PETG composite material for 3D printing of large parts and a preparation method thereof, and the nanofiber reinforced PETG composite material for 3D printing of large parts is a blend containing nanofibers treated by a physical modifier, PETG, a compatilizer and a plasticizer. The preparation method of the nanofiber reinforced PETG composite material comprises the following steps: preparing the modified nanofiber; blending the modified nanofiber, PETG, a compatilizer and a plasticizer through a high-speed mixer to form a blended material; carrying out melt blending extrusion and granulation on the blended material by using a twin-screw extrusion method; after being dried, the prepared composite material particles can be processed into monofilaments through a single-screw extruder, and the particles can also be directly used for 3D printing. According to the material disclosed by the invention, the tensile strength, the bending strength and the bending modulus of the material are improved by utilizing the characteristics of relatively high softening point of PETG and high rigidity of nano cellulose.

The invention belongs to the technical field of electronic ceramic substrate materials, and particularly relates to a preparation method of a microcrystalline glass composite silicon nitride ceramic substrate, which is prepared from the following raw materials: 1-5% of alpha-phase silicon nitride powder, 86-95% of beta-phase silicon nitride powder, 0.2-3% of metal silicon powder, 2.5-8% of glass powder and 1.3-8% of metal oxide. The preparation method comprises the following steps: S1, mixing and grinding raw materials to obtain ceramic slurry; s2, adding Arabic gum into the ceramic slurry as a binder, and carrying out spray granulation; granulation powder is obtained; s3, carrying out dry pressing molding and cold isostatic pressing treatment on the granulation powder to prepare a ceramic plate blank; and S4, sintering and crystallizing the ceramic plate blank. According to the invention, the glass ceramic powder is introduced as a sintering aid and a second phase, and the sintering temperature of the silicon nitride is obviously reduced from the conventional temperature of more than 1800 DEG C to 1500 DEG C by utilizing the liquid phase effect of the glass ceramic powder in the sintering process, so that two modes of air pressure sintering and normal pressure sintering can be used, and the energy consumption and the requirements on equipment are reduced.