5324 results about "Pelletizing" patented technology

The invention discloses a reaction-sintered silicon carbide setter plate and a preparation method thereof. The reaction-sintered silicon carbide setter plate product is obtained through powder granulation, compaction and reaction sintering. Wherein the silicon carbide powder of the four particle size sections is matched, the particle size sections are uniform, stacking is more reasonable, coarse particles form a frame, fine particles are filled among the coarse particles, the powder structure is compact in property, and the compactness of a green body obtained after blank pressing is guaranteed; and spray granulation is performed after ball milling, so that all the raw materials and auxiliary materials are uniformly mixed. The surface of the green body pressed by a set oil pressure mold is also provided with a concave-convex structure, so that the contact area between the load bearing plate and the bottom of the domestic porcelain is reduced, air circulation between the load bearing plate and the bottom of the domestic porcelain is increased, and adhesion is effectively avoided. The product has the advantages of long service life, high strength and fast heat conduction, solves the problems of low strength, low heat conductivity and short service life of mullite, and also solves the industrial pain point of adhesion of a reaction-sintered silicon carbide setter plate.

The invention discloses a preparation method of high-polarization bismuth ferrite-lead titanate-barium zirconate titanate-based ferroelectric ceramic, which comprises the following steps: preparing oxide raw materials according to the chemical formula of the bismuth ferrite-barium titanate ceramic-based ferroelectric ceramic, mixing to obtain mixed powder, pre-sintering the mixed powder to obtain pre-sintered powder, granulating the pre-sintered powder to obtain granules, and sintering the granules to obtain the high-polarization bismuth ferrite-lead titanate-barium zirconate titanate-based ferroelectric ceramic. Performing compression molding on the granules to obtain a green body, performing degumming sintering on the green body to obtain sintered ceramic, and performing annealing treatment on the sintered ceramic to obtain the bismuth ferrite-lead titanate-barium zirconate titanate based ferroelectric ceramic. According to the invention, annealing treatment is carried out on sintered ceramic, after annealing treatment, defect dipoles generated by volatilization of Pb and Bi in the ceramic are rearranged under the action of a temperature field, relaxor ferroelectric-ferroelectric phase change occurs in a ceramic phase, a ferroelectric hysteresis loop reflects that the girdling of the loop is opened, and the rectangularity is increased; a bipolar strain curve is converted into a typical butterfly shape of ferroelectric from a bud shape, and the ferroelectricity of the ceramic is further greatly improved.

The invention relates to the field of cable materials, and provides a flexible flame-retardant polyolefin insulating material for a high-flexibility drag chain cable and a preparation method thereof.The flexible flame-retardant polyolefin insulating material comprises phosphorus-containing flame retardant surface modified boron nitride, polyphosphazene modified magnesium hydroxide nanowires, polyolefin matrix resin and the like. The phosphorus-containing flame retardant surface modified boron nitride is prepared by carrying out surface modification on hydroxyl modified hexagonal boron nitride through 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide and vinyl trimethoxy silane, and shows excellent flame retardant property and flexibility. The polyphosphazene modified magnesium hydroxide nanowire is prepared through silane coupling agent functionalization and polyphosphazene cross-linking polymerization, and has flame retardance and a reinforcing effect. The preparation method of the material comprises the steps of raw material premixing, melt blending, cooling granulation and extrusion molding. The material has the characteristics of flame retardance, high flexibility and the like, and is widely applied to dynamic high-flexibility cables in the fields of industrial automation equipment, robots, machine tool manufacturing, logistics conveying systems and the like.

The invention relates to the technical field of high polymer material preparation, and discloses a bamboo fiber graft modified full-biodegradable composite membrane material preparation process which comprises the following steps: firstly, performing hot mixing and cooling on dried bamboo fiber powder, anhydrous citric acid, choline chloride, activated zinc oxide and pentaerythritol to prepare a bamboo fiber modified premix; then mixing the biodegradable polyester resin with the premix; adding the mixture into an extruder, injecting epoxidized soybean oil into a barrel through a liquid metering device, and performing melt extrusion granulation under a vacuum exhaust condition; and finally carrying out blow molding to form the film. Through in-situ reaction extrusion of multi-component synergism, surface grafting of bamboo fibers, chain extension of a polyester matrix and interface chemical bonding of the bamboo fibers and the polyester matrix are achieved, interface compatibility is effectively improved, degradation of the material in the processing process is inhibited, and the mechanical property and thermal stability of the composite film material are remarkably improved; the process is efficient and environment-friendly, and the cost is controllable.

Provided are a water-resistant wood-plastic reinforced composite flooring and a manufacturing method therefor. Wood flour is boiled in boiling water for 3-4 hours, filtered and dried, to obtain dried wood flour; polypropylene, butyl acrylate, methyl methacrylate, maleic anhydride and dicumyl peroxide are mixed evenly, extruded and granulated, and dried to obtain a compatibilizer; the dried wood flour and polypropylene are mixed evenly, the compatibilizer is added and mixed evenly, then extrusion and granulation, and injection molded, are performed, to obtain a wood-plastic flooring blank; a composite resin emulsion and a photoinitiator are ultrasonically mixed evenly, and the wood-plastic flooring blank is immersed therein, then taken out and dried at room temperature, and then vacuum dried and UV cured, to obtain water-resistant wood-plastic reinforced composite flooring.

An ultrafine grain cemented carbide additive manufacturing method. WC-Co is used as a raw material, a crystal grain growth inhibitor is added, and a rare earth oxide is added as a reinforcing phase; paraffin and a trace amount of low-valence rare earth oxide powder are added, ball milling is carried out for coating cemented carbide powder, and oxygen control is carried out; the cemented carbide powder obtained by ball milling and an organic adhesive are loaded in a vacuum banbury mixer-granulator to prepare a printing feed, then a green body is printed using fused deposition modeling (FDM), and finally, degreasing and two-step sintering are carried out on the green body to prepare ultrafine cemented carbide. By means of the combined effect of the components and process optimization design, the powder properties are regulated, the process range of vacuum banburying and granulation and additive manufacturing is widened, and the problems of pores, interlayer cracks, and oxygen absorption in a printed green body, and abnormal grain growth, oxidation decarburization, and the formation of brittle η-phase in a sintered sample are solved. The prepared ultrafine grain cemented carbide exhibits high relative density, is free of metallurgical defects, possesses excellent mechanical properties, and is suitable for large-scale and mass production.

The invention belongs to the technical field of ceramics, and discloses a preparation method of fracture-resistant and wear-resistant ceramics. The preparation method comprises the following steps: weighing the raw materials in parts by weight; the preparation method comprises the following steps: mixing 40 parts of potassium feldspar, 10 to 25 parts of albite, 1 to 10 parts of kaolin, 1 to 10 parts of serpentine, 5 to 25 parts of dolomite, 2 to 9 parts of nano zirconium oxide, 0.1 to 1 part of nano cerium oxide, 0.1 to 1 part of nano molybdenum disulfide, 0.1 to 0.8 part of silicon carbide fiber, 0.5 to 2.5 parts of polyethylene glycol, 0.1 to 0.6 part of fullerene trifluoromethyl derivative, 0.1 to 3 parts of sodium dodecyl sulfate, 0.1 to 2 parts of sodium tripolyphosphate and 10 to 60 parts of solvent to obtain slurry; and carrying out spray granulation to obtain a blank, carrying out compression molding to obtain a green body, and sintering to obtain the fracture-resistant and wear-resistant ceramic. The breaking strength of the breaking-resistant and wear-resistant ceramic can exceed 70 MPa, and the length of a grinding pit does not exceed 8.5 mm.

The present invention belongs to the technical field of liners, and specifically discloses a high-wear-resistant mixed pelletizing machine liner and a preparation method thereof. The liner includes a base layer and a wear-resistant layer composited on the surface of the base layer. The base layer is made of high-strength alloy steel material, and its chemical composition is calculated by mass percentage as follows: C: 0.25-0.35%, Si: 0.4-0.8%, Mn: 1.2-1.6%, Cr: 0.8-1.2%, Mo: 0.2-0.4%, Ni: 0.3-0.6%, Nb: 1.0-1.6%, and the balance is Fe; the wear-resistant layer includes tungsten carbide particles, a composite alloy material, and an adhesive. The present invention adopts the above-mentioned high-wear-resistant mixed pelletizing machine liner and a preparation method thereof, aiming to solve the problems of insufficient wear resistance and short service life of existing mixed pelletizing machine liners, and improve the comprehensive performance of the mixed pelletizing machine liner through composite structure design and special preparation process.

The invention relates to a preparation method of high-strength and high-toughness composite silicon carbide ceramic, which comprises the following steps: mixing 70-82 parts of micron-sized alpha-silicon carbide powder, 5-15 parts of a mixed reinforced phase, 5-10 parts of a sintering aid, 1.9-2.1 parts of a dispersant and 0.9-1.1 parts of a binder to obtain a powder raw material, adding deionized water into the powder raw material, and carrying out ball milling to obtain water-based slurry; carrying out spray granulation on the water-based slurry to prepare spherical granulation powder; and adding the spherical granulation powder into a graphite mold, putting the graphite mold into a hot-pressing sintering furnace, heating to a sintering temperature, and carrying out hot-pressing sintering to obtain the high-strength and high-toughness composite silicon carbide ceramic. By adopting the method disclosed by the invention, the high-performance silicon carbide ceramic material with higher mechanical property and higher toughness can be obtained.

The invention discloses a clean production process of a blended fertilizer, which comprises the following steps: preparing and selecting raw materials; performing primary granulation on different raw materials to obtain uniform granular raw materials; performing closed ventilation storage on the granular raw materials; proportioning and metering the granular raw materials; mixing and stirring; finally, packaging is carried out, 4-5 mm particles obtained after the raw materials are subjected to extrusion forming through a pair of rollers and subjected to primary granulation are consistent in appearance state, air in the raw materials is removed through extrusion, gaps are compressed, the density and specific gravity of the formed particles tend to be uniform, and the product quality is improved. Blending layering caused by particle size, density difference and different adsorption capacities cannot occur when the raw materials are blended, the blended compound fertilizer meets the international general blending fertilizer proportioning principle, the completely-homogenized blending fertilizer quality requirement can be met, the processing cost is saved, the production efficiency is improved, and the production cost is reduced. And the problem of caking of the raw materials is effectively solved.

The invention discloses a degradable bamboo fiber express packaging bag and a preparation method thereof, and belongs to the technical field of express packaging. The packaging bag is prepared from, by mass, 32-42 parts of pretreated bamboo fibers, 22-28 parts of poly (butylene succinate), 9-14 parts of modified nano calcium carbonate, 12-16 parts of polycaprolactone, 6-11 parts of acetylated chitosan and the like, and the key raw materials are all treated through an exclusive pretreatment or modification process. The preparation method comprises the steps of raw material plasma activation, segmented high-speed mixing, vacuum drying, precise-parameter twin-screw extrusion granulation, secondary drying, precise film blowing, high-precision heat-sealing bag making and the like, and the technological parameters of all the steps are clear. The product disclosed by the invention can be efficiently degraded in a natural environment, has excellent tensile resistance, puncture resistance and impact resistance, is stable and controllable in processing process, and is adaptive to actual requirements of express packaging and industrial batch production.

The invention discloses a vertical circular mould biomass granulator which comprises a rack, the rack is formed by welding a bottom plate and a top plate, the left side of the top end of the bottom plate of the rack is fixedly connected with a mounting seat through a column body, the top of the mounting seat is provided with a grinding disc, and the top of the mounting seat is further provided with a circular mould mechanism. The circular mold mechanism is arranged, the circular mold mechanism is composed of a plurality of circular mold pieces, the circular mold mechanism is provided with two granulation hole sets, in the production process, if the lower granulation hole set is damaged, the circular mold mechanism can be turned over through matched use of the lifting mechanism and the turnover mechanism, the granulation hole set originally located on the upper portion is turned over to the lower portion, and therefore the circular mold mechanism can be turned over. Compared with the prior art, the circular mold mechanism can be replaced without manual operation of workers, continuous production is guaranteed, if a certain circular mold part is damaged, the whole ring-shaped circular mold mechanism is replaced in a traditional mode, only the circular mold part needs to be replaced, resources are saved, and waste is avoided.

The invention relates to a preparation method of high-heat-resistance low-warpage glass fiber reinforced flame-retardant PBT (Polybutylene Terephthalate) engineering plastic, which comprises the following steps: firstly, adding a premix into a double-screw extruder for melting, then respectively feeding a flame retardant and glass fiber into the double-screw extruder from a lateral feeding port, mixing with the molten premix, and extruding to obtain the high-heat-resistance low-warpage glass fiber reinforced flame-retardant PBT engineering plastic. After mixing, extruding a strip-shaped object from a machine head mouth mold of the double-screw extruder, finally cooling the strip-shaped object in a cooling water tank, and granulating by a granulator to obtain the high-heat-resistance low-warpage glass fiber reinforced flame-retardant PBT engineering plastic. The premix is obtained by uniformly mixing PBT resin II, low-warpage PBT master batch, a compatilizer, a crystallization inhibiting polymer, a flame-retardant synergist, an inorganic filler, a nucleating agent and other auxiliaries; the low-warpage PBT master batch is prepared by uniformly mixing PBT resin I, a transesterification inhibitor, a transesterification inhibition synergist and other auxiliaries and then carrying out melt extrusion granulation. The warping problem of the glass fiber reinforced flame-retardant PBT engineering plastic is solved, and the glass fiber reinforced flame-retardant PBT engineering plastic has relatively high thermal deformation temperature.

The invention discloses a high-weather-resistance halogen-free flame-retardant polyamide composite material and a preparation method thereof, and belongs to the technical field of high polymer materials. The composite material comprises the following raw materials in parts by weight: 20-60 parts of polyamide resin A, 0-20 parts of polyamide resin B, 10-50 parts of glass fibers, 0.1-2 parts of an ultraviolet absorbent, 0.1-2 parts of a free radical scavenger, 10-20 parts of a halogen-free flame retardant, 1-15 parts of a flame retardant synergist and 0.5-5 parts of a conventional auxiliary agent. The preparation method comprises the following steps: uniformly mixing the polyamide resin A, the polyamide resin B, the ultraviolet absorbent, the free radical scavenger, the flame-retardant synergist and the conventional auxiliary agent in a high-speed mixer according to the proportion to obtain a mixture, then adding the mixture into a double-screw extruder through main feeding, side feeding of the halogen-free flame retardant through a first side feeding and side feeding of the glass fiber through a second side feeding, and carrying out extrusion molding to obtain the flame-retardant polyamide composite material. And carrying out melt blending and extrusion granulation to obtain the high-weather-resistance halogen-free flame-retardant polyamide composite material. The obtained high-weather-resistance halogen-free flame-retardant glass fiber reinforced polyamide composite material is excellent in mechanical property, flame retardance and weather resistance.

The invention relates to a magnesia-carbon refractory material with high thermal shock resistance and erosion resistance and a preparation method thereof. The magnesia-carbon refractory material with high thermal shock resistance and erosion resistance is prepared from fused magnesia aggregate, fused magnesia fine powder, silicon powder, crystalline flake graphite, Al2O3-MgO-CaO core-shell structure raw materials and phenolic resin. The Al2O3-MgO-CaO core-shell structure raw materials are prepared by the following steps: uniformly mixing calcium carbonate, magnesium hydroxide and alumina micro powder by adopting a planetary ball mill, and then carrying out granulation treatment by adopting a disc granulator by taking polyvinyl alcohol as a binding agent, so as to obtain core particles; and mixing the inner core particles and the alumina micro powder by taking alumina sol as a binding agent, and further sintering to obtain the core-shell structure raw material. The Al2O3-MgO-CaO core-shell structure raw material is utilized to improve the comprehensive performance of the magnesia-carbon refractory material, and the prepared magnesia-carbon refractory material has excellent thermal shock resistance and slag corrosion resistance and can meet the requirements of the current steel industry for the magnesia-carbon refractory material.

The invention relates to a special cable sheath material for trucks and a preparation method thereof, and belongs to the technical field of cable sheath materials, the special cable sheath material comprises the following raw materials: 40-55 parts of polyvinyl chloride, 15-20 parts of high vinyl polybutadiene rubber, 12-16 parts of a modified reinforcing material, 0.5-1.5 parts of a stabilizer, 1-3 parts of an anti-aging agent, 2-4 parts of a compatilizer and 4-8 parts of a filler; according to the technical scheme, the plant-based compound is combined with caffeic acid, epoxidation is performed, and the composite plasticizer is obtained; the composite plasticizer is combined with the silanized graphene oxide to obtain a reinforcing material; combining the reinforcing material with an amino compound to obtain a modified reinforcing material; mixing polyvinyl chloride, high vinyl polybutadiene rubber, the modified reinforcing material, a stabilizer, an anti-aging agent, a compatilizer and a filler, and performing extrusion granulation to obtain the special cable protective sleeve material for the truck. The mechanical property, the corrosion resistance and the aging resistance of the protective sleeve are integrally improved, and the environmental protection property is good.

The invention discloses a plastic hollow plate and a manufacturing method thereof, the plastic hollow plate comprises the following components by weight: 30%-60% of a polypropylene matrix and 40%-70% of phosphogypsum powder, and polypropylene provides thermoplastic formability and toughness. The preparation method specifically comprises the following steps: 1) pretreating ardealite; 2) melt blending granulation; (3) forming a hollow plate; and 4) post-processing. The ardealite hollow plate has the advantages that the ardealite filling amount is increased, meanwhile, the bending strength and impact strength of a traditional hollow plate are improved, and the performance is improved by 20% or above compared with that of a traditional hollow plate with the same filling amount; the moisture content of the pretreated phosphogypsum is less than 6%, so that bubbles in the processing process are avoided, and the interface bonding strength is improved; the comprehensive utilization rate of industrial byproduct phosphogypsum is improved, and the production cost is reduced.

The invention relates to the technical field of solid waste recycling, in particular to a method for preparing ceramsite through multi-element solid waste co-treatment. The method comprises the following steps: S1, uniformly stirring and mixing waterworks sludge, washing-free waste incineration fly ash, polluted soil and iron tailing slag powder in proportion to obtain a stirred mixture; s2, directly putting the stirred mixture which is uniformly mixed and is in a wet state into a ceramsite drying and granulating kiln, and granulating in the kiln to obtain raw material balls; s3, the raw material balls enter a pyrolysis section in the kiln to be subjected to low-temperature pyrolysis treatment; s4, the pyrolyzed raw material balls enter a calcining kiln to be subjected to high-temperature sintering treatment; and S5, passing the obtained sample through a cooling kiln, and taking out the cooled sample to obtain the multi-element solid waste ceramsite. According to the method, pure solid waste is adopted for preparing the ceramsite, and the links of raw material drying and granulation in traditional ceramsite manufacturing are omitted. The sludge of the waterworks, the waste incineration fly ash, the polluted soil and the iron tailing slag are utilized in a high-valued manner, the energy consumption is low, and less secondary environmental pollutants are generated.

The invention discloses a high-performance special ceramic material and a preparation process thereof, and the preparation process comprises the following steps: proportioning tungsten carbide, ternary boride, titanium nitride, molybdenum, nickel, silicon, cobalt and other raw materials with nano silicon carbide whiskers according to a ratio, carrying out ball milling treatment, adding a forming agent, and continuing ball milling and granulation; and then, carrying out compression molding on the ceramic powder, carrying out liquid phase sintering in a CO atmosphere, and cooling to room temperature to obtain the high-performance special ceramic material. The Mo3NiB3 ternary boride is introduced, so that the hardness and impact resistance of the ceramic material can be improved, the interface bonding force between a ceramic matrix and a reinforcing phase is enhanced, and the bending strength is improved; the nano silicon carbide whiskers are subjected to nickel plating treatment, so that the interface bonding force can be improved, microcracks are reduced, and the strength and toughness of the ceramic material are enhanced; by optimizing the sintering process and adopting a staged heating mode, grain growth can be controlled, and the density and mechanical properties of the ceramic material are effectively improved.

The invention relates to a regenerated rubber and plastic asphalt composite modifier based on shear force-temperature-interface modification as well as a preparation method and application thereof. The regenerated rubber and plastic asphalt composite modifier comprises 65-75 parts of tire rubber powder, 17-25 parts of polyethylene, 8-12 parts of aromatic oil and 0-2 parts of a silane coupling agent (not 0). All the raw materials are mixed and then added into a double-screw extruder, gradient temperature control is conducted through a feeding area, a plasticizing area and a homogenizing area, and finally granulation is conducted to obtain the regenerated rubber and plastic asphalt composite modifier. Compared with the prior art, the invention creatively utilizes the effects of double-screw shear force, high temperature, interface activation of the silane coupling agent, physical melting recombination and chemical interface activation, efficiently improves the integration and activation efficiency and effect of the tire rubber powder and polyethylene, and greatly improves the performance of the modified asphalt.

The invention relates to the field of hygienic products, and particularly discloses a probiotic hygienic product and a preparation method thereof. The probiotic hygienic product comprises a probiotic non-woven fabric, the probiotic non-woven fabric contains fibers rich in probiotics, and a preparation method of the fibers rich in the probiotics comprises the following steps: dissolving soybean protein isolate and calcium chloride to obtain a receiving solution; performing coaxial electrostatic spraying on the shell layer solution and the core layer solution to obtain probiotic embedded particles; carrying out electrostatic spinning on polyethersulfone to obtain a polyethersulfone nanofiber membrane; adding the probiotic embedded particles into a pectin solution to obtain a spraying solution, and spraying the spraying solution on the polyether sulfone nanofiber membrane to obtain blended powder; and mixing the blended powder with PE resin and an auxiliary agent according to a mass ratio, extruding, granulating to obtain a shell material, and carrying out composite spinning on the shell material and PET slices. The probiotic hygienic product disclosed by the invention has the advantages of high survival rate of probiotics, good storage stability, high activity retention rate, high water-holding capacity and good antibacterial activity.

A marine vessel designed for the collection, shredding, and pelletizing of oceanic plastic waste. The vessel uses renewable energy sources such as solar panels and wind turbines to power onboard systems, including AI-enhanced sensors that detect and target high-density areas of plastic debris. Once collected, the plastic is shredded and processed into uniform plastic pellets optimized for use in plastic asphalt production. The vessel also includes storage compartments for the pellets and a crane system for transferring containers filled with pellets to adjacent vessels or shore-based transport. This integrated system addresses inefficiencies in traditional ocean cleanup methods by enabling immediate onboard processing, reducing transportation needs, and repurposing plastic waste into a valuable industrial resource, while significantly minimizing environmental impact through sustainable energy use.

The invention provides a superfine light-weight high-strength filler and a preparation method thereof, and belongs to the technical field of fillers. The filler is prepared from the following components in parts by weight: 30 to 100 parts of quartz sand, 1 to 10 parts of cullet, 1 to 15 parts of Al2O3, 7 to 15 parts of Li2O, 2 to 8 parts of P2O5, 1 to 12 parts of ZrO2, 3 to 6 parts of composite nucleating agent, 5 to 10 parts of carbonate, 10 to 20 parts of feldspar and 2 to 5 parts of sulfate. The preparation method comprises the following steps: mixing the quartz sand, the cullet, the Al2O3, the Li2O, the P2O5, the ZrO2 and the composite nucleating agent, melting at a high temperature to obtain a base material, nucleating and crystallizing at different temperatures, grinding, adding the carbonate, the feldspar and the sulfate, adding the binder, granulating, and sintering to obtain the product. The lightweight high-strength filler has the characteristics of sound absorption, noise reduction, fire prevention, flame retardance, light mass density, high compressive strength, low water absorption, ecological environmental protection and the like, and is suitable for lime, gypsum and cement-based products; particularly, the high-temperature-resistant and high-strength dry-mixed mortar has a good application prospect in dry-mixed mortar products, such as ceramic tile adhesives, light plastering and self-leveling, as well as acoustic boards, sound insulation barriers, heat insulation boards and fireproof board products.

The invention belongs to the technical field of ceramsite processing equipment, and particularly relates to unfired ceramsite processing granulation equipment and a preparation technology.The unfired ceramsite processing granulation equipment comprises a disc type granulator body, a granulation disc scraping plate, a scraping plate mounting frame and an adjusting support used for supporting the disc type granulator body, and the bottom end of the disc type granulator body is fixedly connected with a guide hopper; and the bottom end of the guide hopper is fixedly connected with a ceramsite compactness lifting mechanism. The granulation equipment disclosed by the invention not only has the functions of recovering and self-adjusting powdery ceramsite raw materials, but also has the functions of heating, pre-drying and removing pores under negative pressure, and has the function of preparing ceramsite without firing, and the compactness of the formed ceramsite is improved by reducing the pores and moisture in the formed ceramsite, so that the qualification rate of ceramsite granulation is improved, and the production cost is reduced. The ceramsite is prepared without firing, so that the energy-saving and environment-friendly effects of granulation are effectively improved, the requirement of low-carbon production at present is met, and meanwhile, large-scale production of the ceramsite is facilitated.

The invention provides coal-based porous carbon for preparing a silicon-carbon negative electrode material as well as a preparation method and application of the coal-based porous carbon, coal-based porous graphite is used as a matrix carbon material, polymer resin is used as a rigid bonding and coating material, heterogeneous elements such as B, N and P are used as doping materials, a carbon nanotube is used as a flexible conductive buffer material, and the materials are dispersed in a solvent to form slurry; through atomization granulation and high-temperature carbonization, heterogeneous element doped resin hard carbon is bridged with carbon nanotubes to construct a three-dimensional rigid-flexible conductive network to cooperatively coat the surface of the porous coal-based graphite, and doped heterogeneous elements are utilized to induce chemical-physical auxiliary activation to perform micro-mesoporous precise regulation and control pore forming on an inner core and a shell. The prepared novel coal-based porous carbon is high in porous framework particle strength and reasonable in pore distribution and has a three-dimensional rigid-flexible conductive network core-shell structure. The invention aims to solve the problems of unreasonable pore distribution of porous carbon, poor matrix strength and the like in the preparation process of a novel vapor deposition silicon-carbon negative electrode material.

The inventive technique process of grainy calcium material for preventing and treating peanut blight primarily includes: adopting the shell powder and weathered coal as raw materials, machining into peanut blight prevention material through agglomeration granulation. The invention has innovative and reasonable design, which not only has simple process, easy implementing, but also has low cost of raw materials, product application convenience, remarkable peanut blight prevention effect, and capability of promoting high-efficient production pf peanut. In particular, the invention applies coastal oyster shell wastes for machining calcium materials for preventing and treating peanut blight, which not only reduces environmental pollution, but also promotes recycling of resources, has very significant economic, social and ecological benefits and greater promotional value.

The invention relates to a full-biodegradable polyester composite material and a heat shrink film thereof. Corn starch, PBAT and PLA are used as main raw materials, glycerin, water and polyethylene glycol-6000 are used as composite plasticizers, B225 is used as an antioxidant, and solid paraffin and oleamide are used as lubricants. The preparation method comprises the following steps: adding corn starch, glycerol, water, PEG-6000, B225, solid paraffin and oleamide into a high-speed mixer, stirring to obtain plasticized corn starch, adding PBAT and PLA into the high-speed mixer, mixing with the plasticized corn starch, stirring, discharging, putting into an extruder, extruding and granulating to obtain a full-biodegradable polyester composite material, and extruding and blowing to obtain the thermal shrinkage film. The polyester composite material prepared by the invention can be biodegraded under the condition of matured compost, the biodegradation rate is 91.22%, the relative biodegradation rate is 96.55%, and products are carbon dioxide and water and meet the GB / T 41010-2021 standard requirements.

The invention discloses a preparation method of a POK and EVOH blending modified high-barrier material, which comprises the following steps: pre-drying, uniformly mixing, cooling and curing, air injection for water removal, pelletizing, secondary drying and the like to obtain the POK and EVOH modified high-barrier material, compounding the POK, EVOH and EAA according to a certain proportion to form a three-phase mixed system, and playing a synergistic effect to obtain the POK and EVOH blending modified high-barrier material. The oxygen barrier effect is improved; through the special compatilizer for POK, the compatibility of POK and the EVOH material is improved, and the mechanical property of the material is improved; the oxygen barrier effect of POK at high temperature and high humidity is basically not reduced, and the oxygen barrier effect of the whole system at high temperature and high humidity is improved; the antioxidant system improves the thermal stability of the EVOH material and the POK material during processing, and solves the problems that the materials are easy to decompose during processing and easy to yellow after being used for a long time.

The invention discloses a preparation process of a high-temperature-resistant and wear-resistant polymer composite material, which comprises the following preparation steps: (1) selecting polyether-ether-ketone as matrix resin, and drying the matrix resin at 150 DEG C for 4 hours; (2) preparing porous sphere-like boron carbide ceramic powder; (3) carrying out surface treatment on the prepared porous sphere-like boron carbide ceramic powder; and (4) uniformly mixing the boron carbide ceramic powder subjected to surface treatment in the step (3) and polyether-ether-ketone in a mild mixing manner, compounding with carbon fibers, and extruding and granulating by using a double-screw extruder to obtain the high-temperature-resistant and wear-resistant polymer composite material. Through the mode, the composite material prepared by the method does not contain PFAS chemical substances, is superior to the existing PTFE material in the aspects of wear resistance, environmental protection property, high temperature resistance and the like, and is an ideal reliable PTFE substitute material.

The invention discloses a preparation method of aluminum nitride by spray granulation, which belongs to the technical field of ceramic preparation. The method comprises: adding aluminum nitride powder and a dispersant into a ball mill for ball milling for 24 to 26 hours, adding an adhesive and a solvent thereto, wherein the adhesive is acrylic resin or PVB, and continuing ball milling for 15 to 18 hours after the adhesive and the solvent are added, the ball milling speed of the ball mill is set to 100 to 200 rpm, the diameter of the ball milling beads is 20 to 50 mm, the number of the ball milling beads is 200 to 300, and aluminum nitride slurry is formed after ball milling; the aluminum nitride slurry is sucked into a granulation tower, and the parameters of the granulation tower are set to: an air inlet temperature of 130 to 140 DEG C, an air outlet temperature of 80 to 90 DEG C, a rotation speed of an atomizing disk of 7000 to 8000 rpm, and a feed pump rotation speed of 50 to 60 rpm; collecting samples at a discharge port of the granulation tower, and then testing the samples and recording the test results.