2832 results about "Polyethylene terephthalate" patented technology

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The first polyester is contacted with a further organic compound in a volume section V3 to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced in the volume section V3 to obtain a first intermediate mixture. The first intermediate mixture comprises a first intermediate product and the further organic compound. First particulated material is added to the first intermediate mixture in a volume section V4. A filtering means is pre-coated with the first particulated material. At least one impurity is at least partially removed from the first intermediate mixture using the filtering means. The first particulated material has a median pore diameter in the range of 5 mm to 20 mm.

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The feedstock is contacted with a first amount of a first organic compound in a volume section V1 to obtain a first initial mixture. The first amount is in the form of a liquid. The first polyester is transported, and at least a fraction of the first amount of the first organic compound, from the volume section V1 to a volume section V2. The volume section V2 is at least partially filled with the first organic compound. A level of the first organic compound in the volume section V1 is at a height H1 from a floor, and a level of the first organic compound in the volume section V2 is at a height H2 from the floor. The first polyester is contacted with a further organic compound in a volume section V3, to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced in the volume section V3, to obtain a first intermediate mixture. The first intermediate mixture comprisesa first intermediate product,the further organic compound.H1<H2.

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The first polyester in the feedstock is in the form of a plurality of fragments. The feedstock is contacted with a first amount of a first organic compound in a volume section V1 to obtain a first initial mixture. The first amount is in the form of a liquid. The first polyester is contacted with a further organic compound in a volume section V3, to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced in the volume section V3, to obtain a first intermediate mixture. The first intermediate mixture comprisesa first intermediate product andthe further organic compound.30 wt-% or less of the fragments, based on a total weight of the plurality of fragments in the feedstock, have a thickness that is equal to or larger than 1.0 mm.

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The first polyester is contacted with a further organic compound in a volume section V3 to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced in the volume section V3 to obtain a first intermediate mixture. The first intermediate mixture comprisesa first intermediate product and;the further organic compound.First particulated material is added to the first intermediate mixture in a volume section V4. A temperature of the first intermediate mixture in the volume section V4 is in the range of 160° C. to 230° C.

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The first polyester is contacted with a further amount of a first organic compound in a volume section V2. At least one impurity is present in the volume section V2, and the volume section V2 has a first zone and a further zone. The first polyester is contacted with a further organic compound in a volume section V3 to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced in the volume section V3 to obtain a first intermediate mixture. The first intermediate mixture comprisesa first intermediate product; andthe further organic compound.A relative ratio of a particle count per area of the at least one impurity in the first zone to a particle count per area of the at least one impurity in the further zone is equal to or greater than 10.

One aspect is a method for producing a first intermediate product. A feedstock is provided that comprises a first polyester. The feedstock is contacted with a first amount of a first organic compound in a volume section V1 to obtain a first initial mixture. The first amount is in the form of a liquid. The first polyester is contacted with a further organic compound to obtain a further initial mixture. A weight average molar mass of the first polyester is reduced to obtain a first intermediate mixture. The first intermediate mixture has a first intermediate product, the further organic compound. A mass ratio of the feedstock to the first organic compound in the volume section V1 is in the range of 0.02 to 3.

A process for chemically recycling waste polyethylene terephthalate (PET) carpet fibers. The process comprises providing a waste carpet fiber composition comprising at least 75 wt % of PET and 6 wt % or less of ash; reacting the waste carpet fiber composition with methanol to produce a depolymerized poly ester mixture comprising polyester oligomers, dimethyl terephthalate (DMT), and ethylene glycol (EG); and recovering the DMT and the EG from the depolymerized polyester mixture.

The invention discloses a cold-resistant and damp-heat-resistant PETG / PP alloy floor base material and a preparation method thereof, and a floor and a preparation method thereof. The floor base material comprises the following raw materials in parts by mass: 5-20 parts of PETG resin, 2-8 parts of PP resin, 1-5 parts of a compatilizer, 3-10 parts of a flexibilizer, 20-70 parts of calcium carbonate, 3-10 parts of a modified inorganic fibrous filler, 0.2-2 parts of a chain extender, 1-3 parts of a lubricant, 0.5-2 parts of an antioxidant and 0.5-3 parts of an anti-hydrolysis agent. According to the cold-resistant and damp-heat-resistant PETG / PP alloy floor base material and the preparation method thereof as well as the floor and the preparation method thereof, the dimensional stability, cold resistance and damp-heat resistance of a polyester environment-friendly floor material can be improved.

The invention discloses a high-toughness polyester heat shrinkage film not prone to brittle fracture and a preparation method thereof, and belongs to the technical field of polymer packaging materials. A specific formula of the polyester heat shrinkage film consists of pure polyethylene glycol terephthalate, dihydric alcohol modified polyethylene glycol terephthalate, polybutylene terephthalate, a toughening-crystallization nucleating complexing agent, a crystallization accelerant, an opening slipping agent and filler. According to the polyester heat shrinkage film obtained by the invention, the thickness is 31.1-51.6 microns, the tensile strength is TD193-202 MPa, the tensile strength is MD23-85 MPa, the elongation at break is TD26-52%, the elongation at break is MD52-46%, the shrinkage rate TD is 47-80%, the shrinkage rate is MD0-15%, the haze is 4.2-5.0%, the light transmittance is 86.5-87.4%, and the elongation at break is not greatly reduced after the polyester heat shrinkage film is placed in a normal-temperature and normal-humidity environment for 24 months and placed in a high-temperature and high-humidity environment for 18 days.

The invention belongs to the technical field of polymer heat conduction, and particularly relates to a preparation method of a high-heat-conductivity polymer with modified boron nitride as filler, which comprises the following steps: (1) dissolving boron nitride nanosheets into tetrahydrofuran, ultrasonically dispersing uniformly, adding a modifier for reaction, then removing tetrahydrofuran by using a rotary evaporator, transferring into deionized water, and drying to obtain a boron nitride nano-sheet; drying to obtain a modified boron nitride nanosheet; (2) dispersing carbon nanotubes in deionized water, stirring and carrying out ultrasonic treatment, adding the modified boron nitride nanosheets, and then carrying out freeze orientation treatment and freeze drying treatment to obtain a porous foamed composite heat-conducting filler; and (3) carrying out melt blending on the composite heat-conducting filler and polyethylene glycol terephthalate, and carrying out hot press molding to finally prepare the modified high-heat-conductivity polymer. According to the invention, the composite heat-conducting filler improves the interfacial compatibility and dispersity with a polymer matrix, and reduces the interfacial thermal resistance of the composite material, so that the modified polymer has good application in the aspect of heat dissipation of electronic equipment.

The invention relates to an antistatic MLCC release film base film and a preparation method thereof. The antistatic MLCC release film base film is prepared by melt blending and biaxial stretching of PET master batch, an antistatic composition and a nano filler, wherein the antistatic composition is prepared by compounding modified PET-PEG and thiophene modified aromatic polyamide; the nano filler is prepared by carrying out melt extrusion on KH550 modified talcum powder and MAH-g-PET (maleic anhydride-grafted polyethylene terephthalate). The antistatic composition disclosed by the invention has the beneficial effects that the antistatic composition is formed by interweaving two polymers, and a stable three-dimensional conductive network is constructed in the PET film, so that the antistatic performance is more efficient, lasting and stable. In addition, through chemically bonded modified talcum powder, the smoothness and low roughness are provided, and meanwhile reinforcing and toughening are achieved; and the single-layer extrusion process can realize ultrathin thin film, the production process is simplified, and the production cost is greatly reduced.

A packaged food product includes a food product in packaging formed from a polyethylene film laminate body having a main polyethylene (PE) film layer and an ethylene vinyl alcohol (EVOH) layer. The packaging is laser date coded, with the laser date coding being established in the EVOH layer. Of the overall packaging, the ethylene vinyl alcohol layer is quite thin, generally having a thickness which is no greater than 5% of a thickness of the food packaging. The entire food packaging is readily recyclable, particularly by being at least essentially void of any polypropylene polymers and polyethylene terephthalate. The EVOH layer can be the outermost layer of the packaging, such as with the packaging being limited to just the PE and EVOH layers, or the packaging can include one or more other layers, such as cold seal, tie and / or ink layers.

The invention discloses an automobile heat-insulating film and a preparation method thereof, and belongs to the technical field of heat-insulating films, and the heat-insulating film is prepared by introducing nanometer indium tin oxide, nanometer tungsten oxide, nanometer titanium oxide, nanometer zinc oxide and other nanometer oxides and combining with a modified material. The preparation method comprises the following steps: mixing nano oxide with water, performing ultrasonic dispersion, adding a coupling agent and a modified material to form composite slurry, mixing the composite slurry with polymers such as polyethylene glycol terephthalate and a plasticizer, coating the surface of glass with the mixture, and drying. Compared with the prior art, the obtained heat insulation film not only has excellent optical transparency and heat insulation effect, but also shows good mechanical property and environmental erosion resistance, and meets the strict requirements of modern automobiles on heat insulation and protection performance.

The invention relates to the technical field of PET materials, and particularly discloses a wear-resistant PET bottle and a preparation process thereof. The wear-resistant PET bottle is prepared from the following raw materials: PET resin, modified ceramic powder, glass fibers, a flexibilizer, an antioxidant, a light stabilizer and a lubricant. Wherein the modified ceramic powder comprises B2O3-Al2O3 complex-phase powder and a titanate coupling agent, the B2O3-Al2O3 complex-phase powder is modified by the titanate coupling agent, one end of a coupling agent molecule is connected with B2O3-Al2O3 complex-phase powder particles through chemical action, and the other end of the coupling agent molecule is crosslinked with PET resin, so that the compatibility of the ceramic powder and matrix resin is improved; and the ceramic powder is uniformly dispersed in the PET resin, so that the wear resistance of the PET resin is effectively enhanced.

The invention belongs to the technical field of packaging adhesive films for photovoltaic modules, and particularly relates to a water-blocking and oxygen-blocking adhesive film for photovoltaic module packaging and a preparation method of the water-blocking and oxygen-blocking adhesive film for photovoltaic module packaging, and the water-blocking and oxygen-blocking adhesive film comprises a water-blocking layer and an oxygen-blocking layer which are adjacent to each other through co-extrusion; wherein the waterproof layer is prepared from the following materials in parts by mass: 100 parts of grafted polyolefin resin, 0.05 to 0.5 part of alkaline nano oxide and 0.1 to 1 part of antioxidant; the oxygen barrier layer is prepared from the following materials in parts by mass: 100 parts of oxygen barrier resin, 0.1-1 part of an oxygen absorbent, 0.1-1 part of a silane coupling agent and 0.05-0.5 part of a light conversion agent; the oxygen-resistant resin comprises any one or a combination of more of PS (polystyrene), PE (polyethylene), PET (polyethylene terephthalate), PB (polybutylene), PP (polypropylene), PVC (polyvinyl chloride), PVDC (polyvinyl dichloride), PA6 (polyamide 6) and EVOH (ethylene-vinyl alcohol).

The invention relates to the technical field of PET optical films, and particularly discloses a high-light-transmittance blue-light-resistant PET optical film and a preparation method thereof, and the high-light-transmittance blue-light-resistant PET optical film is prepared from the following raw materials by weight: 70-85% of a polyethylene glycol terephthalate resin matrix; 3%-8% of a benzotriazole anti-blue light agent; 5%-12% of a silicon dioxide nano anti-reflection agent; 2%-6% of nano zinc oxide or nano cerium oxide; 1.5% to 4% of a polycarbodiimide cross-linking agent; 0.5%-3% of an anti-blocking agent; 0.4%-1.5% of an antioxidant; 0.4%-1.0% of an ultraviolet light absorber; the balance is a processing aid; the preparation method comprises the following steps: S1, pretreating the raw materials; s2, a mixing procedure; and S3, extruding and coating. The PET optical film provided by the invention has high optical properties of high light transmittance, blue light resistance and low haze, and has the advantages of high light transmittance and blue light blocking rate of the optical film and improvement of the application range of the optical film.

The invention discloses an environment-friendly antibacterial high-barrier retort pouch and a preparation method thereof, belongs to the technical field of packaging materials, and aims to solve the problem that the antibacterial property and barrier property of the retort pouch need to be further improved. The environment-friendly antibacterial high-barrier retort pouch is obtained by laminating, curing and cutting a PET (Polyethylene Terephthalate) film, a nylon film and a modified polypropylene film through an adhesive; the preparation method of the modified polypropylene film comprises the following steps: reacting 10-hydroxycapraldehyde with amino modified titanium dioxide to obtain modified titanium dioxide; reacting allyl succinic anhydride with the modified titanium dioxide to obtain allyl succinic anhydride grafted modified titanium dioxide; carrying out melt blending on the intermediate I, polyethylene and a compatilizer to obtain a melt, and carrying out extrusion, tape casting, trimming and rolling to obtain a modified polypropylene film; the environment-friendly antibacterial high-barrier retort pouch prepared by the preparation method disclosed by the invention not only has antibacterial property and barrier property, but also has good high-temperature resistance.

An apparatus includes an ultrasonic sensor stack configured to transmit and receive ultrasonic waves. The ultrasonic sensor stack includes at least a thin film transistor layer, a piezoelectric layer, and a thin electrode layer. The ultrasonic sensor stack further includes a tunable metal layer coupled to the thin electrode layer and an acoustic layer coupled to the tunable metal layer, where the tunable metal layer has a thickness greater than a thickness of the thin electrode layer. The thickness of the tunable metal layer may be configured to match a peak frequency in an ultrasonic frequency range of the ultrasonic waves transmitted by the ultrasonic sensor stack. In some implementations, the tunable metal layer includes a copper layer and the acoustic layer includes polyimide or polyethylene terephthalate.

The invention relates to the technical field of polyester fibers, and discloses a preparation method of antibacterial modified polyester hollow fibers, which comprises the following steps: by taking nitrilotriacetic acid, thionyl chloride, epoxy chloropropane, eugenol and the like as raw materials, carrying out acylating chlorination reaction, quaternization reaction and esterification reaction to obtain eugenol epoxy quaternary ammonium salt. The preparation method comprises the following steps: carrying out ring-opening reaction on carboxyl groups in graphene oxide and epoxy groups in eugenol epoxy quaternary ammonium salt to obtain modified graphene, uniformly mixing the modified graphene with polyethylene glycol terephthalate, and carrying out a series of steps to finally obtain the antibacterial modified polyester hollow fiber. Eugenol and quaternary ammonium salt are utilized to improve the antibacterial property of the polyester hollow fiber, and graphene is utilized to improve the mechanical property of the polyester hollow fiber. The polyester hollow fiber prepared by the invention has excellent mechanical properties and antibacterial properties.

According to the waterproof composite PET plate disclosed by the invention, a small amount of permeated water can be rapidly absorbed through a water absorption block and water flow is guided to an expansion block, and the expansion block expands after absorbing water and extrudes a sealing sleeve, so that the sealing performance of a splicing area is remarkably enhanced; the water seepage treatment efficiency is further optimized through the flow guide blocks and the flow guide bundles, a secondary sealing barrier is formed under the condition that the water seepage amount is increased, and further water seepage is effectively prevented; in addition, the flow guide heat absorption plate can accelerate water vapor discharge and recover the water absorption capacity of the water absorption block and the expansion block through the design of a wave-shaped structure and evaporation anti-seepage holes in combination with heat transfer of heat conduction fibers, the service life of the assembly is prolonged, and the modular design is adopted, so that the production cost is reduced, and the production efficiency is improved. The whole protection system is convenient to install, maintain and replace, is suitable for scenes such as building outer walls needing waterproof splicing, and has the remarkable protection effect and economical efficiency.

A method of preparing a preformed fiber optic circuit for later termination to at least one fiber optic connector includes providing a substrate for supporting a plurality of optical fibers, the substrate including at least one layer of flexible foil, wherein the flexible foil may be formed from polyethylene terephthalate (PET) according to one example and peeling a layer including at least the optical fibers from the at least one layer of flexible foil.

The invention provides a method for catalytically converting waste PET (Polyethylene Terephthalate) plastic into 1, 4-cyclohexanedimethanol by a two-step method, which comprises the following steps of: 1, hydrogenating the waste PET plastic dispersed in methanol under the action of a nickel-based catalyst to obtain dimethyl 1, 4-cyclohexane dicarboxylate; and 2, centrifugally separating the catalyst and the reaction liquid in the step 1, and hydrogenating the reaction liquid under the action of a CuMgAl catalyst to obtain the target product 1, 4-cyclohexanedimethanol. The 1, 4-cyclohexanedimethanol is a key raw material for producing high-end polyester, and has very high market requirements. Under the optimal reaction condition, the molar yield of the 1, 4-cyclohexanedimethanol can reach 83.8%, and the separation purity reaches up to 99.5%. According to the method, upgrading and recycling of the PET waste are achieved so as to cope with the threat of white pollution to the ecological environment and human health.

The invention provides a PEF hydrogen bond reinforced modified polyester material and a preparation method thereof, and the preparation method comprises the following steps: blending 2, 5-furandicarboxylic acid and a third monomer hydroxy acid, and copolymerizing under the action of ethylene glycol to synthesize bio-based furan polyester, namely the PEF hydrogen bond reinforced modified polyester material. The introduced hydroxyl is used as a hydrogen bond donor to enhance the PEF copolyester material, so that the interaction strength and the chain stacking density between PEF chains are improved, the toughness, the melt strength and the crystallization rate of PEF can be improved by only adding a small amount of hydroxyl, and the barrier property of PEF copolyester is maintained to be more than 5 times of that of PET (Polyethylene Terephthalate).

The invention belongs to the technical field of high polymer materials, and particularly relates to a high-strength papermaking forming net fiber. Comprising the following raw materials in parts by weight: 75-90 parts of polyethylene glycol terephthalate, 5-15 parts of polybutylene terephthalate, 3-10 parts of a modified fiber filler, 2-5 parts of modified graphene, 2-8 parts of silicon dioxide, 0.5-2 parts of a silane coupling agent KH-560, 1-3 parts of an anti-hydrolysis agent, 0.5-1.5 parts of an antioxidant and 0.3-1 part of a lubricant. Wherein the modified fiber filler is prepared by sequentially carrying out modification processes such as silane coupling agent, citric acid-glycerol esterification, iron bismuth oxide loading and the like on glass fibers; the modified graphene is prepared by introducing dopamine, cerium ions and glycidyl methacrylate for modification. The mechanical strength, the hydrolysis resistance and the wear resistance of the fiber are remarkably improved through the synergistic effect of all the components and the melt spinning-multi-stage stretching process, and the fiber is particularly suitable for a forming net of a high-speed paper machine.

The invention relates to a glass fiber reinforced PET composite material and a preparation method thereof, and belongs to the technical field of polymer composite materials. The composite material is prepared from the following raw materials in parts by weight: 100 parts of PET (Polyethylene Terephthalate) master batch, 32 to 45 parts of modified glass fiber, 0.19 to 0.24 part of nucleating agent, 1.6 to 2 parts of lubricating agent and 0.12 to 0.15 part of antioxidant, the modified glass fiber is prepared by grafting sulfydryl on the surface of glass fiber by KH-580 to prepare sulfhydrylated glass fiber, reacting tert-butyldimethylamine with 2-bromoethanol to form hydroxyl-terminated quaternary ammonium salt, substituting with octylene trichlorosilane to form a modifier, and adding alkenyl containing alkyl long chains introduced into the modifier molecule with the sulfydryl grafted on the surface to prepare the modified glass fiber. Introducing modifier molecules to the surfaces of the glass fibers; and the modified glass fiber improves the strength of the composite material and keeps high impact resistance.

The invention discloses supercritical extrusion liquid crystal fiber reinforced PET foam and a preparation process thereof. The preparation process comprises the steps of material drying, liquid crystal spinning, material granulation and extrusion foaming. The liquid crystal polymer macromolecular chain used in the invention is different from the traditional polymer in zigzag, random coil and internetwork macromolecular structure form, and the liquid crystal polymer consists of rigid and straight macromolecules without internetwork; under the melt forming condition, the viscosity is sharply reduced, and rigid macromolecules are very easy to be arranged in one direction along the height orientation of the melt flowing direction; after cooling and curing, the macromolecule arrangement is kept to form highly-oriented rod-like macromolecules; the macromolecular structure form formed by the aromatic polyester basic chain has the advantages of high strength, high modulus and excellent mechanical property.

Provided is an exterior material for a power storage device which excels in formability and heat resistance.　The exterior material for a power storage device is composed of a multilayer body that comprises a base material layer, a barrier layer, and a heat-fusible resin layer, in that order. The base material layer is a polyester film containing polyethylene terephthalate and polybutylene terephthalate at a mass ratio of 65 / 35 to 90 / 10. The tensile elongation at break of the polyester film in the width direction is 90 to 155%.

The invention relates to the technical field of automobile interior and exterior composite material preparation, in particular to a full-structure recyclable polyethylene glycol terephthalate filament felt and a preparation method and application thereof. The method comprises the following steps: spinning by taking low-melting-point modified PET as a skin layer and unmodified PET as a core layer to obtain a PET filament with a skin-core structure; carrying out web forming and heat treatment to obtain a PET long fiber web; needling the PET long fiber net to obtain a PET filament felt; the PET filament felt can be used for preparing an automobile interior and exterior composite material through a mold pressing process. The full-structure recoverable PET filament felt provided by the invention is remarkably improved in the aspects of preparation process and recoverability, and an automobile interior and exterior composite material prepared from the full-structure recoverable PET filament felt also has outstanding performance in the aspects of light weight, NVH (Noise Vibration and Harshness) resistance and cost effectiveness, so that the comprehensive performance of the automobile interior and exterior composite material is favorably improved.

The invention relates to the technical field of polyester, in particular to a flame-retardant and antibacterial dual-function fiber and a preparation method thereof. The flame-retardant antibacterial fiber overcomes the defects that existing fibers are poor in flame retardance and antibacterial property. According to the invention, PET resin, a composite modified auxiliary agent master batch and a composite flexibilizer are used as raw materials, and the bifunctional fiber is prepared through melting and spinning; wherein the composite modified additive master batch is prepared from the following raw materials: PET (Polyethylene Terephthalate) resin, aluminum diethylphosphinate, modified halloysite nanotubes, modified zinc oxide nanowires and zinc borate; the modified halloysite nanotube is prepared from the following raw materials: a halloysite nanotube, KH560 and phosphoric acid; the modified zinc oxide nanowire is prepared from the following raw materials: zinc nitrate hexahydrate, hexamethylenetetramine and sodium hypophosphite. By controlling the dosage of each component and processing technological parameters, the finally prepared difunctional fiber has good flame retardance and good antibacterial property, and is suitable for manufacturing curtains.

The preparation method comprises the following steps: preparing PET non-woven fabric raw paper, preparing a nano-zinc oxide particle dispersion liquid, dipping the PET non-woven fabric raw paper in a solution, carrying out heat treatment to form a functional PET non-woven fabric, preparing a functional alkenyl ionic liquid, carrying out heat treatment to form a PET non-woven fabric, and carrying out heat treatment to form the PET reinforced bi-crosslinked polyionic liquid composite solid electrolyte. Adding a cross-linking agent, a lithium salt, a plasticizer and a photoinitiator to prepare an electrolyte precursor solution; the functional PET non-woven fabric is placed in the electrolyte precursor solution, standing and dipping are carried out under the vacuum condition, then thermal polymerization and photopolymerization are carried out, and the solid electrolyte is prepared and applied to the solid polymer lithium ion battery; the zinc oxide particles are compounded into the PET non-woven fabric to form the non-woven fabric which is thin in thickness, high in tensile strength and appropriate in porosity, and the non-woven fabric is cross-linked with the functionalized alkenyl ionic liquid and the electrolyte precursor solution step by step, so that the ionic conductivity, the electrochemical window and the thermal stability of the solid electrolyte and the safety performance of the battery in use are improved.