The application discloses a preparation method of a polyanionic
sodium ion battery positive
electrode material, and comprises the following steps: S1, preparation of a precursor solution: a
transition metal M source, an acid solution and a complexing agent are mixed and dissolved to form a precursor solution; S2, preparation of a pre-oxidized precursor solution: an
oxidizing agent is added to the solution to generate a pre-oxidized precursor solution; S3, preparation of M(OH)x
precipitation: a pH value of the pre-oxidized precursor solution is adjusted so that
transition metal ions in the solution are precipitated in the form of M(OH)x; S4, preparation of a precursor
powder: the M(OH)x
precipitation, a
sodium source, a
phosphorus source and a
carbon source are mixed wetly to obtain a precursor
slurry; S5,
drying of the precursor
powder: the precursor
slurry is dried and separated to obtain a dried precursor
powder; and S6, high-temperature
sintering: the precursor powder is sintered at a high temperature to obtain a polyanionic material. The polyanionic
sodium ion battery positive
electrode material has the characteristics of excellent electrochemical performance, high compaction density and low cost.