The present invention relates to a SiC@C
nanowire quasi-array with a core-shell structure and a preparation method and application thereof, and belongs to the technical field of
nanomaterials. The present invention discloses a SiC@C
nanowire quasi-array with a core-shell structure, wherein the
phase composition of SiC in the SiC@C
nanowire quasi-array is 3C-SiC, and the C of the shell layer is a carbon material doped with
sulfur after freeze-
drying and
carbonization of a PEDOT layer. The present invention also discloses a preparation method of a SiC@C nanowire quasi-array with a core-shell structure, wherein the preparation method comprises: covering the pretreated carbon cloth on the
crucible mouth containing
polysilazane and
melamine powder, heating in a high-temperature
atmosphere furnace, and cooling to obtain a carbon cloth depositing a SiC quasi-array; arranging the carbon depositing SiC nanowires in a reaction
vacuum chamber, inducing gaseous EDOT into the reaction
vacuum chamber, and introducing gaseous FeCl3 into the reaction
vacuum chamber to deposit a SiC@PEDOT nanowire quasi-array, and washing, freeze-
drying, and carbonizing to obtain a
sulfur-doped SiC@C nanowire
composite material.