Preparation method of super capacitor

A supercapacitor and electrode technology, which is applied in the field of supercapacitor preparation, can solve the problems of preparation process and complex equipment, and achieve the effects of simple preparation method, simplified production process, and reduced internal resistance

Inactive Publication Date: 2010-03-03
JIANGSU CHUANGLAN SOLAR AIR CONDITIONER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] The purpose of the present invention is to solve the shortcomings of the preparation process and complex equipment in the prior art, simplify the preparation process of supercapacitors, save energy, and prevent environmental pollution; the carbon nanotubes of the present invention are directly grown on the foamed nickel substrate without Binder is used; at the same time, porous nickel foam is used as the substrate, the volume density of the electrode material is higher, and the pore distribution is reasonable

Method used

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  • Preparation method of super capacitor
  • Preparation method of super capacitor
  • Preparation method of super capacitor

Examples

Experimental program
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Effect test

Embodiment 1

[0019] Embodiment one: (1) the nickel foam is cut into 10mm*10mm rectangular small pieces; (2) it is placed on the porcelain boat, and then the thermocouple probe and the porcelain boat are put into a suitable area of ​​the CVD reaction furnace; (3) Introduce argon (Ar) to remove the air in the CVD reaction furnace and serve as a protective atmosphere. The flow rate is 200ml / min, and the air is ventilated for 40 minutes to ensure that the air is exhausted; (4) raise the temperature of the CVD reaction furnace to 620°C , and then the reaction gas acetylene (C 2 h 2 ), the flow control was 30ml / min, and the reaction was 10 minutes; (5) turn off the acetylene gate, continue to feed argon to make it drop to normal temperature, then take out the foamed nickel with carbon nanotubes; (6) take out the foamed nickel Nickel is directly used as an electrode of a supercapacitor, and finally assembled into a supercapacitor. The 80,000-fold scanning electron micrograph of the carbon nanot...

Embodiment 2

[0020] Embodiment two: In this embodiment, the reaction furnace is heated up to 550° C., and then the reaction gas acetylene (C 2 h 2 ), flow control is 40ml / min, reacts 1 minute; Other reaction conditions are with embodiment one.

Embodiment 3

[0021] Embodiment Three: In this embodiment, the reaction furnace is brought to 650° C., and then the reaction gas acetylene (C 2 h 2 ), flow control is 25ml / min, reacts 15 minutes; Other reaction conditions are with embodiment one.

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Abstract

The invention relates to a preparation method for a super capacitor, comprising the following steps: (1) placing a foam nickel substrate in a chemical gas phase deposition reacting furnace, introducing argon for 10-60 minutes, exhausting air in the furnace, then heating the furnace to 450-750 DEG C, introducing hydrocarbon gases in an argon atmosphere at a flow rate between 25ml/min and 40ml/min,reacting the mixture for 30 seconds to 50 minutes at a temperature of 450-750 DEG C, and obtaining foam nickel on which carbon nano tubes grow after finishing the reaction; (2) removing surface loosing layer products, directly using the foam nickel substrate on which the carbon nano tubes grow as electrodes of the super capacitor; and (3) drying the electrodes with same thickness and size, which are obtained from the step (2), fully soaking the electrode with electrolyte for 1-36 hours, separating a diaphragm soaked with the electrolyte and assembling the components to obtain the super capacitor; and the hydrocarbon gases are acetylene, methane, ethylene or propylene. The carbon nano tubes directly grow on the foam substrate without a binding agent; and the foam nickel is used as the substrate, the volume density of electrode substances is higher and holes are reasonably distributed.

Description

technical field [0001] The invention belongs to the field of preparation and manufacture of energy storage materials and devices, and in particular relates to a preparation method of a supercapacitor. Background technique [0002] Supercapacitor is a new type of energy storage device whose performance is between traditional capacitors and batteries. It has the characteristics of high specific energy of batteries and high specific power of traditional capacitors. Supercapacitors also have the following advantages, such as: 1) they can charge and discharge instantaneously with large currents, 2) they have a high cycle life, 3) they have a wide operating temperature range, and 4) they are safe and pollution-free. Super electric heaters have been widely used as the main power supply of timers, flashlights and electric toys, as well as backup power supplies for computers and mobile phones, etc. Especially in the booming electric vehicles, the combined use of supercapacitors and ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G9/155H01G9/058H01G11/86
CPCY02E60/13
Inventor 潘春旭石锐
Owner JIANGSU CHUANGLAN SOLAR AIR CONDITIONER
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