The invention discloses a preparation method of a
nickel-based reverse catalyst with an
oxide layer
coating structure and photo-thermal
methanation application, the catalyst takes
metal Ni for dissociating
hydrogen as a carrier, a low-dimensional nano
metal M
oxide coating structure is loaded on the surface of the carrier to construct an M / Ni reverse catalyst, the
metal M is one or two of Ce, Zr, Al, Ti, Zn and Mg, and the metal M is one or two of Ce, Zr, Al, Ti, Zn and Mg. And the
molar fraction of the load phase metal M is 5-40% based on 100% of the
molar fraction of all metals in the catalyst. Through a simple
coprecipitation method, a continuous
nickel metal phase with
hydrogen dissociation capacity is prepared to serve as a carrier, a low-dimensional nano
oxide is loaded to construct a reverse catalyst, an oxide layer
coating structure is constructed on the surface of the catalyst, and the oxide layer coating structure and the loaded nano oxide form a
heterojunction. The catalyst disclosed by the invention shows excellent photo-thermal catalytic performance under mild illumination of 0.7 W.cm <-2 > without an external heat source, the surface heterostructure of the catalyst enhances the photo-response capability under a low-light-intensity condition, and an efficient photo-thermal synergistic effect is realized.