The present invention discloses a Mg, O, Br triple-doped Li-Y-Cl-S-based
amorphous solid electrolyte material, its preparation method and application, belonging to the technical field of all-
solid-state
lithium batteries, with a chemical general formula of Li a Y b S d‑z O z Cl c‑y Br y Mg w , where Mg2 + substitutes for Li + and introduces equimolar
lithium vacancies, O 2‑ substitutes for part of S 2‑ , Br ‑ substitutes for part of CI ‑‑ The preferred
doping range is 0.1 ≤ z ≤ 0.3, 0 < y ≤ 0.4, 0.05 < w ≤ 0.3. This material is prepared by a high-energy ball milling mixing method combined with a low-temperature rapid heat treatment process, presenting a single-phase amorphous structure, with a room-temperature
ionic conductivity ≥ 1.2x10 ‑2 S / cm, significantly reducing the
interfacial impedance and greatly improving the
air humidity resistance stability. When applied to an all-
solid-state
lithium metal battery, it has good compatibility with a high-
nickel NMC811 positive
electrode and a lithium negative
electrode, can achieve long-term stable
cycling at
room temperature, and significantly improve the battery safety and cycle life.