This invention discloses a
dry gas hydrogenation catalyst and its preparation method. The catalyst includes an
alumina support component,
active components consisting of Group VIB and Group VIII
metal sulfides, and
active agent a in a metallic state selected from one or more of Cu, Ag, Ni, Co, W, and Mo.
Active agent b is in an oxidized state consisting of one or more of Li, Na, K, Cs, Mg, and Ca. The preparation method is as follows:
Boehmite dry gel
powder is calcined, impregnated with an
active component impregnation solution, dried, calcined again, and then calcined in a mixed
atmosphere of H2S and H2 to obtain
powder E; the
boehmite dry gel
powder is impregnated with
active agent a impregnation solution, dried, and calcined in a
hydrogen atmosphere to obtain powder F; powder E and F are mixed,
active agent b impregnation solution is added, and the mixture is shaped, dried, and calcined to obtain the
dry gas hydrogenation catalyst. The catalyst prepared by this method exhibits good performance in removing impurities such as
oxygen, CO, and CO2, and suitable olefin hydrogenation saturation performance, effectively improving catalyst lifetime.