5results about How to "Reduce chlorine content" patented technology

The invention discloses a chlorine-containing pyrolysis oil radial moving bed reaction adsorption dechlorination hydro-conversion method, and belongs to the technical field of chlorine-containing oil product hydrotreatment and refining. According to the method, chlorine-containing pyrolytic oil is sequentially subjected to fixed bed selective hydrogenation, radial moving bed reaction adsorption dechlorination and fixed bed deep hydrofining reactor treatment; the radial moving bed is filled with a core-shell structure reaction and adsorption integrated catalyst, the core is a hydrodechlorination active component, the shell mainly adopts zinc oxide to adsorb HCl and is fixed in situ, and meanwhile, online addition and discharge of the catalyst are realized through the radial moving bed. According to the invention, poisoning of chlorine to the catalyst is effectively inhibited, the corrosion risk of equipment is reduced, shutdown of the device is avoided, the dechlorination efficiency is improved, the continuous operation period is prolonged, efficient, stable and economical hydro-conversion of the chlorine-containing pyrolytic oil is realized, and the obtained product can be used as clean fuel oil or a chemical raw material.

The application discloses a kind of domestic waste incineration fly ash washing dechlorination system and process, including fly ash deep dechlorination reactor and with the dechlorination agent dosing device of fly ash deep dechlorination reactor, stirring device, micro-nano aeration device, electrolytic device power supply and temperature control device.The application provides the treatment process for significantly reducing the chlorine content in fly ash by aiming at the dechlorination treatment needs of waste incineration fly ash washing end, and provides significant convenience conditions for the resource utilization of domestic waste incineration fly ash.The main innovation of the process is that after four processes of break point dechlorination, fugitive dechlorination, catalytic oxidation dechlorination and electrolytic dechlorination, the chlorine content in waste incineration fly ash can be significantly reduced.After the process treatment, the chlorine content in fly ash after fly ash washing dechlorination process treatment can be less than 0.1%, which is much lower than the chlorine content in fly ash after waste incineration fly ash washing after countercurrent rinsing, and the process runs stably.

The invention relates to a preparation method of a catalytic cracking catalyst. The method comprises the following steps: carrying out contact treatment on a NaY molecular sieve and a rare earth salt solution or a mixed solution of the rare earth salt solution and an ammonium salt solution, filtering and washing to obtain preparation raw materials including the rare earth-containing NaY molecular sieve, an inorganic oxide binder and natural minerals, mixing, pulping and molding; carrying out deacidification treatment on the formed catalyst, so that the content of Cl <-> on the basis of the catalyst is reduced to be less than or equal to 1.5 wt%; and performing hydrothermal roasting treatment on the deacidified molded catalyst in an atmosphere environment in which pressure is applied externally and an aqueous solution containing an acidic substance or an alkaline substance is added externally, and removing alkali metal through ammonium exchange. According to the method, under the condition that the chlorine content in the catalyst is reduced, the damage of a large amount of released hydrochloric acid gas to a rare earth NaY molecular sieve crystal structure in the catalyst is relieved, so that the cracking performance of the catalyst is improved.

The invention relates to a method and system for recycling waste plastics, and the method comprises the steps that S1, solid waste plastics and replacement gas enter a deoxidation device, so that the replacement gas conducts purging deoxidation treatment on the solid waste plastics, deoxidized plastics are obtained, and the deoxidation device comprises a gas stripping functional area and a diffusion functional area which communicate with each other; s2, the deoxidized plastic enters a softening-dechlorination device to be subjected to softening-dechlorination treatment, and chlorine-containing gas and softened dechlorinated plastic are obtained; s3, the softened dechlorinated plastic enters a liquefying device to be subjected to liquefying treatment, and pyrolysis gas and liquid plastic are obtained; s4, enabling the chlorine-containing gas in the step S2 and the pyrolysis gas in the step S3 to enter an alkali washing device for alkali washing treatment; and at least part of the liquid plastic in the step S3 serves as a circulating material to be heated and then returns to the liquefying device to be continuously treated. The present disclosure can significantly reduce the yield of by-products and continuously and stably provide a liquid feed for waste plastic pyrolysis.

This invention discloses an apparatus and method for separating and removing chlorine in the production of titanium dioxide using the chloride process. The apparatus includes an external device, a vertically arranged first cylinder, a second cylinder disposed within the first cylinder, and a feed pipe tangentially connected to the upper part of the first cylinder. Both the first and second cylinders are made of conductive materials. The external device is electrically connected to both the first and second cylinders to create a voltage difference between them. The second cylinder has multiple vent holes penetrating its interior and exterior. By providing vent holes and using a tangentially designed feed pipe, this invention allows the primary titanium dioxide product to enter between the first and second cylinders at a relatively high pressure and speed. Under the action of centrifugal force and gravity, gas and solid are separated. Furthermore, by increasing vibration, adding external electrodes, and purging with inert gas, the separation efficiency is greatly improved, and the chlorine content adsorbed on the surface of the titanium dioxide is reduced.