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31results about How to "Changing the relative volatility" patented technology

Method and device for performing refined separation on high-purity yellow phosphorous

The invention discloses a method and a device for performing refined separation on high-purity yellow phosphorous. A raw material storage tank is connected with a tower bottom; a rectifying tower is positioned above the tower bottom; one end of a condenser is connected with a tower top of the rectifying tower, while the other end is connected with a return tank; the return tank is connected with the tower top of the rectifying tower through a return flowmeter and connected with a front fraction tank and a product tank through a product flowmeter, and a discharge pipe of the product tank is connected with a product collecting tank; a vacuum pump is connected with the condenser, the return tank, the front fraction tank and the product tank through a buffer tank; and a nitrogen tank is connected with the raw material storage tank, the condenser, the return tank, the front fraction tank and the product tank. Through operation of performing rectification under reduced pressure and changinga reflux ratio, the method and the device reduce the boiling point of each component of the material greatly, change the relative volatility among the components, and have the advantages of uniform heating in the tower bottom, simple operation process, high separation efficiency and high purity of the product at the same time.
Owner:湖北兴福电子材料股份有限公司

Method for separating acetonitrile and triethylamine azeotropic mixture by extractive distillation

The invention relates to a method for separating an acetonitrile and triethylamine azeotropic mixture by extractive distillation. An extractive distillation column and a solvent recovery tower adopt negative pressure operation; the acetonitrile and triethylamine mixture are introduced from the upper middle part of the extractive distillation column; ethylene glycol as an extractant is introduced from the upper part of the column; after the extractive distillation column, acetonitrile is extracted from the top of the extractive distillation column; the extractant and triethylamine are extracted from the bottom of the extractive distillation column and introduced from the upper middle part of the recovery tower; the triethylamine is extracted from the top of the solvent recovery tower; and the extractant ethylene glycol is extracted from the bottom of the recovery tower for recycling. The negative pressure operation adopted by the invention can reduce the heat load of the reboiler, and reduce the energy consumption for operation; the extractant ethylene glycol can significantly improve the relative volatility of acetonitrile and triethylamine; and the recovery rate is as high as 99.9%.
Owner:QINGDAO UNIV OF SCI & TECH

Extraction agent for extracting, rectifying and separating methanol and dimethyl carbonate azeotrope, application of extraction agent, and treatment method

The invention provides an extraction agent for extracting, rectifying and separating methanol and dimethyl carbonate azeotrope, application of the extraction agent, and a treatment method. The extraction agent is a mixed extraction agent containing ionic liquid. A system for extracting, rectifying and separating methanol and dimethyl carbonate azeotrope comprises a reaction rectifying tower, an extraction rectifying tower and an extraction agent regeneration tower which are sequentially connected, wherein the extraction rectifying tower uses the extraction agent to perform extraction and rectification. The extraction agent has the advantages that the extraction agent can effectively change the relative volatility of methanol and dimethyl carbonate azeotrope, increase the separation effectof the methanol and dimethyl carbonate azeotrope, the purity of obtained dimethyl carbonate can reach 99.8wt% or above, and the circulating loss rate of the extraction agent can be lowered to 0.01% orbelow; the extraction agent can guarantee the conversion rate of ethylene carbonate and lower the concentration of circulating methanol, and accordingly thermal load is reduced, and separation energyconsumption is reduced.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Separation method of propylene oxidation products epoxypropane, acrolein and acetone

The invention relates to a separation method of propylene oxidation products epoxypropane, acrolein and acetone, and belongs to the technical field of propylene oxidation product separation. Materialsto be separated enter an epoxypropane separation tower from the middle section of a tower section for rectification separation, epoxypropane is extracted from the top of the tower, and acrolein and acetone extracted from the bottom of the tower enter an extractive distillation tower; a mixture of the to-be-separated materials acrolein and acetone and an extraction agent are divided into two pathsto enter the extractive distillation tower for extractive distillation separation, and acetone is extracted from the top of the tower; the acrolein and the extraction agent distilled from the tower kettle enter a solvent recovery tower to be subjected to rectification separation, the acrolein is extracted from the tower top, and the extraction agent is extracted from the tower kettle; and the extraction agent is recycled back to the extractive distillation tower for use. The method is scientific and reasonable in design, high-purity and high-recovery-rate separation of the materials is achieved, more economical separation is achieved on the basis of comprehensively considering process cost such as energy consumption and material consumption, and the method has a large application prospectin industry.
Owner:山东联创产业发展集团股份有限公司

A kind of extraction agent used for extracting and rectifying separation of methanol and dimethyl carbonate azeotrope and its use and treatment method

The invention provides an extraction agent for extracting, rectifying and separating methanol and dimethyl carbonate azeotrope, application of the extraction agent, and a treatment method. The extraction agent is a mixed extraction agent containing ionic liquid. A system for extracting, rectifying and separating methanol and dimethyl carbonate azeotrope comprises a reaction rectifying tower, an extraction rectifying tower and an extraction agent regeneration tower which are sequentially connected, wherein the extraction rectifying tower uses the extraction agent to perform extraction and rectification. The extraction agent has the advantages that the extraction agent can effectively change the relative volatility of methanol and dimethyl carbonate azeotrope, increase the separation effectof the methanol and dimethyl carbonate azeotrope, the purity of obtained dimethyl carbonate can reach 99.8wt% or above, and the circulating loss rate of the extraction agent can be lowered to 0.01% orbelow; the extraction agent can guarantee the conversion rate of ethylene carbonate and lower the concentration of circulating methanol, and accordingly thermal load is reduced, and separation energyconsumption is reduced.
Owner:INST OF PROCESS ENG CHINESE ACAD OF SCI

Separating and purifying device and process for heavy-component residual liquid of hydrogenation process of coking crude benzene

The invention discloses a separating and purifying device and process for heavy component residual liquid of a hydrogenation process of coking crude benzene, belonging to the technical field of fractioning separation. The separating and purifying device of the invention comprises a tower kettle, a batch fractioning tower, a tower top fraction storage tank and a vacuum pump, wherein the batch fractioning tower is connected with the tower kettle; a condenser is arranged at the tower top of the batch fractionating tower; and the vacuum pump is respectively connected with the condenser and the tower top fraction storage tank through a buffer tank. The process comprises the following steps: when the tower top pressure is 10.0-15.0kPa, and the tower top temperature is 115.0-120.0 DEG C, collecting indan from the tower top by a reflux ratio of 4-5; after the indan is collected, when the tower top pressure is 10.0-15.0kPa, and the tower top temperature is 125.0-130.0 DEG C, collecting tetraline from the tower top by the reflux ratio of 8-10; and finally when the tower top pressure is 10.0-15.0kPa, and the tower top temperature is 155.0-160.0 DEG C, collecting naphthalene from the tower top by a reflux ratio of 4-5. The purity of the indan is 99.0wt%, the purity of the tetraline is 99.5wt%, and the purity of the naphthalene is 98.0wt%.
Owner:XINGTAI RISUN COAL CHEM IND

Separation method of difficult separation system containing triethylamine

The invention discloses a separation method of a triethylamine-containing system difficult to separate. According to the technical scheme, water, alkaline water or brine is adopted as an extractant, acontinuous or intermittent extraction process is adopted to separate triethylamine and a second component without introduction of new impurities, and the water can be recycled with no production of wastewater; then rectification is performed so as to remove residual triethylamine and second component in a raffinate phase, the relative volatility of the triethylamine and second component in the raffinate phase can be changed greatly, and high-content triethylamine and second component can be recovered efficiently from the raffinate phase containing low content of triethylamine and second component; and the operation in the distillation step can be completed by using a simple rectification unit, the evaporation amount is limited, and the energy consumption is controllable; therefore, extraction and rectification are coupled in the process so as to realize separation of triethylamine and the second component, and since water, alkaline water or brine is adopted as the extractant in the whole process with no introduction of other impurities, and addition of the alkali or salts is beneficial to separation of the triethylamine and the second component, the process has the advantages of simple equipment, investment cost saving, simple operation and operation cost saving, and the advantages are innovation points of the process.
Owner:杭州九清科技有限公司

Method for purifying hydrogen fluoride in trifluoromethanesulfonyl fluoride

The invention discloses a method for purifying hydrogen fluoride in trifluoromethanesulfonyl fluoride, which comprises the following steps: firstly, pumping negative pressure in a mixing kettle, then introducing a crude trifluoromethanesulfonyl fluoride liquid, and adding an extracting agent to obtain a mixture; introducing nitrogen into the mixing kettle, transferring the mixture into a rectifying tower for rectifying, discharging heavy component impurities, and distilling out a light component trifluoromethanesulfonyl fluoride; and then introducing the evaporated light component trifluoromethanesulfonyl fluoride into an adsorption tower, adsorbing by adopting an adsorbent to obtain a refined trifluoromethanesulfonyl fluoride gas, and condensing into liquid in a refined tank. According to the invention, the extraction agent is adopted, and the action between the hydrogen fluoride and the extraction agent is utilized, so that the relative volatility between the hydrogen fluoride and the trifluoromethanesulfonyl fluoride is changed, and the vast majority of hydrogen fluoride can be removed; after the rectification process, the content of hydrogen fluoride in trifluoromethanesulfonyl fluoride is low, and the hydrogen fluoride is removed by using the adsorbent, so that the collapse of the adsorbent is avoided.
Owner:PERIC SPECIAL GASES CO LTD

Method for performing refined separation on high-purity yellow phosphorous

The invention discloses a method and a device for performing refined separation on high-purity yellow phosphorous. A raw material storage tank is connected with a tower bottom; a rectifying tower is positioned above the tower bottom; one end of a condenser is connected with a tower top of the rectifying tower, while the other end is connected with a return tank; the return tank is connected with the tower top of the rectifying tower through a return flowmeter and connected with a front fraction tank and a product tank through a product flowmeter, and a discharge pipe of the product tank is connected with a product collecting tank; a vacuum pump is connected with the condenser, the return tank, the front fraction tank and the product tank through a buffer tank; and a nitrogen tank is connected with the raw material storage tank, the condenser, the return tank, the front fraction tank and the product tank. Through operation of performing rectification under reduced pressure and changinga reflux ratio, the method and the device reduce the boiling point of each component of the material greatly, change the relative volatility among the components, and have the advantages of uniform heating in the tower bottom, simple operation process, high separation efficiency and high purity of the product at the same time.
Owner:HUBEI SINOPHORUS ELECTRONIC MATERIALS CO LTD
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