The invention relates to a process and a device for 
smelting chromium irons and 
chromium-containing molten iron by using 
chromium ore 
powder, which belongs to 
metallurgical industry steel-making 
raw material. The process comprises the following steps: mixing chromium iron containing raw materials with 
reducing agent, 
solvent and catalyst to prepare 
ultra fine powder, mixing to make 
pelletizing materials, sending the 
pelletizing materials into a reducing furnace, obtaining chromium irons 
pellets after the reduction reaction, and directly adding reduced 
pellets into a lining electroslag furnace for being smelted into the chromium-iron 
alloy or the chromium-containing molten iron. The device comprises an internal-external heating vertical reducing furnace, a lining electroslag furnace and a residual heat 
recovery system. The invention has the advantages that: firstly, the reduction temperature is low, the speed is high, the 
energy consumption is reduced, the production cost is lowered, the production efficiency is high, and the uniformity of the quality is good; secondly, the degree of 
mechanization is high, the procedure is simple, the yield is large, the 
mass production can be performed; thirdly, the waste of raw materials is reduced, the environment 
pollution is lowered; fourthly, the source of raw materials adopting the chromium ore 
powder and chromium-containing waste, the cost is low; fifthly, the waste resource can be recycled so as to save the 
resource consumption; and sixthly, the high-temperature 
pellets are directly smelted by adopting the lining electroslag furnace, the heat efficiency is high, the 
energy consumption is low, the material purity is high and the quality is good, and the device is simple with less investment.