The invention belongs to the technical field of infrastructure structures and materials, and discloses an intrinsic self-prestress ECC material, a
surface layer structure prepared from the intrinsic self-prestress ECC material and application of the intrinsic self-prestress ECC material. A low-dosage
volume expansion component and a building and curing combined strategy are utilized, the
bottleneck that self-stress and a construction
window period are not coordinated is broken through, the highest
free expansion deformation of the intrinsic self-prestress ECC material in the temperature and
humidity curing process is controlled to range from 1500 mu epsilon to 10000 mu epsilon, the later-period service free
volume deformation is kept to be 55% higher than the early-period highest
free expansion deformation, and the service life of the intrinsic self-prestress ECC material is prolonged. And the dual requirements of intrinsic self-prestress and construction windows are innovatively met. The maintenance-free seamless ultrathin target of the ECC
surface layer structure is achieved through high-performance intrinsic self-prestress and self-healing. The method is widely applied to the fields of ocean ultra-thin large-
buoyancy floating bodies, road surfaces, bridge floors, airport runways, ultra-thin box culverts, concrete panels, pumped storage
power station panels, anti-seepage panels, floor panels, canal linings, tunnel linings, old structure updating and repairing and the like.