A molded insert, and methods for forming same, for an arch cavity of a boot, such as, but not limited to ice skating boots, or an arch cavity of a shoe, such as, but not limited to exercise, therapeutic, or physiological footwear, is described. The molded insert can be formed of any moldable material that is substantially firm, yet comfortable, when cured or dried. The moldable material can be used to fill in the arch cavity to form a substantially firm, yet comfortable, surface to support the arch of the wearer's foot, especially in the area corresponding from the beginning of the heel portion of the foot to the beginning of the ball of the foot (e.g., the mid-foot) and includes a vertically extending side portion along the side of the foot's arch, thus providing adequate support for the foot's arch during typical ice skating maneuvers.