3189 results about "Inorganic acids" patented technology

The cleaning composition for removing resists includes a salt of hydrofluoric acid and a base not containing a metal (A component), a water-soluble organic solvent (B1 component), at least one organic acid or inorganic acid (C component), water (D component), and, optionally, an ammonium salt (E1 component), and having a pH 4-8. Thus, in manufacturing a semiconductor device, such as a copper interconnecting process, efficiency of removing resist residue and other etching residue after etching or ashing is improved, and corrosion resistance of a copper and an insulating film is also improved.

Methods and devices for at least reducing the mass of, if not dissolving, renal calculi in situ are provided. In the subject methods, a renal calculus is contacted, e.g. flushed, with an acidic dissolution solution in situ, where the acidic dissolution solution is a solution of a strong, inorganic acid, e.g. hydrochloric acid. In many embodiments, the renal calculus is first enclosed in an isolated local environment of a device prior contact with the dissolution solution. Also provided are novel devices and kits for practicing the subject invention.

The invention discloses a method for preparing iron lithium phosphate by recovering water-system waste lithium-ion power batteries, comprising the following steps: 1) cutting and brushing a water-system waste lithium-ion power battery, processing by deionized water, sieving and drying to recover the mixture of an electrode material and a conductive agent; 2) adding inorganic acid to the dried mixture of the electrode material and the conductive agent to process, filtering to obtain acid solution containing Li+, Fe2+ and PO43-; 3) adding lithium salt or iron salt to the acid solution containing Li+, Fe2+ and PO43-, adding ascorbic acid and stirring, controlling the pH value to equal to 3-7, and filtering to obtain precipitation; and 4) adding the crude product LiFePO4 obtained in step 3) to a water solution of cane sugar for ball milling, drying and calcining to obtain a regenerative LiFePO4 material. The method has low cost, simple operation and no secondary pollution.

The invention discloses an alkali and chlorine-free liquid setting accelerator based on industrial polyaluminium sulfate. The liquid setting accelerator comprises the following raw materials by weight: 35-55% of polyaluminium sulfate, 5-25% of magnesium sulfate, alcohol amine accounting for 15-30% of the polyaluminum sulfate, 0-5% of an inorganic acid, 0-5% of a stabilizer, and the balance water. The liquid setting accelerator provided by the invention can be used in the wet jetting industry of sprayed concrete, belongs to alkali and chlorine-free liquid setting accelerators, has a stable period of more than 6 months, a 28d compressive strength ratio of greater than 100%, and good adaptability to different cement. When the dosage is 4.5%, the technical requirements of the JC477-2005 ''setting accelerators for sprayed concrete'' can be satisfied. The liquid alkali-free setting accelerator has superior performance, and can be widely used in tunnels, bridges, first-aid repair and other projects.

The present invention relates to new addition salts of lercanidipine comprising lercanidipine and an acid counterion wherein the acid counterion is selected from the group consisting of: (i) inorganic acids, (ii) sulfonic acids, (iii) monocarboxylic acids, (iv) dicarboxylic acids, (v) tricarboxylic acids, and (vi) aromatic sulfonimides, with the proviso that said acid counterion is not hydrochloric acid.

The present invention relates to a coating composite for making coated granular fertilizer and its production method, and the fertilizer made up by using said coating composite. The coating composite is formed from coating agent, solidfying agent, nitrogen synergist, inorganic acid or organic acid, surfactant and adjuvant. As compared with non-coated fertilizer the nitrogen utilization rate of fertilizer produced by adopting said invention can be raised by 6%-10%, the fertilizer can be saved by 15-45%, and its fertilizer efficiency time can be obviously prolonged, and can be reached to 60-120 days.

A lithium secondary battery includes: an electrode body having a positive electrode, a negative electrode, and a separator, the positive electrode and the negative electrode being wound or laminated by means of the separator; and a nonaqueous electrolyte solution containing a lithium compound as a electrolyte. At least one of the positive electrode, the negative electrode, the separator, the nonaqueous electrolyte solution contains at least one of: (a) an organic and / or inorganic inhibitor, which functions as a Cu-corrosion inhibitor or a Cu-trapping agent, (b) a compound having an organic base and an inorganic acid which are unitarily combined in a molecule, (c) a cyclic compound containing a N-O radical in a molecular structure, (d) a cyclic compound which becomes a Mn<2+> supplier in the nonaqueous electrolyte solution, (e) a compound containing an atom showing Lewis acidity and an atom showing Lewis basisity in one molecule, (f) a three-dimensional siloxane compound, and (g) a nonionic surfactant; or the nonaqueous electrolyte solution contains: (h) a water-extracting agent, or (i) a hydrofluoric acid-extracting agent. This lithium secondary battery exhibits an excellent effect that self-discharge property, cycle characteristics, long period stability and reliability can be planned.

Disclosed are: an etching solution for a multilayer thin film having a copper layer and a molybdenum layer contained therein; and a method for etching a multilayer thin film having a copper layer and a molybdenum layer contained therein using the etching solution. Specifically disclosed are: an etching solution for a multilayer thin film having a copper layer and a molybdenum layer contained therein, which comprises (A) hydrogen peroxide, (B) an inorganic acid having no fluorine atom, (C) an organic acid, (D) an amine compound having 2 to 10 carbon atoms and also having an amino group and a hydroxy group in the total number of two or more, (E) an azole, and (F) a hydrogen peroxide stabilizer, and which has a pH value of 2.5 to 5; and an etching method using the etching solution.

(Problem) It is to provide a stripper having excellent ability to suppress corrosion or damage to the copper wiring or the low-k film, and having excellent photoresist residue removability after ashing. (Solution) The invention provides a photoresist stripper composition characterized in containing salts of at least two different inorganic acids, surfactants and a corrosion inhibitor for metal, and having a pH in the range of 3-10; and a process for preparation of semiconductor devices characterized in that the photoresist residues generated during the preparation of semiconductor devices which employs copper or a copper-dominant alloy as the material for wiring is stripped using said photoresist stripper.

The invention discloses a method for separating and recovering lithium from a waste lithium ion battery. The method comprises the following steps: dismounting after discharging the waste lithium ion battery, and removing a battery case; crashing a battery cell; leaching and filtering the crushed battery cell with inorganic acid and oxidant to obtain a filter liquor; regulating the pH of the filter liquor to be more than or equal to 8, then filtering to remove impurities and sediment to obtain a recovery liquor containing lithium ions; adsorbing the lithium ions in the recovery liquor through resin; and desorbing the resin to obtain the separated and recovered lithium salt. The recovery method provided by the invention is simple and efficient, has high purity of lithium and brings no pollution.

The invention relates to hydrocracking of lignin, and specifically relates to a method for applying a tungsten-based catalyst to catalyze lignin hydrocracking for producing an aromatic compound. The catalyst comprises a main active component of non-zero-valent tungsten, and a second metal component of a small amount of one or more transition metals selected from zero-valent nickel, cobalt, ruthenium, iridium, palladium, platinum, iron, and copper. According to the method, raw materials such as lignin, biomass hydrolysis residue, lignosulfonate, and alkaline lignin are subject to catalytic hydrogenation under a hydrothermal condition with a temperature of 120 to 450 DEG C and a hydrogen pressure of 1 to 20MPa; the raw materials are cracked into C6-C9 phenolic compounds with high selectivity. A maximal phenol yield reaches 55.6%. Compared to existing technologies, according to the invention, renewable natural biomasses are adopted as raw materials, such that the raw materials are cheap, and have wide sources; inorganic acid and alkali are not required, such the production of a large amount of alkaline solution in traditional lignin catalysis is avoided; the tungsten-based catalyst is cheap; the reaction process is green, and has atom economical characteristics.

Etching compositions, curable compositions, packaged products and methods of use for the treatment of bone substrate, i.e., teeth, are described. The etch compositions generally include a gelling agent, an inorganic acid, an organic acid and either a solvent, a surfactant or mixtures thereof. The curable composites include reactive monomers and crosslinking agents that are effective to adhere to the surface of the treated substrate. The methods of the invention provide the ability to modify a bone or bone-like surface so that the curable composition, such as an adhesive resin, can be used in combination with a restorative material.

The invention provides an amido-containing ionic liquid used for absorbing acidic gases and a preparation method and application thereof and in particular relates to a method for absorbing acidic gases of CO2, H2S, SO2 and the like by using an amido-containing ionic liquid. The amido-containing ionic liquid comprises one or more of primary amine, secondary amine and tertiary amine, wherein positive ions of the ionic liquid are derived from organic polyamines, negative ions of the ionic liquid are derived from inorganic acid or organic acid, and the ionic liquid is prepared by mixing the organic polyamines with the inorganic acid or organic acid and then carrying out neutralization reaction through acid and alkali. The ionic liquid has the advantages of low cost, simple preparation method,strong absorbing capability and short balance time, can be used for the enriching of acidic gases, the deacidification refining of acid-containing gases of natural gas, refinery gas, methane, coal gas, synthesis gas, coke-oven gas, pyrolysis gas, smoke, motor vehicle tail gas and the like and the purification of gases under a proper space and an operating environment; meanwhile, the ionic liquid absorbing the acidic gases can release the acidic gases through pressure reduction and temperature raise, thus the absorbing capability of the ionic liquid is restored and the multiple absorption property of the ionic liquid is better.

The invention discloses a multifunctional aluminum material corrosion-inhibition polishing pickling agent. The multifunctional aluminum material corrosion-inhibition polishing pickling agent is prepared from the following components in parts by weight: 70-85 parts of inorganic acid, 3-8 parts of a compound organic corrosion inhibitor, 1-2 parts of an inorganic corrosion inhibitor, 2-4 parts of a surfactant, 1-3 parts of a complexing agent, 0.05-0.3 part of micro high-valent metal ion salt and 5-15 parts of a solvent. The multifunctional aluminum material corrosion-inhibition polishing pickling agent disclosed by the invention can be used for quickly and efficiently cleaning the surface of the aluminum material to achieve effects of removing oil, scrubbing, polishing, passivating and the like, thereby avoiding resource waste caused by an over corrosion phenomenon; after being pickled, the aluminum material can be restored to be bright and clean, so that the aluminum material is almost not corroded.

The invention discloses a porous silicon negative material of a lithium ion battery, and a preparation method and application of the material. The method comprises the following steps of: reacting silicon alloy powder, which is taken as a raw material, with inorganic acid to generate porous silicon particles; and washing the porous silicon particles by an HF (Hydrogen Fluoride) acid solution to eliminate surface silicon oxide, and washing and drying the washed porous silicon particles so as to obtain the porous silicon material. The porous silicon material prepared by the method has a sponge-shaped structure which is formed by linking nano silicon particles; the particle sizes of the particles of the porous silicon negative material range from 0.01 micron to 50 microns; the specific surface area of the material is 30-600cm<2> / g; the porous silicon negative material can be taken as a negative material of a lithium ion battery; and in a lithium ion battery electrolyte, the porous silicon powder shows high specific discharge capacity and charge-discharge circulation stability. The porous silicon negative material has the advantages of low cost, simplicity and convenience in method and high electrochemical property, and can be applied to production of silicon negative materials of high-performance lithium ion batteries.

The invention discloses a polymeric aluminum sulfate synthesis method and discloses a preparation method of a novel alkali-free liquid accelerator based on synthesis of polymeric aluminum sulfate. According to the alkali-free accelerator, an aluminum sulfate solution is neutralized by ammonia water, active aluminum hydroxide gel is prepared, active aluminum hydroxide is filtered, dried and ground into powder, then the aluminum sulfate solution is added, and the polymeric aluminum sulfate is prepared. The alkali-free accelerator comprises, in percentage, 45%-55% of the polymeric aluminum sulfate, 0%-5% of inorganic acid, 0%-2% of a stabilizer, 0%-2% of an organic early strength agent, 0%-2% of an organic tackifier and the balance of water. The cement setting time and the colloidal mortar strength of the accelerator can meet the requirement of first-class accelerators for JC477-2005 sprayed concrete under the condition of the lower mixing amount, and meanwhile, the accelerator is an alkali-free liquid accelerator and can effectively avoid adverse effects caused by excessively high alkali content. The cement types of the accelerator have good adaptability.

The invention provides an antibacterial master batch based on a guanidinium polymer and a preparation method thereof. The antibacterial master batch comprises the following blended components: a matrix resin, a composite antibacterial agent and a dispersant, wherein, on the basis of 100 parts by weight of the matrix resin, the composite antibacterial agent is 10 to 30 parts by weight, the dispersant is 2 to 10 parts by weight, the matrix resin is at least one selected from the group consisting of low-density polyethylene and high-melt index polypropylene, and the composite antibacterial agentis a polyguanidine / polysilicate composite antibacterial agent and is prepared by mixing an aqueous solution of water-soluble polyguanidine inorganic acid salt or organic acid salt with an aqueous solution of water-soluble silicate and adding an aqueous solution of water-soluble metal salt. The antibacterial master batch is used for antimicrobial modification of polypropylene, and addition amount of the antibacterial master batch is 2 to 10 wt % of the matrix material polypropylene; prepared modified polypropylene has the advantages of high antibacterial efficiency, a white color, good washingfastness, etc.

The invention discloses a method for preparing a graphene oxide. The method comprises the following steps of: a) adding concentrated inorganic acid into a sealed reactor, adding graphite powder with stirring, reducing the temperature to the temperature of between 0 and 4 DEG C, and adding potassium permanganate to react for 0.5 to 2 hours; b) heating the obtained reaction system to the temperature of between 60 and 70 DEG C, and standing for 12 to 24 hours; c) adding hydrogen peroxide into distilled water in a volume ratio of 1:10, freezing to obtain ice, transferring the graphite oxide to the distilled water containing the hydrogen peroxide until the ice is completely dissolved, uniformly stirring, performing suction filtration, washing and drying to obtain the graphene oxide. The graphite powder, the concentrated acid and the potassium permanganate serve as raw materials, and the raw materials are low in cost and readily available; NO, NO2 and other toxic gases are prevented from being produced; the reaction temperature is as low as 60-70 DEG C; and the product has high dye adsorption capacity and high industrial application value.

The invention provides anti-sludge inhibiter and the application method thereof. The inhibiter comprises multi-amino multi-ether methene phosphonic acid, poly-aspartic acid and acrylic polymer which comprises sulfonic groups, and at least one of other organic phosphonic acid, as well as zinc salt, inorganic acid, manganese salt and copper inhibiter. The inhibiter is applicable to the water quality with high rigidity, high alkaline and high salt. The sum of the rigidity the calcium and total alkalinity in water reaches 1500mg per liter, wherein, the inhibiter has excellent anti-sludge and corrosion inhibition effect when the rigidity of the calcium (counting in accordance with calcium carbonate ) is 1000mg per liter. The invention can be used in the circulated cooling water system of the industries such as petroleum chemical, as well as power and paper making plant. The invention can also be used in the water treatment process of poor water quality conditions such as seawater desalination and reverse osmosis.

A bio-enzyme consists of pectinase, protease, lipase, cellulose, catalase and amylase; the application of bio-enzyme catalysis in residual sludge treatment is that: the residual sludge is treated by utilizing the high-efficiency biocatalysis of the bio-enzyme, odor molecules in the sludge are decomposed and deodorized through enzyme technology, pathogenic bacteria, ova and larvae are killed by utilizing an acid environment formed by inorganic acid generated by the sludge and a high temperature environment in the fermentation process, heavy metal ions in the sludge are stabilized by utilizing the chelation of the bio-enzyme, and the sludge is catalyzed by the enzyme, so that the sludge and water are quickly separated, a large amount of supernate is discharged, the sludge volume is reduced, and the sludge in inland river is reduced and is subjected to innocent treatment; meanwhile, through the bio-enzyme catalysis, long-chain molecules in the sludge are converted into short-chain molecules, polysaccharide and cellulose are converted into protein and amino acid, nutritional components of organic fertilizers are remained, the fertilizer efficiency is improved and the fermentation period can be shortened.

The invention discloses reformate hydrogenation catalyst and the production method thereof. The invention is characterized in that the catalyst consists of a main active component, auxiliary agent, and carriers, the structural formula is Pd-Ma (Mb) / carriers; the main active component is a double noble metal component Pd, and the content is 0.01 to 0.5 wt percent; Ma is one of Au, Ag, Pt, Rh, and Ir, and the content is 0.01 to 0.5 wt percent; Mb is one of Sn, Pb, Sb, and Bi, and the content is 0.2 to 1.0 wt percent; the rest are carriers; inorganic acid or organic acid is taken as competitive adsorption auxiliary agent to achieve that the active component presents the distribution of an eggshell-shaped shallow layer, the active metal and the auxiliary agent are loaded by a distribution impregnation method or a co-impregnation method, and then the hydrogenation catalyst is produced through drying and roasting.

This invention relates to tiotropium containing stable pharmaceutical solution formulations suitable for aerosol administration. More particularly, this invention relates to tiotropium containing stable pharmaceutical solution formulations suitable for aerosol administration wherein either an inorganic acid or an organic acid is added to the aerosol solution formulation which contains a tiotropium salt, preferably tiotropium bromide in solution with an environmentally safe hydrofluorocarbon (HFC) as a propellant, together with an organic compound as a cosolvent. The acid provides stability against degradation or decomposition of the medicament resulting largely from interaction of the medicament with the cosolvent and / or water present in the solution formulation.

The invention discloses silicon dioxide aerogel and a preparation method thereof. The silicon dioxide aerogel of a three-dimensional network structure is prepared by the step of subjecting alkaline silicate and inorganic acid to neutralization reaction, washing, rapidly dehydrating for drying, and crushing; the aerogel is internally filled with pores of about 20nm and has the silica content (dry basis) of more than 99.0%, the BET (Brunauer, Emmett and Teller) specific surface area of 300-800m<2> / g, the pore space volume of 1.6-3.0, the average granularity of 3-20 mum and the pore volume of 1.7-3.6ml / g. In the invention, the alkaline silicate is used as a silicon source and is subjected to neutralization reaction with the inorganic acid, the raw materials are readily available, cheap and innoxious, and the process flow is short and is easy for industrialization.

The invention relates to a method for extracting refined tellurium from tellurium-contained smelting slag, which is characterized in that the method comprises the following steps of: oxidizing and leaching inorganic acid, replacing noble metal with a copper plate, depositing the copper by sodium sulfide, counteracting and depositing tellurium, alkaline leaching coarse TeO2, removing impurities by Na2S, concentrating and electrowinning. The method has the advantages of high recovery rate for tellurium, comprehensive and effective recovery of other useful metals, and suitably treating the tellurium-contained waste slag with high water content and small granularity generated in the metallurgy process by a wet-method.

The invention discloses a green synthesis method for high-content carvacrol capable of replacing natural oregano. The method comprises the steps of taking food-grade L-carvone as raw material, adopting organic acid or inorganic acid as a main catalyst, taking PEG-400 or PEG-600 as an auxiliary catalyst and preparing the high-content carvacrol through intramolecular rearrangement reaction. The method adopts one step to synthesize a target product, and has the advantages of mild reaction conditions and convenient operation. The product is high in yield and good in quality, and can replace natural carvacrol. As no solvent harmful to human body and environment is added in reaction, the method is safe and friendly to environment.

The invention relates to an antibacterial mildewproof polylactic acid composition and a preparation method thereof. The composition comprises the following mixed components: polylactic acid, an antibacterial mildewproof agent, and a dispersant; wherein on a basis of 100 parts by weight of polylactic acid, the composition comprises 0.3-2 parts by weight of antibacterial mildewproof agents, and 0-0.5 parts by weight of dispersants; the antibacterial mildewproof agent is a polyguanidine pyrithione antibacterial mildewproof agent which is obtained by mixing an aqueous solution of water-soluble polyguanidine inorganic acid salts or organic acid salts and an aqueous solution of sodium pyrithione; the molar ratio of the water-soluble polyguanidine inorganic acid salts or organic acid salts and sodium pyrithione is 1:(0.1-5). The polylactic acid composition of the invention has good antibacterial and mildewproof effect. The antibacterial effect on staphylococcus aureus and escherichia coli is up to 99.9%; the mildewproof grade for mold such as aspergillus niger, aspergillus terreus, paecilomyces varioti bainier, and the like reaches 0 grade; the composition has good water resistant stability, and has wide application prospects.

Belonging to the field of composite material preparation, the invention provides a preparation method of a polyaniline / graphene composite material able to disperse in water stably. The material is prepared by the following steps of: 1) reducing graphene oxide to graphene with hydrazine hydrate; 2) dispersing the newly prepared graphene in a solution containing a macromolecular dispersant; 3) then adding aniline for dispersing; 4) at a low temperature, adding a solution of an oxidizing agent and an inorganic acid into the obtained mixed solution dropwisely, and conducting stirring for polymerization; and 5) carrying out centrifugation and washing, thus obtaining the polyaniline / graphene composite material. Due to the auxiliary effect of the macromolecular dispersant, the polyaniline / graphene composite material obtained in the invention can disperse uniformly in water and can be stored stably. And the obtained dispersed solution generates no sediment after 6 months of placement. Thus, the method of the invention solves the problem of difficult processing of a polyaniline / graphene composite material.