The invention relates to a method for preparing a thiofide of
tetraethylthiuram disulfide. The method uses raw materials with the mol ratio as follows: the mol ratio of dibenzyl amine,
carbon bisulfide,
sodium hydroxide,
hydrogen peroxide and sulphuric acid is 1:1-1.30:1.0-1.2:0.5-0.6:0.28-0.35mol. The method comprises the technical process as follows: under normal pressure, the dibenzyl amine and the
sodium hydroxide are sequentially added into a reaction kettle which contains
purified water under the state of being stirred; subsequently, the temperature is reduced to 20 DEG C to 30 DEG C,
liquid carbon bisulfide is dropwise added for 2 to 3 hours; after dropwise adding, reactant continues to be stirred for 0.5 hour; then, at the temperature of 58 DEG C to 63 DEG C, the
hydrogen peroxide is dropwise added into the reactant for oxidation reaction which lasts 3 to 4 hours; when the oxidation reaction is going to finish, the sulphuric acid is added to adjust the pH value of reaction solution to be within the range of 6.5-7.5, and the reaction is finished; then the reaction is taken for 1 hour again by heat preservation for
solid-liquid separation, and the
solid is dried, crushed, filtered and packed to obtain a product. The method can improve the quality, the yield and the performance of the product effectively, reduce the potential safety
hazard during the production process greatly, save energy, reduce consumption, reduce the waste water and
exhaust emission during the production process and meet the national relative policy of
environmental protection.