This invention discloses a hierarchical
guanidine resin-based CO2 adsorbent material and its preparation method, belonging to the field of
polymer synthesis technology. The adsorbent material prepared by this invention has a composite spherical structure and a hierarchical pore structure, including micropores, mesopores, and macropores. By introducing a hierarchical pore structure, the adsorption capacity of the material for CO2 is effectively improved. The introduction of hierarchical pores can significantly reduce
molecular diffusion resistance and increase the contact area between the adsorbent and CO2 molecules, thereby achieving rapid adsorption. Furthermore, pyridyl, polyamino compounds, and
guanidine groups have strong basicity and
chemical affinity for CO2. Through surface functionalization modification, the number of active sites on the material surface is significantly increased, thereby further improving the CO2 adsorption capacity and selectivity.