The invention relates to a preparation method of an all-
solid-state
lithium battery positive
electrode material. According to the method, the
polyaniline derivative and the organic
sulfide are compounded, so that the compatibility of the
polyaniline derivative and the organic
sulfide is better than that of
polyaniline, and the interaction of a
molecular level is achieved. Part of
nitrogen-substituted polyaniline is used, the
alkalinity of the polyaniline is higher than that of polyaniline, a better
catalytic effect on organic sulfides is achieved, and the positive
electrode material with higher catalytic energy than that of polyaniline can be obtained. In an
organic solvent such as N-methyl pyrrolidone, a composite solution of a polyaniline derivative and an organic
sulfide is prepared, and conductive
carbon black is added. The composite solution is coated or brushed on the surface of a
current collector, such as
copper, aluminum,
platinum or stainless steel, so that the
lithium secondary battery positive
electrode with high
specific energy is obtained. The method is simple to operate, is suitable for the field of high-specific-energy
lithium batteries, and has a wide application prospect.